AR241433A1 - Un catalizador para la oxidacion de olefinas a productos carbonilados y procedimiento mejorado que lo aplica. - Google Patents

Un catalizador para la oxidacion de olefinas a productos carbonilados y procedimiento mejorado que lo aplica.

Info

Publication number
AR241433A1
AR241433A1 AR86305322A AR30532286A AR241433A1 AR 241433 A1 AR241433 A1 AR 241433A1 AR 86305322 A AR86305322 A AR 86305322A AR 30532286 A AR30532286 A AR 30532286A AR 241433 A1 AR241433 A1 AR 241433A1
Authority
AR
Argentina
Prior art keywords
catalyst system
oxidation catalyst
olefin oxidation
ch3coo
numbers
Prior art date
Application number
AR86305322A
Other languages
English (en)
Original Assignee
Catalytica Associates Cesionar
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Catalytica Associates Cesionar filed Critical Catalytica Associates Cesionar
Application granted granted Critical
Publication of AR241433A1 publication Critical patent/AR241433A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

UN CATALIZADOR PARA LA OXIDACION DE OLEFINAS, QUE COMPRENDE:A) UN COMPONENTE POLIOXOANION QUE ES UN MIEMBRO DEL GRUPO DE COMPUESTOS CON LA FORMULA:¡XXMAM'BM''COZ¿EXPONENTE =-M,DONDE X ES B, SI, G, P, AS, SE, TE, I, CO, MN Y CU; M, M' Y M'' SON W, MO, V, NB, TA Y RE; X ES 0 PARA ISOPOLIOXOANIONES SIMPLES Y MIXTOS; X ES UN NUMERO POSITIVO PARA HETEROPOLIOXOANIONES; A, Z Y M SON NUMEROS POSTIVOS; B Y C SON NUMEROS, QUE A + B + C >= 2; B)COMPUESTO DE PALADIO, VANADIO O MOLIBDENO; C) COMPONENTE REDOX DE CUSO4,CU(CH3COO)2, CU(NO3)2, FE(CH3COO)2, FESO4 Y MNSO4; D) COMPUESTO CON UN NITRLO.
AR86305322A 1985-09-24 1986-09-22 Un catalizador para la oxidacion de olefinas a productos carbonilados y procedimiento mejorado que lo aplica. AR241433A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/779,501 US4720474A (en) 1985-09-24 1985-09-24 Olefin oxidation catalyst system

Publications (1)

Publication Number Publication Date
AR241433A1 true AR241433A1 (es) 1992-07-31

Family

ID=25116653

Family Applications (1)

Application Number Title Priority Date Filing Date
AR86305322A AR241433A1 (es) 1985-09-24 1986-09-22 Un catalizador para la oxidacion de olefinas a productos carbonilados y procedimiento mejorado que lo aplica.

Country Status (15)

