AR045802A1 - Composicion catalizadora con donador interno de ester de acido monocarboxilico y proceso de polimerizacion de propileno - Google Patents

Composicion catalizadora con donador interno de ester de acido monocarboxilico y proceso de polimerizacion de propileno

Info

Publication number
AR045802A1
AR045802A1 ARP040103415A ARP040103415A AR045802A1 AR 045802 A1 AR045802 A1 AR 045802A1 AR P040103415 A ARP040103415 A AR P040103415A AR P040103415 A ARP040103415 A AR P040103415A AR 045802 A1 AR045802 A1 AR 045802A1
Authority
AR
Argentina
Prior art keywords
donator
ester
internal
polymerization process
propylene polymerization
Prior art date
Application number
ARP040103415A
Other languages
English (en)
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of AR045802A1 publication Critical patent/AR045802A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/128—Mixtures of organometallic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/58—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with silicon, germanium, tin, lead, antimony, bismuth or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/22—Magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Una composición catalizadora para la polimerización de propileno comprendiendo una o más composiciones procatalizadores Ziegler-Natta que comprenden uno o más compuestos de metal de transición y uno o más monoésteres de donadores de electrón interno de ácido carboxílico aromático; uno o más cocatalizadores que contienen aluminio; y una mezcla de dos o más agentes de control de selectividad diferentes; dicha mezcla SCA comprendiendo de 70 a 98 por ciento de mol de uno o más ésteres de uno o más ácidos monocarboxílicos aromáticos o derivados sustituidos de los mismos y de 30 a 2 por ciento de mol de uno o más compuestos de alcoxisilano que contienen uno o más grupos cíclicos de 5 ó 6 miembros que contienen opcionalmente uno o más heteroátomos del grupo 14, 15 ó 16.
ARP040103415A 2003-09-23 2004-09-22 Composicion catalizadora con donador interno de ester de acido monocarboxilico y proceso de polimerizacion de propileno AR045802A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US50531203P 2003-09-23 2003-09-23

Publications (1)

Publication Number Publication Date
AR045802A1 true AR045802A1 (es) 2005-11-16

Family

ID=34434878

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP040103415A AR045802A1 (es) 2003-09-23 2004-09-22 Composicion catalizadora con donador interno de ester de acido monocarboxilico y proceso de polimerizacion de propileno

Country Status (8)

Country Link
US (2) US7393806B2 (es)
EP (1) EP1668045B1 (es)
KR (1) KR101109345B1 (es)
AR (1) AR045802A1 (es)
CZ (1) CZ2006179A3 (es)
PL (1) PL379383A1 (es)
RU (1) RU2361885C2 (es)
WO (1) WO2005035596A1 (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101787927B1 (ko) * 2007-12-21 2017-10-18 더블유.알. 그레이스 앤드 캄파니-콘. 두자리 내부 공여체를 가진 자기-제한성 촉매 조성물
US9068030B2 (en) * 2010-01-22 2015-06-30 China Petroleum & Chemical Corporation Propylene homopolymer having high melt strength and preparation method thereof
US20120116034A1 (en) * 2010-11-08 2012-05-10 Dow Global Technologies, Inc. Solution polymerization process and procatalyst carrier systems useful therein
US20120157295A1 (en) 2010-12-21 2012-06-21 Linfeng Chen Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product
US9382343B2 (en) 2010-12-21 2016-07-05 W. R. Grace & Co.-Conn. Procatalyst composition with alkoxypropyl ester internal electron donor and polymer from same
US9382342B2 (en) 2010-12-21 2016-07-05 W. R. Grace & Co.-Conn. Procatalyst composition with alkoxyalkyl 2-propenoate internal electron donor and polymer from same
US20120157645A1 (en) * 2010-12-21 2012-06-21 Linfeng Chen Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same
US20140316084A1 (en) 2011-05-13 2014-10-23 Reliance Industries Limited Catalyst system for polymerization of propylene
US10647790B2 (en) * 2011-06-30 2020-05-12 W. R. Grace & Co.-Conn. Process for gas-phase polymerization having high bed bulk density
ES2665889T3 (es) * 2011-12-30 2018-04-30 Borealis Ag Componente catalítico
US10195581B2 (en) 2012-03-26 2019-02-05 Unchained Labs Parallel reactor systems and methods for preparing materials
EP2992335B1 (en) 2013-04-30 2018-04-18 Unchained Labs Methods for sampling from non-atmospheric vessels in a parallel reactor system
RU2702633C1 (ru) * 2013-11-15 2019-10-09 У.Р. Грейс Энд Ко.-Конн Полимер на основе пропилена с уменьшенной высокомолекулярной частью
CN105524192B (zh) * 2015-12-09 2017-11-14 大唐国际化工技术研究院有限公司 具有高温活性抑制作用的聚丙烯催化剂组合物及其用途
US11427660B2 (en) 2016-08-17 2022-08-30 Formosa Plastics Corporation, Usa Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same
US11384166B2 (en) * 2016-09-08 2022-07-12 Sabic Global Technologies B.V. Process of preparing polyolefin with the discontinuous addition of a thermal runaway reducing agent

