AR110803A1 - Estireno funcionalizado con [bis(trihidrocarbilsilil)aminosililo] y un método para su preparación - Google Patents

Estireno funcionalizado con [bis(trihidrocarbilsilil)aminosililo] y un método para su preparación

Info

Publication number
AR110803A1
AR110803A1 ARP170102794A ARP170102794A AR110803A1 AR 110803 A1 AR110803 A1 AR 110803A1 AR P170102794 A ARP170102794 A AR P170102794A AR P170102794 A ARP170102794 A AR P170102794A AR 110803 A1 AR110803 A1 AR 110803A1
Authority
AR
Argentina
Prior art keywords
carbon atoms
group containing
integer
aryl
alkyl group
Prior art date
Application number
ARP170102794A
Other languages
English (en)
Inventor
Jaroslaw Rogoza
Bartlomiej Janowski
Hieronim Maciejewski
Anna Szymanska
Ireneusz Kownacki
Original Assignee
Synthos Sa
Fundacja Univ Im Adama Mickiewicza W Poznaniu
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Synthos Sa, Fundacja Univ Im Adama Mickiewicza W Poznaniu filed Critical Synthos Sa
Publication of AR110803A1 publication Critical patent/AR110803A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by hetero atoms or groups containing heteroatoms
    • C08F12/26—Nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
    • C08F212/26—Nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B49/00—Grignard reactions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)

Abstract

El derivado de estireno funcionalizado con [bis(trihidrocarbilsilil)aminosililo] de la fórmula (1) donde R¹ se selecciona del grupo que consiste en: a) una unión simple; b) -(CH₂)ₙ-, donde n representa un número entero de 1 a 12; c) -(CH₂CH₂Y)ₙ-, donde n representa un número entero de 1 a 12, e Y puede ser independientemente oxígeno o azufre; d) -CH₂-(CH₂CH₂Y)ₙ-CH₂-, donde n representa un número entero de 1 a 12, e Y puede ser independientemente oxígeno o azufre; e) -(CH₂CH₂NR)ₙ-, donde n representa un número entero de 1 a 12, y R puede representar independientemente un grupo alquilo que contiene de 1 a 10 átomos de carbono, o un grupo arilo o aralquilo que contiene de 6 a 10 átomos de carbono; f) -CH₂-(CH₂CH₂NR)ₙ-CH₂-, donde n representa un número entero de 1 a 12, y R puede representar independientemente un grupo alquilo que contiene de 1 a 10 átomos de carbono, o un grupo arilo o aralquilo que contiene de 6 a 10 átomos de carbono; R², R³ pueden ser iguales o diferentes y representan un grupo alquilo que contiene de 1 a 10 átomos de carbono, o un grupo arilo o aralquilo que contiene de 6 a 10 átomos de carbono; y R⁴ y R⁵ pueden ser iguales o diferentes y cada R⁴ y R⁵ representa un grupo alquilo que contiene de 1 a 10 átomos de carbono, o un grupo arilo o aralquilo que contiene de 6 a 10 átomos de carbono. El derivado de estireno se usa preferentemente como comonómero en la producción de copolímeros elastoméricos. Alternativamente, o en forma adicional, se usa en la preparación de un iniciador de polimerización.
ARP170102794A 2016-10-06 2017-10-06 Estireno funcionalizado con [bis(trihidrocarbilsilil)aminosililo] y un método para su preparación AR110803A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP16461559 2016-10-06

Publications (1)

Publication Number Publication Date
AR110803A1 true AR110803A1 (es) 2019-05-08

Family

ID=57113237

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP170102794A AR110803A1 (es) 2016-10-06 2017-10-06 Estireno funcionalizado con [bis(trihidrocarbilsilil)aminosililo] y un método para su preparación

Country Status (19)