Country Link
US (1) US4720474A (es)
EP (1) EP0238633A4 (es)
JP (1) JPS63500923A (es)
KR (1) KR870700405A (es)
CN (2) CN1010010B (es)
AR (1) AR241433A1 (es)
AU (1) AU6375286A (es)
BR (1) BR8606883A (es)
CA (1) CA1268166A (es)
DK (1) DK262387A (es)
FI (1) FI872275A0 (es)
IL (1) IL80091A (es)
IN (1) IN168521B (es)
WO (1) WO1987001615A1 (es)
ZA (1) ZA866653B (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4853357A (en) * 1985-09-24 1989-08-01 Catalytica Associates Olefin oxidation catalyst system
US4885399A (en) * 1986-11-26 1989-12-05 Catalytica, Inc. Process for obtaining substantially aldehyde-free ketone products
WO1988006489A1 (en) * 1987-02-27 1988-09-07 University Of Oregon Organic solvent soluble oxide supported hydrogenation catalyst precursors
US4988800A (en) * 1988-05-31 1991-01-29 Akzo America Inc. Preparation of rare earth alkoxides using catalyst
US5091354A (en) * 1988-10-07 1992-02-25 Sun Refining And Marketing Company Alkane oxidation catalysts
US5557014A (en) * 1990-03-05 1996-09-17 Catalytica, Inc. Catalytic system for olefin oxidation to carbonyl products
US5792721A (en) * 1990-03-05 1998-08-11 Catalytica, Inc. Preparation of phosphomolybdovanadate polyoxoanions
JPH05506853A (ja) * 1990-03-05 1993-10-07 カタリティカ，インコーポレイテッド オレフィンをカルボニル生成物に酸化するための触媒系
EP0498305B1 (en) * 1991-02-01 1995-12-27 Idemitsu Kosan Company Limited Process for preparing carbonyl compounds
US5344630A (en) * 1991-06-28 1994-09-06 Rohm And Haas Company Deep oxidation of halogenated organics with porous carbonaceous materials
US5414137A (en) * 1992-05-29 1995-05-09 Idemitsu Kosan Company Limited Process for preparing carbonyl compounds
DE19530787A1 (de) * 1995-08-22 1997-02-27 Hoechst Ag Mangan enthaltende Polyoxometallate, Synthese und Verwendung
DE10201783A1 (de) * 2002-01-17 2003-08-21 Stockhausen Chem Fab Gmbh Verfahren zur Oxidation ungesättigter Kohlenwasserstoffe
WO2009116512A1 (ja) 2008-03-19 2009-09-24 住友化学株式会社 カルボニル化合物の製造方法
JP2010163413A (ja) * 2008-03-19 2010-07-29 Sumitomo Chemical Co Ltd カルボニル化合物の製造法
KR20100126496A (ko) * 2008-03-19 2010-12-01 스미또모 가가꾸 가부시끼가이샤 카르보닐 화합물의 제조 방법
CN107051562B (zh) * 2016-12-28 2019-07-16 中南大学 一种用于环己烯氧化的石墨烯基碳酸钴催化剂的制备方法

