EA201071118A1 - Алкилирование ароматических субстратов и способ трансалкилирования - Google Patents

Алкилирование ароматических субстратов и способ трансалкилирования

Info

Publication number
EA201071118A1
EA201071118A1 EA201071118A EA201071118A EA201071118A1 EA 201071118 A1 EA201071118 A1 EA 201071118A1 EA 201071118 A EA201071118 A EA 201071118A EA 201071118 A EA201071118 A EA 201071118A EA 201071118 A1 EA201071118 A1 EA 201071118A1
Authority
EA
Eurasian Patent Office
Prior art keywords
alkylation
aromatic
aromatic substrate
translation
benzene
Prior art date
Application number
EA201071118A
Other languages
English (en)
Other versions
EA020157B1 (ru
Inventor
Жан-Бернард Кэри
Original Assignee
Тотал Петрокемикалз Франс
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Тотал Петрокемикалз Франс filed Critical Тотал Петрокемикалз Франс
Publication of EA201071118A1 publication Critical patent/EA201071118A1/ru
Publication of EA020157B1 publication Critical patent/EA020157B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C07C6/06—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond at a cyclic carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Данное изобретение относится к способу алкилирования ароматического субстрата и к способу трансалкилирования полиалкилированных ароматических компонентов, где соединения-примеси, содержащие азот, в исходном сырье ароматического субстрата и/или исходном сырье алкилирующего средства наблюдают в диапазоне 15 wppb-35 wppm при помощи сухой колориметрии. В преимущественном варианте осуществления способа алкилирования ароматическим субстратом является бензол, а алкилирующим средством является этилен. В преимущественном варианте осуществления способа трансалкилирования ароматическим субстратом является бензол, а полиалкилированным ароматическим компонентом является диэтилбензол.
EA201071118A 2008-04-18 2009-04-03 Алкилирование ароматических субстратов и способ трансалкилирования EA020157B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP20080290392 EP2110368A1 (en) 2008-04-18 2008-04-18 Alkylation of aromatic substrates and transalkylation process
PCT/EP2009/053992 WO2009127533A1 (en) 2008-04-18 2009-04-03 Alkylation of aromatic substrates and transalkylation process.

Publications (2)

Publication Number Publication Date
EA201071118A1 true EA201071118A1 (ru) 2011-06-30
EA020157B1 EA020157B1 (ru) 2014-09-30

Family

ID=39798243

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201071118A EA020157B1 (ru) 2008-04-18 2009-04-03 Алкилирование ароматических субстратов и способ трансалкилирования

Country Status (8)

Country Link
US (3) US8802910B2 (ru)
EP (2) EP2110368A1 (ru)
JP (1) JP2011517691A (ru)
KR (1) KR101233484B1 (ru)
CN (1) CN102066291A (ru)
BR (1) BRPI0911205A2 (ru)
EA (1) EA020157B1 (ru)
WO (1) WO2009127533A1 (ru)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8816145B2 (en) 2007-06-21 2014-08-26 Exxonmobil Chemical Patents Inc. Liquid phase alkylation process
US9322793B2 (en) 2010-05-20 2016-04-26 Exxonmobil Chemical Patents Inc. Method for monitoring performance of process catalysts
EA029134B1 (ru) * 2011-05-02 2018-02-28 Файна Текнолоджи, Инк. Способ получения этилбензола
TWI483775B (zh) * 2011-09-16 2015-05-11 Exxonmobil Chem Patents Inc 經改善之ｍｃｍ－５６製法
CN106565407A (zh) * 2015-10-12 2017-04-19 中国石油化工股份有限公司 液相烷基化制乙苯的方法
CN108530247B (zh) * 2017-03-03 2021-09-03 中国石油化工股份有限公司 环己烯和苯烷基化制备环己基苯的方法
CN112142549B (zh) * 2019-06-26 2023-08-29 中国石油化工股份有限公司 甲基异丙苯的合成方法
FR3104576B1 (fr) * 2019-12-17 2021-12-31 Ifp Energies Now Dispositif et procédé de conversion de composés aromatiques par alkylation de benzène par l’éthanol
CN113045375A (zh) * 2021-03-22 2021-06-29 浙江大学衢州研究院 一种由二戊基蒽烷基转移制备2-戊基蒽的方法
CN114315500A (zh) * 2021-12-15 2022-04-12 浙江恒逸石化研究院有限公司 一种烷基转移反应制备烷基蒽及烷基苯的方法

