ATE198210T1 - Katalysatorsysteme für die polymerisation und copolymerisation von alpha-olefinen - Google Patents

Katalysatorsysteme für die polymerisation und copolymerisation von alpha-olefinen

Info

Publication number
ATE198210T1
ATE198210T1 AT97500187T AT97500187T ATE198210T1 AT E198210 T1 ATE198210 T1 AT E198210T1 AT 97500187 T AT97500187 T AT 97500187T AT 97500187 T AT97500187 T AT 97500187T AT E198210 T1 ATE198210 T1 AT E198210T1
Authority
AT
Austria
Prior art keywords
group
groups
equal
periodic table
different
Prior art date
Application number
AT97500187T
Other languages
English (en)
Inventor
Royo Jose Sancho
Llinas Gerardo Hidalgo
Lafuente Antoni Munoz-Escalona
Nunez Francisca Martinez
Marcos Carlos Martin
Canas Pilar Lafuente
Garcia Begona Pena
Original Assignee
Repsol Quimica Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Repsol Quimica Sa filed Critical Repsol Quimica Sa
Application granted granted Critical
Publication of ATE198210T1 publication Critical patent/ATE198210T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT97500187T 1996-10-31 1997-10-31 Katalysatorsysteme für die polymerisation und copolymerisation von alpha-olefinen ATE198210T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES9602310 1996-10-31

Publications (1)

Publication Number Publication Date
ATE198210T1 true ATE198210T1 (de) 2001-01-15

Family

ID=8296555

Family Applications (1)

Application Number Title Priority Date Filing Date
AT97500187T ATE198210T1 (de) 1996-10-31 1997-10-31 Katalysatorsysteme für die polymerisation und copolymerisation von alpha-olefinen

Country Status (8)

Country Link
US (2) US20030195109A1 (de)
EP (1) EP0839836B1 (de)
JP (1) JP3955140B2 (de)
AT (1) ATE198210T1 (de)
DE (1) DE69703728T2 (de)
ES (1) ES2154017T3 (de)
NO (1) NO318716B1 (de)
PT (1) PT839836E (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1283010B1 (it) * 1996-05-15 1998-04-03 Enichem Spa Complesso metallocenico supportato e procedimento per la sua prepa- razione
PT839836E (pt) * 1996-10-31 2001-06-29 Repsol Quimica Sa Sistemas cataliticos para a polimerizacao e copolimerizacao de alfa-olefinas
US7148173B2 (en) 1998-04-27 2006-12-12 Repsol Quimica, S.A. Catalytic systems for the polymerization and copolymerization of alpha-olefins
EP0953581B1 (de) * 1998-04-27 2004-01-07 Repsol Quimica S.A. Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
PT955306E (pt) * 1998-04-29 2003-06-30 Repsol Quimica Sa Compostos metaloceno funcionalizados processo de sintese e utilizacao
ATE264344T1 (de) * 1998-04-29 2004-04-15 Repsol Quimica Sa Verfahren und verwendung von heterogenen katalysatorbestandteilen für die olefinpolymerisation
KR100367463B1 (ko) * 1999-03-03 2003-01-14 주식회사 엘지화학 메탈로센 화합물 및 이를 이용한 올레핀 중합
US7041618B2 (en) * 1999-06-22 2006-05-09 Lg Chemical Ltd. Supported metallocene catalyst and olefin polymerization using the same
US7247595B2 (en) 1999-06-22 2007-07-24 Lg Chem, Ltd. Supported metallocene catalyst and olefin polymerization using the same
KR100354290B1 (ko) * 1999-06-22 2002-09-28 주식회사 엘지화학 담지 메탈로센 촉매 및 이를 이용한 올레핀 중합
ES2216474T3 (es) 1999-10-26 2004-10-16 Repsol Quimica S.A. Compuestos de bis cicoplentadienilo con enlaces de un solo carbono y complejos de metaloceno de los mismos.
US6723675B1 (en) * 2000-05-25 2004-04-20 Univation Technologies, Llc Catalyst for the production of olefin polymers
US6632770B2 (en) * 2000-12-22 2003-10-14 Univation Technologies, Llc Catalyst system and its use in a polymerization process
ATE264335T1 (de) 2001-01-18 2004-04-15 Repsol Quimica Sa Olefinpolymerisationskatalysatoren
FR2824066B1 (fr) 2001-04-30 2004-02-06 Atofina Composante catalytique solide de type metallocene et son procede d'obtention
KR100690345B1 (ko) * 2004-09-03 2007-03-09 주식회사 엘지화학 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법
KR101703274B1 (ko) * 2014-08-12 2017-02-22 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조방법
FR3104585B1 (fr) * 2019-12-17 2021-12-03 Michelin & Cie Système catalytique à base d’un métallocène et d’un diorganomagnésien
CN116120377A (zh) * 2022-12-29 2023-05-16 江苏爱姆欧光电材料有限公司 一种含柔性基团茂锆配合物及其制备方法

