AR085428A1 - (3r,4r)-4-ciano-3,4-difenilbutanoatos sustituidos, procedimiento para su preparacion y su uso como herbicidas y reguladores de crecimiento de plantas - Google Patents

(3r,4r)-4-ciano-3,4-difenilbutanoatos sustituidos, procedimiento para su preparacion y su uso como herbicidas y reguladores de crecimiento de plantas

Info

Publication number
AR085428A1
AR085428A1 ARP120100878A ARP120100878A AR085428A1 AR 085428 A1 AR085428 A1 AR 085428A1 AR P120100878 A ARP120100878 A AR P120100878A AR P120100878 A ARP120100878 A AR P120100878A AR 085428 A1 AR085428 A1 AR 085428A1
Authority
AR
Argentina
Prior art keywords
alkyl
group
case
haloalkoxy
haloalkyl
Prior art date
Application number
ARP120100878A
Other languages
English (en)
Inventor
Jakobi Harald Dr
Mosrin Marc Dr
Gatzweiler Elmar Dr
Huser-Hahn Isolde Dr
Heinemann Ines Dr
Rosinger Christopher Hugh Dr
Angermann Alfred Dr
Hoffmann Michael Gerhard Dr
Schnatterer Stefan Dr
Zei Hans-Joachim Dr
Original Assignee
Bayer Cropscience Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Cropscience Ag filed Critical Bayer Cropscience Ag
Publication of AR085428A1 publication Critical patent/AR085428A1/es

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/20—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom three- or four-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34—Nitriles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/48—Nitro-carboxylic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10—Sulfones; Sulfoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/41—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by carboxyl groups, other than cyano groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/57—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and carboxyl groups, other than cyano groups, bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/10—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C323/11—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/12—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Epoxy Compounds (AREA)

Abstract

Resultan apropiados como herbicidas y reguladores del crecimiento, especialmente para el uso selectivo en cultivos de plantas y se provee además un método para su preparación.Reivindicación 1: Compuestos de la fórmula (1) o sus sales, en cada caso en la forma ópticamente activa (3R,4R)-treo, en la que R1 significa hidrógeno o un resto hidrolizable; (R2)n significa n sustituyentes R2, significando R2 (cuando n = 1) o cada uno de los sustituyentes R2 (cuando n es mayor que 1) independientemente entre sí halógeno, ciano, nitro, alquilo C1-8, alcoxi C1-8, alquiltio C1-8, alquilsulfinilo C1-8, alquilsulfonilo C1-8, haloalquilo C1-6, haloalcoxi C1-6, haloalquiltio C1-6, haloalquilsulfinilo C1-6, haloalquilsulfonilo C1-6, alquenilo C2-6, alquinilo C2-6, tri-[alquil-C1-4]-sililo o tri [alquil-C1-4]-silil-alquilo C1-4 o significando en cada caso dos grupos R2 ubicados en posiciones orto en el anillo junto con un grupo de la fórmula Z1-A*-Z2, en el cual A* representa un grupo alquileno con 1 a 4 átomos de carbono, que está dado el caso sustituido con uno o varios restos del grupo de halógeno, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4 y haloalcoxi C1-4, Z1 representa un enlace directo, O ó S y Z2 representa un enlace directo, O ó S, formando el grupo Z1-A*-Z2 junto con los átomos de carbono del anillo fenilo unidos al grupo un anillo 5 ó 6 agregado por condensación, y (R3)m significa m sustituyentes R3, significando R3 (cuando m = 1) o cada uno de los sustituyentes R3 (cuando m es mayor que 1) independientemente entre sí halógeno, ciano, nitro, alquilo C1-8, alcoxi C1-8, alquiltio C1-8, alquilsulfinilo C1-8, alquilsulfonilo C1-8, haloalquilo C1-6, haloalcoxi C1-6, haloalquiltio C1-6, haloalquilsulfinilo C1-6, haloalquilsulfonilo C1-6, alquenilo C2-6, alquinilo C2-6, NR*R**, estando R* y R** definidos más adelante, tri-[alquil-C1-4]-sililo o tri-[alquil-C1-4]-silil-alquilo C1-4 o significando en cada caso dos grupos R3 ubicados en el anillo en posición orto junto con un grupo de la fórmula Z3-A**-Z4, en el cual A** representa un grupo alquileno con 1 a 4 átomos de carbono, que está dado el caso sustituido con uno o varios restos del grupo de halógeno, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4 y haloalcoxi C1-4, Z3 representa un enlace directo, O ó S y Z4 representa un enlace directo, O ó S, formando el grupo Z3-A**-Z4 junto con los átomos de carbono del anillo fenilo unidos al grupo un anillo 5 ó 6 agregado por condensación, y n, m significan en cada caso independientemente entre sí 0, 1, 2, 3, 4 ó 5, preferentemente 0, 1, 2, ó 3, con la salvedad de que no pueden ser ambos simultáneamente 0, presentando la configuración estereoquímica en el átomo de carbono en posición 3 del derivado de ácido butírico una pureza estereoquímica del 60 al 100% (R), preferentemente del 70 al 100% (R), más preferentemente del 80 al 100% (R), especialmente del 90 al 100% (R), referida a la presente mezcla de los enantiómeros treo, y presentando la configuración estereoquímica en el átomo de carbono en posición 4 del derivado de ácido butírico una pureza estereoquímica del 60 al 100% (R), preferentemente del 70 al 100% (R), más preferentemente del 80 al 100% (R), especialmente del 90 al 100% (R), referida a la presente mezcla de los enantiómeros treo.
ARP120100878A 2011-03-18 2012-03-16 (3r,4r)-4-ciano-3,4-difenilbutanoatos sustituidos, procedimiento para su preparacion y su uso como herbicidas y reguladores de crecimiento de plantas AR085428A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161454143P 2011-03-18 2011-03-18
EP11158828 2011-03-18

Publications (1)

Publication Number Publication Date
AR085428A1 true AR085428A1 (es) 2013-10-02

Family

ID=44370698

Family Applications (1)

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ARP120100878A AR085428A1 (es) 2011-03-18 2012-03-16 (3r,4r)-4-ciano-3,4-difenilbutanoatos sustituidos, procedimiento para su preparacion y su uso como herbicidas y reguladores de crecimiento de plantas

Country Status (7)

Country Link
US (1) US9049863B2 (es)
EP (1) EP2693878B8 (es)
JP (1) JP2014516920A (es)
CN (1) CN103476251A (es)
AR (1) AR085428A1 (es)
BR (1) BR112013023921A2 (es)
WO (1) WO2012126765A1 (es)

Families Citing this family (6)

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BR112017007198A2 (pt) 2014-10-08 2018-04-10 Bayer Cropscience Ag derivados de 5-hidróxi-2-fenil-3-heteroaril pentanonitrila substituída, método para sua produção e uso como herbicidas e/ou reguladores de crescimento da planta
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CN103476251A (zh) 2011-03-18 2013-12-25 拜耳知识产权有限责任公司 取代的(3r,4r)-4-氰基-3,4-二苯基丁酸酯，其制法和作为除草剂和植物生长调节剂的用途

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CN103476251A (zh) 2013-12-25
EP2693878A1 (de) 2014-02-12
BR112013023921A2 (pt) 2016-08-09
EP2693878B1 (de) 2018-06-27
US9049863B2 (en) 2015-06-09
WO2012126765A1 (de) 2012-09-27
EP2693878B8 (de) 2018-08-29
JP2014516920A (ja) 2014-07-17

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