ATE162529T1 - Verfahren zur herstellung von verbrückten, chiralen metallocenkatalysatoren des types bisindenyl - Google Patents

Verfahren zur herstellung von verbrückten, chiralen metallocenkatalysatoren des types bisindenyl

Info

Publication number
ATE162529T1
ATE162529T1 AT92109988T AT92109988T ATE162529T1 AT E162529 T1 ATE162529 T1 AT E162529T1 AT 92109988 T AT92109988 T AT 92109988T AT 92109988 T AT92109988 T AT 92109988T AT E162529 T1 ATE162529 T1 AT E162529T1
Authority
AT
Austria
Prior art keywords
metallocene catalysts
chiral metallocene
formula
suspension
compound
Prior art date
Application number
AT92109988T
Other languages
German (de)
English (en)
Inventor
Juergen Dr Rohrmann
Frank Dr Kueber
Original Assignee
Hoechst Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8209704&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE162529(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Hoechst Ag filed Critical Hoechst Ag
Application granted granted Critical
Publication of ATE162529T1 publication Critical patent/ATE162529T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/0825—Preparations of compounds not comprising Si-Si or Si-cyano linkages
    • C07F7/0827—Syntheses with formation of a Si-C bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds
    • C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/30—Germanium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AT92109988T 1992-06-13 1992-06-13 Verfahren zur herstellung von verbrückten, chiralen metallocenkatalysatoren des types bisindenyl ATE162529T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP92109988A EP0574597B2 (en) 1992-06-13 1992-06-13 Process for the preparation of bridged, chiral metallocene catalysts of the bisindenyl type

Publications (1)

Publication Number Publication Date
ATE162529T1 true ATE162529T1 (de) 1998-02-15

Family

ID=8209704

Family Applications (1)

Application Number Title Priority Date Filing Date
AT92109988T ATE162529T1 (de) 1992-06-13 1992-06-13 Verfahren zur herstellung von verbrückten, chiralen metallocenkatalysatoren des types bisindenyl

Country Status (13)

Country Link
US (2) US5391790A (en:Method)
EP (1) EP0574597B2 (en:Method)
JP (1) JP3419501B2 (en:Method)
KR (1) KR100293042B1 (en:Method)
AT (1) ATE162529T1 (en:Method)
AU (1) AU664896B2 (en:Method)
CA (1) CA2098258A1 (en:Method)
DE (1) DE69224184T2 (en:Method)
DK (1) DK0574597T3 (en:Method)
ES (1) ES2113900T3 (en:Method)
GR (1) GR3026690T3 (en:Method)
TW (1) TW223645B (en:Method)
ZA (1) ZA934148B (en:Method)

Families Citing this family (102)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5700896A (en) * 1988-07-30 1997-12-23 Hoechst Aktiengesellschaft Polymer having long isotactic sequences and randomly-distributed ethylene content obtained by polymerizing propylene in presence of specific catalysts
EP0584609B1 (de) * 1992-08-15 1999-03-10 TARGOR GmbH Verfahren zur Herstellung von Polyolefinen
JPH06271594A (ja) * 1993-03-22 1994-09-27 Mitsui Petrochem Ind Ltd シクロペンタジエニル基含有ケイ素化合物またはシクロペンタジエニル基含有ゲルマニウム化合物の製造方法
EP0654476B1 (de) * 1993-11-24 2001-01-24 TARGOR GmbH Metallocene, Verfahren zu ihrer Herstellung und ihrer Verwendung als Katalysatoren
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US6339135B1 (en) * 1995-03-30 2002-01-15 Idemitsu Kosan Co., Ltd. Transition metal compound, catalyst for olefin polymerization, process for preparing olefin polymer
US5631203A (en) * 1995-05-04 1997-05-20 Phillips Petroleum Company Metallocene compounds and preparation thereof containing terminal alkynes
US5705578A (en) * 1995-05-04 1998-01-06 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
US5679814A (en) * 1995-12-11 1997-10-21 Albemarle Corporation Purification of metallocenes
DE59609748D1 (de) * 1995-12-18 2002-11-07 Basell Polyolefine Gmbh Verfahren zur Abreicherung von Nebenprodukten in Produktgemischen
ID16442A (id) 1996-01-22 1997-10-02 Dow Chemical Co Polimer etilena berat molekul ultra rendah
AT403919B (de) * 1996-02-02 1998-06-25 Danubia Petrochem Polymere Verfahren zur herstellung von katalysatorträgern und geträgerter polyolefin-katalysatoren sowie deren verwendung für die herstellung von polyolefinen
EP0816371A1 (de) * 1996-06-28 1998-01-07 PCD-Polymere Gesellschaft m.b.H. Verfahren zur stereoselektiven Herstellung von chiralen Metallocenen
JP3694371B2 (ja) * 1996-10-04 2005-09-14 関東化学株式会社 メタロセン化合物の新規な合成方法
JP3566819B2 (ja) * 1996-10-04 2004-09-15 関東化学株式会社 新規な有機遷移金属化合物
PT835886E (pt) * 1996-10-09 2004-05-31 Atofina Res Processo para a preparacao e utilizacao de compostos de dicloreto de (bis(indenil)etano)zirconio meso/racemico
US5780660A (en) * 1996-11-07 1998-07-14 Albemarle Corporation Zirconocene ismerization process
CA2246417C (en) * 1996-11-22 2009-09-08 Boulder Scientific Company Preparation of chiral titanocenes
WO1998027155A1 (en) 1996-12-17 1998-06-25 Advanced Elastomer Systems, L.P. Thermoplastic elastomeric compositions
ID19264A (id) * 1996-12-20 1998-06-28 Union Carbide Chem Plastic Pro-katalisator dan pengolahan untuk membuatnya
US6107501A (en) * 1997-01-30 2000-08-22 Fina Technology, Inc. Synthesis of metallocenes and enrichment of their rac isomer
BR9806952A (pt) 1997-02-07 2000-03-21 Exxon Chemical Patents Inc Preparação de macrÈmeros contendo vinila.
DE69809192T2 (de) 1997-02-07 2003-07-24 Exxonmobil Chemical Patents Inc., Baytown Propylenpolymere enthaltend polyethylenmakromonomere
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
US6197910B1 (en) 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
EP0953582A1 (en) * 1998-04-27 1999-11-03 Fina Research S.A. Polyolefin production
US6784269B2 (en) 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
HK1039495B (zh) 1998-05-13 2004-10-08 埃克森美孚化学专利公司 丙烯均聚物及其制备方法
US6306960B1 (en) 1998-05-13 2001-10-23 Exxonmobil Chemical Patents Inc. Articles formed from foamable polypropylene polymer
US6245868B1 (en) 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
EP1115761B1 (en) 1998-08-26 2013-09-18 ExxonMobil Chemical Patents Inc. Branched polypropylene compositions
US5965759A (en) * 1998-09-23 1999-10-12 Albemarle Corporation Catalytic process for isomerizing metallocenes
AU768427B2 (en) * 1999-01-21 2003-12-11 Boulder Scientific Company Synthesis and isomerization of 1,2-bis (indenyl) ethanes
US6174930B1 (en) 1999-04-16 2001-01-16 Exxon Chemical Patents, Inc. Foamable polypropylene polymer
JP4564612B2 (ja) * 1999-10-18 2010-10-20 日本ポリプロ株式会社 ラセミ体メタロセン化合物の製造方法
US6153777A (en) * 1999-11-02 2000-11-28 University Of Iowa Research Foundation Synthesis of ansa-metallocene catalysts
MXPA02005716A (es) * 1999-12-10 2002-09-18 Exxon Chemical Patents Inc Polimeros copolimerizados de propileno y dieno.
