AR041197A1 - Derivados triciclicos insecticidas - Google Patents

Derivados triciclicos insecticidas

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Publication number
AR041197A1
AR041197A1 ARP030103353A ARP030103353A AR041197A1 AR 041197 A1 AR041197 A1 AR 041197A1 AR P030103353 A ARP030103353 A AR P030103353A AR P030103353 A ARP030103353 A AR P030103353A AR 041197 A1 AR041197 A1 AR 041197A1
Authority
AR
Argentina
Prior art keywords
aryl
hydrogen
alkyl
alkoxy
halogen
Prior art date
Application number
ARP030103353A
Other languages
English (en)
Original Assignee
Fmc Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fmc Corp filed Critical Fmc Corp
Publication of AR041197A1 publication Critical patent/AR041197A1/es

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/10Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with sulfur as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/18Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with sulfur as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/22Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/62Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms three- or four-membered rings or rings with more than six members

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Se ha encontrado que ciertos derivados tricíclicos han proporcionado una actividad insecticida inesperada. Estos compuestos son representados por la fórmula (1), donde R1 a R8, inclusive, y X e Y se describen en forma completa. También se revelan las composiciones que comprenden una cantidad efectiva como insecticida de por lo menos un compuesto de fórmula (1), y opcionalmente una cantidad efectiva de por lo menos un segundo compuesto, con por lo menos un portador insecticidamente compatible, juntamente con los métodos para controlar insectos que comprenden aplicar dichas composiciones al lugar donde los insectos se encuentran presentes o se espera que se encuentren presentes. Reivindicación 1: Una composición insecticida que comprende por lo menos una cantidad efectiva como insecticida de un compuesto de la fórmula (1) y por lo menos un portador insecticidamente compatible para la misma, en donde de R1 a R8, inclusive, son independientemente seleccionados entre hidrógeno, halógeno, alquilo, cicloalquilo, alquenilo, alquinilo, trialquilsililalquinilo, alcoxi, haloalquilo, haloalcoxi, alquiltio, alquilsulfinilo, alquilsulfonilo, haloalquiltio, haloalquilsulfinilo, haloalquilsulfonilo, dialquilaminosulfonilo, nitro, ciano, amino, formilo, o alquilcarbonilo; X es seleccionado entre -CR9R10-, -CR11R12CR13R14-, -CR15=CR16-, -NR17-, -CR18R19NR20-, o -CR21=N-; e Y es seleccionado entre -CR22R23-, -CR24R25CR26R27-, -CR28=CR29-, -NR30-, -CR31R32NR33-, -O-, -S-, -S(O)-, -S(O)2-, -CR34R35O-, -CR36R37S-, o -CR38=N-; where R9 y R10 son independientemente seleccionados entre hidrógeno, alquilo, o (piperidin-4-il)alquilo; o R9 y R10 pueden ser tomados conjuntamente con un resto de fórmula (2), o con =CHC2H4NR40R41, donde R39, R40 y R41 son independientemente seleccionados entre hidrógeno; alquilo; hidroxilalquilo; alcoxialquilo; alquiltioalquilo; alcoxicarbonilalquilo; haloalcoxicarbonilo; arilalquilo; ariloxialquilo; arilcarbonilalquilo; arilcarboniloxialquilo, en donde arilo es opcionalmente substituido con uno o más halógeno, alcoxi, haloalquilo, o arilo; o R40 y R41 pueden ser tomados conjuntamente con -C2H4N(CH3)C2H4- para formar un anillo piperazina; u es 0 o 1, y cuando u es 1, se forma un N-óxido; n es 0, y Ra es hidrógeno; o n es 1 a 8, y Ra es seleccionado entre opcionalmente substituido uno o más alquilo, alcoxialquilo, alcoxicarbonilo, y arilo, en donde arilo es opcionalmente substituido con uno o más halógeno, alcoxi, haloalquilo, o arilo; R11 es seleccionado entre hidrógeno, alquilo, alquilaminoalcoxi, dialquilaminoalcoxi, N(alquil)(alquilaminoalquilo), N(alquil)(dialquilaminoalquilo), alquilaminoalquilalquinilo, dialquilaminoalquilalquinilo, morfolinilo, imidazolinilo, alquilpirrolidiniloxi o el grupo de fórmulas (3) a (8), donde v es 0 o 1, y cuando v es 1, A es un grupo puente seleccionado entre -O-, -S-, -NH-, y -CH2-; u es tal como se define anteriormente; R42 a R45, inclusive, son independientemente seleccionados entre hidrógeno; alquilo; alquenilo; alquinilo; hidroxilalquilo; alcoxialquilo; alquiltioalquilo; alquilcarbonilo; alcoxicarbonilalquilo; haloalcoxicarbonilo; arilalquilo; ariloxialquilo; arilcarbonilalquilo; arilcarboniloxialquilo; heteroarilo; heteroarilalquilo; heteroarilalquilamino; en donde arilo y heteroarilo son opcionalmente substituidos