ATE286921T1 - Carbenium-aktivierte polymerisationskatalysatoren mit hoher aktivität - Google Patents
Carbenium-aktivierte polymerisationskatalysatoren mit hoher aktivitätInfo
- Publication number
- ATE286921T1 ATE286921T1 AT00973781T AT00973781T ATE286921T1 AT E286921 T1 ATE286921 T1 AT E286921T1 AT 00973781 T AT00973781 T AT 00973781T AT 00973781 T AT00973781 T AT 00973781T AT E286921 T1 ATE286921 T1 AT E286921T1
- Authority
- AT
- Austria
- Prior art keywords
- cyclopentadienyl ligand
- polymerization
- olefin
- aromatic fused
- ring substituted
- Prior art date
Links
- 230000000694 effects Effects 0.000 title abstract 2
- 239000002685 polymerization catalyst Substances 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 abstract 5
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 4
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 4
- 239000003446 ligand Substances 0.000 abstract 4
- 125000003118 aryl group Chemical group 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 150000001336 alkenes Chemical class 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 125000006659 (C1-C20) hydrocarbyl group Chemical group 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229920001038 ethylene copolymer Polymers 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- -1 hafnium organometallic compound Chemical class 0.000 abstract 1
- 238000003780 insertion Methods 0.000 abstract 1
- 230000037431 insertion Effects 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/645—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/642 - C08F4/643
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/422,533 US6300433B1 (en) | 1998-10-23 | 1999-10-21 | Olefin copolymerization process with bridged hafnocenes |
| PCT/US2000/029197 WO2001029096A1 (en) | 1999-10-21 | 2000-10-23 | High activity carbenium-activated polymerization catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE286921T1 true ATE286921T1 (de) | 2005-01-15 |
Family
ID=23675314
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT00973781T ATE286921T1 (de) | 1999-10-21 | 2000-10-23 | Carbenium-aktivierte polymerisationskatalysatoren mit hoher aktivität |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6300433B1 (https=) |
| EP (1) | EP1259553B1 (https=) |
| JP (1) | JP2003518146A (https=) |
| KR (1) | KR20020040905A (https=) |
| CN (1) | CN1376168A (https=) |
| AT (1) | ATE286921T1 (https=) |
| BR (1) | BR0014119A (https=) |
| CA (1) | CA2397818A1 (https=) |
| DE (1) | DE60017467T2 (https=) |
| ES (1) | ES2233471T3 (https=) |
| MX (1) | MXPA02003940A (https=) |
| WO (1) | WO2001029096A1 (https=) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7232871B2 (en) * | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
| ES2233109T3 (es) * | 1998-10-23 | 2005-06-01 | Exxonmobil Chemical Patents Inc. | Metalocenos puenteados para la copolimerizacion de olefinas. |
| US6825295B2 (en) * | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
| KR100884294B1 (ko) * | 2001-02-08 | 2009-02-18 | 미쓰이 가가쿠 가부시키가이샤 | 에틸렌과 탄소수 3 ~ 20의 α-올레핀의 랜덤 공중합체와 그것을 사용한 성형품 |
| DE60238049D1 (de) | 2001-04-12 | 2010-12-02 | Exxonmobil Chem Patents Inc | Verfahren zur Polymerisation von Propylen und Ethylen in Lösung |
| US7511104B2 (en) | 2001-06-20 | 2009-03-31 | Exxonmobil Chemical Patents Inc. | Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them |
| WO2004029062A1 (ja) * | 2002-09-27 | 2004-04-08 | Mitsui Chemicals, Inc. | オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法 |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| WO2004046214A2 (en) | 2002-10-15 | 2004-06-03 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| JP5255833B2 (ja) * | 2004-03-24 | 2013-08-07 | エクソンモービル・ケミカル・パテンツ・インク | エチレン・インターポリマーの製造方法、該方法により製造されたインターポリマー、組成物、および該インターポリマーを含む電気デバイス |
| EP1934266B1 (en) * | 2005-09-09 | 2015-11-18 | SABIC SK Nexlene Company Pte. Ltd. | Homogeneous catalyst system for producing ethylene homopolymer or ethylene copolymers with alpha-olefins |
| KR101141359B1 (ko) * | 2005-09-09 | 2012-05-03 | 에스케이이노베이션 주식회사 | 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용균일 촉매계 |
| US8222358B2 (en) | 2006-03-02 | 2012-07-17 | Exxonmobil Chemical Patents Inc. | Process for producing propylene copolymers |
| JP4714088B2 (ja) * | 2006-06-16 | 2011-06-29 | 株式会社小糸製作所 | 車両用前照灯 |
| US7872086B2 (en) | 2008-01-17 | 2011-01-18 | Tonen Chemical Corporation | Polymeric material and its manufacture and use |
