AR118840A2 - Combinaciones de compuestos activos que comprenden un derivado de (tio)carboxamida y un compuesto fungicida - Google Patents

Combinaciones de compuestos activos que comprenden un derivado de (tio)carboxamida y un compuesto fungicida

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AR118840A2
AR118840A2 ARP200101244A ARP200101244A AR118840A2 AR 118840 A2 AR118840 A2 AR 118840A2 AR P200101244 A ARP200101244 A AR P200101244A AR P200101244 A ARP200101244 A AR P200101244A AR 118840 A2 AR118840 A2 AR 118840A2
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Argentina
Prior art keywords
pyrazol
fluorophenyl
dimethyl
phenyl
chloro
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ARP200101244A
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English (en)
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Pierre Yves Coqueron
Pierre Cristau
Peter Dahmen
Philippe Desbordes
Tomoki Tsuchiya
Ulrike Wachendorff-Neumann
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Bayer Cropscience Ag
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Publication of AR118840A2 publication Critical patent/AR118840A2/es

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    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

Reivindicación 1: Una combinación de compuestos activos que comprende (A) al menos un derivado de fórmula (1) en donde T representa un átomo de oxígeno o un átomo de azufre y X se selecciona del listado de 2-isopropilo, 2-ciclopropilo, 2-tert-butilo, 5-cloro-2-etilo, 5-cloro-2-isopropilo, 2-etil-5-fluoro, 5-fluoro-2-isopropilo, 2-ciclopropil-5-fluoro, 2-ciclopentil-5-fluoro, 2-fluoro-6-isopropilo, 2-etil-5-metilo, 2-isopropil-5-metilo, 2-ciclopropil-5-metilo, 2-tert-butil-5-metilo, 5-cloro-2-(trifluorometilo), 5-metil-2-(trifluorometilo), 2-cloro-6-(trifluorometilo), 3-cloro-2-fluoro-6-(trifluorometilo) y 2-etil-4,5-dimetilo, o una sal agroquímicamente aceptable del mismo, y (B) al menos un compuesto fungicida activo adicional seleccionado entre el grupo L1 que consiste en (b1) isofetamida; (b2) (2E,3Z)-5-{[1-(4-clorofenil)-1H-pirazol-3-il]oxi}-2-(metoxiimino)-N,3-dimetilpent-3-enamida; (b3) [3-(4-cloro-2-fluorofenil)-5-(2,4-difluorofenil)-1,2-oxazol-4-il](piridin-3-il)metanol; (b4) (S)-[3-(4-cloro-2-fluorofenil)-5-(2,4-difluorofenil)-1,2-oxazol-4-il](piridin-3-il)metanol; (b5) (R)-[3-(4-cloro-2-fluorofenil)-5-(2,4-difluorofenil)-1,2-oxazol-4-il](piridin-3-il)metanol; (b6) 2-{[3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-2,4-dihidro-3H-1,2,4-triazol-3-tiona; (b7) 1-{[3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-1H-1,2,4-triazol-5-il tiocianato; (b8) 5-(alilsulfanil)-1-{[3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-1H-1,2,4-triazol; (b9) 2-[1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro-3H-1,2,4-triazol-3-tiona; (b10) 2-{[rel(2R,3S)-3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-2,4-dihidro3H-1,2,4-triazol-3-tiona; (b11) 