Family Cites Families (77)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3751504A (en) 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
US4016218A (en) 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
US4169111A (en) 1978-02-02 1979-09-25 Union Oil Company Of California Manufacture of ethylbenzene
US4459426A (en) 1980-04-25 1984-07-10 Union Oil Company Of California Liquid-phase alkylation and transalkylation process
US4547605A (en) 1983-09-28 1985-10-15 Mobil Oil Corporation Catalyst for alkylation of aromatic hydrocarbons
US4954325A (en) 1986-07-29 1990-09-04 Mobil Oil Corp. Composition of synthetic porous crystalline material, its synthesis and use
US4849569A (en) 1987-11-16 1989-07-18 Chemical Research & Licensing Company Alkylation of organic aromatic compounds
US5198595A (en) 1987-11-23 1993-03-30 The Dow Chemical Company Alkylation of aromatic compounds
US5081323A (en) 1987-12-17 1992-01-14 Chevron Research And Technology Company Liquid phase alkylation or transalkylation process using zeolite beta
US4891458A (en) * 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
US4992606A (en) 1988-10-06 1991-02-12 Mobil Oil Corp. Process for preparing short chain alkyl aromatic compounds
US5030786A (en) 1989-06-23 1991-07-09 Fina Technology, Inc. Liquid phase aromatic conversion process
US4950834A (en) 1989-07-26 1990-08-21 Arganbright Robert P Alkylation of organic aromatic compounds in a dual bed system
US5157185A (en) 1989-09-01 1992-10-20 Mobil Oil Corporation Alkylation of aromatics
FR2656300B1 (fr) 1989-12-21 1993-06-11 Inst Francais Du Petrole Procede de production de phenol.
US5334795A (en) 1990-06-28 1994-08-02 Mobil Oil Corp. Production of ethylbenzene
DE69026613T2 (de) 1990-07-18 1996-10-24 Fina Technology Transalkylierungsverfahren
US5021141A (en) 1990-09-14 1991-06-04 Mobil Oil Corp. Synthesis of crystalline ZSM-12 type structure
US5086193A (en) 1990-11-09 1992-02-04 Chemical Research & Licensing Company Aromatic alkylation process
US5113031A (en) 1990-11-09 1992-05-12 Angel Sy Aromatic alkylation process
US5215725A (en) 1990-11-09 1993-06-01 Chemical Research & Licensing Company Aromatic alkylation process
EP0485683B1 (en) 1990-11-13 2001-01-10 Fina Technology, Inc. Preparation of alkylated aromatics
US5250277A (en) 1991-01-11 1993-10-05 Mobil Oil Corp. Crystalline oxide material
US5077445A (en) 1991-02-06 1991-12-31 Mobil Oil Corp. Liquid-phase alkylbenzene synthesis using hydrated catalyst
EP0507761B2 (en) 1991-04-05 2003-04-16 Fina Technology, Inc. Modified zeolite alkylation catalyst and process employing same
US5236575A (en) 1991-06-19 1993-08-17 Mobil Oil Corp. Synthetic porous crystalline mcm-49, its synthesis and use
US5240889A (en) 1991-07-12 1993-08-31 Union Oil Company Of California Hydrated alkylation catalyst
US5258565A (en) 1992-05-04 1993-11-02 Mobil Oil Corp. Process for preparing short chain alkylaromatic compounds
US5362697A (en) 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
US5476823A (en) 1993-05-28 1995-12-19 Mobil Oil Corp. Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and method to increase the activity thereof
IT1264626B1 (it) 1993-06-16 1996-10-04 Eniricerche Spa Processo per la preparazione di cumene
EP0703887A1 (en) 1993-06-16 1996-04-03 Mobil Oil Corporation Liquid phase ethylbenzene synthesis
US5563311A (en) 1993-09-14 1996-10-08 Mobil Oil Corporation Process for preparing short chain alkyl aromatic compounds
AU684306B2 (en) 1993-10-18 1997-12-11 Mobil Oil Corporation Synthetic porous crystalline MCM-58, its synthesis and use
US5437855A (en) 1993-10-18 1995-08-01 Mobil Oil Corp. Synthetic porous crystalline MCM-58, its synthesis and use
US5430211A (en) 1993-10-29 1995-07-04 The Dow Chemical Company Process of preparing ethylbenzene or substituted derivatives thereof
US5522984A (en) 1994-08-18 1996-06-04 Uop Modified zeolite beta, processes for preparation and use thereof
US5980859A (en) 1994-08-18 1999-11-09 Uop Llc Modified zeolite beta processes for preparation
US5900520A (en) 1995-01-23 1999-05-04 Mobil Oil Corporation Aromatics alkylation
CA2168418C (en) 1995-02-08 2007-04-17 James Butler Process for ethylbenzene production