Country Link
US (1) US10723822B2 (es)
EP (1) EP3341423B1 (es)
JP (1) JP6811250B2 (es)
KR (1) KR102205884B1 (es)
CN (1) CN108699182B (es)
AR (1) AR110803A1 (es)
BR (1) BR112018016199A2 (es)
CA (1) CA3011779A1 (es)
DK (1) DK3341423T3 (es)
EA (1) EA036907B1 (es)
ES (1) ES2714552T3 (es)
HK (1) HK1257706B (es)
HU (1) HUE043533T2 (es)
MX (1) MX2018009323A (es)
PL (1) PL3341423T3 (es)
RS (1) RS58542B1 (es)
SG (1) SG11201810786RA (es)
TR (1) TR201903646T4 (es)
WO (1) WO2018065486A1 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016162473A1 (en) 2015-04-10 2016-10-13 Synthos S.A. [bis(trihydrocarbylsilyl)aminosilyl]-functionalized styrene and a method for its preparation
MX2017013010A (es) 2015-04-10 2018-04-24 Synthos Sa Iniciadores para la copolimerizacion de monomeros de dieno y monomeros aromaticos de vinilo.
PL3341424T3 (pl) 2016-10-06 2019-09-30 Synthos Dwory 7 spółka z ograniczoną odpowiedzialnością spółka jawna Kopolimery elastomerowe na bazie [bis(trihydrokarbylosililo)aminosililo]- funkcjonalizowanego styrenu i ich zastosowanie do wytwarzania kauczuków
JP6811250B2 (ja) 2016-10-06 2021-01-13 シントス ドボリ ７ スプウカ ズ オグラニザツィーノン オトゥポビエジャルノシチョン スプウカ ヤフナＳｙｎｔｈｏｓ Ｄｗｏｒｙ ７ Ｓｐｏｌｋａ Ｚ Ｏｇｒａｎｉｃｚｏｎａ Ｏｄｐｏｗｉｅｄｚｉａｌｎｏｓｃｉａ Ｓｐｏｌｋａ Ｊａｗｎａ ［ビス（トリヒドロカルビルシリル）アミノシリル］−官能化スチレンおよびその調製方法
US11312843B2 (en) 2017-08-08 2022-04-26 Synthos Dwory 7 Spolka Z Ograniczona Odpowiedzialnoscia Spolka Jawna Bissilylaminosilyl-functionalized conjugated dienes and their use in the production of rubbers
JP7358378B2 (ja) * 2018-04-11 2023-10-10 シントス エス．アー． アミノシリル官能化スチレンの混合物、それらの調製及びエラストマーコポリマーの製造におけるそれらの使用
US11118050B2 (en) 2018-12-07 2021-09-14 The Goodyear Tire & Rubber Company Functionalized polymer, rubber composition and pneumatic tire
US11117997B2 (en) 2018-12-07 2021-09-14 The Goodyear Tire & Rubber Company Functionalized polymer, rubber composition and pneumatic tire

