AR024682A1 - Metodo para la preparacion de catalizadores de cianuro de metal mediante el uso de acidos policarboxilicos, y un proceso para polimerizar oxidos dealquileno. - Google Patents

Metodo para la preparacion de catalizadores de cianuro de metal mediante el uso de acidos policarboxilicos, y un proceso para polimerizar oxidos dealquileno.

Info

Publication number
AR024682A1
AR024682A1 ARP000103497A ARP000103497A AR024682A1 AR 024682 A1 AR024682 A1 AR 024682A1 AR P000103497 A ARP000103497 A AR P000103497A AR P000103497 A ARP000103497 A AR P000103497A AR 024682 A1 AR024682 A1 AR 024682A1
Authority
AR
Argentina
Prior art keywords
metal cyanide
dealquylene
catalyzers
polymerize
oxide
Prior art date
Application number
ARP000103497A
Other languages
English (en)
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of AR024682A1 publication Critical patent/AR024682A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08—Saturated oxiranes
    • C08G65/10—Saturated oxiranes characterised by the catalysts used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Toxicology (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Health & Medical Sciences (AREA)
  • Polyethers (AREA)

Abstract

Los catalizadores de cianuro de metal se preparan en la presencia de un poliácido orgánico. Los catalizadores activos de polimerizacion de oxido dealquileno se forman teniendo mayores tamanos de partícula que los catalizadores convencionales de cianuro de metal y, por lo tanto se separan más facilmente deun polímero preparado con el catalizador. Los poliácidos orgánicos preferidos son polímeros degradados o no degradados que contienen grupos colgantes carboxiloo carboxilato.
ARP000103497A 1999-07-09 2000-07-07 Metodo para la preparacion de catalizadores de cianuro de metal mediante el uso de acidos policarboxilicos, y un proceso para polimerizar oxidos dealquileno. AR024682A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US14308599P 1999-07-09 1999-07-09

Publications (1)

Publication Number Publication Date
AR024682A1 true AR024682A1 (es) 2002-10-23

Family

ID=22502538

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP000103497A AR024682A1 (es) 1999-07-09 2000-07-07 Metodo para la preparacion de catalizadores de cianuro de metal mediante el uso de acidos policarboxilicos, y un proceso para polimerizar oxidos dealquileno.

Country Status (8)

Country Link
EP (1) EP1196473A1 (es)
JP (1) JP2003504465A (es)
KR (1) KR20020027473A (es)
CN (1) CN1360608A (es)
AR (1) AR024682A1 (es)
AU (1) AU5921000A (es)
MX (1) MXPA02000305A (es)
WO (1) WO2001004180A1 (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6716788B2 (en) † 2002-06-14 2004-04-06 Shell Oil Company Preparation of a double metal cyanide catalyst
DE10235130A1 (de) 2002-08-01 2004-02-19 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US6696383B1 (en) 2002-09-20 2004-02-24 Bayer Polymers Llc Double-metal cyanide catalysts which can be used to prepare polyols and the processes related thereto
US6806348B2 (en) * 2003-02-11 2004-10-19 Basf Corporation Process for removing and regenerating a double metal cyanide (DMC) catalyst from a polymer polyol
DE102005011581A1 (de) * 2005-03-10 2006-09-14 Basf Ag Verfahren zur Herstellung von DMC-Katalysatoren
DE102005057895A1 (de) * 2005-12-02 2007-06-06 Basf Ag Verfahren zur Herstellung von Multimetallcyanidverbindungen
WO2011160296A1 (en) 2010-06-23 2011-12-29 Basf Se Modified double metal cyanide catalyst
US9758619B2 (en) 2011-08-25 2017-09-12 Dow Global Technologies Llc Process for making polyether alcohols having oxyethylene units by polymerization of ethylene carbonate in the presence of double metal cyanide catalysts
US9562134B2 (en) 2013-03-12 2017-02-07 Covestro Llc Catalyst for the production of polyols having lower amounts of high molecular weight tail
EP3087109B1 (en) * 2013-12-26 2018-08-29 Itaconix Corporation Soluble aqueous compositions of selected polyitaconic acid polymers
US9790395B2 (en) 2013-12-26 2017-10-17 Itaconix Corporation Soluble aqueous compositions of zinc salts of selected polyitaconic acid polymers
KR101466803B1 (ko) 2014-02-14 2014-11-28 부산대학교 산학협력단 이중금속시안염 촉매 및 이를 제조하는 방법
US20190185399A1 (en) * 2017-12-19 2019-06-20 Oriental Union Chemical Corp. High-activity double-metal-cyanide catalyst, method for fabricating the same, and applications of the same
WO2020062816A1 (zh) * 2018-09-29 2020-04-02 杭州普力材料科技有限公司 一种混合酸改性的锌钴双金属氰化物催化剂及其制备方法
CN110964191B (zh) * 2018-09-29 2021-02-02 杭州普力材料科技有限公司 一种混合酸改性的锌钴双金属氰化物催化剂及其制备方法
CN112537798A (zh) * 2020-12-07 2021-03-23 中国民用航空飞行学院 一种钴酸锌纳米线的制备方法
CN114516953A (zh) * 2022-03-07 2022-05-20 中国科学院过程工程研究所 一种可分离回收的双金属氰化物催化剂及其制备方法与应用

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU552988B2 (en) * 1982-03-31 1986-06-26 Shell Internationale Research Maatschappij B.V. Polymerizing epoxides and catalyst suspensions for this
US5714428A (en) * 1996-10-16 1998-02-03 Arco Chemical Technology, L.P. Double metal cyanide catalysts containing functionalized polymers
ID24172A (id) * 1997-10-13 2000-07-13 Bayer Ag Katalis logam ganda yang sangat aktif untuk memproduksi poliol-poliol poliester

Also Published As

Publication number Publication date
MXPA02000305A (es) 2002-06-21
AU5921000A (en) 2001-01-30
KR20020027473A (ko) 2002-04-13
JP2003504465A (ja) 2003-02-04
EP1196473A1 (en) 2002-04-17
CN1360608A (zh) 2002-07-24
WO2001004180A1 (en) 2001-01-18

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