Family Cites Families (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1022382B (de) 1956-04-12 1958-01-09 Hoechst Ag Verfahren zur Polymerisation von niederen Olefinen
US3184416A (en) * 1958-05-22 1965-05-18 Monsanto Co Production of ziegler polymerization catalysts
US3440237A (en) * 1958-05-22 1969-04-22 Monsanto Co Production of polyethylene with water-modified ziegler catalyst
GB1527598A (en) * 1974-11-12 1978-10-04 Dow Corning Ltd Catalysts and carriers therefor
DE2608863A1 (de) 1976-03-04 1977-09-08 Basf Ag Verfahren zum herstellen von polyaethylen
SU956003A1 (ru) * 1977-01-20 1982-09-07 Институт нефтехимического синтеза им.А.В.Топчиева Мембранный катализатор дл гидрировани органических соединений
SU828471A1 (ru) 1978-07-19 1983-11-30 Ленинградский Ордена Трудового Красного Знамени Технологический Институт Им.Ленсовета Способ приготовлени катализатора дл алкилировани фенола
GB2092017B (en) 1981-01-30 1985-05-22 Inst Neftechimicheskogo Sintez Membrane catalyst for hydrogenation of organic compounds and method of preparing the same
DE3127133A1 (de) * 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
CA1268754A (en) 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
US5077255A (en) 1986-09-09 1991-12-31 Exxon Chemical Patents Inc. New supported polymerization catalyst
US4921825A (en) 1986-12-30 1990-05-01 Mitsui Petrochemical Industries, Ltd. Solid catalyst for olefin polymerization and processes for its production
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US4939217A (en) * 1987-04-03 1990-07-03 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
US5064797A (en) * 1987-04-03 1991-11-12 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
US5122491A (en) 1987-04-20 1992-06-16 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
US5202398A (en) * 1987-06-05 1993-04-13 Hoechst Aktiengesellschaft Process for the preparation of a 1-olefin polymer
DE3718888A1 (de) 1987-06-05 1988-12-22 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
JPS6485141A (en) 1987-09-26 1989-03-30 Jgc Corp Manufacture of catalyst with surface layer of noble metal carried by silica
US4925821A (en) 1987-12-17 1990-05-15 Exxon Chemical Patents Inc. Method for utilizing triethyaluminum to prepare an alumoxane support for an active metallocene catalyst
US4937217A (en) 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst
US4912075A (en) 1987-12-17 1990-03-27 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
US5008228A (en) 1988-03-29 1991-04-16 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US4935397A (en) 1988-09-28 1990-06-19 Exxon Chemical Patents Inc. Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same
DE3840772A1 (de) * 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US6825369B1 (en) * 1989-09-14 2004-11-30 The Dow Chemical Company Metal complex compounds
ES2071086T5 (es) 1989-10-30 2002-01-16 Fina Technology Preparacion de catalizadores metalocenicos para polimerizacion de olefina.
DE69114087T2 (de) 1990-08-21 1996-04-11 Nippon Oil Co Ltd Polyolefine.
US5312938A (en) * 1990-09-20 1994-05-17 The Dow Chemical Company Homogeneous catalysts and olefin polymerization process
US5466766A (en) 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5391789A (en) * 1991-08-08 1995-02-21 Hoechst Aktiengesellschaft Bridged, chiral metallocenes, processes for their preparation and their use as catalysts
US5416228A (en) * 1991-10-07 1995-05-16 Fina Technology, Inc. Process and catalyst for producing isotactic polyolefins
TW294669B (de) * 1992-06-27 1997-01-01 Hoechst Ag
ATE198207T1 (de) * 1992-08-03 2001-01-15 Targor Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung spezieller metallocene
EP1110974B1 (de) 1992-08-05 2007-11-28 ExxonMobil Chemical Patents Inc. Verfahren zur Herstellung von einem geträgertem Aktivatorkomponenten