| EP2287145A1 (en) * | 2009-08-12 | 2011-02-23 | BP p.l.c. | Process for purifying ethylene |
| US9969827B2 (en) | 2014-02-13 | 2018-05-15 | Mitsui Chemicals, Inc. | Process for producing ethylene/α-olefin copolymer |
| US10442920B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations |
| US10442921B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations |
| US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
| US10995166B2 (en) | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
| US10882987B2 (en) | 2019-01-09 | 2021-01-05 | Nova Chemicals (International) S.A. | Ethylene interpolymer products having intermediate branching |
| US11046843B2 (en) | 2019-07-29 | 2021-06-29 | Nova Chemicals (International) S.A. | Ethylene copolymers and films with excellent sealing properties |
| KR102872215B1 (ko) | 2022-07-05 | 2025-10-16 | 한화토탈에너지스 주식회사 | 신규한 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물 및 이를 이용한 에틸렌 및 α-올레핀의 공중합체의 제조방법 |
| KR20250026547A (ko) * | 2023-08-17 | 2025-02-25 | 한화솔루션 주식회사 | 전이금속 화합물을 이용한 에틸렌-α-올레핀 공중합체의 용액중합방법 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5408017A (en) | 1987-01-30 | 1995-04-18 | Exxon Chemical Patents Inc. | High temperature polymerization process using ionic catalysts to produce polyolefins |
| ATE137247T1 (de) * | 1989-10-30 | 1996-05-15 | Fina Technology | Addition von alkylaluminium zum verbessern eines metallocenkatalysators |
| US6313240B1 (en) * | 1993-02-22 | 2001-11-06 | Tosoh Corporation | Process for producing ethylene/α-olefin copolymer |
| US6008307A (en) * | 1994-04-28 | 1999-12-28 | Exxon Chemical Patents Inc | Process for producing olefin polymers using cationic catalysts |
| EP0708117B1 (en) * | 1994-10-03 | 1999-08-11 | Sumitomo Chemical Company Limited | Process for producing copolymer rubber |
| JPH08208736A (ja) * | 1994-11-28 | 1996-08-13 | Chisso Corp | 塩化ビニル系樹脂の製造方法 |
| CN1116309C (zh) | 1995-03-10 | 2003-07-30 | 陶氏环球技术公司 | 负载型催化剂组分、负载型催化剂及制备方法,聚合方法,配位化合物及其制备方法 |
| US5696213A (en) | 1995-04-21 | 1997-12-09 | Exxon Chemical Patents Inc. | Ethylene-α-olefin-diolefin elastomers solution polymerization process |
| US5767208A (en) | 1995-10-20 | 1998-06-16 | Exxon Chemical Patents Inc. | High temperature olefin polymerization process |
| WO1997022639A1 (en) * | 1995-12-19 | 1997-06-26 | Exxon Chemical Patents Inc. | High temperature solution polymerization process |
| DE69720823T2 (de) | 1996-01-25 | 2004-01-22 | Tosoh Corp., Shinnanyo | Verfahren zur Olefinpolymerisierung unter Verwendung eines Übergangsmetallkatalysators. |
| US5856256A (en) | 1996-02-20 | 1999-01-05 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
| ES2160289T3 (es) | 1996-08-13 | 2001-11-01 | Basell Polyolefine Gmbh | Sistema catalizador soportado, un procedimiento para su obtencion y su empleo para la polimerizacion de olefinas. |
| AU2629799A (en) | 1998-03-03 | 1999-09-20 | Avecia B.V. | Water soluble films |
| US6262202B1 (en) * | 1998-03-04 | 2001-07-17 | Univation Technologies, Llc | Noncoordinating anions for olefin polymerization |
-
1999
- 1999-10-21 US US09/422,533 patent/US6300433B1/en not_active Expired - Lifetime
-
2000
- 2000-10-23 BR BR0014119-4A patent/BR0014119A/pt not_active IP Right Cessation
- 2000-10-23 KR KR1020027005129A patent/KR20020040905A/ko not_active Ceased
- 2000-10-23 MX MXPA02003940A patent/MXPA02003940A/es active IP Right Grant
- 2000-10-23 EP EP00973781A patent/EP1259553B1/en not_active Expired - Lifetime
- 2000-10-23 AT AT00973781T patent/ATE286921T1/de not_active IP Right Cessation
- 2000-10-23 CA CA002397818A patent/CA2397818A1/en not_active Abandoned
- 2000-10-23 ES ES00973781T patent/ES2233471T3/es not_active Expired - Lifetime
- 2000-10-23 WO PCT/US2000/029197 patent/WO2001029096A1/en not_active Ceased
- 2000-10-23 CN CN00813183A patent/CN1376168A/zh active Pending
- 2000-10-23 JP JP2001531892A patent/JP2003518146A/ja not_active Withdrawn
- 2000-10-23 DE DE60017467T patent/DE60017467T2/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1259553A1 (en) | 2002-11-27 |
| MXPA02003940A (es) | 2002-10-23 |
| DE60017467D1 (de) | 2005-02-17 |
| CN1376168A (zh) | 2002-10-23 |
| KR20020040905A (ko) | 2002-05-30 |
| BR0014119A (pt) | 2002-05-14 |
| CA2397818A1 (en) | 2001-04-26 |
| US6300433B1 (en) | 2001-10-09 |
| JP2003518146A (ja) | 2003-06-03 |
| DE60017467T2 (de) | 2006-02-16 |
| ES2233471T3 (es) | 2005-06-16 |
| EP1259553B1 (en) | 2005-01-12 |
| WO2001029096A1 (en) | 2001-04-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |