AR118348A1 - 3-(2-bromo-4-alquinil-6-alcoxifenil)-3-pirrolin-2-onas y su uso como herbicidas - Google Patents

3-(2-bromo-4-alquinil-6-alcoxifenil)-3-pirrolin-2-onas y su uso como herbicidas

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Publication number
AR118348A1
AR118348A1 ARP200100701A ARP200100701A AR118348A1 AR 118348 A1 AR118348 A1 AR 118348A1 AR P200100701 A ARP200100701 A AR P200100701A AR P200100701 A ARP200100701 A AR P200100701A AR 118348 A1 AR118348 A1 AR 118348A1
Authority
AR
Argentina
Prior art keywords
alkyl
alkoxy
ion
cycloalkyl
group
Prior art date
Application number
ARP200100701A
Other languages
English (en)
Inventor
Dirk Schmutzler
Asmus Elisabeth Dr
Machettira Anu Bheemaiah Dr
Gatzweiler Elmar Dr
Lehr Stefan Dr
Rembiak Andreas Dr
Buscato Arsequell Estella Dr
Angermann Alfred Dr
Bojack Guido Dr
Original Assignee
Bayer Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Ag filed Critical Bayer Ag
Publication of AR118348A1 publication Critical patent/AR118348A1/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/30—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
    • C07D491/10—Spiro-condensed systems
    • C07D491/107—Spiro-condensed systems with only one oxygen atom as ring hetero atom in the oxygen-containing ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/56—Ring systems containing three or more rings
    • C07D209/96—Spiro-condensed ring systems
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A01N25/14—Powders or granules wettable

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

La presente se refiere a 3-pirrolidin-2-onas con acción herbicida según la fórmula general (1) o sus sales aceptables para uso agroquímico, así como a su uso para combatir malezas y malas gramíneas en cultivos de plantas útiles. Reivindicación 1: Espirociclopentilpirrolin-2-onas de la fórmula general (1), caracterizados porque W significa oxígeno, el grupo S(O)ₙ o un grupo CR⁴R⁵; R¹ significa hidrógeno, alquilo C₁₋₆, alcoxi C₁₋₄-alquilo C₁₋₄, halógenoalquilo C₁₋₆, cicloalquilo C₃₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, alcoxi C₁₋₆ o halógenoalcoxi C₁₋₆; R² significa alquilo C₁₋₆ o halógenoalquilo C₁₋₆; R³ significa hidrógeno, alquilo C₁₋₄, halógenoalquilo C₁₋₄, cicloalquilo C₃₋₆ o halógeno; R⁴ significa alquilo C₁₋₆, cicloalquilo C₃₋₆, alcoxi C₃₋₆, alcoxi C₁₋₄-alcoxi C₁₋₆, halógenoalcoxi C₁₋₄-alcoxi C₁₋₆, alqueniloxi C₂₋₆ o halógenoalqueniloxi C₂₋₆; R⁵ significa hidrógeno o metilo; o R⁴ y R⁵ forman junto con el átomo de carbono al que están unidos, un grupo ceto o un anillo espirocíclico cicloalquilo C₃₋₇ o cicloalquenilo C₅₋₇ en el que dado el caso uno o dos átomos anulares pueden estar sustituidos con átomos de oxígeno y el que dado el caso puede estar mono o disustituido independientemente entre sí con alquilo C₁₋₂ o alcoxi C₁₋₂; n significa 0, 1 ó 2; G significa hidrógeno, un grupo L escindible o un catión E; siendo que L es uno de los restos del grupo de fórmulas (2), en los que R⁶ significa alquilo C₁₋₄ o alcoxi C₁₋₃-alquilo C₂₋₄; R⁷ significa alquilo C₁₋₄; R⁸ significa un fenilo no sustituido o un fenilo mono o polisustituido con halógeno, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, haloalcoxi C₁₋₄, nitro o ciano; R⁹, R⁹’ independientemente entre sí significan metoxi o etoxi; R¹⁰, R¹¹ en cada caso significan independientemente entre sí metilo, etilo, fenilo o forman juntos un anillo saturado de 5, 6 ó 7 miembros o juntos forman un heterociclo saturado de 5, 6 ó 7 miembros con un átomo de oxígeno o sulfuro, E es un ión metálico alcalino, un ión equivalente a un metal alcalinotérreo, un ión equivalente al aluminio, un ión equivalente a un metal de transición, un catión de haluro de magnesio o un ión de amonio, en el que opcionalmente uno, dos o tres de los cuatro átomos de hidrógeno pueden ser sustituidos por restos idénticos o diferentes de los grupos alquilo C₁₋₁₀ o cicloalquilo C₃₋₇, donde estos independientemente entre sí pueden estar cada uno de ellos mono- o polisustituidos con flúor, cloro, bromo, ciano, hidroxilo o interrumpidos por uno o varios por átomos de oxígeno o de azufre; significa un ión cíclico de amonio alifático o heteroalifático secundario o terciario, por ejemplo, en cada caso morfolinio, tiomorfolinio, piperidinio, pirrolidinio o, en cada caso puede ser equivalente a 1,4-diazabiciclo[1.1.2]octano protonado (DABCO) o 1,5-diazabiciclo[4.3.0]undec-7-eno (DBU); un catión de amonio heteroaromático, por ejemplo, en cada caso piridina protonizada, 2-metilpiridina, 3-metilpiridina, 4-metilpiridina, 2,4-dimetilpiridina, 2,5-dimetilpiridina, 2,6-dimetilpiridina, 5-etil-2-metilpiridina, colidina, pirrol, imidazol, quinolina, quinoxalina, 1,2-dimetilimidazol, metilsulfato de 1,3-dimetilimidazolio o además también puede ser equivalente a trimetilsulfonio.
ARP200100701A 2019-03-15 2020-03-13 3-(2-bromo-4-alquinil-6-alcoxifenil)-3-pirrolin-2-onas y su uso como herbicidas AR118348A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP19163150 2019-03-15

Publications (1)

Publication Number Publication Date
AR118348A1 true AR118348A1 (es) 2021-09-29

Family

ID=65817914

Family Applications (1)

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ARP200100701A AR118348A1 (es) 2019-03-15 2020-03-13 3-(2-bromo-4-alquinil-6-alcoxifenil)-3-pirrolin-2-onas y su uso como herbicidas

Country Status (11)

Country Link
US (1) US20220056040A1 (es)
EP (1) EP3938348A1 (es)
JP (1) JP2022525173A (es)
CN (1) CN113557231A (es)
AR (1) AR118348A1 (es)
AU (1) AU2020242211A1 (es)
BR (1) BR112021012818A2 (es)
CA (1) CA3133187A1 (es)
EA (1) EA202192470A1 (es)
IL (1) IL286164A (es)
WO (1) WO2020187627A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3793977A1 (de) * 2018-05-15 2021-03-24 Bayer Aktiengesellschaft 2-brom-6-alkoxyphenyl-substituierte pyrrolin-2-one und deren verwendung als herbizide
WO2022253700A1 (de) 2021-06-01 2022-12-08 Bayer Aktiengesellschaft Speziell substituierte pyrrolin-2-one und deren verwendung als herbizide
CN116102565B (zh) * 2023-01-16 2024-11-05 贵州大学 一类含异丙醇胺的螺色酮类化合物及其制备方法和应用

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WO2015040114A1 (en) 2013-09-20 2015-03-26 Syngenta Limited Herbicidally active 2-halogen-4-alkynyl-phenyl-pyrazolidine-dione or pyrrolidine-dione derivatives

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CN113557231A (zh) 2021-10-26
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