BR112013023921A2 - (3r,4r) -4-ciano-3, 4-difenilbutanoatos substituídos, processos para a sua preparação e sua utilização como herbecidas e reguladores de crescimento de plantas - Google Patents

(3r,4r) -4-ciano-3, 4-difenilbutanoatos substituídos, processos para a sua preparação e sua utilização como herbecidas e reguladores de crescimento de plantas

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Publication number
BR112013023921A2
BR112013023921A2 BR112013023921A BR112013023921A BR112013023921A2 BR 112013023921 A2 BR112013023921 A2 BR 112013023921A2 BR 112013023921 A BR112013023921 A BR 112013023921A BR 112013023921 A BR112013023921 A BR 112013023921A BR 112013023921 A2 BR112013023921 A2 BR 112013023921A2
Authority
BR
Brazil
Prior art keywords
herbicides
growth regulators
cyano
processes
preparation
Prior art date
Application number
BR112013023921A
Other languages
English (en)
Inventor
Alfred Angermann
Christopher Hugh Rosinger
Elmar Gatzweiler
Hans-Joachim Zeib
Harald Jakobi
Ines Heinemann
Isolde Häuser-Hahn
Marc Mosrin
Michael Gerhard Hoffmann
Stefan Schnatterer
Original Assignee
Bayer Ip Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Ip Gmbh filed Critical Bayer Ip Gmbh
Publication of BR112013023921A2 publication Critical patent/BR112013023921A2/pt

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/20Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom three- or four-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34Nitriles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/48Nitro-carboxylic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10Sulfones; Sulfoxides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/01Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/32Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/41Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by carboxyl groups, other than cyano groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/49Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/57Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and carboxyl groups, other than cyano groups, bound to the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/10Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C323/11Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/12Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Epoxy Compounds (AREA)

Abstract

(3r,4r) -4-ciano-3, 4-difenilbutanoatos substituídos, processos para a sua preparação e sua utilização como herbecidas e reguladores de crescimento de plantas (3r,4r)-4-ciano-3,4-difenibutanoatos substituídos, processos para a sua preparação e sua utilização como herbicidas e reguladores do crescimento de plantas compostos da fórmula (i) ou sais dos mesmos, em cada caso na forma treo-(3r, 4r) opticamente ativa r^ 1^ é hidrogênio ou radical hidrolisável, e (r^ 2^)~ n~, (r^ ~3^)~ m~, n e m são como definido na fórmula (i) de acordo com a reivindicação 1, onde a configuração estereoquímica no átomo de carbono na posição 3 do derivado de ácido butanóico possui uma pureza estereoquímica de 60 a 100% (r), de preferência de 70 a 100% (r), e ainda preferencialmente de 80 a 100% (r), em particular de 90 a 100% (r), com base na mistura presente de enantiómeros treo, e a configuração estereoquímica no átomo de carbono na posição 4 do derivado de ácido butanóico possui uma pureza estereoquímica de 60 a 100% (r), de preferência de 70 a 100% (r), e ainda preferencialmente de 80 a 100% (r), em particular de 90 a 100% (r), com base na mistura presente de enantiómeros treo, que são adequados para utilização como herbicidas e reguladores de crescimento, em particular para a utilização selectiva em culturas de plantas e podem ser preparados pelo processo de reivindicação 9.
BR112013023921A 2011-03-18 2012-03-12 (3r,4r) -4-ciano-3, 4-difenilbutanoatos substituídos, processos para a sua preparação e sua utilização como herbecidas e reguladores de crescimento de plantas BR112013023921A2 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161454143P 2011-03-18 2011-03-18
EP11158828 2011-03-18
PCT/EP2012/054292 WO2012126765A1 (de) 2011-03-18 2012-03-12 Substituierte (3r,4r)-4-cyan-3,4-diphenylbutanoate, verfahren zu deren herstellung und deren verwendung als herbizide und pflanzenwachstumsregulatoren

Publications (1)

Publication Number Publication Date
BR112013023921A2 true BR112013023921A2 (pt) 2016-08-09

Family

ID=44370698

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013023921A BR112013023921A2 (pt) 2011-03-18 2012-03-12 (3r,4r) -4-ciano-3, 4-difenilbutanoatos substituídos, processos para a sua preparação e sua utilização como herbecidas e reguladores de crescimento de plantas

Country Status (7)

Country Link
US (1) US9049863B2 (pt)
EP (1) EP2693878B8 (pt)
JP (1) JP2014516920A (pt)
CN (1) CN103476251A (pt)
AR (1) AR085428A1 (pt)
BR (1) BR112013023921A2 (pt)
WO (1) WO2012126765A1 (pt)

Families Citing this family (6)

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Publication number Priority date Publication date Assignee Title
JP2014516920A (ja) 2011-03-18 2014-07-17 バイエル・インテレクチユアル・プロパテイー・ゲー・エム・ベー・ハー 置換された(3r,4r)−4−シアノ−3,4−ジフェニルブタノエート類、それらの製造方法、ならびに除草剤および植物成長調節剤としてのそれらの使用
AU2013361704B2 (en) 2012-12-21 2017-04-20 Bayer Cropscience Ag Substituted 4-cyan-3-(pyridyl)-4-phenylbutanoates, method for the production thereof and uses as herbicides and plant growth regulators
AR096517A1 (es) * 2013-06-07 2016-01-13 Bayer Cropscience Ag Derivados de 5-hidroxi-2,3-difenilpentanonitrilo sustituido, procedimientos para su preparación y su uso como herbicidas y/o reguladores del crecimiento de las plantas
CN106795113A (zh) 2014-07-04 2017-05-31 拜耳作物科学股份公司 取代的5‑羟基‑2‑杂芳基‑3‑苯基戊腈衍生物、其制备方法及其作为除草剂和/或植物生长调节剂的用途
EP3203841B1 (de) 2014-10-08 2018-06-13 Bayer CropScience Aktiengesellschaft Substituierte 5-hydroxy-2-phenyl-3-heteroarylpentanonitrilderivate, verfahren zu deren herstellung und deren verwendung als herbizide und/oder pflanzenwachstumsregulatoren
WO2021151976A1 (de) * 2020-01-31 2021-08-05 Bayer Aktiengesellschaft [(1,4,5-trisubstituierte-1h-pyrazol-3-yl)sulfanyl]essigsäure derivate sowie deren salze und ihre verwendung als herbizide wirkstoffe

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Also Published As

Publication number Publication date
EP2693878B1 (de) 2018-06-27
JP2014516920A (ja) 2014-07-17
US20140194291A1 (en) 2014-07-10
EP2693878B8 (de) 2018-08-29
EP2693878A1 (de) 2014-02-12
AR085428A1 (es) 2013-10-02
CN103476251A (zh) 2013-12-25
US9049863B2 (en) 2015-06-09
WO2012126765A1 (de) 2012-09-27

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