Family Cites Families (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5082907A (en) * 1990-10-18 1992-01-21 Shell Oil Company Olefin polymerization catalyst
US5077357A (en) * 1990-10-22 1991-12-31 Shell Oil Company Olefin polymerization catalyst
US5066737A (en) * 1990-10-22 1991-11-19 Shell Oil Company Olefin polymerization catalyst
US5106806A (en) * 1990-10-18 1992-04-21 Shell Oil Company Olefin polymerization catalyst
US4107413A (en) * 1971-06-25 1978-08-15 Montedison S.P.A. Process for the stereoregular polymerization of alpha olefins
IT1042711B (it) * 1975-09-19 1980-01-30 Montedison Spa Compnenti di catalizzatori per la polimerizzazione di olefine
GB1603724A (en) * 1977-05-25 1981-11-25 Montedison Spa Components and catalysts for the polymerisation of alpha-olefins
IT1114822B (it) * 1977-07-04 1986-01-27 Montedison Spa Componenti di catalizzatori per la polimerizzazione delle alfa-olefine
JPS56811A (en) * 1979-06-18 1981-01-07 Mitsui Petrochem Ind Ltd Preparation of olefin polymer or copolymer
US4442276A (en) * 1982-02-12 1984-04-10 Mitsui Petrochemical Industries, Ltd. Process for polymerizing or copolymerizing olefins
JPS5991107A (ja) * 1982-11-17 1984-05-25 Toho Titanium Co Ltd オレフイン類重合用触媒成分の製造方法
US4472521A (en) * 1982-12-20 1984-09-18 Stauffer Chemical Company Supported catalyst for polymerization of olefins
JPS6023404A (ja) * 1983-07-20 1985-02-06 Toho Titanium Co Ltd オレフィン類重合用触媒成分
US4540679A (en) * 1984-03-23 1985-09-10 Amoco Corporation Magnesium hydrocarbyl carbonate supports
US4548915A (en) * 1984-04-10 1985-10-22 Shell Oil Company Olefin polymerization catalyst composition
JPS6155104A (ja) * 1984-08-24 1986-03-19 Toho Titanium Co Ltd オレフィン類重合用触媒成分
JPS61203105A (ja) 1985-03-06 1986-09-09 Idemitsu Petrochem Co Ltd α−オレフインの重合方法
JPS61213150A (ja) 1985-03-19 1986-09-22 株式会社　名南製作所 積層板の製造方法
JPH06104693B2 (ja) * 1986-01-06 1994-12-21 東邦チタニウム株式会社 オレフイン類重合用触媒
US4728705A (en) * 1986-02-28 1988-03-01 Shell Oil Company Olefin polymerization catalyst composition
US4829037A (en) * 1986-05-06 1989-05-09 Toho Titanium Co., Ltd. Catalyst for polymerization of olefins
CA1310955C (en) * 1987-03-13 1992-12-01 Mamoru Kioka Process for polymerization of olefins and polymerization catalyst
US4927797A (en) * 1987-04-09 1990-05-22 Fina Technology, Inc. Catalyst system for the polymerization of olefins
US5066738A (en) * 1987-04-09 1991-11-19 Fina Technology, Inc. Polymerization of olefins with an improved catalyst system using a new electron donor
DE3819577A1 (de) * 1988-06-09 1989-12-14 Hoechst Ag Verfahren zur herstellung eines polypropylens
DE68913375T3 (de) * 1988-06-17 2002-05-02 Mitsui Chemicals Inc Olefinpolymerisationsverfahren und dabei anwendbarer Polymerisationskatalysator.