US6809168B2 (en) * 1999-12-10 2004-10-26 Exxonmobil Chemical Patents Inc. Articles formed from propylene diene copolymers
US6977287B2 (en) * 1999-12-10 2005-12-20 Exxonmobil Chemical Patents Inc. Propylene diene copolymers
WO2001062690A1 (en) 2000-02-23 2001-08-30 Akzo Nobel N.V. Process for preparing bisindenylalkanes
US7122498B2 (en) * 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US7459511B2 (en) 2001-06-12 2008-12-02 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
ES2290309T3 (es) * 2001-06-13 2008-02-16 Beta Technologie Ag Reactores de polimerizacion en masa y metodos de polimerizacion.
AU2002339174A1 (en) * 2001-11-16 2003-06-10 Cdt Oxford Limited Light emitting device and compounds for use therein
US6916892B2 (en) * 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
US7074865B2 (en) * 2002-04-12 2006-07-11 Dow Global Technologies Inc. Azaborolyl group 4 metal complexes, catalysts and olefin polymerization process
US20030236365A1 (en) * 2002-06-24 2003-12-25 Fina Technology, Inc. Polyolefin production with a high performance support for a metallocene catalyst system
US20040052690A1 (en) * 2002-09-12 2004-03-18 Eaton Gerald B. Polymerization reactant injection system
US7589160B2 (en) * 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
US7534848B2 (en) * 2002-12-04 2009-05-19 Basell Polyolefine Gmbh 1-butene copolymers and process for preparing them
US7195806B2 (en) * 2003-01-17 2007-03-27 Fina Technology, Inc. High gloss polyethylene articles
EP1611169B1 (en) * 2003-03-21 2010-06-02 Dow Global Technologies Inc. Morphology controlled olefin polymerization process
US20050234198A1 (en) * 2004-04-20 2005-10-20 Fina Technology, Inc. Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system
US20060052540A1 (en) 2004-09-09 2006-03-09 Maria Ellul Thermoplastic vulcanizates
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
PL1831303T3 (pl) 2004-12-17 2010-09-30 Dow Global Technologies Inc Kompozycje polietylenowe o zmodyfikowanej reologii
US7232869B2 (en) * 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
DE102005061326A1 (de) * 2005-12-20 2007-06-21 Basell Polyolefine Gmbh Verfahren zur Herstellung von Metallocenen aus recycelten, substituierten Cyclopentadienylderivaten
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
DE102006020486A1 (de) 2006-04-28 2007-10-31 Basell Polyolefine Gmbh Geträgerte Metallalkylverbindung und Verfahren zur Polymerisation von Olefinen in deren Gegenwart
ES2338936T3 (es) 2006-05-02 2010-05-13 Dow Global Technologies Inc. Composiciones de polietileno de alta densidad, metodo para fabricar las mismas, articulos fabricados a partir de ellas, y metodo para fabricar tales articulos.
US7456244B2 (en) * 2006-05-23 2008-11-25 Dow Global Technologies High-density polyethylene compositions and method of making the same
KR20100014214A (ko) * 2007-05-02 2010-02-10 다우 글로벌 테크놀로지스 인크. 고-밀도 폴리에틸렌 조성물, 그의 제조 방법, 그로부터 만들어진 사출 성형 물품, 및 이러한 물품의 제조 방법
US8487033B2 (en) 2007-05-16 2013-07-16 Exxonmobil Chemical Patents Inc. Thermoplastic elastomer compositions, methods for making the same, and articles made therefrom
WO2008154068A1 (en) * 2007-06-13 2008-12-18 Advanced Elastomer Systems, L.P. Thermoplastic polymer compositions, methods for making the same, and articles made therefrom
US7981517B2 (en) * 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
MX2010004470A (es) * 2007-10-25 2010-07-28 Lummus Novolen Technology Gmbh Sintesis racemoselectiva de compuestos de ansa-metaloceno, compuestos de ansa-metaloceno catalizadores que los comprenden, procesos para producir un polimero de olefina mediante el uso de los catalizadores y homo- y co-polimeros de olefina.
WO2010071798A1 (en) 2008-12-18 2010-06-24 Univation Technologies, Llc Method for seed bed treatment for a polymerization reaction
RU2011135979A (ru) 2009-01-30 2013-03-10 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Композиции полиэтилена высокой плотности, способ их получения, изготовленные из них укупоривающие изделия и способ изготовления таких укупоривающих изделий