2-{[rel(2R,3R)-3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-2,4-dihidro3H-1,2,4-triazol-3-tiona; (b12) 1-{[rel(2R,3S)-3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-1H-1,2,4-triazol-5-il tiocianato; (b13) 1-{[rel(2R,3R)-3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-1H-1,2,4-triazol-5-il tiocianato; (b14) 5-(alilsulfanil)-1-{[rel(2R,3S)-3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-1H-1,2,4-triazol; (b15) 5-(alilsulfanil)-1-{[rel(2R,3R)-3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-1H-1,2,4-triazol; (b16) 2-[(2S,4S,5S)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro3H-1,2,4-triazol-3-tiona; (b17) 2-[(2R,4S,5S)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro3H-1,2,4-triazol-3-tiona; (b18) 2-[(2R,4R,5R)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro3H-1,2,4-triazol-3-tiona; (b19) 2-[(2S,4R,5R)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro3H-1,2,4-triazol-3-tiona; (b20) 2-[(2S,4S,5R)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro3H-1,2,4-triazol-3-tiona; (b21) 2-[(2R,4S,5R)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro3H-1,2,4-triazol-3-tiona; (b22) 2-[(2R,4R,5S)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro3H-1,2,4-triazol-3-tiona; (b23) 2-[(2S,4R,5S)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro3H-1,2,4-triazol-3-tiona; (b24) 2-fluoro-6-(trifluorometil)-N-(1,1,3-trimetil-2,3-dihidro-1H-inden-4-il)benzamida; (b25) 2-(6-bencilpiridin-2-il)quinazolina; (b26) 2-[6-(3-fluoro-4-metoxifenil)-5-metilpiridin-2-il]quinazolina; (b27) 3-(4,4-difluoro-3,3-dimetil-3,4-dihidroisoquinolin-1-il)quinolina; (b28) ácido abscísico; (b29) 3-(difluorometil)-N-metoxi-1-metil-N-[1-(2,4,6-triclorofenil)propan-2-il]-1Hpirazol-4-carboxamida; (b30) N’-[5-bromo-6-(2,3-dihidro-1H-inden-2-iloxi)-2-metilpiridin-3-il]-N-etil-N-metilimido formamida; (b31) N’-{5-bromo-6-[1-(3,5-difluorofenil)etoxi]-2-metilpiridin-3-il}-N-etil-N-metilimido formamida; (b32) N’-{5-bromo-6-[(1R)-1-(3,5-difluorofenil)etoxi]-2-metilpiridin-3-il}-N-etil-N-metilimido formamida; (b33) N’-{5-bromo-6-[(1S)-1-(3,5-difluorofenil)etoxi]-2-metilpiridin-3-il}-N-etil-N-metilimido formamida; (b34) N’-{5-bromo-6-[(cis-4-isopropilciclohexil)oxi]-2-metilpiridin-3-il}-N-etil-N-metilimido formamida; (b35) N’-{5-bromo-6-[(trans-4-isopropilciclohexil)oxi]-2-metilpiridin-3-il}-N-etil-N-metilimido formamida; (b36) 3-(difluorometil)-N-(7-fluoro-1,1,3-trimetil-2,3-dihidro-1H-inden-4-il)-1-metil-1H-pirazol-4-carboxamida; (b37) 3-(difluorometil)-N-[(3R)-7-fluoro-1,1,3-trimetil-2,3-dihidro-1H-inden-4-il]-1-metil-1H-pirazol-4-carboxamida; (b38) 3-(difluorometil)-N-[(3S)-7-fluoro-1,1,3-trimetil-2,3-dihidro-1H-inden-4-il]-1-metil-1H-pirazol-4-carboxamida; (b39) N-(4-cloro-2,6-difluorofenil)-4-(2-cloro-4-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b40) 