ATE122060T1 (de) 1989-03-02 1995-05-15 Mitsui Petrochemical Ind Verfahren zur polymerisation von olefinen und katalysator für olefinpolymerisation.
US5034361A (en) * 1990-05-24 1991-07-23 Shell Oil Company Catalyst precursor production
US5146028A (en) * 1990-10-18 1992-09-08 Shell Oil Company Olefin polymerization catalyst and process of polymerization
FR2669639A1 (fr) 1990-11-27 1992-05-29 Atochem Cocatalyseur de polymerisation du propylene a base de silane et de monoether.
US5432244A (en) 1990-12-12 1995-07-11 Union Carbide Chemicals & Plastics Technology Corporation Process for the production of polypropylene
TW300235B (es) 1992-12-04 1997-03-11 Mitsui Petroleum Chemicals Ind
US5414063A (en) 1993-03-30 1995-05-09 Huntsman Polypropylene Corporation Process for the production of polypropylene
EP0657477B1 (en) 1993-12-07 2001-03-14 Sumitomo Chemical Company Limited Process for producing olefin polymers for biaxially oriented film and olefin-polymerizing catalyst
EP0743960B1 (en) * 1994-02-04 1998-05-13 Exxon Chemical Patents Inc. Dual donor catalyst system for the polymerization of olefins
US6133385A (en) 1994-04-06 2000-10-17 Fina Technology, Inc. Catalyst systems for improved stereoselectivity and broader molecular weight distribution in polymerization of olefins
US6184328B1 (en) 1994-09-07 2001-02-06 Showa Denko Kabushiki Kaisha Propylene-based polymer, method for its production, composition thereof, catalyst component for polymerization, and method for its production
US5869418A (en) * 1994-05-31 1999-02-09 Borealis Holding A/S Stereospecific catalyst system for polymerization of olefins
DE69520332T2 (de) 1994-11-25 2001-08-09 Japan Polyolefins Co Ltd Katalysator zur Polymerisation von Olefinen und Verfahren zur Herstellung von Polyolefinen unter dessen Verwendung
KR100334167B1 (ko) 1997-05-08 2002-11-22 삼성종합화학주식회사 알파-올레핀중합방법
US6303698B1 (en) 1997-09-04 2001-10-16 Chisso Corporation Propylene copolymer and process for the production thereof
WO1999020663A2 (en) 1997-10-17 1999-04-29 Exxon Chemical Patents Inc. High impact, flexural moduli polymeric materials formed using sequential donors
US6087459A (en) * 1998-05-14 2000-07-11 Exxon Chemical Patents Inc. Polymeric materials formed using blends of electron donors
JP2002514666A (ja) 1998-05-14 2002-05-21 エクソンモービル・ケミカル・パテンツ・インク 電子供与体のブレンドを使用して形成されたポリマー性物質
US20030087755A1 (en) * 2001-05-29 2003-05-08 Linfeng Chen Olefin polymerization catalyst compositions and method of preparation
US6825146B2 (en) * 2001-05-29 2004-11-30 Union Carbide Chemicals & Plastics Technology Corporation Olefin polymerization catalyst compositions and method of preparation

