AR019740A1 - PROCEDIMIENTO PARA LA ELABORACIoN DE HOMO-Y COPOLíMEROS DE ETILENO DE BAJA DENSIDAD. - Google Patents
PROCEDIMIENTO PARA LA ELABORACIoN DE HOMO-Y COPOLíMEROS DE ETILENO DE BAJA DENSIDAD.Info
- Publication number
- AR019740A1 AR019740A1 ARP990103183A ARP990103183A AR019740A1 AR 019740 A1 AR019740 A1 AR 019740A1 AR P990103183 A ARP990103183 A AR P990103183A AR P990103183 A ARP990103183 A AR P990103183A AR 019740 A1 AR019740 A1 AR 019740A1
- Authority
- AR
- Argentina
- Prior art keywords
- procedure
- preparation
- melt index
- homo
- low density
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
Abstract
Procedimiento para la elaboracion de homo- y copolímeros de etileno con un rango de densidad de hasta 0,930 g/cm3 y un rango de índice de fusion entre0,15 y 25 g/10 min (2,16 kg; 463 sK), con una mejor estabilidad operativa y disponibilidad deequipo s, con presiones superiores a 1000 bar y a temperaturas dehasta 603 sK en reactores tubulares, en presencia de iniciadores formadores de radicales, entre ellos, oxígeno y reguladores de cadena, de los cuales a lomenos uno presenta unaestructura alde hídica. En tal procedimiento se acoplan datos de cinética química de los materiales reactivos empleados (períodos de vidamedia térmica, concentraciones, cantidades a dosificar) con datos relevantes de la mecánica de fluidos delreactor tubular (veloc idad de circulacion ),tomando en consideracion la calidad deseada del producto (índice de fusion, índice de fluencia), de modo de reducir a un mínimo las reacciones secundariasperturbadoras, en particular, los efectos desustitucion polar inductivos que puedan conducir a un enriquecimiento en hidroperoxidos orgánicos y, con ello,poder lograr condiciones de proceso extraordinariamente estables.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19829399A DE19829399A1 (de) | 1998-07-01 | 1998-07-01 | Verfahren zur Herstellung von Ethylenhomo- und Ethylencopolymerisaten niederer Dichte |
Publications (1)
Publication Number | Publication Date |
---|---|
AR019740A1 true AR019740A1 (es) | 2002-03-13 |
Family
ID=7872638
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP990103183A AR019740A1 (es) | 1998-07-01 | 1999-06-30 | PROCEDIMIENTO PARA LA ELABORACIoN DE HOMO-Y COPOLíMEROS DE ETILENO DE BAJA DENSIDAD. |
Country Status (14)
Country | Link |
---|---|
US (1) | US6569962B1 (es) |
EP (1) | EP1098914B1 (es) |
JP (1) | JP4979106B2 (es) |
KR (1) | KR100632543B1 (es) |
AR (1) | AR019740A1 (es) |
AT (1) | ATE278718T1 (es) |
AU (1) | AU5503699A (es) |
BR (1) | BR9912229A (es) |
CA (1) | CA2336346C (es) |
CZ (1) | CZ20004754A3 (es) |
DE (2) | DE19829399A1 (es) |
PL (1) | PL346218A1 (es) |
RU (1) | RU2221814C2 (es) |
WO (1) | WO2000001740A2 (es) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19860396A1 (de) * | 1998-12-28 | 2000-06-29 | Bosch Gmbh Robert | Elektromotor mit elektromagnetischer Bremse |
JP2003527474A (ja) * | 2000-03-16 | 2003-09-16 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | ポリエチレンの製造方法 |
DE10060372A1 (de) * | 2000-12-05 | 2002-06-06 | Basell Polyolefine Gmbh | Vorrichtung zur Initiatoreinspeisung an Reaktoren |
DE10128221A1 (de) * | 2001-06-11 | 2002-12-19 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Ethylenhomo-und -copolymeren durch radikalische Hochdruckpolymerisation |