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH415623A (de) 1960-11-11 1966-06-30 Monsanto Co Verfahren zur Herstellung von Stickstoff-Silicium-Verbindungen
US3109871A (en) 1960-12-27 1963-11-05 Phillips Petroleum Co Production and curing of polyfunctional terminally reactive polymers
US4196154A (en) 1977-10-11 1980-04-01 The Dow Chemical Company Soluble multifunctional lithium containing initiator
JPS63118343A (ja) 1986-11-07 1988-05-23 Japan Synthetic Rubber Co Ltd 共役ジエン系ゴム組成物
JPH0778151B2 (ja) * 1987-07-17 1995-08-23 日本合成ゴム株式会社 ゴム組成物
DE3729144A1 (de) 1987-09-01 1989-03-09 Basf Ag Bifunktionelle alkaliverbindungen, verfahren zu ihrer herstellung und verwendung als polymerisationsinitiatoren
US4935471A (en) 1987-10-15 1990-06-19 The Goodyear Tire & Rubber Company Capped polydienes
US5329005A (en) 1992-10-02 1994-07-12 Bridgestone Corporation Soluble anionic polymerization initiators and preparation thereof
JP3378313B2 (ja) 1993-09-10 2003-02-17 株式会社ブリヂストン ゴム組成物
US5527753A (en) 1994-12-13 1996-06-18 Fmc Corporation Functionalized amine initiators for anionic polymerization
JP3641868B2 (ja) 1996-02-23 2005-04-27 Ｊｓｒ株式会社 ジオレフィン系（共）重合体の製造方法
JP2000086727A (ja) 1998-09-15 2000-03-28 Agency Of Ind Science & Technol カップリング型ブタジエン系重合体、および、カップリング型共役ジエン系重合体の製造方法
US6627722B2 (en) 2000-12-05 2003-09-30 Stephan Rodewald Functionalized elastomers
US6627721B1 (en) 2002-09-19 2003-09-30 The Goodyear Tire & Rubber Company Functionalized elastomers
US6515087B2 (en) 2000-12-14 2003-02-04 The Goodyear Tire & Rubber Company Synthesis of elastomers having low hysteresis
JP2004059781A (ja) * 2002-07-30 2004-02-26 Jsr Corp ブロック共重合体及び該共重合体を含有するアスファルト組成物
US6933358B2 (en) 2002-08-16 2005-08-23 The Goodyear Tire & Rubber Company Functionalized monomers for synthesis of rubbery polymers
US6753447B2 (en) 2002-08-16 2004-06-22 The Goodyear Tire & Rubber Company Functionalized monomers for synthesis of rubbery polymers
US6825306B2 (en) 2002-08-16 2004-11-30 The Goodyear Tire & Rubber Company Functionalized monomers for synthesis of rubbery polymers
JP4302547B2 (ja) 2004-02-18 2009-07-29 株式会社ブリヂストン 変性天然ゴムラテックス、変性天然ゴム及びそれらの製造方法
WO2006016480A1 (ja) * 2004-08-10 2006-02-16 Jsr Corporation 樹脂組成物及びその成形品
BRPI0604797A (pt) * 2005-11-30 2007-10-09 Goodyear Tire & Rubber polìmeros de borracha funcionalizados
JPWO2009133888A1 (ja) 2008-04-30 2011-09-01 株式会社ブリヂストン 変性共役ジエン系共重合体の製造方法、その方法により得られた変性共役ジエン系共重合体、ゴム組成物及びタイヤ
JP5466474B2 (ja) 2008-10-16 2014-04-09 住友ゴム工業株式会社 ゴム組成物およびそれを用いたタイヤ
CN101724184B (zh) 2008-10-29 2013-05-01 住友橡胶工业株式会社 橡胶组合物及轮胎
US20100116404A1 (en) 2008-11-11 2010-05-13 Annette Lechtenboehmer Tire with component containing polyketone short fiber and functionalized elastomer
US20100152364A1 (en) 2008-12-12 2010-06-17 The Goodyear Tire & Rubber Company Polymers, rubber compositions, and tires
US20100190885A1 (en) 2009-01-29 2010-07-29 Kuo-Chih Hua Tire with rubber component containing silica and use of combination of blocked and unblocked alkoxyorganomercaptosilane coupling agents
JP5324384B2 (ja) 2009-10-05 2013-10-23 住友ゴム工業株式会社 重合体、タイヤ用ゴム組成物及び空気入りタイヤ