2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-1-(1H-1,2,4-triazol-1-il)propan-2-ol; (b41) 2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-1-(1H-1,2,4-triazol-1-il)butan-2-ol; (b42) 2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-1-(1H-1,2,4-triazol-1-il)pentan-2-ol; (b43) 2-[2-cloro-4-(4-clorofenoxi)fenil]-1-(1H-1,2,4-triazol-1-il)butan-2-ol; (b44) 2-[2-cloro-4-(2,4-diclorofenoxi)fenil]-1-(1H-1,2,4-triazol-1-il)propan-2-ol; (b45) 9-fluoro-2,2-dimetil-5-(quinolin-3-il)-2,3-dihidro-1,4-benzoxazepina; (b46) 2-{2-fluoro-6-[(8-fluoro-2-metilquinolin-3-il)oxi]fenil}propan-2-ol; (b47) 2-{2-[(7,8-difluoro-2-metilquinolin-3-il)oxi]-6-fluorofenil}propan-2-ol; (b48) (2R)-2-(1-clorociclopropil)-4-[(1R)-2,2-diclorociclopropil]-1-(1H-1,2,4-triazol-1-il)butan-2-ol; (b49) (2R)-2-(1-clorociclopropil)-4-[(1S)-2,2-diclorociclopropil]-1-(1H-1,2,4-triazol-1-il)butan-2-ol; (b50) (2S)-2-(1-clorociclopropil)-4-[(1S)-2,2-diclorociclopropil]-1-(1H-1,2,4-triazol-1-il)butan-2-ol; (b51) (2S)-2-(1-clorociclopropil)-4-[(1R)-2,2-diclorociclopropil]-1-(1H-1,2,4-triazol-1-il)butan-2-ol; (b52) (1S,2R,5R)-5-(4-clorobencil)-2-(clorometil)-2-metil-1-(1H-1,2,4-triazol-1-ilmetil)ciclo pentanol; (b53) (1R,2S,5S)-5-(4-clorobencil)-2-(clorometil)-2-metil-1-(1H-1,2,4-triazol-1-ilmetil)ciclo pentanol; (b54) 4-(2-cloro-4-fluorofenil)-N-(2-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b55) 4-(2-cloro-4-fluorofenil)-N-(2,6-difluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b56) 4-(2-cloro-4-fluorofenil)-N-(2-cloro-6-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b57) 4-(2-bromo-4-fluorofenil)-N-(2-cloro-6-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b58) N-(2-bromo-6-fluorofenil)-4-(2-cloro-4-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b59) 4-(2-bromo-4-fluorofenil)-N-(2-bromofenil)-1,3-dimetil-1H-pirazol-5-amina; (b60) 4-(2-bromo-4-fluorofenil)-N-(2-bromo-6-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b61) 4-(2-bromo-4-fluorofenil)-N-(2-clorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b62) N-(2-bromofenil)-4-(2-cloro-4-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b63) 4-(2-cloro-4-fluorofenil)-N-(2-clorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b64) 4-(2-bromo-4-fluorofenil)-N-(2,6-difluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b65) 4-(2-bromo-4-fluorofenil)-N-(2-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b66) N’-(4-{3-[(difluorometil)sulfanil]fenoxi}-2,5-dimetilfenil)-N-etil-N-metilimido formamida; (b67) N’-(2,5-dimetil-4-{3-[(1,1,2,2-tetrafluoroetil)sulfanil]fenoxi}fenil)-N-etil-N-metilimido formamida; (b68) N’-(2,5-dimetil-4-{3-[(2,2,2-trifluoroetil)sulfanil]fenoxi}fenil)-N-etil-N-metilimido formamida; (b69) N’-(2,5-dimetil-4-{3-[(2,2,3,3-tetrafluoropropil)sulfanil]fenoxi}fenil)-N-etil-N-metilimido formamida; (b70) N’-(2,5-dimetil-4-{3-[(pentafluoroetil)sulfanil]fenoxi}fenil)-N-etil-N-metilimido