US6673878B2 (en) | 2001-12-19 | 2004-01-06 | Exxonmobil Chemical Patents Inc. | Tubular polymerization reactors and polymers made therein |
US7745550B2 (en) * | 2001-12-19 | 2010-06-29 | Exxonmobil Chemical Patents Inc. | Tubular polymerization reactors and polymers made therein |
RU2009137375A (ru) * | 2007-03-09 | 2011-04-20 | Дау Глобал Текнолоджиз Инк. (Us) | Система свободнорадикального инициатора и способ свободнорадикальной полимеризации высокого давления для получения полимерного полиэтилена низкой плотности |
CN101802021A (zh) * | 2007-07-13 | 2010-08-11 | 陶氏环球技术公司 | 用于高压聚烯烃生产的超高压压缩机润滑剂 |
WO2009012092A1 (en) * | 2007-07-13 | 2009-01-22 | Dow Global Technologies Inc. | Low dielectric loss power cable sheaths comprising high pressure polyolefins free of silane functionality |
WO2010042390A1 (en) | 2008-10-07 | 2010-04-15 | Dow Global Technologies Inc. | High pressure low density polyethylene resins with improved optical properties produced through the use of highly active chain transfer agents |
KR101668890B1 (ko) | 2009-01-16 | 2016-10-24 | 바젤 폴리올레핀 게엠베하 | 개시제 공급이 개선된 고압 반응기에서의 에틸렌 중합 |
CN102282180B (zh) | 2009-01-16 | 2013-11-20 | 巴塞尔聚烯烃股份有限公司 | 在减少输出量的管式反应器中的乙烯聚合方法 |
EP2239283B1 (en) | 2009-11-10 | 2012-01-25 | Basell Polyolefine GmbH | High pressure LDPE for medical applications |
US20110172354A1 (en) * | 2010-01-04 | 2011-07-14 | Dow Global Technologies Inc. | Ethylene-based polymer compositions for use in fiber applications |
US20110196105A1 (en) * | 2010-02-08 | 2011-08-11 | Dow Global Technologies Inc. | Novel high pressure, low density polyethylene resins produced through the use of highly active chain transfer agents |
EP3002300B1 (en) | 2011-10-19 | 2017-07-19 | Dow Global Technologies LLC | Polymerization processes with fresh ethylene distributions for preparation of low density ethylene-based polymers |
JP6454152B2 (ja) | 2011-11-23 | 2019-01-16 | ダウ グローバル テクノロジーズ エルエルシー | 低分子量の抽出物を有する低密度エチレン系ポリマー |
EP3098262B1 (en) | 2011-11-23 | 2019-06-05 | Dow Global Technologies LLC | Low density ethylene-based polymers with broad molecular weight distributions and low extractables |
US10400046B2 (en) | 2015-06-25 | 2019-09-03 | Joseph J. Matsko | Portable powered paint system |
ES2786677T3 (es) | 2015-06-25 | 2020-10-13 | Dow Global Technologies Llc | Proceso para formar polímeros basados en etileno |
CN107750257B (zh) | 2015-06-25 | 2021-03-30 | 陶氏环球技术有限责任公司 | 制备具有较高g′和较宽mwd的管状乙烯基聚合物的改进方法 |
EP3313903B1 (en) | 2015-06-25 | 2020-01-01 | Dow Global Technologies LLC | Ethylene-based polymers with low hexane extractables |
US10730973B2 (en) | 2015-06-25 | 2020-08-04 | Dow Global Technologies Llc | Ethylene-based polymers with low hexane extractables and low densities |
US10941220B2 (en) | 2016-06-24 | 2021-03-09 | Dow Global Technologies Llc | Process for making high pressure free radical ethylene copolymers |
EP3260473A1 (en) | 2016-06-24 | 2017-12-27 | Dow Global Technologies LLC | High pressure, free radical polymerizations to produce ethylene-based polymers |
BR112019027598B1 (pt) | 2017-06-28 | 2023-05-02 | Dow Global Technologies Llc | Processo para formar um polímero à base de etileno em um sistema de reator |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2891936A (en) * | 1956-06-12 | 1959-06-23 | Eastman Kodak Co | High density polyethylene by high pressure polymerization with small amounts of aldehydes |
BE607527A (es) * | 1960-08-29 | 1900-01-01 | ||
US3420807A (en) | 1966-12-19 | 1969-01-07 | Wallace & Tiernan Inc | Vinyl chloride polymerization |
DE1795365A1 (de) * | 1968-09-20 | 1972-01-05 | Basf Ag | Verfahren zum kontinuierlichen Herstellen von AEthylenhomopolymerisaten |
BE754577A (es) | 1969-08-08 | 1971-02-08 | Wacker Chemie Gmbh | |
US3687867A (en) | 1970-04-08 | 1972-08-29 | Argus Chem | Novel co-initiator systems |
DE2034534B2 (de) * | 1970-07-11 | 1978-08-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zum Herstellen niedermolekularer, wachsartiger Polyäthylene |
DE3404742A1 (de) * | 1984-02-10 | 1985-08-14 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von copolymerisaten des ethylens mit carboxylgruppenhaltigen comonomeren in einem 2-zonen-reaktor bei druecken oberhalb 500 bar |
DD276598A3 (de) * | 1988-04-12 | 1990-03-07 | Leuna Werke Veb | Verfahren zur einstellung und regelung der einsatzgasstroeme fuer mehrzonenrohrreaktoren |
DE3844047A1 (de) * | 1988-12-28 | 1990-07-05 | Basf Ag | Copolymerisate aus ethylen mit alkencarbonsaeuren und/oder alkencarbonsaeurederivaten |
DE3912975A1 (de) * | 1989-04-20 | 1990-11-08 | Basf Ag | Polyethylen sowie copolymerisate aus ueberwiegenden anteilen von ethylen |
DE4219129A1 (de) * | 1992-06-11 | 1993-12-16 | Basf Ag | Verfahren zur Herstellung von Copolymerisaten des Ethylens mit Acrylsäureestern |
-
1998
- 1998-07-01 DE DE19829399A patent/DE19829399A1/de not_active Withdrawn
-
1999
- 1999-06-26 KR KR1020007015003A patent/KR100632543B1/ko not_active IP Right Cessation
- 1999-06-26 BR BR9912229-4A patent/BR9912229A/pt not_active IP Right Cessation
- 1999-06-26 US US09/719,602 patent/US6569962B1/en not_active Expired - Lifetime
- 1999-06-26 AU AU55036/99A patent/AU5503699A/en not_active Abandoned
- 1999-06-26 PL PL99346218A patent/PL346218A1/xx not_active Application Discontinuation
- 1999-06-26 CA CA002336346A patent/CA2336346C/en not_active Expired - Fee Related
- 1999-06-26 WO PCT/DE1999/001874 patent/WO2000001740A2/de active IP Right Grant
- 1999-06-26 EP EP99941396A patent/EP1098914B1/de not_active Expired - Lifetime
- 1999-06-26 CZ CZ20004754A patent/CZ20004754A3/cs unknown
- 1999-06-26 AT AT99941396T patent/ATE278718T1/de not_active IP Right Cessation
- 1999-06-26 JP JP2000558140A patent/JP4979106B2/ja not_active Expired - Lifetime
- 1999-06-26 DE DE59910762T patent/DE59910762D1/de not_active Expired - Lifetime
- 1999-06-26 RU RU2001102790/04A patent/RU2221814C2/ru not_active IP Right Cessation
- 1999-06-30 AR ARP990103183A patent/AR019740A1/es active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
WO2000001740A2 (de) | 2000-01-13 |
EP1098914A2 (de) | 2001-05-16 |
KR20010071685A (ko) | 2001-07-31 |
JP2002519485A (ja) | 2002-07-02 |
WO2000001740A3 (de) | 2000-08-24 |
RU2221814C2 (ru) | 2004-01-20 |
PL346218A1 (en) | 2002-01-28 |
EP1098914B1 (de) | 2004-10-06 |
BR9912229A (pt) | 2001-05-02 |
US6569962B1 (en) | 2003-05-27 |
KR100632543B1 (ko) | 2006-10-09 |
CA2336346C (en) | 2009-01-27 |
CA2336346A1 (en) | 2000-01-13 |
JP4979106B2 (ja) | 2012-07-18 |
DE19829399A1 (de) | 2000-02-03 |
CZ20004754A3 (cs) | 2002-02-13 |
ATE278718T1 (de) | 2004-10-15 |
AU5503699A (en) | 2000-01-24 |
DE59910762D1 (de) | 2004-11-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant, registration |