AR056882A1 - Derivados del fungicida n- cicloalquil- bencil- amida - Google Patents

Derivados del fungicida n- cicloalquil- bencil- amida

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Publication number
AR056882A1
AR056882A1 ARP060104983A ARP060104983A AR056882A1 AR 056882 A1 AR056882 A1 AR 056882A1 AR P060104983 A ARP060104983 A AR P060104983A AR P060104983 A ARP060104983 A AR P060104983A AR 056882 A1 AR056882 A1 AR 056882A1
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Argentina
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alkyl
different
same
halogen atoms
substituted
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Bayer Cropscience Sa
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D333/38—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00—Drugs for dermatological disorders
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
    • A61P31/10—Antimycotics
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/90—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/04—1,2,3-Triazoles; Hydrogenated 1,2,3-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D261/00—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
    • C07D261/02—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
    • C07D261/06—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
    • C07D261/10—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D261/18—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
    • C07D263/30—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D263/34—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D275/00—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings
    • C07D275/02—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings not condensed with other rings
    • C07D275/03—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D277/56—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D285/00—Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
    • C07D285/01—Five-membered rings
    • C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
    • C07D285/04—Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
    • C07D285/06—1,2,3-Thiadiazoles; Hydrogenated 1,2,3-thiadiazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen

Abstract

Derivados de N-cicloalquil-bencil-amida, su procedimiento de preparacion, a su utilizacion como agentes activos fungicidas, particularmente en forma de composiciones fungicidas, y a los métodos para el control de hongos fitopatogenos, especialmente plantas, utilizando estos compuestos o composiciones. Reivindicacion 1: Un compuesto de formula (1), en el que A representa un grupo heterociclilo de 5 elementos insaturado, unido por carbo, que puede estar sustituido por hasta cuatro grupos R; Z1 representa un cicloalquilo C3-7 no sustituido o un cicloalquilo C3-7 sustituido por hasta 10 átomos o grupos que pueden ser iguales o diferentes y que pueden seleccionarse de la lista consistente en átomos de halogeno; ciano; alquilo C1-8 halogenoalquilo C1-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alcoxi C1-8, halogenoalcoxi C1-8, que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alcoxi C1-8-carbonilo; halogenoalcoxi C1-8-carbonilo que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquil C1-8-aminocarbonilo; di-alquil C1-8-aminocarbonilo; Z2 y Z3, que pueden ser iguales o diferentes, representan un átomo de hidrogeno; alquilo C1-8, alquenilo C2-8; alquinilo C2-8, ciano; nitro; un átomo de halogeno; alcoxi C1-8; alqueniloxi C2-8, alquiniloxi C2-8, cicloalquilo C3-7, alquilsulfenilo C1-8; amino; alquil C1-8-amino; dialquil C1-8-amino; alcoxi C1-8-carbonilo; alquilcarbamoilo C1- 8; di-alquilcarbamoilo C1-8; N-alquil C1-8-alcoxi C1-8-carbamoilo; o Z2 y Z3 junto con el átomo de carbono al que están unidos pueden formar un cicloalquilo C3-7 sustituido o no sustituido; X, que puede ser igual o diferente, representa un átomo de halogeno; nitro; ciano; hidroxilo; sulfanilo; amino; pentafluoro-l6-sulfanilo ; alquilo C1-8; halogenoalquilo C1-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquil C1-8-amino; dialquil C1-8-amino; alcoxi C1-8; halogenoalcoxi C1-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; -alcoxi C1-8-alquilo C1-8; alquilsulfanilo C1-8; halogenoalquilsulfanilo C1-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquenilo C2-8; halogenoalquenilo C2-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquinilo C2-8; halogenoalquinilo C2-5 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alqueniloxi C2-8; halogenoalqueniloxi C2-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquiniloxi C2-8; halogenoalquiniloxi C2-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; cicloalquilo C3-7; cicloalquil C3-7-alquilo C1-8; halogenocicloalquilo C3-7 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; formilo; formiloxi; formilamino; carboxi; carbamoilo; N-hidroxicarbamoilo; carbamato; (hidroxiimino)-alquilo C1-8; alquilcarbonilo C1-8; halogenoalquilcarbonilo C1-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquilcarbamoilo G1-8; di-alquilcarbamoilo C1-8; N-alquil C1-8-oxicarbamoilo; alcoxicarbamoilo C1-8; N-alquil C1-8-alcoxi C1-8-carbamoilo; alcoxi C1-8-carbonilo; halogenoalcoxi C1-8-carbonilo que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquil C1-8-aminocarbonilo; di-alquil C1-8- aminocarbonilo; alquil C1-8-carboniloxi; halogenoalquilcarboniloxi C1-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquil C1-8-carbonilamino; halogenoalquilcarbonilamino C1-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquil C1-8-aminocarboniloxi; di-alquil C1-8 aminocarboniloxi; alquiloxicarboniloxi C1-8; alquil C1-8-sulfenilo; halogenoalquil C1-8-sulfenilo que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquil C1-8-sulfinilo; halogenoalquil C1-8-sulfinilo que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquil C1-8-sulfonilo; halogenoalquil C1-8-sulfonilo que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alcoxi C1-8imino; (alcoxi C1-8-imino)-alquilo C1-8; (alquenil C1-8-oxiimino)-alquilo C1-8; (alquiniloxiimino C1-8)-alquilo C1-8, un (benciloxiimino)-alquilo C1-8; tri(alquil C1-8)sililo; tri(alquil C1-8)silil- alquilo C1-8; benciloxi que puede estar sustituido por hasta 5 grupos Q; bencilsulfanilo que puede estar sustituido por hasta 5 grupos Q; bencilamino que puede estar sustituido por hasta 5 grupos Q; naftilo que puede estar sustituido por hasta 6 grupos Q; fenoxi que puede estar sustituido por hasta 5 grupos Q; fenilamino que puede estar sustituido por hasta 5 grupos Q; fenilsulfanilo que puede estar sustituido por hasta 5 grupos Q; fenilmetileno que puede estar sustituido por hasta 5 grupos Q; piridinilo que puede estar sustituido por hasta cuatro grupos Q y piridiniloxi que puede estar sustituido por hasta cuatro grupos Q; dos sustituyentes X junto con los átomos de carbono consecutivos a los que están unidos pueden formar un carbociclo o heterociclo, saturado, de 5 o 6 elementos, que puede estar sustituido por hasta cuatro grupos Q que pueden ser iguales o diferentes; n representa 1, 2, 3, 4 o 5; R, que puede ser igual o diferente, representa un átomo de hidrogeno; un átomo de halogeno; ciano; nitro; amino; sulfanilo; pentafluoro-l6-sulfanilo; alquil C1-8-amino; dialquil C1-8-amino; tri-alquil C1-8-sililo; alquilsulfanilo C1-8 halogenoalquilsulfanilo C1-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquilo C1-8; halogenoalquilo C1-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquenilo C2-8; halogenoalquenilo C2-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquinilo C2-8; halogenoalquinilo C2-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alcoxi C1-8; halogenoalcoxi C1-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alqueniloxi C2-8; alquiniloxi C2-8; cicloalquilo C3-7; cicloalquil C3-7-alquilo C1-8; alquil C1-8-sulfinilo; alquil C1-8-sulfonilo; alcoxi C1-8-imino ; (alcoxi C1-8-imino)-alquilo C1-8; (benciloxiimino)-alquilo C1-8; fenoxi; benciloxi; bencilsulfanilo; bencilamino; naftilo; halogenofenoxi que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alquilcarbonilo C1-8 halogenoalquilcarbonilo C1-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; alcoxi C1-8-carbonilo; halogenoalcoxi C1-8-carbonilo que comprende hasta 9 átomos de halogeno que pueden ser iguale o diferentes; alquil C1-8-aminocarbonilo ; di-alquil C1-8-aminocarbonilo; Q, que puede ser igual o diferente, representa un átomo de halogeno; ciano; nitro; alquilo C1-8; alcoxi C1-8; alquilsulfanilo C1-8; halogenoalquilo C1-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; halogenoalcoxi C1-8 que comprende hasta 9 átomos de halogeno que pueden ser iguales o diferentes; tri-alquil C1-8-sililo y tri-alquil C1-8-sililalquilo C1-8; así como sus sales, N-oxidos, complejos metálicos, complejos metaloides e isomeros opticamente activos o geométricos, con la excepcion de 2- furancarboxamida, N-(1,3-benzodioxol-5-ilmetil)-N-ciclopentil-5-metilo y 2-furancarboxamida, N-(1,3-benzodioxol-5-ilmetil)-N-ciclopentil-2,5-dimetilo.
ARP060104983A 2006-02-01 2006-11-14 Derivados del fungicida n- cicloalquil- bencil- amida AR056882A1 (es)

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US (1) US8088927B2 (es)
EP (2) EP2351747B1 (es)
JP (1) JP5052531B2 (es)
KR (1) KR101312761B1 (es)
CN (1) CN101360730B (es)
AR (1) AR056882A1 (es)
AU (1) AU2006337483B2 (es)
BR (1) BRPI0620513B1 (es)
CA (1) CA2632870C (es)
DK (1) DK2351747T3 (es)
ES (2) ES2405304T3 (es)
PL (2) PL2351747T3 (es)
PT (2) PT2351747E (es)
RU (1) RU2419616C2 (es)
UA (1) UA95796C2 (es)
WO (1) WO2007087906A1 (es)
ZA (1) ZA200805608B (es)

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