Also Published As

Publication number Publication date
KR101109345B1 (ko) 2012-01-31
RU2361885C2 (ru) 2009-07-20
CZ2006179A3 (cs) 2007-01-31
EP1668045A1 (en) 2006-06-14
KR20060126942A (ko) 2006-12-11
US20070066771A1 (en) 2007-03-22
PL379383A1 (pl) 2006-09-04
RU2006113594A (ru) 2006-09-10
EP1668045B1 (en) 2012-10-03
US7687426B2 (en) 2010-03-30
US20080319146A1 (en) 2008-12-25
US7393806B2 (en) 2008-07-01
WO2005035596A1 (en) 2005-04-21

Similar Documents

Publication Publication Date Title
AR045802A1 (es) Composicion catalizadora con donador interno de ester de acido monocarboxilico y proceso de polimerizacion de propileno
AR045800A1 (es) Composicion catalizadora de auto - extincion con donador interno de ester de acido monocarboxilico y proceso de polimerizacion de propileno
AR045801A1 (es) Composicion catalizadora auto- limitante con donador interno de ester de acido dicarboxilico y proceso de polimerizacion de propileno
AR045941A1 (es) Composicion catalizadora auto - limitante y proceso de polimerizacion de propileno
AR030989A1 (es) Componentes de catalizadores para la polimerizacion de olefinas
DE69419658T2 (de) Veresterungsverfahren
AR006463A1 (es) Composicion de magnesio, titanio, halogeno y ester de acido carboxilico; proceso para su preparacion, uso de la misma como un catalizador, componentecatalizador o en la preparacion de un catalizador, producto o producto intermedio de polimerizacion catalizado por la composicion o preparado por
ES2067036T3 (es) Productos de alcoxilacion de derivados de acidos carboxilicos y/o acidos carboxilicos que contienen grupos oh.
ES2146268T3 (es) Procedimiento para la fabricacion de acido amidoetercarboxilico o de una sal del mismo y de una mezcla de agentes con actividad superficial que los contienen.
BR9706064A (pt) Aductos 1,2-bis de nitróxidos estáveis com etilenos substituìdos e composições estabilizadas
ATE373634T1 (de) Verfahren zur herstellung von 2-(4-n, n- dialkylamino-2-hydroxybenzoyl)benzoes ureestern
DE602005008090D1 (de) Verbessertes verfahren zur herstellung eines (meth)acrylanhydrids
DE10347863A1 (de) Verfahren zur Herstellung von Benzoesäureestern
ATE22453T1 (de) Katalysatorzusammensetzung und verfahren zur polymerisation von olefinen.
BR0017020A (pt) Processo de polimerização
DE60226203D1 (de) Laktonisierung im Verfahren zur Herstellung von Statinen
AR007982A1 (es) Procedimiento para la fabricacion catalitica de derivados de n-acilglicina y procedimiento para la fabricacion de aminoacidos opticamente puros.
BR0314966A (pt) Processo para preparar um composto, e, composto
AU2003298243A1 (en) Partially esterified copolymers of monoethylenically unsaturated dicarboxylic acid anhydrides, vinylaromatic compounds and other monoethylenically unsaturated monomers containing heteroatoms
FR2931159B1 (fr) Procede de preparation de bioplastifiants de polymeres
NO830453L (no) Fremgangsmaate ved polymerisering av olefiner, samt katalysator for anvendelse ved fremgangsmaaten
DE69412095D1 (de) Neue antivirale mittel
NZ503880A (en) Orally-active nipecotamide glycolamide esters for the treatment of thrombosis disorders
AR045940A1 (es) Composicion catalizadoa con sca mezclado y proceso de polimerizacion de propileno
ES2108575T3 (es) Procedimiento para la obtencion de copolimeros, formados por esteres vinilicos y acidos carboxilicos monoetilenicamente insaturados y su empleo.

Legal Events

Date Code Title Description
FB Suspension of granting procedure