CA2172207A1 (en) 1995-03-21 1996-09-22 Mark Edward Kuchenmeister Transalkylation of polyalkylaromatic hydrocarbons
ES2191772T3 (es) * 1996-06-06 2003-09-16 Exxonmobil Oil Corp Catalizador de zeolita selectivo de forma y su uso en la conversion de compuestos aromaticos.
US6162416A (en) 1996-07-12 2000-12-19 Uop Llc Zeolite beta and its use in aromatic alkylation
WO1998003455A1 (fr) 1996-07-19 1998-01-29 Asahi Kasei Kogyo Kabushiki Kaisha Procede pour la preparation d'ethylbenzene
EP0826653A1 (en) 1996-08-30 1998-03-04 Fina Technology, Inc. Process for the alkylation of aromatic hydrocarbons with recycle of reactor effluent
EP0929502B1 (en) 1996-09-06 2001-08-01 ExxonMobil Chemical Patents Inc. Alkylation process using zeolite beta
US5990031A (en) 1996-11-26 1999-11-23 Fina Technology, Inc. Zeolite catalyst with enhanced dealkylation activity and method for producing same
US5847255A (en) 1997-05-21 1998-12-08 Fina Technology, Inc. Gas phase alkylation-liquid phase transalkylation process
US5907073A (en) 1998-02-24 1999-05-25 Fina Technology, Inc. Aromatic alkylation process
US6051521A (en) 1998-08-25 2000-04-18 Mobil Oil Corporation Method of producing an aromatics alkylation catalyst
JP2000131225A (ja) * 1998-10-26 2000-05-12 Resuka:Kk 透過光強度比測定式比色計
US6057485A (en) 1998-11-17 2000-05-02 Fina Technology, Inc. Gas phase alkylation with split load of catalyst
US6313362B1 (en) 1998-12-17 2001-11-06 Exxonmobil Corporation Aromatic alkylation process
US6049018A (en) 1999-01-21 2000-04-11 Mobil Corporation Synthetic porous crystalline MCM-68, its synthesis and use
US6268305B1 (en) 1999-02-27 2001-07-31 Fina Technology, Inc. Catalysts with low concentration of weak acid sites
US6090991A (en) 1999-02-27 2000-07-18 Fina Technology, Inc. Gas phase alkylation method and catalyst
US6222084B1 (en) 1999-04-09 2001-04-24 Fina Technology, Inc. Gas phase alkylation-liquid phase transalkylation process
US6897346B1 (en) 1999-06-10 2005-05-24 Fina Technology, Inc. Aromatic conversion process employing low surface area zeolite Y
US6617482B1 (en) 2000-08-16 2003-09-09 Exxonmobil Chemical Patents Inc. Removable of polar contaminants from aromatic feedstocks
EP1188734B1 (en) 2000-09-14 2004-03-31 Fina Technology, Inc. Process for the preparation of ethylbenzene by alkylation and transalkylation
US7371911B2 (en) 2005-02-25 2008-05-13 Fina Technology, Inc. Critical phase alkylation and transalkylation process in the presence of a beta zeolite
US6486371B1 (en) 2000-11-28 2002-11-26 Fina Technology, Inc. Multistage reaction system with interstage sparger systems
US6376729B1 (en) 2000-12-04 2002-04-23 Fina Technology, Inc. Multi-phase alkylation process
EP1485335B1 (en) 2002-02-28 2015-04-08 Badger Licensing LLC Production of alkyl aromatic compounds
JP4148716B2 (ja) * 2002-08-02 2008-09-10 日陶科学株式会社 セル型窒素酸化物捕集器及び窒素酸化物の捕集測定方法
US7268264B2 (en) 2002-10-04 2007-09-11 Fina Technology, Inc. Critical phase alkylation process
US6933418B2 (en) 2002-10-04 2005-08-23 Fina Technology, Inc. Critical phase alkylation process
US20040138511A1 (en) 2003-01-10 2004-07-15 James Butler Aromatic alkylation process with direct recycle
US7199275B2 (en) * 2003-03-24 2007-04-03 Exxonmobil Chemical Patents Inc. Feed pretreating
US6987078B2 (en) 2003-10-03 2006-01-17 Fina Technology, Inc. Alkylation and catalyst regenerative process
US20050085677A1 (en) 2003-10-15 2005-04-21 Fina Technology, Inc. Method for improved production of cyclohexenyl and alkenyl aromatic compounds
US20050135970A1 (en) * 2003-12-18 2005-06-23 Mroczynski Shawn A. Hydrogen sulfide monitoring system
DE102004045879B4 (de) * 2004-09-20 2007-06-14 Basf Ag Verfahren zur Reinigung von Aromaten enthaltenden Zufuhrströmen mit Zeolithen
US7405336B2 (en) 2004-10-18 2008-07-29 Fina Technology, Inc. Promoters for controlling acidity and pore size of zeolite catalysts for use in alkylation
US7727383B2 (en) * 2005-06-30 2010-06-01 Amt International, Inc. Process for producing petroleum oils with ultra-low nitrogen content
US20070161837A1 (en) 2006-01-07 2007-07-12 Fina Technology, Inc. Zeolitic transalkylation with aluminum chloride alkylation
US7425659B2 (en) * 2006-01-31 2008-09-16 Exxonmobil Chemical Patents Inc. Alkylaromatics production