WO2011076377A1 (en) 2009-12-21 2011-06-30 Styron Europe Gmbh Modified polymer compositions
JP2011252137A (ja) 2010-05-06 2011-12-15 Sumitomo Chemical Co Ltd 共役ジエン系重合体、共役ジエン系重合体組成物、及び、共役ジエン系重合体の製造方法
DE102011109823B4 (de) * 2010-08-11 2023-10-12 Sumitomo Chemical Company, Limited Polymer auf Basis von konjugiertem Dien, Polymerzusammensetzung auf Basis von konjugiertem Dien und Verfahren zur Herstellung von Polymer auf Basis von konjugiertem Dien
US8334339B2 (en) 2010-08-11 2012-12-18 Sumitomo Chemical Co., Ltd. Conjugated diene-based polymer, conjugated diene-based polymer composition, and process for producing conjugated diene-based polymer
CN103764682B (zh) 2011-08-26 2016-01-20 旭化成化学株式会社 改性共轭二烯系聚合物的制造方法、改性共轭二烯系聚合物、改性共轭二烯系聚合物组合物、橡胶组合物和轮胎
US9120890B2 (en) 2011-11-24 2015-09-01 Sumitomo Rubber Industries, Ltd. Rubber composition and pneumatic tire
JP5864288B2 (ja) 2012-01-27 2016-02-17 住友ゴム工業株式会社 ゴム組成物及び空気入りタイヤ
JP6062662B2 (ja) 2012-06-01 2017-01-18 住友ゴム工業株式会社 共重合体、ゴム組成物及び空気入りタイヤ
JP5529930B2 (ja) 2012-06-18 2014-06-25 住友ゴム工業株式会社 トレッド用ゴム組成物及び空気入りタイヤ
JP2014105241A (ja) 2012-11-26 2014-06-09 Sumitomo Rubber Ind Ltd トレッド用ゴム組成物及び空気入りタイヤ
PL3169712T3 (pl) 2014-07-14 2019-04-30 Trinseo Europe Gmbh Związki diaryloetenowe podstawione grupą aminosilylową do polimeryzacji anionowej
DK3280766T3 (en) 2015-04-10 2018-10-29 Synthos Sa Elastomeric copolymers based on [bis (trihydrocarbylsilyl) aminosilyl] functionalized styrene and their use in the production of rubber
MX2017013010A (es) 2015-04-10 2018-04-24 Synthos Sa Iniciadores para la copolimerizacion de monomeros de dieno y monomeros aromaticos de vinilo.
WO2016162473A1 (en) 2015-04-10 2016-10-13 Synthos S.A. [bis(trihydrocarbylsilyl)aminosilyl]-functionalized styrene and a method for its preparation
JP6811250B2 (ja) 2016-10-06 2021-01-13 シントス ドボリ ７ スプウカ ズ オグラニザツィーノン オトゥポビエジャルノシチョン スプウカ ヤフナＳｙｎｔｈｏｓ Ｄｗｏｒｙ ７ Ｓｐｏｌｋａ Ｚ Ｏｇｒａｎｉｃｚｏｎａ Ｏｄｐｏｗｉｅｄｚｉａｌｎｏｓｃｉａ Ｓｐｏｌｋａ Ｊａｗｎａ ［ビス（トリヒドロカルビルシリル）アミノシリル］−官能化スチレンおよびその調製方法
PL3341424T3 (pl) 2016-10-06 2019-09-30 Synthos Dwory 7 spółka z ograniczoną odpowiedzialnością spółka jawna Kopolimery elastomerowe na bazie [bis(trihydrokarbylosililo)aminosililo]- funkcjonalizowanego styrenu i ich zastosowanie do wytwarzania kauczuków

Also Published As

Publication number Publication date
TR201903646T4 (tr) 2019-04-22
CA3011779A1 (en) 2018-04-12
CN108699182B (zh) 2020-07-24
CN108699182A (zh) 2018-10-23
KR102205884B1 (ko) 2021-01-25
HK1257706B (zh) 2020-07-10
EP3341423B1 (en) 2018-12-12
HUE043533T2 (hu) 2019-08-28
EA201891740A1 (ru) 2019-01-31
KR20180135883A (ko) 2018-12-21
SG11201810786RA (en) 2018-12-28
JP6811250B2 (ja) 2021-01-13
DK3341423T3 (en) 2019-04-01
MX2018009323A (es) 2018-11-09
US10723822B2 (en) 2020-07-28
EP3341423A1 (en) 2018-07-04
JP2019521951A (ja) 2019-08-08
ES2714552T3 (es) 2019-05-29
BR112018016199A2 (pt) 2019-04-24
RS58542B1 (sr) 2019-04-30
EA036907B1 (ru) 2021-01-13
PL3341423T3 (pl) 2019-07-31
US20190256624A1 (en) 2019-08-22
WO2018065486A1 (en) 2018-04-12

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