WO1994007928A1 (en) 1992-10-02 1994-04-14 The Dow Chemical Company Supported homogeneous catalyst complexes for olefin polymerization
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5602067A (en) * 1992-12-28 1997-02-11 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
IT1264680B1 (it) 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori supportati per la polimerizzazione delle olefine
BR9500663A (pt) 1994-02-17 1995-10-31 Union Carbide Chem Plastic Composição de catalisador processo de preparação de uma composição de catalisador e processo para a produção de homopolímeros ou copolímeros de etileno
DE4406964A1 (de) * 1994-03-03 1995-09-07 Basf Ag Geträgerte Metalloxenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem als Katalysatorsysteme
EP0816395B1 (de) * 1994-04-11 2000-07-19 Mitsui Chemicals, Inc. Verfahren zur Herstellung von einer Propylen-Polymer-Zusammensetzung und Propylen-Polymer-Zusammensetzung
EP0685494B1 (de) * 1994-06-03 1998-10-07 PCD Polymere AG Katalysatorträger, geträgerte Metallocenkatalysatoren und deren Verwendung für die Herstellung von Polyolefinen
AUPM632894A0 (en) * 1994-06-21 1994-07-14 Alldredge, Robert Louis Immobilised branched polyalkyleneimines
US5955625A (en) * 1995-01-31 1999-09-21 Exxon Chemical Patents Inc Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
KR0151873B1 (ko) * 1994-10-13 1998-10-15 김영욱 메탈로센 화합물, 이의 제조방법 및 이를 촉매로 이용한 고분자의 제조방법
IT1272939B (it) * 1995-02-01 1997-07-01 Enichem Spa Catalizzatore metallocenico supportato per la (co)polimerizzazione delle olefine
US5731253A (en) * 1995-07-27 1998-03-24 Albemarle Corporation Hydrocarbylsilloxy - aluminoxane compositions
DE19527652A1 (de) 1995-07-28 1997-01-30 Hoechst Ag Metallocenverbindung
ES2120868B1 (es) 1995-08-03 2000-09-16 Repsol Quimica Sa Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
RU2178421C2 (ru) 1995-11-27 2002-01-20 Дзе Дау Кемикал Компани Катализатор на носителе, содержащий связанный активатор, образующий катион
FI104826B (fi) * 1996-01-30 2000-04-14 Borealis As Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi
US5780659A (en) * 1996-03-29 1998-07-14 Phillips Petroleum Company Substituted indenyl unbridged metallocenes
FI961511L (fi) 1996-04-03 1997-10-04 Mikrokemia Oy Menetelmä olefiinien polymerointikatalyyttien valmistamiseksi
ES2129323B1 (es) 1996-04-18 2000-09-16 Repsol Quimica Sa Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas
IT1283010B1 (it) * 1996-05-15 1998-04-03 Enichem Spa Complesso metallocenico supportato e procedimento per la sua prepa- razione
US5747404A (en) * 1996-05-28 1998-05-05 Lyondell Petrochemical Company Polysiloxane supported metallocene catalysts
EP0837068A3 (de) * 1996-10-15 2002-04-17 Basell Polyolefine GmbH Stereorigide Metallocenverbindung
NO319295B1 (no) 1996-10-30 2005-07-11 Repsol Quimica Sa Katalysatorsystem for polymerisering
DE69705186T2 (de) * 1996-10-30 2002-03-14 Repsol Quimica S.A., Madrid Katalysatorsysteme für die (Co)Polymerisation von Alpha-Olefinen
PT839836E (pt) 1996-10-31 2001-06-29 Repsol Quimica Sa Sistemas cataliticos para a polimerizacao e copolimerizacao de alfa-olefinas
DE69813058T2 (de) * 1997-02-01 2004-02-19 Repsol Quimica S.A. Metallocene, deren Herstellung und Verwendung
EP0914323B1 (de) * 1997-03-29 2003-08-06 Basell Polyolefine GmbH Metallocene und katalysatoren zur polymerisation von olefinen
US5892079A (en) * 1997-10-17 1999-04-06 Sri International Metallocene catalysts and associated methods of preparation and use
US7148173B2 (en) * 1998-04-27 2006-12-12 Repsol Quimica, S.A. Catalytic systems for the polymerization and copolymerization of alpha-olefins
ATE264344T1 (de) * 1998-04-29 2004-04-15 Repsol Quimica Sa Verfahren und verwendung von heterogenen katalysatorbestandteilen für die olefinpolymerisation
PT955306E (pt) * 1998-04-29 2003-06-30 Repsol Quimica Sa Compostos metaloceno funcionalizados processo de sintese e utilizacao