con uno o más halógeno, alcoxi, haloalquilo, o arilo; o R43 y R44 pueden ser tomados conjuntamente con -C5H10- para formar un anillo de piperidina; m, p, y q son 0, y Rb, Rc y Rd son hidrógeno; o m es 1 a 8, p es 1 a 7, y q es 1 a 10, y Rb, Rc y Rd, respectivamente, son independientemente seleccionados entre uno o más alquilo, alcoxialquilo, alquilamino, dialquilamino, alcoxicarbonilo, o arilo, en donde arilo es opcionalmente substituido con uno o más halógeno, alcoxi, haloalquilo, o arilo; o R11 y R12 pueden ser tomados conjuntamente con la fórmula (2) donde Ra, n, u, y R39 son tal como se describe anteriormente; R12, cuando no se toma conjuntamente con R11 y R13, R14 y R16, son independientemente seleccionados entre hidrógeno, hidroxi, halógeno, alquilo, alcoxi, alquilcarbonilo, alquilcarboniloxi, alcoxicarbonilo, alcoxicarboniloxi, alquilaminocarbonilo, dialquilaminocarbonilo, alquilaminocarboniloxi, dialquilaminocarboniloxi, alquilaminosulfonilo, o dialquilaminosulfonilo; R15 es seleccionado entre las fórmulas (5) y (6) donde m, u, v, A, Rb y R42 tal como se definen anteriormente; R17 es hidrógeno; alquilo; alcoxialquilo; alcoxicarbonilo; dialquilaminoalquilo; alquilaminocarbonilo; dialquilaminocarbonilo; alquilsulfonilo; arilo, y arilalquilo en donde arilo es opcionalmente substituido con uno o más halógeno, alcoxi, haloalquilo, arilo; la fórmula (9); o -C3H6NR47R48 donde A, v, y u son tal como se definen anteriormente; R46 es seleccionado entre hidrógeno; alquilo; alquenilo; alquinilo; hidroxilalquilo; alcoxialquilo; alquiltioalquilo; alquilcarbonilo; alcoxicarbonilalquilo; haloalcoxicarbonilo; arilalquilo; ariloxialquilo; arilcarbonilalquilo; arilcarboniloxialquilo; heteroarilo; heteroarilalquilo; heteroarilalquilamino; en donde arilo y heteroarilo son opcionalmente substituidos con uno o más halógeno, alcoxi, haloalquilo, o arilo; R47 y R48 son independientemente seleccionados entre hidrógeno y alquilo; o R47 y R48 pueden ser tomados conjuntamente con -C5H10- para formar un anillo de piperidina, o con -C2H4N(CH3)C2H4-, o -C2H4N(C2H4OH)C2H4- para formar un anillo de piperazina; R18 y R19 son independientemente seleccionados entre hidrógeno, alquilo, amino, alquilaminoalquilo, y dialquilaminoalquilo; R20 es seleccionado entre hidrógeno; alquilo; alcoxialquilo; alcoxicarbonilo; dialquilaminoalquilo; alquilaminocarbonilo; dialquilaminocarbonilo; alquilsulfonilo; arilo, y arilalquilo en donde arilo es opcionalmente substituido con uno o más halógeno, alcoxi, haloalquilo, o arilo; R21 es seleccionado entre hidrógeno, alquilo o las fórmulas (10), (11) y (12) donde A, v, y u son tal como se define anteriormente; R49 a R52, inclusive, son independientemente seleccionados entre hidrógeno; alquilo; alquenilo, alquinilo, hidroxilalquilo; alcoxialquilo; alquiltioalquilo; alquilcarbonilo, alcoxicarbonilalquilo; haloalcoxicarbonilo; arilalquilo; ariloxialquilo; arilcarbonilalquilo; arilcarboniloxialquilo, heteroarilo, heteroarilalquilo, heteroarilalquilamino, en donde arilo y heteroarilo son opcionalmente substituidos con uno o más halógeno, alcoxi, haloalquilo, o arilo; o R50 y R51 pueden ser tomados conjuntamente con -C5H10- para formar un anillo de piperidina; r, s y t son 0, y Re, Rf, y Rg son hidrógeno, o r es 1 a 8, s es 1 a 7, t es 1 a 10, y Re, Rf, y Rg, respectivamente, son independientemente seleccionados entre uno o más alquilo, alcoxialquilo, alquilamino, dialquilamino, alcoxicarbonilo, o arilo, en donde arilo es opcionalmente substituido con uno o más halógeno, alcoxi, haloalquilo, o arilo; R22 a R29, inclusive, son independientemente seleccionados entre hidrógeno y alquilo; R30 es seleccionado entre hidrógeno; alquilo; alcoxialquilo; alcoxicarbonilo; dialquilaminoalquilo; alquilaminocarbonilo; dialquilaminocarbonilo; alquilsulfonilo; arilo, y arilalquilo en donde arilo es opcionalmente substituido con uno o más halógeno, alcoxi, haloalquilo, o arilo; R31 y R32 son independientemente seleccionados entre hidrógeno y alquilo, R33 es seleccionado entre hidrógeno; alquilo; alcoxialquilo; alcoxicarbonilo; dialquilaminoalquilo; alquilaminocarbonilo; dialquilaminocarbonilo; alquilsulfonilo; arilo, y arilalquilo en donde arilo es opcionalmente substituido con uno o más halógeno, alcoxi, haloalquilo, o arilo; R34 a R38, inclusive, son independientemente seleccionados entre hidrógeno, y alquilo; y, sales agrícolamente aceptables del mismo.
ARP030103353A 2002-09-18 2003-09-16 Derivados triciclicos insecticidas AR041197A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US41192602P 2002-09-18 2002-09-18

