AR087515A1 - Compuestos de n-tio-antranilamida y sus usos como plaguicidas - Google Patents
Compuestos de n-tio-antranilamida y sus usos como plaguicidasInfo
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- AR087515A1 AR087515A1 ARP120102938A ARP120102938A AR087515A1 AR 087515 A1 AR087515 A1 AR 087515A1 AR P120102938 A ARP120102938 A AR P120102938A AR P120102938 A ARP120102938 A AR P120102938A AR 087515 A1 AR087515 A1 AR 087515A1
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- A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/16—Amides, e.g. hydroxamic acids
- A61K31/165—Amides, e.g. hydroxamic acids having aromatic rings, e.g. colchicine, atenolol, progabide
- A61K31/166—Amides, e.g. hydroxamic acids having aromatic rings, e.g. colchicine, atenolol, progabide having the carbon of a carboxamide group directly attached to the aromatic ring, e.g. procainamide, procarbazine, metoclopramide, labetalol
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- A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
- A61K31/435—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with one nitrogen as the only ring hetero atom
- A61K31/44—Non condensed pyridines; Hydrogenated derivatives thereof
- A61K31/4418—Non condensed pyridines; Hydrogenated derivatives thereof having a carbocyclic group directly attached to the heterocyclic ring, e.g. cyproheptadine
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- A61K31/44—Non condensed pyridines; Hydrogenated derivatives thereof
- A61K31/4427—Non condensed pyridines; Hydrogenated derivatives thereof containing further heterocyclic ring systems
- A61K31/444—Non condensed pyridines; Hydrogenated derivatives thereof containing further heterocyclic ring systems containing a six-membered ring with nitrogen as a ring heteroatom, e.g. amrinone
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- A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
- A61K31/495—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with two or more nitrogen atoms as the only ring heteroatoms, e.g. piperazine or tetrazines
- A61K31/505—Pyrimidines; Hydrogenated pyrimidines, e.g. trimethoprim
- A61K31/506—Pyrimidines; Hydrogenated pyrimidines, e.g. trimethoprim not condensed and containing further heterocyclic rings
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- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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Abstract
Compuestos de N-tio-antranilamida y los estereoisómeros, las sales, los tautómeros y los N-óxidos de estos, y las composiciones que los comprenden. También, uso de los compuestos de N-tio-antranilamida o de las composiciones que comprenden tales compuestos para combatir las plagas de invertebrados. Además, métodos para aplicar dichos compuestos.Reivindicación 1: Un compuesto de la fórmula general (1) en donde A1, A2, A3 y A4 son N o CH, siempre que, como máximo, dos de A1, A2, A3 y A4 sean N; B1 es N o CH; cada R1 se selecciona independientemente del grupo que consiste en halógeno; ciano; azido; nitro; -SCN; SF5; alquilo C1-6 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7; cicloalquilo C3-8 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7; alquenilo C2-6 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7; alquinilo C2-6 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7; -Si(R14)2R13; -OR8; -OS(O)nR8; -SR8; -S(O)mR8; -S(O)nN(R9a)R9b; -N(R9a)R9b; -N(R9a)C(=O)R7; -C(=O)R7; -C(=O)OR8; -C(=NR9a)R7; -C(=O)N(R9a)R9b; -C(=S)N(R9a)R9b; fenilo que se puede sustituir con 1, 2, 3, 4 ó 5 radicales R10; y un anillo heterocíclico saturado, parcial o totalmente insaturado