Also Published As

Publication number Publication date
JP2011517691A (ja) 2011-06-16
US20140094633A1 (en) 2014-04-03
US20110130608A1 (en) 2011-06-02
US8742191B2 (en) 2014-06-03
CN102066291A (zh) 2011-05-18
BRPI0911205A2 (pt) 2015-09-29
EP2110368A1 (en) 2009-10-21
US8802910B2 (en) 2014-08-12
KR101233484B1 (ko) 2013-02-15
EP2274259B1 (en) 2018-08-15
WO2009127533A1 (en) 2009-10-22
EA020157B1 (ru) 2014-09-30
KR20100125422A (ko) 2010-11-30
EP2274259A1 (en) 2011-01-19
US20140206917A1 (en) 2014-07-24
US9120715B2 (en) 2015-09-01

Similar Documents

Publication Publication Date Title
EA201071118A1 (ru) Алкилирование ароматических субстратов и способ трансалкилирования
TW200744984A (en) Alkylaromatics production
CO2021002706A2 (es) Inhibición de la integrina ανβ6
NO20080075L (no) Sammensetninger og fremgangsmater for inhibering av JAK-nervefiberkjeden
TR201902243T4 (tr) İzopropanol veya izopropanol ve propilen harmanları ile benzenin alkilasyonuna yönelik proses.
IN2012DN04895A (ru)
BR112013009698B1 (pt) composto de agentes de azulagem
BRPI0615705A2 (pt) processo para preparar um composto, e, composto
BRPI0812251A2 (pt) processo aperfeiçoado de alquilação em fase líquida
JO3073B1 (ar) مثبطات ثنائية ملتحمة ثلاثية الحلقة ل cdk 4/6 و flt3
BRPI0912541B8 (pt) composto de benzeno sulfonamida tiazol, sua composição farmacêutica e seu uso
CL2011000242A1 (es) Uso de compuestos derivados de fenilaminopirimidina para tratar talasemia alfa, delta y anemia celular falciforme, talasemia mayor, talasemia menor, talasemia e-beta o talasemia beta falciforme, o para mejorar o retrasar los sintomas de las mismas y uso de un compuesto especifico para tratar la talasemia.
BRPI0816736A2 (pt) cristais zsm-5, processo para selecionar cristais zsm-5, composição de catalisador, e, processo de desalquilação de etilbenzeno.
BRPI0914603A2 (pt) catalizador de isomerização de alquilaromáticos, e, processo para a isomerização de alquilaromáticos para fornecer uma mistura de reação.
WO2011112189A8 (en) Alkylated aromatics production
CL2010001639A1 (es) Proceso para preparacion del hemitartrato de [5-(4,6-dimetil-1h-benzoimidazol-2-il-metil-pirimidin-2-il]-[3-(metil-piperidin-4-il)propil]amina; proceso de recristalizacion del hemitartrato; y hemitaatrato cristalino de [5-(4,6-dimetil-1h-benzoimidazol-2-il)-4-metil- pirimidin-2-il]-[3-(1-metil-piperidin-4-il)-propil]-amina.
BR112013032840A2 (pt) processo para a alquilação de hidrocarbonetos aromáticos com olefinas
AR090609A1 (es) Proceso de produccion de xilenos mediante la integracion de la metilacion con la transalquilacion
WO2011008423A3 (en) Process for alkylation of aromatic hydrocarbons using uzm-35
WO2011071977A3 (en) Aromatic alkylation process
EA200702419A1 (ru) Новые соединения как агонисты glp-1
EA201170726A1 (ru) Способ получения этилбензола
JO2812B1 (en) A method of obtaining the aggregate V crystal form of agomelatine
EP1856012A4 (en) AROMATIC ALKYLATION PROCESS IN STEAM PHASE
EA201270762A1 (ru) Способ для регенерации катализатора и длительного применения

Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM RU