Publications (1)

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AR041197A1 true AR041197A1 (es) 2005-05-04

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Country Status (12)

Country Link
US (1) US20060111342A1 (es)
EP (1) EP1538906A2 (es)
JP (1) JP2005539076A (es)
KR (1) KR20050048633A (es)
CN (1) CN1681388A (es)
AR (1) AR041197A1 (es)
AU (1) AU2003272362A1 (es)
BR (1) BR0314108A (es)
MX (1) MXPA05002884A (es)
TW (1) TW200418383A (es)
WO (1) WO2004026030A2 (es)
ZA (1) ZA200501774B (es)

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TWI698430B (zh) * 2015-02-13 2020-07-11 南北兄弟藥業投資有限公司 三環化合物及其在藥物中的應用
CN110128432B (zh) * 2018-02-02 2021-03-02 广东东阳光药业有限公司 含氮三环化合物及其在药物中的应用
CN109897027B (zh) * 2019-04-28 2021-11-02 梯尔希(南京)药物研发有限公司 一种3-羟基地氯雷他定代谢物的合成方法
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Publication number Publication date
AU2003272362A1 (en) 2004-04-08
CN1681388A (zh) 2005-10-12
US20060111342A1 (en) 2006-05-25
WO2004026030A3 (en) 2004-06-03
JP2005539076A (ja) 2005-12-22
ZA200501774B (en) 2005-11-30
KR20050048633A (ko) 2005-05-24
MXPA05002884A (es) 2005-06-22
TW200418383A (en) 2004-10-01
WO2004026030A2 (en) 2004-04-01
BR0314108A (pt) 2006-04-25
EP1538906A2 (en) 2005-06-15

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