AR051971A1 - Proceso para la alquilacion de benceno y la transalquilacion de aromaticos polialquilados en un catalizador de beta - zeolita mejorado - Google Patents

Proceso para la alquilacion de benceno y la transalquilacion de aromaticos polialquilados en un catalizador de beta - zeolita mejorado

Info

Publication number
AR051971A1
AR051971A1 ARP050104941A ARP050104941A AR051971A1 AR 051971 A1 AR051971 A1 AR 051971A1 AR P050104941 A ARP050104941 A AR P050104941A AR P050104941 A ARP050104941 A AR P050104941A AR 051971 A1 AR051971 A1 AR 051971A1
Authority
AR
Argentina
Prior art keywords
beta zeolite
alkylation
transalquilation
polyalylated
benceno
Prior art date
Application number
ARP050104941A
Other languages
English (en)
Inventor
Philip J Angevine
Chuen Y Yeh
Jinsuo Xu
Original Assignee
Abb Lummus Global Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Abb Lummus Global Inc filed Critical Abb Lummus Global Inc
Publication of AR051971A1 publication Critical patent/AR051971A1/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60—Synthesis on support
    • B01J2229/64—Synthesis on support in or on refractory materials
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Un proceso de alquilacion aromática que incluye poner en contacto un compuesto aromático con un agente de alquilacion en presencia de una beta zeolita en una zona de reaccion bajo condiciones de reaccion de alquilacion, en donde dicha beta zeolita es una beta zeolita de alto rendimiento que posee una relacion entre sitios ácidos fuertes y sitios ácidos débiles es mayor que 1. la beta zeolita de alto rendimiento es superior a la beta zeolita convencional en la reaccion de alquilacion de aromáticos, tal como alquilacion de benceno con etileno para la produccion de etilbenceno, y alquilacion de benceno con propileno para la produccion de cumeno.
ARP050104941A 2004-12-01 2005-11-25 Proceso para la alquilacion de benceno y la transalquilacion de aromaticos polialquilados en un catalizador de beta - zeolita mejorado AR051971A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US11/000,859 US7371910B2 (en) 2000-10-20 2004-12-01 Process for benzene alkylation and transalkylation of polyalkylated aromatics over improved zeolite beta catalyst

Publications (1)

Publication Number Publication Date
AR051971A1 true AR051971A1 (es) 2007-02-21

Family

ID=36120944

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP050104941A AR051971A1 (es) 2004-12-01 2005-11-25 Proceso para la alquilacion de benceno y la transalquilacion de aromaticos polialquilados en un catalizador de beta - zeolita mejorado

Country Status (12)