formamida; (b71) N’-(4-{[3-(difluorometoxi)fenil]sulfanil}-2,5-dimetilfenil)-N-etil-N-metilimido formamida; (b72) N’-(2,5-dimetil-4-{[3-(1,1,2,2-tetrafluoroetoxi)fenil]sulfanil}fenil)-N-etil-N-metilimido formamida; (b73) N’-(2,5-dimetil-4-{[3-(2,2,2-trifluoroetoxi)fenil]sulfanil}fenil)-N-etil-N-metilimido formamida; (b74) N’-(2,5-dimetil-4-{[3-(2,2,3,3-tetrafluoropropoxi)fenil]sulfanil}fenil)-N-etil-Nmetilimido formamida; (b75) N’-(2,5-dimetil-4-{[3-(pentafluoroetoxi)fenil]sulfanil}fenil)-N-etil-N-metilimido formamida; (b76) 5-(4-clorobencil)-2-(clorometil)-2-metil-1-(1H-1,2,4-triazol-1-ilmetil)ciclopentanol; (b77) 2-[3,5-bis(difluorometil)-1H-pirazol-1-il]-1-[4-(4-{5-[2-(prop-2-in-1-iloxi)fenil]-4,5-dihidro-1,2-oxazol-3-il}-1,3-tiazol-2-il)piperidin-1-il]etanona; (b78) 2-[3,5-bis(difluorometil)-1H-pirazol-1-il]-1-[4-(4-{5-[2-fluoro-6-(prop-2-in-1-iloxi)fenil]-4,5-dihidro-1,2-oxazol-3-il}-1,3-tiazol-2-il)piperidin-1-il]etanona; (b79) 2-[3,5-bis(difluorometil)-1H-pirazol-1-il]-1-[4-(4-{5-[2-cloro-6-(prop-2-in-1-iloxi)fenil]-4,5-dihidro-1,2-oxazol-3-il}-1,3-tiazol-2-il)piperidin-1-il]etanona; (b80) 2-{3-[2-(1-{[3,5-bis(difluorometil)-1H-pirazol-1-il]acetil}piperidin-4-il)-1,3-tiazol-4-il]-4,5-dihidro-1,2-oxazol-5-il}fenil metanosulfonato; (b81) 2-{3-[2-(1-{[3,5-bis(difluorometil)-1H-pirazol-1-il]acetil}piperidin-4-il)-1,3-tiazol-4-il]-4,5-dihidro-1,2-oxazol-5-il}-3-clorofenil metanosulfonato; (b82) 2-[3,5-bis(difluorometil)-1H-pirazol-1-il]-1-[4-(4-{(5S)-5-[2-(prop-2-in-1-iloxi)fenil]-4,5-dihidro-1,2-oxazol-3-il}-1,3-tiazol-2-il)piperidin-1-il]etanona; (b83) 2-[3,5-bis(difluorometil)-1H-pirazol-1-il]-1-[4-(4-{(5R)-5-[2-(prop-2-in-1-iloxi)fenil]-4,5-dihidro-1,2-oxazol-3-il}-1,3-tiazol-2-il)piperidin-1-il]etanona; (b84) 2-[3,5-bis(difluorometil)-1H-pirazol-1-il]-1-[4-(4-{(5S)-5-[2-fluoro-6-(prop-2-in-1-iloxi)fenil]-4,5-dihidro-1,2-oxazol-3-il}-1,3-tiazol-2-il)piperidin-1-il]etanona; (b85) 2-[3,5-bis(difluorometil)-1H-pirazol-1-il]-1-[4-(4-{(5R)-5-[2-fluoro-6-(prop-2-in-1-iloxi)fenil]-4,5-dihidro-1,2-oxazol-3-il}-1,3-tiazol-2-il)piperidin-1-il]etanona; (b86) 2-[3,5-bis(difluorometil)-1H-pirazol-1-il]-1-[4-(4-{(5S)-5-[2-cloro-6-(prop-2-in-1-iloxi)fenil]-4,5-dihidro-1,2-oxazol-3-il}-1,3-tiazol-2-il)piperidin-1-il]etanona; (b87) 2-[3,5-bis(difluorometil)-1H-pirazol-1-il]-1-[4-(4-{(5R)-5-[2-cloro-6-(prop-2-in-1-iloxi)fenil]-4,5-dihidro-1,2-oxazol-3-il}-1,3-tiazol-2-il)piperidin-1-il]etanona; (b88) 2-{(5S)-3-[2-(1-{[3,5-bis(difluorometil)-1H-pirazol-1-il]acetil}piperidin-4-il)-1,3-tiazol-4-il]-4,5-dihidro-1,2-oxazol-5-il}fenil metanosulfonato; (b89) 2-{(5R)-3-[2-(1-{[3,5-bis(difluorometil)-1H-pirazol-1-il]acetil}piperidin-4-il)-1,3-tiazol-4-il]-4,5-dihidro-1,2-oxazol-5-il}fenil metanosulfonato; (b90) 2-{(5S)-3-[2-(1-{[3,5-bis(difluorometil)-1H-pirazol-1-il]acetil}piperidin-4-il)-1,3-tiazol-4-il]-4,5-dihidro-1,2-oxazol-5-il}-3-clorofenil metanosulfonato; (b91) 