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1136685B (de) * 1959-03-21 1962-09-20 Hoechst Ag Verfahren zur Oxydation von Olefinen mit 3 und mehr C-Atomen zu Aldehyden und Ketonen
US3379651A (en) * 1961-12-29 1968-04-23 Hargis Charles Wesley Contact agents for converting ethylenically unsaturated hydrocarbons to carbonylic compounds
FR1359141A (fr) * 1962-12-27 1964-04-24 Eastman Kodak Co Procédé pour convertir les hydrocarbures à insaturation éthylénique en composés carbonylés
US3365499A (en) * 1963-07-11 1968-01-23 Gulf Research Development Co Oxidation of olefins to ketones
GB1024684A (en) * 1964-06-04 1966-03-30 Distillers Co Yeast Ltd Improvements in or relating to the production of carbonyl compounds
DE1951759A1 (de) * 1968-10-14 1970-05-21 Maruzen Oil Company Ltd Verfahren zur Herstellung von Methylaethylketon
DD123085A1 (es) * 1971-12-15 1976-11-20
SU504754A1 (ru) * 1974-02-13 1976-02-28 Институт Катализа Сибирского Отделения Ан Ссср Способ получени ацетатов этиленгликол
US4049574A (en) * 1974-05-28 1977-09-20 Petro-Tex Chemical Corporation Catalyst and process for preparing maleic anhydride from C4 hydrocarbons
US4043934A (en) * 1974-07-24 1977-08-23 The Regents Of The University Of California Catalyst and method for oxidizing reducing gases
US4042623A (en) * 1974-09-24 1977-08-16 Nippon Kayaku Kabushiki Kaisha Method of manufacturing methacrylic acid and an oxidation catalyst
GB1508331A (en) * 1975-03-18 1978-04-19 Inst Kataliza Sibir Otdel An S Catalyst for liquid-phase oxidation of olefins and a method of preparing same
BE828603A (fr) * 1975-04-14 1975-10-30 Catalyseur pour l'oxydation en phase liquide des olefines et procede d'obtention dudit catalyseur
EG12284A (en) * 1975-07-12 1978-09-30 Hoechst Ag Process for the preparation of 1-methyl-2-(phenyl 6 oxymethyl)-5-nitro-imidazoles
US4057506A (en) * 1975-12-30 1977-11-08 Colgate Palmolive Company Heavy-duty liquid detergent
FR2366061A1 (fr) * 1976-09-30 1978-04-28 Inst Francais Du Petrole Procede perfectionne de fabrication de catalyseurs bimetalliques supportes actifs pour l'oxydation en phase heterogene des olefines en cetones
US4152354A (en) * 1977-06-29 1979-05-01 Phillips Petroleum Company Olefin oxidation process
JPS5457488A (en) * 1977-10-17 1979-05-09 Sagami Chem Res Center Acetic acid production catalyst
US4203927A (en) * 1978-04-11 1980-05-20 Phillips Petroleum Company Olefin oxidation process
JPS56138159A (en) * 1980-03-31 1981-10-28 Mitsui Toatsu Chem Inc Preparation of aromatic isocyanate
JPS60331B2 (ja) * 1981-03-20 1985-01-07 工業技術院長 シクロヘキサノンの製造方法
US4386217A (en) * 1981-05-21 1983-05-31 E. I. Du Pont De Nemours And Company Oxidative alkoxycarbonylation of olefins with palladium/heteropoly acid catalyst systems
JPS58109446A (ja) * 1981-12-23 1983-06-29 Mitsubishi Gas Chem Co Inc 蓚酸エステルの製法
US4419525A (en) * 1982-03-11 1983-12-06 Phillips Petroleum Company Recovery and rejuvenation of Wacker-type catalysts
US4448892A (en) * 1982-04-01 1984-05-15 Phillips Petroleum Company Olefin oxidation catalyst
US4507507A (en) * 1982-04-12 1985-03-26 Phillips Petroleum Company Catalysts
US4434082A (en) * 1982-04-12 1984-02-28 Phillips Petroleum Company Palladium/heteropolyacid/surfactant catalyst system
US4447638A (en) * 1982-08-02 1984-05-08 Atlantic Richfield Company Preparation of dialkyl oxalates by the oxidative carbonylation of alcohols with a heterogeneous Pd-V-P-Ti containing catalyst system
US4447639A (en) * 1982-08-06 1984-05-08 Atlantic Richfield Company Oxidative carbonylation of alcohols to dialkyl oxalates using a heterogeneous iron promoted Pd-V-P catalyst
US4451666A (en) * 1982-08-06 1984-05-29 Atlantic Richfield Company Synthesis of oxalate esters by the oxidative carbonylation of alcohols with a heterogeneous manganese promoted Pd-V-P catalyst
CA1243041A (en) * 1982-09-30 1988-10-11 Howard Alper Process for the conversion of a terminal carbon- carbon double bond of an olefinic hydrocarbon to carbonyl groups
JPS5980619A (ja) * 1982-10-29 1984-05-10 Nippon Zeon Co Ltd シクロペンテンの酸化方法
US4507506A (en) * 1983-04-21 1985-03-26 Phillips Petroleum Company Alpha-olefin conversion
IL134936A0 (en) * 1997-09-10 2001-05-20 Vion Pharmaceuticals Inc Genetically modified tumor-targeted bacteria with reduced virulence