de 3, 4, 5, 6 ó 7 miembros que contiene 1, 2 ó 3 heteroátomos o grupos de heteroátomos seleccionados de N, O, S, NO, SO y SO2, como miembros del anillo, en donde el anillo heterocíclico se puede sustituir con uno o más radicales R10; o dos radicales R1 unidos en átomos de carbono adyacentes pueden ser, en forma conjunta, un grupo seleccionado de -CH2CH2CH2CH2-, -CH=CH-CH=CH-, -N=CH-CH=CH-, -CH=N-CH=CH-, -N=CH-N=CH-, -OCH2CH2CH2-, -OCH=CHCH2-, -CH2OCH2CH2-, -OCH2CH2O-, -OCH2OCH2-, -CH2CH2CH2-, -CH=CHCH2-, -CH2CH2O-, -CH=CHO-, -CH2OCH2-, -CH2C(=O)O-, -C(=O)OCH2-, -O(CH2)O-, -SCH2CH2CH2-, -SCH=CHCH2-, -CH2SCH2CH2-, -SCH2CH2S-, -SCH2SCH2-, -CH2CH2S-, -CH=CHS-, -CH2SCH2-, -CH2C(=S)S-, -C(=S)SCH2-, -S(CH2)S-, -CH2CH2NR18-, -CH2CH=N-, -CH=CH-NR18-, -OCH=N- y -SCH=N-, para así formar, junto con los átomos de carbono a los que están unidos, un anillo de 5 ó 6 miembros, en donde los átomos de hidrógeno de los grupos anteriores se pueden reemplazar por uno o más sustituyentes seleccionados de halógeno, metilo, halometilo, hidroxilo, metoxi y halometoxi, o uno o más grupos CH2 de los grupos anteriores se pueden reemplazar por un grupo C=O; R2 se selecciona del grupo que consiste en hidrógeno; ciano; alquilo C1-10 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7; cicloalquilo C3-8 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7; alquenilo C2-10 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7; alquinilo C2-10 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7; -N(R9a)R9b; -Si(R14)2R13; -OR8; -SR8; -S(O)mR8; -S(O)nN(R9a)R9; -C(=O)R7; -C(=O)OR8; -C(=O)N(R9a)R9b; -C(=S)R7; -C(=S)OR8; -C(=S)N(R9a)R9b; -C(=NR9a)R7; fenilo que se puede sustituir con 1, 2, 3, 4 ó 5 radicales R10; y un anillo heterocíclico saturado, parcial o totalmente insaturado de 3, 4, 5, 6 ó 7 miembros que contiene 1, 2 ó 3 heteroátomos o grupos de heteroátomos seleccionados de N, O, S, NO, SO y SO2, como miembros del anillo, en donde el anillo heterocíclico se puede sustituir con uno o más radicales R10; cada R3 se selecciona independientemente del grupo que consiste en halógeno, ciano, azido, nitro, -SCN, SF5, alquilo C1-6 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7, cicloalquilo C3-8 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7, alquenilo C2-6 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7, alquinilo C2-6 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7, -Si(R14)2R13, -OR8, -OS(O)nR8, -SR8, -S(O)mR8, -S(O)nN(R9a)R9b, -N(R9a)R9b, -N(R9a)C(=O)R7, -C(=O)R7, -C(=O)OR8, -C(=S)R7, -C(=S)OR8, -C(=NR9a)R7, -C(=O)N(R9a)R9b, -C(=S)N(R9a)R9b, fenilo que se puede sustituir con 1, 2, 3, 4 ó 5 radicales R10, y un anillo heterocíclico saturado, parcial o totalmente insaturado de 3, 4, 5, 6 ó 7 miembros que contiene 1, 2 ó 3 heteroátomos o grupos de heteroátomos seleccionados de N, O, S, NO, SO y SO2, como miembros del anillo, en donde el anillo heterocíclico se puede sustituir con uno o más radicales R10; cada R4 se selecciona independientemente del grupo definido para R3; R5, R6 se seleccionan, independientemente entre sí, del grupo que consiste en alquilo C1-6 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7, alquenilo C2-6 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7, alquinilo C2-6 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R7, R7, -C(=G)R7, -C(=NOR8)R7, C[=NN(R9a)R9b]R7, -C(=G)OR8, -C(=G)N(R9a)R9b, -OC(=G)R7, -OC(=G)OR8, -NR9aC(=G)R7, -N[C(=G)R7]2, -NR9aC(=G)OR8, -C(=G)N(R9a)-N(R9b)2, -C(=G)NR9a-NR9b[C(=G)R7], -NR9a-C(=G)N(R9b)2, -NR9aNR9bC(=G)R7, -NR9a-N[C(=G)R7]2, -N[(C=G)R7]-N(R9a)2 -NR9a-NR9b[(C=G)GR8], -NR9a[(C=G)N(R9b)2], -NR9a[C=NR9b]R7, -NR9a(C=NR9b)N(R9b)2, -O-N(R9a)2, -O-NR9a(C=G)R7, -SO2NR9aR9b, -NR9aSO2R8, -SO2OR8, -OSO2R8, -OR8, -NR9aR9b, -SR8, -Si(R14)2R13, -PR9aR9b, -P(=G)R9a, -SOR8, -SO2R8, -PG2(R9a)2 y -PG3R72; en donde G es O, S o NR9a; o R5 y R6 junto con el átomo de azufre al que están unidos, forman un anillo saturado, parcial o totalmente insaturado de 3, 4, 5, 6, 7 u 8 miembros que contiene, de manera opcional, 1, 2, 3 ó 4 heteroátomos o grupos de heteroátomos seleccionados de N, O, S, NO, SO y SO2 como miembros del anillo, en donde el anillo puede estar fusionado con uno o dos anillos carbocíclicos o heterocíclicos saturados, parcial o totalmente insaturados de 5 ó 6 miembros que pueden contener 1, 2, 3 ó 4 heteroátomos o grupos de heteroátomos seleccionados de N, O, S, NO, SO y SO2, como miembros del anillo, en donde todos los anillos anteriores son no sustituidos o sustituidos mediante cualquier combinación de 1, 2, 3, 4, 5 ó 6 radicales R10; cada R7 se selecciona independientemente del grupo que consiste en ciano, azido, nitro, -SCN, SF5, cicloalquilo C3-8, halocicloalquilo C3-8, -Si(R14)2R13, -OR8, -OSO2R8, -SR8, -S(O)mR8, -S(O)nN(R9a)R9b, -N(R9a)R9b, -C(=O)N(R9a)R9b, -C(=S)N(R9a)R9b, -C(=O)OR8, -C(=O)R19, fenilo que se puede sustituir con 1, 2, 3, 4 ó 5 radicales R10, y un anillo heterocíclico saturado, parcial o totalmente insaturado de 3, 4, 5, 6 ó 7 miembros que contiene 1, 2 ó 3 heteroátomos o grupos de heteroátomos seleccionados de N, O, S, NO, SO y SO2, como miembros del anillo, en donde el anillo heterocíclico se puede sustituir con uno o más radicales R10; y, en caso de que R7 se una a un grupo cicloalquilo o a un anillo heterocíclico, R7 también se puede seleccionar del grupo que consiste en alquilo C1-6, haloalquilo C1-6, alcoxi C1-6-alquilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6, haloalquinilo C2-6 y bencilo que se puede sustituir con 1, 2, 3, 4 ó 5 radicales R10; y en grupos -C(=O)R7, -C(=S)R7, -C(=NR9a)R7, -N(R9a)C(=O)R7, -C(=G)R7, -C(=NOR8)R7, -C[=NN(R9a)R9b]R7, -OC(=G)R7, -NR9aC(=G)R7, -N[C(=G)R7]2, -C(=G)NR9a-NR9b[C(=G)R7], -NR9a-NR9bC(=G)R7, -NR9a-N[C(=G)R7]2, -N[(C=G)R7]-N(R9a)2, -NR9a[C=NR9b]R7, -O-NR9a(C=G)R7 y -PG3R72, R7 también se puede seleccionar de hidrógeno, halógeno, alquilo C1-6, haloalquilo C1-6, alcoxi C1-6-alquilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6, haloalquinilo C2-6 y bencilo que se puede sustituir con 1, 2, 3, 4 ó 5 radicales R10; o dos radicales R7 unidos de manera geminal forman junto un grupo seleccionado de =CR11R12, =S(O)mR8, =S(O)mN(R9a)R9b, =NR9a, =NOR8 y =NNR9aR9b; o dos radicales R7, junto con los átomos de carbono a los que están unidos, forman un anillo carbocíclico o heterocíclico de 3, 4, 5, 6, 7 u 8 miembros, saturado o parcialmente insaturado que contiene 1, 2 ó 3 heteroátomos o grupos de heteroátomos seleccionados de N, O, S, NO, SO y SO2, como miembros del anillo; cada R8 se selecciona independientemente del grupo que consiste en hidrógeno, ciano, alquilo C1-6, haloalquilo C1-6, alcoxi C1-6, haloalcoxi C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6, haloalquilsulfonilo C1-6, cicloalquilo C3-8, cicloalquil C3-8-alquilo C1-4, halocicloalquilo C3-8, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6, haloalquinilo C2-6, -Si(R14)2R13, -SR20, -S(O)mR20, -S(O)nN(R9a)R9b, -N(R9a)R9b, -N=CR15R16, -C(=O)R19, -C(=O)N(R9a)R9b, -C(=S)N(R9a)R9b, -C(=O)OR20, fenilo que se puede sustituir con 1, 2, 3, 4 ó 5 radicales R10, y un anillo heterocíclico saturado, parcial o totalmente insaturado de 3, 4, 5, 6 ó 7 miembros que contiene 1, 2 ó 3 heteroátomos o grupos de heteroátomos seleccionados de N, O, S, NO, SO y SO2, como miembros del