Also Published As

Publication number Publication date
JPH10226709A (ja) 1998-08-25
US20050065019A1 (en) 2005-03-24
NO318716B1 (no) 2005-05-02
JP3955140B2 (ja) 2007-08-08
DE69703728T2 (de) 2001-06-28
EP0839836A1 (de) 1998-05-06
EP0839836B1 (de) 2000-12-20
US7211538B2 (en) 2007-05-01
DE69703728D1 (de) 2001-01-25
NO975049L (no) 1998-05-04
ES2154017T3 (es) 2001-03-16
NO975049D0 (no) 1997-10-31
PT839836E (pt) 2001-06-29
US20030195109A1 (en) 2003-10-16

Similar Documents

Publication Publication Date Title
ATE198210T1 (de) Katalysatorsysteme für die polymerisation und copolymerisation von alpha-olefinen
FI863216A0 (fi) Polymerisation av olefiner under anvaendning av en ziegler-natta-katalysator och tvao metallorganiska foereningar.
KR940005641A (ko) 리간드로서 아릴- 치환된 인데닐 유도체를 함유하는 메탈로센, 이의 제조방법 및 촉매로서의 이의 용도
DK0742801T3 (da) Fremgangsmåde til (co)polymerisation af olefiner
FI956244A0 (fi) Titaani(II) tai zirkonium(II)komplekseja ja niistä valmistettuja additiopolymerointikatalyyttejä
ATE207085T1 (de) Polymerisationskatalysatorsystem, ihre herstellung und verwendung
DK0720629T3 (da) Flertrinsproces til (co)polymerisationen af olefiner
KR900011793A (ko) 올레핀 중합용 촉매
KR960704940A (ko) 올레핀 중합 방법 및 촉매(catalysts and processes for the polymerization of olefins)
TW369547B (en) Olefin polymerization catalyst and process for olefin polymerization
ATE277092T1 (de) Katalysatorbestandteil für olefinpolymerisation und katalysatorsystem und polymerisationsverfahren unter verwendung eines solchen katalysatorsystems
FI864072A0 (fi) Polymerisering av olefiner medelst anvaendning av en modifierad ziegler-natta-katalysator.
KR880001711A (ko) α-올레핀 블럭 공중합체의 제조방법
KR900014444A (ko) 스티렌계 중합체의 제조방법
ATE256706T1 (de) Katalysatorsysteme für die polymerisation und die copolymerisation von alpha-olefinen
MY112866A (en) Gas phase polymerisation process.
HUP9800017A2 (hu) Szerves [(omega-alkenil)-ciklopentakarbil]-(szilán-áthidalt)-metallocén-vegyületek és eljárás ezek alkalmazására
KR910009744A (ko) 일산화탄소와 불포화 화합물의 중합체 제조방법
ATE256692T1 (de) Verfahren zur polymerisation von olefinen in anwesenheit von indenylverbindungen.
EA199800979A1 (ru) Каталитическая композиция на носителе и способ полимеризации олефиновых мономеров
DE69916358T2 (de) Verfahren und Verwendung von heterogenen Katalysatorbestandteilen für die Olefinpolymerisation
HUP0101729A1 (hu) Polimerizációs katalizátorok és eljárások
KR960041204A (ko) 올레핀 중합 촉매 및 이를 사용하는 폴리올레핀의 제조방법
DE69604077D1 (de) Organometallverbindung enthaltende katalysatorzusammensetzungen
ATE2083T1 (de) Verfahren zur erweiterung der molekularen verteilung von polyaethylen unter anwendung von zwei bei sehr unterschiedlichen druecken und temperaturen und in abwesenheit von wasserstoff funktionierenden reaktoren und vorrichtung zu seiner durchfuehrung.

Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification
REN Ceased due to non-payment of the annual fee