ES2185998T3 - Catalizadores de oxidacion basados en molibdeno. - Google Patents

Catalizadores de oxidacion basados en molibdeno.

Info

Publication number
ES2185998T3
ES2185998T3 ES97942555T ES97942555T ES2185998T3 ES 2185998 T3 ES2185998 T3 ES 2185998T3 ES 97942555 T ES97942555 T ES 97942555T ES 97942555 T ES97942555 T ES 97942555T ES 2185998 T3 ES2185998 T3 ES 2185998T3
Authority
ES
Spain
Prior art keywords
cations
group formed
molibdene
cation
oxidation catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97942555T
Other languages
English (en)
Inventor
Kostantinos Kourtakis
John Donal Sullivan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Application granted granted Critical
Publication of ES2185998T3 publication Critical patent/ES2185998T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8898—Manganese, technetium or rhenium containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8875—Germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A CATALIZADORES QUE COMPRENDEN UN COMPUESTO DE MOLIBDENO, DE FORMULA (I): V Q MOA Y O SUB,Z , (II): NIMO X B Y O Z'' , (III): VNI W MO SUB,X C Y'' O Z'''' , (IV): CONI W MO X D Y OZ'''''' O (V): VNI W CO R MO X E Y O Z'' '''''' , DONDE: A ES AL MENOS UN CATION SELECCIONADO A PARTIR DEL GRUPO FORMADO POR CATIONES DE: CR, SB, CO, CE Y PB; B ES AL MENOS UN CATION SELECCIONADO A PARTIR DEL GRUPO FORMADO POR CATIONES DE: SB, AL Y W; C ES AL MENOS UN CATION SELECCIONADO A PARTIR DEL GRUPO FORMADO POR CATIONES DE: BA, MN, AL, SB, SN Y W; E ES AL MENOS UN CATION SELECCIONADO A PARTIR DEL GRUPO FORMADO POR CATIONES DE: FE, CA, MN, SR, EU, LA, ZR, GA, SN Y PB; Q, R, W, X E Y SON INDEPENDIENTEMENTE UN NUMERO DE 0,1 A 10 E Y'' ES UN NUMERO DE 0 A 10; Z, Z'', Z'''', Z'''''', Y Z'''''''' SE DETERMINAN UTILIZANDO LAS CANTIDADES Y LOS ESTADOS DE OXIDACION DE TODOS LOS CATIONES PRESENTES EN CADA FORMULA. DICHOS CATALIZADORES SE PUEDEN UTILIZAR EN PROCESOS DE OXIDACION DE C 4 , ESPECIALMENTE EN PROCESOS DEOXIDACION DE BUTANO.
ES97942555T 1996-09-24 1997-09-18 Catalizadores de oxidacion basados en molibdeno. Expired - Lifetime ES2185998T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2659796P 1996-09-24 1996-09-24

Publications (1)

Publication Number Publication Date
ES2185998T3 true ES2185998T3 (es) 2003-05-01

Family

ID=21832722

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97942555T Expired - Lifetime ES2185998T3 (es) 1996-09-24 1997-09-18 Catalizadores de oxidacion basados en molibdeno.

Country Status (5)

Country Link
US (3) US6271169B1 (es)
EP (1) EP0929511B1 (es)
DE (1) DE69717651T2 (es)
ES (1) ES2185998T3 (es)
WO (1) WO1998013329A1 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010036675A (ko) * 1999-10-11 2001-05-07 정명식 황화수소 가스 산화용 촉매 및 이를 이용한 황 회수 방법
US6602819B2 (en) * 2000-01-05 2003-08-05 E. I. Du Pont De Nemours And Company Process for the reduction of carbon monoxide and carbonyl sulfide emissions
US6693059B2 (en) * 2000-02-09 2004-02-17 Rohm And Haas Company Process for preparing a catalyst and catalytic oxidation therewith
AU2001236161A1 (en) * 2000-02-23 2001-09-03 Kwanghyun Ahn Selective oxidation of sulfides by the use of an oxidant system consisting of lithium molibdenate niobate and hydrogen peroxide
US6841699B2 (en) * 2001-04-25 2005-01-11 Rohm And Haas Company Recalcined catalyst
US6737531B1 (en) 2002-12-17 2004-05-18 Brookhaven Science Associates, Llc Catalysts for hydrogenation and hydrosilylation, methods of making and using the same
AR043243A1 (es) * 2003-02-24 2005-07-20 Shell Int Research Composicion de catalizador ,su preparacion y uso
AR043242A1 (es) 2003-02-24 2005-07-20 Shell Int Research Preparacion y uso de una composicion de catalizador
WO2004078143A2 (en) * 2003-03-05 2004-09-16 The Brigham And Women's Hospital Inc. Methods for identification and uses of anti-inflammatory receptors for eicosapentaenoic acid analogs
US7229946B2 (en) * 2003-03-24 2007-06-12 Saudi Basic Industries Corporation Catalyst composition for the selective conversion of alkanes to unsaturated carboxylic acids, method of making and method of using thereof
US7294734B2 (en) * 2003-05-02 2007-11-13 Velocys, Inc. Process for converting a hydrocarbon to an oxygenate or a nitrile
US20040235657A1 (en) * 2003-05-21 2004-11-25 Fina Technology, Inc. Freeze dry process for the preparation of a high surface area and high pore volume catalyst
EP1598110A1 (en) * 2004-04-22 2005-11-23 Rohm and Haas Company Structured oxidation catalysts
KR100619070B1 (ko) * 2005-03-08 2006-08-31 삼성전자주식회사 조명유닛 및 이를 채용한 화상투사장치
CA2705420C (en) 2007-11-19 2017-02-28 Shell Internationale Research Maatschappij B.V. Method for the start-up of a catalytic process

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2625519A (en) 1950-03-07 1953-01-13 Du Pont Oxidation catalysts
CA990305A (en) * 1970-08-26 1976-06-01 The Standard Oil Company Manufacture of maleic anhydride from butane
US3928392A (en) * 1973-10-17 1975-12-23 Sun Ventures Inc Oxidation of butane to make anhydride and catalyst therefor
US3968054A (en) * 1973-10-17 1976-07-06 Sun Ventures, Inc. Catalyst for the oxidation of butane to maleic anhydride
US4192951A (en) 1975-08-11 1980-03-11 Celanese Corporation Hydrocarbon oxidation process
US4390736A (en) * 1980-11-26 1983-06-28 Sumitomo Chemical Company, Limited Process for producing phenols
US4668802A (en) 1985-01-18 1987-05-26 E. I. Du Pont De Nemours And Company Improved vapor phase catalytic oxidation of butane to maleic anhydride
US5055441A (en) * 1990-02-01 1991-10-08 E. I. Du Pont De Nemours And Company Process for preparation of metal oxides of molybdenum or mlybdenum and tungsten

Also Published As

Publication number Publication date
US20030236432A1 (en) 2003-12-25
DE69717651D1 (de) 2003-01-16
US6841686B2 (en) 2005-01-11
US6271169B1 (en) 2001-08-07
EP0929511B1 (en) 2002-12-04
US20020049136A1 (en) 2002-04-25
US6500779B2 (en) 2002-12-31
WO1998013329A1 (en) 1998-04-02
DE69717651T2 (de) 2003-09-18
EP0929511A1 (en) 1999-07-21

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