anillo, en donde el anillo heterocíclico se puede sustituir con uno o más radicales R10; siempre que R8 no sea alcoxi C1-6 ni haloalcoxi C1-6 si se une en un átomo de oxígeno; R9a, R9b se seleccionan, independientemente entre sí e independientemente en cada caso, del grupo que consiste en hidrógeno, ciano, alquilo C1-6 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R19, alcoxi C1-6, haloalcoxi C1-6, alquiltio C1-6, haloalquiltio C1-6, en donde la porción alquilo en los cuatro últimos radicales mencionados se puede sustituir con uno o más radicales R19, cicloalquilo C3-8 que puede ser parcial o totalmente halogenado y/o se puede sustituir con uno o más radicales R19, cicloalquil C3-8-alquilo C1-4 que puede ser parcial o totalmente halogenado y/o se puede sustituir con
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WO2007020877A1 (ja) * | 2005-08-12 | 2007-02-22 | Ishihara Sangyo Kaisha, Ltd. | アントラニルアミド系化合物、それらの製造方法及びそれらを含有する有害生物防除剤 |
BRPI0617076B1 (pt) | 2005-09-02 | 2021-07-06 | Nissan Chemical Corporation | Composto benzamida substituída por isoxazolina da fórmula (1) ou sal do mesmo; composto benzamida substituido por 4-hidroxiiminametila da fórmula (2) ou sal do mesmo; pesticida; agente agroquímico; parasiticida interno ou externo para mamíferos ou aves; inseticida ou acaricida |
CA2623202C (en) | 2005-10-14 | 2014-09-16 | Sumitomo Chemical Company, Limited | Hydrazide compound and pesticidal use of the same |
AU2006317486B9 (en) | 2005-11-22 | 2011-08-04 | Sumitomo Chemical Company, Limited | Organic sulfur compounds and use thereof as arthropodicides |
TWI412322B (zh) | 2005-12-30 | 2013-10-21 | Du Pont | 控制無脊椎害蟲之異唑啉 |
DE102006015197A1 (de) | 2006-03-06 | 2007-09-13 | Bayer Cropscience Ag | Wirkstoffkombination mit insektiziden Eigenschaften |
DE102006015467A1 (de) | 2006-03-31 | 2007-10-04 | Bayer Cropscience Ag | Substituierte Enaminocarbonylverbindungen |
JP5269609B2 (ja) | 2006-11-30 | 2013-08-21 | Meiji Seikaファルマ株式会社 | 害虫防除剤 |
JP5449669B2 (ja) | 2006-12-14 | 2014-03-19 | 石原産業株式会社 | 有害生物防除組成物 |
JP2009001541A (ja) | 2006-12-15 | 2009-01-08 | Ishihara Sangyo Kaisha Ltd | 新規ピラゾール化合物を中間体として用いるアントラニルアミド系化合物の製造方法 |
CN103535360B (zh) | 2007-03-08 | 2016-06-22 | 明治制果药业株式会社 | 害虫防治组合物 |
JP2008115155A (ja) | 2007-04-06 | 2008-05-22 | Nippon Soda Co Ltd | 有害生物防除剤組成物及び有害生物防除方法 |
JP2008260716A (ja) * | 2007-04-12 | 2008-10-30 | Sumitomo Chemical Co Ltd | ヒドラジド化合物及びそれを含有する有害節足動物防除剤 |
WO2009051956A2 (en) | 2007-10-16 | 2009-04-23 | E. I. Du Pont De Nemours And Company | Pyrazole-substituted isoxazoline insecticides |
TWI432421B (zh) | 2007-12-19 | 2014-04-01 | Du Pont | 製備2-胺基-5-氰基苯甲酸衍生物之方法 |
TW201444787A (zh) | 2008-04-09 | 2014-12-01 | Du Pont | 製備3-三氟甲基查耳酮(chalcone)之方法 |
CN102325758A (zh) * | 2008-12-23 | 2012-01-18 | 巴斯夫欧洲公司 | 用于防治无脊椎动物害虫的亚胺化合物 |
-
2012
- 2012-08-10 BR BR112014003221A patent/BR112014003221A2/pt not_active IP Right Cessation
- 2012-08-10 JP JP2014524388A patent/JP2014522872A/ja active Pending
- 2012-08-10 AR ARP120102938A patent/AR087515A1/es not_active Application Discontinuation
- 2012-08-10 CN CN201280047330.5A patent/CN103889955A/zh active Pending
- 2012-08-10 EP EP12748013.5A patent/EP2742023A1/en not_active Withdrawn
- 2012-08-10 WO PCT/EP2012/065644 patent/WO2013024003A1/en active Application Filing
- 2012-08-10 US US14/237,052 patent/US20140243195A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
JP2014522872A (ja) | 2014-09-08 |
EP2742023A1 (en) | 2014-06-18 |
WO2013024003A1 (en) | 2013-02-21 |
CN103889955A (zh) | 2014-06-25 |
US20140243195A1 (en) | 2014-08-28 |
BR112014003221A2 (pt) | 2017-04-18 |
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