CN1376168A - 高活性碳鎓活化的聚合催化剂 - Google Patents

高活性碳鎓活化的聚合催化剂 Download PDF

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Publication number
CN1376168A
CN1376168A CN00813183A CN00813183A CN1376168A CN 1376168 A CN1376168 A CN 1376168A CN 00813183 A CN00813183 A CN 00813183A CN 00813183 A CN00813183 A CN 00813183A CN 1376168 A CN1376168 A CN 1376168A
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CN
China
Prior art keywords
phenyl
olefin polymerization
catalyst system
polymerization process
substituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN00813183A
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English (en)
Chinese (zh)
Inventor
D·J·克罗瑟尔
G·罗德里戈兹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of CN1376168A publication Critical patent/CN1376168A/zh
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/645—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/642 - C08F4/643
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN00813183A 1999-10-21 2000-10-23 高活性碳鎓活化的聚合催化剂 Pending CN1376168A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/422,533 1999-10-21
US09/422,533 US6300433B1 (en) 1998-10-23 1999-10-21 Olefin copolymerization process with bridged hafnocenes

Publications (1)

Publication Number Publication Date
CN1376168A true CN1376168A (zh) 2002-10-23

Family

ID=23675314

Family Applications (1)

Application Number Title Priority Date Filing Date
CN00813183A Pending CN1376168A (zh) 1999-10-21 2000-10-23 高活性碳鎓活化的聚合催化剂

Country Status (12)

Country Link
US (1) US6300433B1 (https=)
EP (1) EP1259553B1 (https=)
JP (1) JP2003518146A (https=)
KR (1) KR20020040905A (https=)
CN (1) CN1376168A (https=)
AT (1) ATE286921T1 (https=)
BR (1) BR0014119A (https=)
CA (1) CA2397818A1 (https=)
DE (1) DE60017467T2 (https=)
ES (1) ES2233471T3 (https=)
MX (1) MXPA02003940A (https=)
WO (1) WO2001029096A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102712556A (zh) * 2009-08-12 2012-10-03 英国石油有限公司 乙烯处理方法

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7232871B2 (en) * 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6528670B1 (en) * 1998-10-23 2003-03-04 Exxonmobil Chemical Patents Inc. Bridged metallocenes for olefin copolymerization
US6825295B2 (en) * 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
KR100884294B1 (ko) * 2001-02-08 2009-02-18 미쓰이 가가쿠 가부시키가이샤 에틸렌과 탄소수 3 ~ 20의 α-올레핀의 랜덤 공중합체와 그것을 사용한 성형품
EP1390417B1 (en) 2001-04-12 2010-10-20 ExxonMobil Chemical Patents Inc. Process for polymerizing propylene and ethylene in solution
EP1406761B1 (en) 2001-06-20 2016-11-02 ExxonMobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
EP2465879B1 (en) * 2002-09-27 2019-04-24 Mitsui Chemicals, Inc. Bridged metallocene compound for olefin polymerization and method of polymerizing olefin using the same
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
ES2394304T3 (es) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
JP5255833B2 (ja) * 2004-03-24 2013-08-07 エクソンモービル・ケミカル・パテンツ・インク エチレン・インターポリマーの製造方法、該方法により製造されたインターポリマー、組成物、および該インターポリマーを含む電気デバイス
CA2621307C (en) * 2005-09-09 2014-12-02 Sk Energy Co., Ltd. Homogeneous catalyst system for producing ethylene homopolymer or ethylene copolymers with alpha-olefins
KR101141359B1 (ko) * 2005-09-09 2012-05-03 에스케이이노베이션 주식회사 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용균일 촉매계
SG169377A1 (en) 2006-03-02 2011-03-30 Exxonmobil Chem Patents Inc Process for producing propylene copolymers
JP4714088B2 (ja) * 2006-06-16 2011-06-29 株式会社小糸製作所 車両用前照灯
US7872086B2 (en) 2008-01-17 2011-01-18 Tonen Chemical Corporation Polymeric material and its manufacture and use
CA2936511C (en) 2014-02-13 2019-06-11 Mitsui Chemicals, Inc. Process for producing ethylene/.alpha.-olefin copolymer
US10442921B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations
US10442920B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations
US10683376B2 (en) 2017-11-07 2020-06-16 Nova Chemicals (International) S.A. Manufacturing ethylene interpolymer products at higher production rate
US10995166B2 (en) 2017-11-07 2021-05-04 Nova Chemicals (International) S.A. Ethylene interpolymer products and films
US10882987B2 (en) 2019-01-09 2021-01-05 Nova Chemicals (International) S.A. Ethylene interpolymer products having intermediate branching
US11046843B2 (en) 2019-07-29 2021-06-29 Nova Chemicals (International) S.A. Ethylene copolymers and films with excellent sealing properties
KR102872215B1 (ko) 2022-07-05 2025-10-16 한화토탈에너지스 주식회사 신규한 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물 및 이를 이용한 에틸렌 및 α-올레핀의 공중합체의 제조방법
KR20250026547A (ko) * 2023-08-17 2025-02-25 한화솔루션 주식회사 전이금속 화합물을 이용한 에틸렌-α-올레핀 공중합체의 용액중합방법

