AR127077A2 - Proceso para la preparacion de un catalizador de pre-reformado para el pre-reformado con vapor de hidrocarburos dotado de resistencia a la desactivacion por paso de vapor en ausencia de un agente reductor, y catalizador de pre-reformado preparado por dicho proceso - Google Patents

Proceso para la preparacion de un catalizador de pre-reformado para el pre-reformado con vapor de hidrocarburos dotado de resistencia a la desactivacion por paso de vapor en ausencia de un agente reductor, y catalizador de pre-reformado preparado por dicho proceso

Info

Publication number
AR127077A2
AR127077A2 ARP220102512A ARP220102512A AR127077A2 AR 127077 A2 AR127077 A2 AR 127077A2 AR P220102512 A ARP220102512 A AR P220102512A AR P220102512 A ARP220102512 A AR P220102512A AR 127077 A2 AR127077 A2 AR 127077A2
Authority
AR
Argentina
Prior art keywords
steam
reforming
storage tank
pumping
reforming catalyst
Prior art date
Application number
ARP220102512A
Other languages
English (en)
Inventor
Bittencourt Roberto Carlos Pontes
Original Assignee
Petroleo Brasileiro Sa Petrobras
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Petroleo Brasileiro Sa Petrobras filed Critical Petroleo Brasileiro Sa Petrobras
Publication of AR127077A2 publication Critical patent/AR127077A2/es

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0213—Preparation of the impregnating solution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
    • B01J2523/18—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/82—Metals of the platinum group
    • B01J2523/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

La presente invención está relacionada a técnicas de movilización de hidrocarburos en tanques de almacenamiento para evitar la formación de lodo. En este contexto, la presente invención provee un sistema externo de movilización de fluidos en un tanque de almacenamiento (10), que comprende por lo menos dos conjuntos de bombeo (20, 20a, 20b, 20c, 20d), comprendiendo (i) cada conjunto de bombeo (20, 20a, 20b, 20c, 20d) un conducto de bombeo (30) externo con respecto al tanque de almacenamiento (10) en comunicación hidráulica con el interior del tanque de almacenamiento (10) en por lo menos dos puntos distintos del tanque de almacenamiento a través de dos extremidades de dicho conducto de bombeo (32, 34), y (ii) una bomba (40) adaptada para hacer circular el fluido a través del conducto de bombeo (30), en donde el fluido que se hace circular a través del conducto de bombeo (30) es tomado del tanque de almacenamiento (10) en una extremidad del tubo de bombeo (32, 34) y descargado en el mismo tanque de almacenamiento (10) a través de otra extremidad (32, 34) del conducto de bombeo, y en donde la corriente de fluido en el conducto de bombeo (30) es reversible.
ARP220102512A 2017-10-05 2022-09-16 Proceso para la preparacion de un catalizador de pre-reformado para el pre-reformado con vapor de hidrocarburos dotado de resistencia a la desactivacion por paso de vapor en ausencia de un agente reductor, y catalizador de pre-reformado preparado por dicho proceso AR127077A2 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BR102017021428-1A BR102017021428B1 (pt) 2017-10-05 2017-10-05 Processo para preparação de um catalisador de pré-reforma

Publications (1)

Publication Number Publication Date
AR127077A2 true AR127077A2 (es) 2023-12-13

Family

ID=63787972

Family Applications (2)

Application Number Title Priority Date Filing Date
ARP180102441A AR112985A1 (es) 2017-10-05 2018-08-28 Proceso para preparación de un catalizador de pre-reformado dotado de resistencia a la desactivación por paso de vapor en ausencia de un agente reductor y catalizador de pre-reformado preparado por dicho proceso
ARP220102512A AR127077A2 (es) 2017-10-05 2022-09-16 Proceso para la preparacion de un catalizador de pre-reformado para el pre-reformado con vapor de hidrocarburos dotado de resistencia a la desactivacion por paso de vapor en ausencia de un agente reductor, y catalizador de pre-reformado preparado por dicho proceso