Also Published As

Publication number Publication date
BR8606883A (pt) 1987-11-03
DK262387D0 (da) 1987-05-22
AU6375286A (en) 1987-04-07
US4720474A (en) 1988-01-19
ZA866653B (en) 1987-07-29
DK262387A (da) 1987-05-22
FI872275A (fi) 1987-05-22
IN168521B (es) 1991-04-20
WO1987001615A1 (en) 1987-03-26
CN1046890A (zh) 1990-11-14
IL80091A (en) 1991-06-30
KR870700405A (ko) 1987-12-29
CN86106266A (zh) 1987-04-08
EP0238633A1 (en) 1987-09-30
JPS63500923A (ja) 1988-04-07
EP0238633A4 (en) 1988-07-29
CN1010010B (zh) 1990-10-17
IL80091A0 (en) 1986-12-31
FI872275A0 (fi) 1987-05-22
CA1268166A (en) 1990-04-24

Similar Documents

Publication Publication Date Title
AR241433A1 (es) Un catalizador para la oxidacion de olefinas a productos carbonilados y procedimiento mejorado que lo aplica.
AR010798A1 (es) Complejos de 3-aril sustituido indenilo, con metales del grupo 4, catalizadores de polimerizacion que incluyen dichos complejos y procedimientode polimerizacion de olefinas utilizando dichos complejos.
ATE276034T1 (de) Verwendung von metalloxidverbindungen mit perovskitstruktur
BR9510173A (pt) Catalisador para tratar uma corrente de gás que contém compostos selecionados a partir do grupo que consiste de compostos
DE69812234D1 (de) Rostfreier austenoferritischer Stahl mit sehr niedrigem Nickelgehalt und hoher Zugverformung
ATE45107T1 (de) Uebergangsmetallkatalysatoren von hoher aktivitaet und verfahren zu ihrer herstellung.
DE3774999D1 (de) Aethylenoxid-katalysator und verfahren zur katalytischen herstellung von aethylenoxid.
ES2110257T3 (es) Composiciones cataliticas.
AR001210A1 (es) Producción catalitica de aril alquil hidroperóxidos por agregados de metales de transición polinucleares
BR9915227B1 (pt) óxido de multimetais, processo para preparar o mesmo, pré-catalisador para a produção de catalisadores revestidos, e, catalisador revestido para a oxidação parcial.
DE68903397D1 (de) Traegerkatalysator fuer die nichtselektive oxydation von organischen verbindungen, verfahren fuer die nichtselektive oxydation, insbesondere von organischen verbindungen.
ATE116572T1 (de) Trägerkatalysator, verfahren zu seiner herstellung und seine verwendung für die dehydrierung von kohlenwasserstoffen.
ATE30010T1 (de) Verfahren zur herstellung von ethylen-ethangemischen.
DE60043492D1 (de) Katalysatorkomponente für Additionspolymerisation, Katalysator für Additionspolymerisation, und Verfahren zur Herstellung von Additionspolymeren
PT804380E (pt) Processo e catalisador para oxidar por via catalitica o h2s contido com fraca concentracao num gas libertando enxofre
FI861706A0 (fi) Synnerligen bestaendig katalyt med hoegt utbyte, laemplig speciellt foer oxidation av metylalkohol till formaldehyd.
KR830005900A (ko) 메타크롤레인 산화촉매
DE69407897D1 (de) Verfahren zur hochselektiven katalytischen direktoxidation von in niedriger konzentrationen in einem gas vorhandenem h2s
EP0249103A3 (de) Triarly- und Trihetarylmethanderivate als Redoxindikatoren und deren Verwendung
ES2185998T3 (es) Catalizadores de oxidacion basados en molibdeno.
BR0013338A (pt) Catalizador de leito fluidificado para a amoxidacão de propileno para acrilonitrila
KR830005898A (ko) 비스머스 함유 메타크롤레인 산화촉매
FR2358925A1 (fr) Catalyseur de deshydrogenation oxydante, a base de ferrite de zinc modifie, et son application
ES2143515T3 (es) Combinaciones ciclicas del fosforo trivalente.
DE69502949D1 (de) Zusammensetzungen des schalenkatalysator-typus, enthaltend wismut, nickel, kobalt, eisen und molybdän, und deren verwendung zur herstellung von ungesättigten aldehyden