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5408017A (en) 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
EP0426638B2 (en) * 1989-10-30 2005-03-02 Fina Technology, Inc. Addition of aluminium alkyl for improved metallocene catalyst
US6313240B1 (en) * 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
US6008307A (en) * 1994-04-28 1999-12-28 Exxon Chemical Patents Inc Process for producing olefin polymers using cationic catalysts
DE69511352T2 (de) * 1994-10-03 2000-03-30 Sumitomo Chemical Co., Ltd. Verfahren zur Herstellung eines Copolymerkautschuks
JPH08208736A (ja) * 1994-11-28 1996-08-13 Chisso Corp 塩化ビニル系樹脂の製造方法
ATE233790T1 (de) 1995-03-10 2003-03-15 Dow Global Technologies Inc Geträgerter katalysatorbestandteil, trägerkatalysator, herstellungsverfahren, polymerisationsverfahren, komplexverbindungen und ihre herstellung
US5696213A (en) 1995-04-21 1997-12-09 Exxon Chemical Patents Inc. Ethylene-α-olefin-diolefin elastomers solution polymerization process
US5767208A (en) 1995-10-20 1998-06-16 Exxon Chemical Patents Inc. High temperature olefin polymerization process
WO1997022639A1 (en) * 1995-12-19 1997-06-26 Exxon Chemical Patents Inc. High temperature solution polymerization process
EP0786466B1 (en) 1996-01-25 2003-04-16 Tosoh Corporation Olefin polymerisation process which comprises a transition metal catalyst.
US5856256A (en) 1996-02-20 1999-01-05 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
DE59703850D1 (de) 1996-08-13 2001-07-26 Basell Polyolefine Gmbh Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
DE69904449T2 (de) 1998-03-03 2003-09-25 Aquasol Limited, Chelmsford Wasserlösliche folien
CN1133660C (zh) * 1998-03-04 2004-01-07 埃克森美孚化学专利公司 烯烃的高温聚合方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102712556A (zh) * 2009-08-12 2012-10-03 英国石油有限公司 乙烯处理方法
CN102712556B (zh) * 2009-08-12 2014-10-29 英国石油有限公司 乙烯处理方法

Also Published As

Publication number Publication date
ES2233471T3 (es) 2005-06-16
EP1259553B1 (en) 2005-01-12
EP1259553A1 (en) 2002-11-27
KR20020040905A (ko) 2002-05-30
BR0014119A (pt) 2002-05-14
WO2001029096A1 (en) 2001-04-26
CA2397818A1 (en) 2001-04-26
US6300433B1 (en) 2001-10-09
ATE286921T1 (de) 2005-01-15
DE60017467D1 (de) 2005-02-17
DE60017467T2 (de) 2006-02-16
MXPA02003940A (es) 2002-10-23
JP2003518146A (ja) 2003-06-03

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