2-{(5R)-3-[2-(1-{[3,5-bis(difluorometil)-1H-pirazol-1-il]acetil}piperidin-4-il)-1,3-tiazol-4-il]-4,5-dihidro-1,2-oxazol-5-il}-3-clorofenil metanosulfonato; (b92) (2R)-2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-1-(1H-1,2,4-triazol-1-il)propan-2-ol; (b93) (2S)-2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-1-(1H-1,2,4-triazol-1-il)propan-2-ol; con la condición de que, cuando el derivado de fórmula (1) es N-ciclopropil-3-(difluorometil)-5-fluoro-N-(2-isopropilbencil)-1-metil-1H-pirazol-4-carboxamida, entonces el compuesto fungicida activo B no es (b54) 4-(2-cloro-4-fluorofenil)-N-(2-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b55) 4-(2-cloro-4-fluorofenil)-N-(2,6-difluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b56) 4-(2-cloro-4-fluorofenil)-N-(2-cloro-6-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b57) 4-(2-bromo-4-fluorofenil)-N-(2-cloro-6-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b58) N-(2-bromo-6-fluorofenil)-4-(2-cloro-4-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b59) 4-(2-bromo-4-fluorofenil)-N-(2-bromofenil)-1,3-dimetil-1H-pirazol-5-amina; (b60) 4-(2-bromo-4-fluorofenil)-N-(2-bromo-6-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b61) 4-(2-bromo-4-fluorofenil)-N-(2-clorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b62) N-(2-bromofenil)-4-(2-cloro-4-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b63) 4-(2-cloro-4-fluorofenil)-N-(2-clorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b64)4-(2-bromo-4-fluorofenil)-N-(2,6-difluorofenil)-1,3-dimetil-1H-pirazol-5-amina; (b65) 4-(2-bromo-4-fluorofenil)-N-(2-fluorofenil)-1,3-dimetil-1H-pirazol-5-amina. Reivindicación 7: Composición de acuerdo con la reivindicación 6 que comprende al menos un ingrediente activo adicional seleccionado de entre el grupo de los insecticidas, cebos, esterilizantes, bactericidas, acaricidas, nematicidas, fungicidas, reguladores del crecimiento, herbicidas, fertilizantes, protectores y semioquímicos. Reivindicación 8: Método para el control de hongos nocivos fitopatógenos, caracterizado porque se aplica una combinación de compuestos activos de acuerdo con una cualquiera de las reivindicaciones 1 a 5 a los hongos nocivos fitopatógenos y/o a su hábitat. Reivindicación 9: Proceso para la producción de composiciones para controlar hongos nocivos fitopatógenos, caracterizado porque se mezcla una combinación de compuestos activos de acuerdo con una cualquiera de las reivindicaciones 1 a 5 con diluyentes y/o agentes surfactantes. Reivindicación 10: El uso de una combinación de compuestos activos de acuerdo con una cualquiera de las reivindicaciones 1 a 5 para el control de hongos nocivos fitopatógenos. Reivindicación 11: El uso de una combinación de compuestos activos de acuerdo con una cualquiera de las reivindicaciones 1 a 5 para el tratamiento de plantas transgénicas.
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