CN102971454B (zh) 2010-06-15 2015-05-27 埃克森美孚化学专利公司 由聚合物共混物制造的非织造织物及其制造方法
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
CN104918947A (zh) 2012-12-28 2015-09-16 尤尼威蒂恩技术有限责任公司 将铝氧烷的生产整合到催化剂生产中的方法
CA2897456C (en) 2013-01-14 2021-08-31 Univation Technologies, Llc Methods for preparing catalyst systems with increased productivity
US9376518B2 (en) 2013-08-28 2016-06-28 Exxonmobil Chemical Patents Inc. Racemo selective metallation process
WO2015030996A1 (en) * 2013-08-28 2015-03-05 Exxonmobil Chemical Patents Inc. Racemo selective metallation process
WO2016094843A2 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system comprising mesoporous organosilica support
WO2016094848A1 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Organosilica materials for use as adsorbents for oxygenate removal
CN107667123B (zh) 2015-04-20 2020-09-01 埃克森美孚化学专利公司 聚乙烯组合物
US10640583B2 (en) 2015-04-20 2020-05-05 Exxonmobil Chemical Patents, Inc. Catalyst composition comprising fluorided support and processes for use thereof
CN107660216B (zh) 2015-05-08 2021-05-14 埃克森美孚化学专利公司 聚合方法
WO2018063764A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063765A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063767A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018118155A1 (en) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Polymerization process
WO2019118073A1 (en) 2017-12-13 2019-06-20 Exxonmobil Chemical Patents Inc. Deactivation methods for active components from gas phase polyolefin polymerization process
WO2019173030A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Methods of preparing and monitoring a seed bed for polymerization reactor startup
WO2019213227A1 (en) 2018-05-02 2019-11-07 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
CN112055720B (zh) 2018-05-02 2022-11-22 埃克森美孚化学专利公司 从中试装置放大到较大生产设施的方法
WO2020014138A1 (en) 2018-07-09 2020-01-16 Exxonmobil Chemical Patents Inc. Polyethylene cast films and methods for making the same
US11383483B2 (en) 2018-07-26 2022-07-12 Exxonmobil Chemical Patents Inc. Multilayer foam films and methods for making the same
WO2020056119A1 (en) 2018-09-14 2020-03-19 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
EP3880738B1 (en) 2018-11-13 2025-03-19 ExxonMobil Chemical Patents Inc. Polyethylene blends and films
WO2020102385A1 (en) 2018-11-13 2020-05-22 Exxonmobil Chemical Patents Inc. Polyethylene films
WO2020163079A1 (en) 2019-02-06 2020-08-13 Exxonmobil Chemical Patents Inc. Films and backsheets for hygiene articles
CN113474404A (zh) 2019-02-20 2021-10-01 弗纳技术股份有限公司 具有低翘曲的聚合物组合物
US20220389133A1 (en) 2019-10-30 2022-12-08 China Petroleum & Chemical Corporation Metallocene compound, and preparation method therefor and application thereof
WO2021126458A1 (en) 2019-12-17 2021-06-24 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved sealing performance and mechanical properties
US12152135B2 (en) 2020-03-12 2024-11-26 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved bending stiffness and high MD tear resistance
BR112023019645A2 (pt) 2021-04-26 2023-11-07 Fina Technology Folhas de polímero catalisadas de sítio único finas
CN117098785A (zh) 2021-04-30 2023-11-21 埃克森美孚化学专利公司 用于聚合反应器中不同聚合催化剂之间的转变的方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3742934A1 (de) * 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
IL89525A0 (en) * 1988-03-21 1989-09-10 Exxon Chemical Patents Inc Silicon-bridged transition metal compounds
DE3844282A1 (de) * 1988-12-30 1990-07-05 Hoechst Ag Bisindenyl-derivat und verfahren zu seiner herstellung
US5117020A (en) * 1989-10-30 1992-05-26 Fina Research, S.A. Process for the preparation of metallocenes
EP0426643B1 (en) * 1989-10-30 1995-12-27 Fina Research S.A. Process for the preparation of metallocenes
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
TW300901B (en:Method) † 1991-08-26 1997-03-21 Hoechst Ag
NL9101502A (nl) † 1991-09-06 1993-04-01 Dsm Nv Werkwijze voor het bereiden van een gebrugde metalloceenverbinding alsmede een katalysatorcomponent en een werkwijze voor de polymerisatie van een olefinen.

