AR121855A1 - Pirrolin-2-onas especialmente sustituidas y su uso como herbicidas - Google Patents

Pirrolin-2-onas especialmente sustituidas y su uso como herbicidas

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Publication number
AR121855A1
AR121855A1 ARP210101003A ARP210101003A AR121855A1 AR 121855 A1 AR121855 A1 AR 121855A1 AR P210101003 A ARP210101003 A AR P210101003A AR P210101003 A ARP210101003 A AR P210101003A AR 121855 A1 AR121855 A1 AR 121855A1
Authority
AR
Argentina
Prior art keywords
alkyl
methylpyridine
alkoxy
general formula
cycloalkyl
Prior art date
Application number
ARP210101003A
Other languages
English (en)
Inventor
Hartmut Ahrens
Alfred Angermann
Lars Arve
Guido Bojack
Arsequell Estella Buscato
Elisabeth Asmus
Elmar Gatzweiler
Jan Dittgen
Christopher Hugh Rosinger
Original Assignee
Bayer Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Ag filed Critical Bayer Ag
Publication of AR121855A1 publication Critical patent/AR121855A1/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/54—Spiro-condensed
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/46—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino or carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings of the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/45—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups
    • C07C233/52—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/385—Saturated compounds containing a keto group being part of a ring
    • C07C49/517—Saturated compounds containing a keto group being part of a ring containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/30—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings
    • C07C57/42—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings having unsaturation outside the rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/52—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing halogen
    • C07C57/58—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing halogen containing six-membered aromatic rings
    • C07C57/60—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing halogen containing six-membered aromatic rings having unsaturation outside the rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
    • C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/12—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Abstract

Compuestos derivados de 2-oxo-1-azaespiro[4,5]dec-3-eno que poseen actividad herbicida, procedimiento para su preparación e intermediarios de síntesis de los mismos, agente agroquímico que los contiene y el empleo de los mismos en procedimientos para el combate de plantas no deseadas y de regulación del crecimiento de las plantas como así también para el recubrimiento de semillas. Reivindicación 1: Pirrolin-2-onas sustituidas de la fórmula general (1) o una de sus sales agroquímicamente aceptables, en donde X significa alquilo C₁₋₆, halogenalquilo C₁₋₆, cicloalquilo C₃₋₆, cloro, bromo o fluoro; Y significa alquilo C₁₋₆, halogenalquilo C₁₋₆ o cicloalquilo C₃₋₆; R¹ significa difluoroalcoxi C₂₋₆; R² significa hidrógeno, alquilo C₁₋₆, alcoxi C₁₋₄-alquilo C₁₋₄, halogenalquilo C₁₋₆, cicloalquilo C₃₋₆, cicloalquil C₃₋₆-alquilo C₁₋₄, alquenilo C₂₋₆, alquinilo C₂₋₆, alcoxi C₁₋₆ o halogenalcoxi C₁₋₆; G significa hidrógeno, un grupo L escindible o un catión E, en donde L es uno de los siguientes radicales del grupo de fórmulas (2), en donde R³ significa alquilo C₁₋₄ o alcoxi C₁₋₃-alquilo C₁₋₄; R⁴ significa alquilo C₁₋₄; R⁵ significa alquilo C₁₋₄, un fenilo no sustituido o un fenilo mono- o polisustituido con halógeno, alquilo C₁₋₄, halogen-alquilo (C₁₋₄), alcoxi (C₁₋₄), halogen-alcoxi (C₁₋₄), nitro o ciano; R⁶, R⁶’ significan, de modo independiente entre sí, metoxi o etoxi; R⁷, R⁸ significan, de modo independiente entre sí, metilo, etilo, fenilo o junto con el átomo de nitrógeno, al que están unidos, forman un anillo saturado de 5, 6 ó 7 miembros, en donde un átomo de carbono del anillo puede estar opcionalmente reemplazado por un átomo de oxígeno o de azufre; E significa un ión de metal alcalino, un equivalente iónico de un metal alcalinotérreo, un equivalente iónico de aluminio, un equivalente iónico de un metal de transición, un catión de magnesio-halógeno o un ión amonio, en donde opcionalmente uno, dos, tres o los cuatro átomos de hidrógeno están reemplazados por radicales iguales o diferentes de los grupos alquilo C₁₋₁₀ o cicloalquilo C₃₋₇, que pueden estar sustituidos, de modo independiente entre sí, una o varias veces con fluoro, cloro, bromo, ciano, hidroxi o interrumpidos con uno o más átomos de oxígeno o azufre, es un ión amonio alifático o heteroalifático secundario o terciario cíclico, por ejemplo, morfolinio, tiomorfolinio, piperidinio, pirrolidinio o 1,4-diazabiciclo[1.1.2]octano (DABCO) o 1,5-diazabiciclo[4.3.0]undec-7-eno (DBU) en cada caso protonado; es un catión amonio heteroaromático, por ejemplo, en cada caso protonado piridina, 2-metilpiridina, 3-metilpiridina, 4-metilpiridina, 2,4-dimetilpiridina, 2,5-di-metilpiridina, 2,6-dimetilpiridina, 5-etil-2-metilpiridina, colidina, pirrol, imidazol, quinolina, quinoxalina, 1,2-dimetilimidazol, metilsulfato de 1,3-dimetilimidazolio o también representa un ión trimetilsulfonio. Reivindicación 8: Compuestos de la fórmula general (3) o una de sus sales agroquímicamente aceptables, en donde los radicales R¹, R², R⁹, X e Y se definen como en las reivindicaciones 1 a 4 y 7. Reivindicación 9: Compuestos de la fórmula general (4) o una de sus sales agroquímicamente aceptables, en donde los radicales R¹, R² y R⁹ se definen como en las reivindicaciones 1 a 4 y 7. Reivindicación 14: Compuestos de la fórmula general (5) o una de sus sales agroquímicamente aceptables, en donde R¹ se define como en las reivindicaciones 1 a 4. Reivindicación 15: Compuestos de la fórmula general (6) o una de sus sales agroquímicamente aceptables, en donde R¹ se define como en las reivindicaciones 1 a 4.
ARP210101003A 2020-04-15 2021-04-15 Pirrolin-2-onas especialmente sustituidas y su uso como herbicidas AR121855A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP20169629 2020-04-15

Publications (1)

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AR121855A1 true AR121855A1 (es) 2022-07-13

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Country Status (2)

Country Link
AR (1) AR121855A1 (es)
WO (1) WO2021209486A1 (es)

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AR115088A1 (es) 2018-05-15 2020-11-25 Bayer Ag Espirociclohexilpirrolin-2-onas y su uso como herbicidas

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