Country Link
US (1) US7371910B2 (es)
EP (1) EP1833775A1 (es)
JP (1) JP2008521895A (es)
KR (1) KR20070109986A (es)
CN (1) CN101111461A (es)
AR (1) AR051971A1 (es)
BR (1) BRPI0518817A2 (es)
CA (1) CA2589119A1 (es)
MX (1) MX2007006532A (es)
RU (1) RU2007124641A (es)
WO (1) WO2006060158A1 (es)
ZA (1) ZA200704585B (es)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7683228B2 (en) 2007-02-12 2010-03-23 Exxonmobil Chemical Patents Inc. Production of high purity cumene from non-extracted feed and hydrocarbon composition useful therein
US8222467B2 (en) 2007-02-12 2012-07-17 Exxonmobil Chemical Patents Inc. Production of high purity cumene from non-extracted feed and hydrocarbon composition useful therein
US20080227630A1 (en) * 2007-03-16 2008-09-18 Riley Mark G Layered Catalyst for Transalkylation of Heavy Alkylate
CN102056868A (zh) 2008-06-10 2011-05-11 三井化学株式会社 烷基化芳香族化合物的制造方法以及苯酚的制造方法
US8105969B2 (en) * 2008-12-29 2012-01-31 Fina Technology Inc. Catalyst with an ion-modified binder
US8071829B2 (en) * 2009-02-20 2011-12-06 Conocophillips Company Alkylation process
US9150469B2 (en) * 2009-05-18 2015-10-06 Uop Llc Aromatic alkylation process with reduced byproduct formation
CZ301937B6 (cs) 2010-02-05 2010-08-04 Výzkumný ústav anorganické chemie, a. s. Zpusob výroby zeolitu pentasilové struktury s rízenou distribucí hliníkových atomu ve skeletu
CN102791366B (zh) 2010-02-25 2015-05-06 日本碍子株式会社 沸石膜以及沸石膜的制造方法
US8350111B2 (en) 2010-10-12 2013-01-08 Uop Llc Method for producing cumene
CN102746097A (zh) * 2011-04-20 2012-10-24 中国石油化工股份有限公司 多乙基苯与苯液相烷基转移生产乙苯的方法
US10144685B2 (en) 2014-02-07 2018-12-04 Saudi Basic Industries Corporation Removal of aromatic impurities from an alkene stream using an acid catalyst
WO2015118471A1 (en) 2014-02-07 2015-08-13 Saudi Basic Industries Corporation Removal of aromatic impurities from an alkene stream using an acid catalyst, such as an acidic ionic liquid
KR101603610B1 (ko) * 2014-08-13 2016-03-15 한국화학연구원 2,5-디메틸퓨란과 에틸렌으로부터 파라자일렌의 합성공정에 사용되는 나노기공성 스폰지 또는 시트 형태의 제올라이트 촉매
WO2016106773A1 (zh) * 2015-01-04 2016-07-07 北京化工大学 一种蜂窝式结构化催化剂制备异丙苯的方法
IT201900015066A1 (it) 2019-08-27 2021-02-27 Versalis Spa Procedimento per il trattamento di idrocarburi polialchilaromatici.
CN114591135B (zh) * 2022-03-24 2023-09-15 中国科学院大连化学物理研究所 一种萘择形烷基化制备2,6-二异丙基萘的方法
CN114736089B (zh) * 2022-03-24 2023-08-08 中国科学院大连化学物理研究所 一种生产2,6-二异丙基萘的方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3385906A (en) * 1965-05-25 1968-05-28 Union Carbide Corp Production of cumene
US4169111A (en) * 1978-02-02 1979-09-25 Union Oil Company Of California Manufacture of ethylbenzene
US4292458A (en) * 1978-04-18 1981-09-29 Standard Oil Company (Indiana) Production of hydrocarbons from alcohols
DE3868194D1 (de) 1987-09-02 1992-03-12 Mobil Oil Corp Verfahren zur transalkylierung von (polyalkyl)aromatischen kohlenwasserstoffen.
US4891458A (en) * 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
RU1839668C (ru) * 1988-11-28 1993-12-30 МИЦУИ ПЕТРОКЕМИКАЛ ИНДАСТРИЗ, Лтд (JP) Способ получени фенола
FR2656300B1 (fr) * 1989-12-21 1993-06-11 Inst Francais Du Petrole Procede de production de phenol.
IT1270230B (it) 1994-06-16 1997-04-29 Enichem Sintesi Composizione catalitica e processo per l'alchilazione di composti aromatici
US6162416A (en) * 1996-07-12 2000-12-19 Uop Llc Zeolite beta and its use in aromatic alkylation
IT1290846B1 (it) 1996-12-12 1998-12-14 Enichem Spa Composizione catalitica e processo per l'alchilazione e/o la transalchilazione di composti aromatici
US6809055B2 (en) * 2000-10-20 2004-10-26 Abb Lummus Global, Inc. Zeolites and molecular sieves and the use thereof
DE10059398A1 (de) * 2000-11-30 2002-06-13 Basf Ag Verfahren zur Herstellung von Alkylarylsulfonaten

Also Published As

Publication number Publication date
KR20070109986A (ko) 2007-11-15
US7371910B2 (en) 2008-05-13
WO2006060158A1 (en) 2006-06-08
MX2007006532A (es) 2007-07-25
US20050154243A1 (en) 2005-07-14
BRPI0518817A2 (pt) 2008-12-09
EP1833775A1 (en) 2007-09-19
RU2007124641A (ru) 2009-01-10
CN101111461A (zh) 2008-01-23
CA2589119A1 (en) 2006-06-08
ZA200704585B (en) 2008-09-25
JP2008521895A (ja) 2008-06-26

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