Also Published As

Publication number Publication date
ZA934148B (en) 1994-01-13
EP0574597B1 (en) 1998-01-21
JP3419501B2 (ja) 2003-06-23
TW223645B (en:Method) 1994-05-11
EP0574597A1 (en) 1993-12-22
AU664896B2 (en) 1995-12-07
JPH06122692A (ja) 1994-05-06
DE69224184D1 (de) 1998-02-26
DK0574597T3 (da) 1998-09-14
US5391790A (en) 1995-02-21
DE69224184T2 (de) 1999-06-02
AU4018193A (en) 1993-12-16
KR100293042B1 (ko) 2001-11-22
EP0574597B2 (en) 2002-06-26
CA2098258A1 (en) 1993-12-14
GR3026690T3 (en) 1998-07-31
KR940000472A (ko) 1994-01-03
US5616747A (en) 1997-04-01
ES2113900T3 (es) 1998-05-16

Similar Documents

Publication Publication Date Title
ATE162529T1 (de) Verfahren zur herstellung von verbrückten, chiralen metallocenkatalysatoren des types bisindenyl
HUT56379A (en) Process for producing a-norsteroid-3-carboxylic acid derivatives and compositions comprising such compounds
ATE145891T1 (de) Verfahren zur herstellung von alkoxyiminoacetamid-derivaten und ein zwischenproduckt dafür
KR840000515A (ko) N-아릴-피페라진알칸아미드의 제조법
DE59409435D1 (de) Verfahren zur Herstellung von 3-Arylbenzofuranonen
ATE93521T1 (de) Verfahren zur herstellung von substituierten indolinonderivaten.
DE69814635D1 (de) Verfahren zur herstellung von 2-hydroxybenzamidderivaten
ATE169626T1 (de) Verfahren zur herstellung von substituierten n- aryl-1,2,4-triazolopyrimidin-2-sulfonamiden
DE69328962D1 (de) Verfahren zur herstellng von cyano-methoxyiminomethylderivaten
ATE92034T1 (de) Verfahren zur herstellung von benzylaminen.
DE3781879D1 (de) Anthracyclinderivate, verfahren zu ihrer herstellung und ihre verwendung als arzneimittel.
ATE106397T1 (de) Verfahren zur herstellung von 3,3- diarylacrylsäureamiden.
ATE247641T1 (de) Pyridin-zwischenprodukte, verwendbar zur herstellung von beta-adrenergischen rezeptor- agonisten
DE59309077D1 (de) Verfahren zur Herstellung von 2-Halogen-4,6-dialkoxypyrimidinen
DE59803194D1 (de) Verfahren zur herstellung von 1,3-disubstituierten 2-nitroguanidinen
ATE39689T1 (de) Neues verfahren zur herstellung von chromenderivaten.
DE3777464D1 (de) Fluorine enthaltende vitamin-d3-derivate und verfahren zu ihrer herstellung.
ATE151422T1 (de) 8-azabicyclo(3.2.1>octylalkylthiazolidinone, verfahren zu ihrer herstellung und ihre verwendung als arzneimittel
ATE224393T1 (de) Verfahren zur herstellung von cephalosporinen und zwischenverbindungen in diesem verfahren
ATE195115T1 (de) Verfahren zur herstellung von 5,6-dihydroxy-2- amino-1,2,3,4-tetrahydronaphthalin-derivaten
DE59208769D1 (de) Verfahren zur enantioselektiven Synthese von 2(R)-Benzylbernsteinsäuremonoamid-Derivaten
ATE132863T1 (de) Verfahren zur herstellung von 6-(substituiertes aminopropionyl)-derivaten von forskolin
DE69016380D1 (de) Verfahren zur Herstellung von molluskiziden 2,4,5-Tribrompyrrol-3-Carbonitrilen.
DE69127960D1 (de) Verfahren zur Herstellung von (S)-vinyl- und (S)-allenyl-Gaba
ATE111093T1 (de) Verfahren zur herstellung von enantiomeren von 3- aminchromanderivaten.

Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties