AR040800A1 - Procedimiento y dispositivo para la obtencion de formiato de acido formico y su uso - Google Patents
Procedimiento y dispositivo para la obtencion de formiato de acido formico y su usoInfo
- Publication number
- AR040800A1 AR040800A1 AR20030102817A ARP030102817A AR040800A1 AR 040800 A1 AR040800 A1 AR 040800A1 AR 20030102817 A AR20030102817 A AR 20030102817A AR P030102817 A ARP030102817 A AR P030102817A AR 040800 A1 AR040800 A1 AR 040800A1
- Authority
- AR
- Argentina
- Prior art keywords
- formic acid
- water
- formate
- methyl ester
- obtaining
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/02—Formic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/02—Formic acid
- C07C53/06—Salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fodder In General (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procedimiento para la obtención de formiatos de ácido fórmico, en donde: a)se hidroliza éster metílico de ácido formiato parcialmente con agua; b) se separa de la mezcla de reacción procedente de la etapa de procedimiento a) el éster metílico de ácido fórmico y el metanol por destilación, formándose una corriente que contiene ácido fórmico y agua; y c) se reúne la corriente que contiene ácido fórmico y agua de la etapa de procedimiento b) con el correspondiente formiato, formándose una mezcla que contiene el formiato de ácido fórmico y agua, un dispositivo para su obtención y el uso de los mismos. Reivindicación 1: Procedimiento para la obtención de formiatos de ácido fórmico, caracterizado porque: a) se hidroliza éster metílico de ácido fórmico parcialmente con agua; b) se separa de la mezcla de reacción procedente de la etapa de procedimiento a) el éster metílico de ácido fórmico y el metanol por destilación, formándose una corriente que contiene ácido fórmico y agua; y c) se reúne la corriente que contiene ácido fórmico y agua de la etapa de procedimiento b) con el correspondiente formiato, formándose una mezcla que contiene el formiato de ácido fórmico y agua. Reivindicación 13: Uso de los formiatos de ácido fórmico preparados según las reivindicaciones 1 a 9 para la preparación y / o acidulación de sustancias vegetales y / o animales. Reivindicación 14: Uso de los formiatos de ácido fórmico preparados según las reivindicaciones 1 a 9 para el tratamiento de desperdicios biológicos. Reivindicación 15: Uso de los formiatos de ácido fórmico preparados según las reivindicaciones 1 a 9 como aditivo en la nutrición animal y / o como estimulante de crecimiento para animales.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10237380A DE10237380A1 (de) | 2002-08-12 | 2002-08-12 | Verfahren und Vorrichtung zur Herstellung von ameisensauren Formlaten und deren Verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR040800A1 true AR040800A1 (es) | 2005-04-20 |
Family
ID=30469746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AR20030102817A AR040800A1 (es) | 2002-08-12 | 2003-08-06 | Procedimiento y dispositivo para la obtencion de formiato de acido formico y su uso |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US7323593B2 (es) |
| EP (1) | EP1530560A1 (es) |
| JP (1) | JP2006503021A (es) |
| KR (1) | KR20050069983A (es) |
| CN (1) | CN1275924C (es) |
| AR (1) | AR040800A1 (es) |
| AU (1) | AU2003253357A1 (es) |
| BR (1) | BR0313247A (es) |
| CA (1) | CA2495369A1 (es) |
| DE (1) | DE10237380A1 (es) |
| MX (1) | MXPA05001135A (es) |
| MY (1) | MY131142A (es) |
| NO (1) | NO20050534L (es) |
| PL (1) | PL375589A1 (es) |
| RU (1) | RU2005106993A (es) |
| TW (1) | TW200420532A (es) |
| WO (1) | WO2004022517A1 (es) |
| ZA (1) | ZA200502074B (es) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10321733A1 (de) * | 2003-05-14 | 2004-12-02 | Basf Ag | Verfahren zur Herstellung von ameisensauren Formiaten |
| TW200523246A (en) * | 2003-11-06 | 2005-07-16 | Basf Ag | Preparation of acid formates |
| MY158458A (en) * | 2005-04-13 | 2016-10-14 | Basf Ag | Sodium diformate production and use |
| DE102005020890A1 (de) | 2005-05-04 | 2006-11-09 | Basf Ag | Herstellung von Natriumformiat |
| DE102005062931A1 (de) * | 2005-12-29 | 2007-07-05 | Basf Ag | Herstellung von Natriumdiformiat |
| EP2414475A1 (en) * | 2009-03-31 | 2012-02-08 | E. I. du Pont de Nemours and Company | Temperature adjustment device |
| US9012345B2 (en) | 2010-03-26 | 2015-04-21 | Dioxide Materials, Inc. | Electrocatalysts for carbon dioxide conversion |
| US9790161B2 (en) | 2010-03-26 | 2017-10-17 | Dioxide Materials, Inc | Process for the sustainable production of acrylic acid |
| US10173169B2 (en) | 2010-03-26 | 2019-01-08 | Dioxide Materials, Inc | Devices for electrocatalytic conversion of carbon dioxide |
| US9181625B2 (en) | 2010-03-26 | 2015-11-10 | Dioxide Materials, Inc. | Devices and processes for carbon dioxide conversion into useful fuels and chemicals |
| US9566574B2 (en) | 2010-07-04 | 2017-02-14 | Dioxide Materials, Inc. | Catalyst mixtures |
| US9815021B2 (en) | 2010-03-26 | 2017-11-14 | Dioxide Materials, Inc. | Electrocatalytic process for carbon dioxide conversion |
| US9957624B2 (en) | 2010-03-26 | 2018-05-01 | Dioxide Materials, Inc. | Electrochemical devices comprising novel catalyst mixtures |
| US8956990B2 (en) | 2010-03-26 | 2015-02-17 | Dioxide Materials, Inc. | Catalyst mixtures |
| US9193593B2 (en) | 2010-03-26 | 2015-11-24 | Dioxide Materials, Inc. | Hydrogenation of formic acid to formaldehyde |
| US20110237830A1 (en) | 2010-03-26 | 2011-09-29 | Dioxide Materials Inc | Novel catalyst mixtures |
| US10647652B2 (en) | 2013-02-24 | 2020-05-12 | Dioxide Materials, Inc. | Process for the sustainable production of acrylic acid |
| US10774431B2 (en) | 2014-10-21 | 2020-09-15 | Dioxide Materials, Inc. | Ion-conducting membranes |
| CN104387255B (zh) * | 2014-11-11 | 2017-01-25 | 湖北瑞富阳化工科技有限公司 | 一种甲酸钙的制备方法 |
| US10975480B2 (en) | 2015-02-03 | 2021-04-13 | Dioxide Materials, Inc. | Electrocatalytic process for carbon dioxide conversion |
| CN109848191B (zh) * | 2019-04-12 | 2021-05-28 | 南京大学 | 一种连续化处理高盐高cod化工危废的装置 |
| CN113999102A (zh) * | 2021-11-03 | 2022-02-01 | 武汉联德化学品有限公司 | 一种制备甲酸的方法 |
| CN117504769B (zh) * | 2024-01-05 | 2024-08-06 | 江苏中丹化工技术有限公司 | 一种利用微反应器连续制备酸式甲酸盐的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4299981A (en) * | 1978-06-05 | 1981-11-10 | Leonard Jackson D | Preparation of formic acid by hydrolysis of methyl formate |
| NZ192046A (en) | 1978-11-15 | 1981-02-11 | Bp Chemicals Co | Cementitious composition comprising an acid formate of ammonium, sodium or potassium as an accelerator |
| DE2914671A1 (de) | 1979-04-11 | 1980-10-23 | Basf Ag | Verfahren zur gewinnung von wasserfreier oder weitgehend wasserfreier ameisensaeure |
| NO300038B1 (no) | 1995-05-12 | 1997-03-24 | Norsk Hydro As | Fremgangsmåte for fremstilling av produkter inneholdende dobbelsalter av maursyre |
| NO300912B1 (no) | 1995-05-12 | 1997-08-18 | Norsk Hydro As | Additiv for dyrefôr og fôr inneholdende slike additiv |
| NO308210B1 (no) | 1996-11-08 | 2000-08-14 | Norsk Hydro As | FremgangsmÕte til behandling av vÕtorganisk avfall samt anvendelse av løsning for behandling av organisk avfall |
| NO307591B1 (no) | 1998-08-14 | 2000-05-02 | Norsk Hydro As | Vandig konserveringsmiddel |
| CN1585735A (zh) * | 2001-11-09 | 2005-02-23 | 巴斯福股份公司 | 酸式甲酸盐的制备方法 |
| DE10210730A1 (de) | 2002-03-12 | 2003-09-25 | Basf Ag | Verfahren zur Herstellung von ameisensauren Formiaten |
| DE10154757A1 (de) | 2001-11-09 | 2003-05-22 | Basf Ag | Verfahren zur Herstellung von Metallformiat-Ameisensäure-Mischungen |
-
2002
- 2002-08-12 DE DE10237380A patent/DE10237380A1/de not_active Withdrawn
-
2003
- 2003-07-30 JP JP2004533288A patent/JP2006503021A/ja not_active Withdrawn
- 2003-07-30 WO PCT/EP2003/008400 patent/WO2004022517A1/de active Application Filing
- 2003-07-30 US US10/524,202 patent/US7323593B2/en not_active Expired - Fee Related
- 2003-07-30 CN CNB038192780A patent/CN1275924C/zh not_active Expired - Fee Related
- 2003-07-30 AU AU2003253357A patent/AU2003253357A1/en not_active Abandoned
- 2003-07-30 RU RU2005106993/04A patent/RU2005106993A/ru not_active Application Discontinuation
- 2003-07-30 KR KR1020057002311A patent/KR20050069983A/ko not_active Application Discontinuation
- 2003-07-30 CA CA002495369A patent/CA2495369A1/en not_active Abandoned
- 2003-07-30 BR BR0313247-1A patent/BR0313247A/pt not_active IP Right Cessation
- 2003-07-30 MX MXPA05001135A patent/MXPA05001135A/es not_active Application Discontinuation
- 2003-07-30 EP EP03793657A patent/EP1530560A1/de not_active Withdrawn
- 2003-07-30 PL PL03375589A patent/PL375589A1/xx unknown
- 2003-08-05 MY MYPI20032952A patent/MY131142A/en unknown
- 2003-08-06 AR AR20030102817A patent/AR040800A1/es not_active Application Discontinuation
- 2003-08-12 TW TW092122119A patent/TW200420532A/zh unknown
-
2005
- 2005-01-31 NO NO20050534A patent/NO20050534L/no not_active Application Discontinuation
- 2005-03-11 ZA ZA200502074A patent/ZA200502074B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU2003253357A1 (en) | 2004-03-29 |
| RU2005106993A (ru) | 2005-08-10 |
| NO20050534L (no) | 2005-03-02 |
| EP1530560A1 (de) | 2005-05-18 |
| CN1675158A (zh) | 2005-09-28 |
| ZA200502074B (en) | 2006-05-31 |
| MXPA05001135A (es) | 2005-05-16 |
| US7323593B2 (en) | 2008-01-29 |
| BR0313247A (pt) | 2005-07-12 |
| DE10237380A1 (de) | 2004-02-19 |
| TW200420532A (en) | 2004-10-16 |
| KR20050069983A (ko) | 2005-07-05 |
| MY131142A (en) | 2007-07-31 |
| CA2495369A1 (en) | 2004-03-18 |
| WO2004022517A1 (de) | 2004-03-18 |
| US20050256338A1 (en) | 2005-11-17 |
| JP2006503021A (ja) | 2006-01-26 |
| PL375589A1 (en) | 2005-11-28 |
| CN1275924C (zh) | 2006-09-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA | Abandonment or withdrawal |