Family Applications Before (1)

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ARP180102441A AR112985A1 (es) 2017-10-05 2018-08-28 Proceso para preparación de un catalizador de pre-reformado dotado de resistencia a la desactivación por paso de vapor en ausencia de un agente reductor y catalizador de pre-reformado preparado por dicho proceso

Country Status (9)

Country Link
US (1) US11794168B2 (es)
EP (1) EP3691786B1 (es)
JP (1) JP7190486B2 (es)
CN (1) CN111465448B (es)
AR (2) AR112985A1 (es)
BR (1) BR102017021428B1 (es)
CA (1) CA3078422A1 (es)
MX (1) MX2020003477A (es)
WO (1) WO2019069058A1 (es)

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JP3226558B2 (ja) 1991-03-12 2001-11-05 日石三菱株式会社 炭化水素の高温水蒸気改質用触媒
AU742830B2 (en) 1997-11-27 2002-01-10 Idemitsu Kosan Co. Ltd Alumina-supported ruthenium catalyst
US6409939B1 (en) * 2000-05-31 2002-06-25 Uop Llc Method for producing a hydrogen-rich fuel stream
DE60224925T2 (de) * 2001-03-29 2009-01-29 Idemitsu Kosan Co. Ltd. Katalytisches verfahren zum reformieren von kohlenwasserstoff unter verwendung des katalysators
WO2004058634A2 (en) * 2002-12-20 2004-07-15 Honda Giken Kogyo Kabushiki Kaisha Catalyst formulations for hydrogen generation
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JP2005185989A (ja) * 2003-12-26 2005-07-14 Idemitsu Kosan Co Ltd 酸素含有炭化水素の改質触媒、それを用いた水素又は合成ガスの製造方法及び燃料電池システム
JP4753639B2 (ja) 2004-06-28 2011-08-24 大阪瓦斯株式会社 合成ガスの製造方法
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US7345214B2 (en) * 2005-10-03 2008-03-18 Uop Llc Modified PT/RU catalyst for ring opening and process using the catalyst
JP4707526B2 (ja) 2005-10-12 2011-06-22 株式会社日本触媒 炭化水素の部分酸化用触媒
CA2593413C (en) * 2007-06-26 2012-02-28 Innovatek, Inc. Hydrocarbon fuel reforming catalyst and use thereof
JP5394280B2 (ja) * 2010-02-16 2014-01-22 Ｊｘ日鉱日石エネルギー株式会社 水素製造用改質触媒及びその製造方法、並びに該触媒を用いた水素製造方法
JP2012061399A (ja) 2010-09-15 2012-03-29 Nippon Shokubai Co Ltd 水素製造用触媒、その触媒の製造方法およびその触媒を用いた水素の製造方法
ES2710851T3 (es) * 2011-09-02 2019-04-29 Neste Oyj Método para reformar gas de gasificación
JP5809049B2 (ja) * 2011-12-27 2015-11-10 東京瓦斯株式会社 燃料電池用水蒸気改質触媒の使用方法及び水素製造システム
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GB201506325D0 (en) * 2015-04-14 2015-05-27 Johnson Matthey Plc Shaped catalyst particle

Also Published As

Publication number Publication date
BR102017021428A2 (pt) 2019-04-24
EP3691786B1 (en) 2024-06-12
US20200290021A1 (en) 2020-09-17
EP3691786A1 (en) 2020-08-12
JP2020535963A (ja) 2020-12-10
AR112985A1 (es) 2020-01-15
US11794168B2 (en) 2023-10-24
CN111465448A (zh) 2020-07-28
CA3078422A1 (en) 2019-04-11
CN111465448B (zh) 2023-06-20
JP7190486B2 (ja) 2022-12-15
MX2020003477A (es) 2020-07-20
WO2019069058A1 (en) 2019-04-11
BR102017021428B1 (pt) 2022-04-19

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