ZA916073B - Process for the recovery of rhodium from the residues of the distillation of products of the oxo process - Google Patents

Process for the recovery of rhodium from the residues of the distillation of products of the oxo process

Info

Publication number
ZA916073B
ZA916073B ZA916073A ZA916073A ZA916073B ZA 916073 B ZA916073 B ZA 916073B ZA 916073 A ZA916073 A ZA 916073A ZA 916073 A ZA916073 A ZA 916073A ZA 916073 B ZA916073 B ZA 916073B
Authority
ZA
South Africa
Prior art keywords
residues
monocarboxylic acid
rhodium
recovery
products
Prior art date
Application number
ZA916073A
Other languages
English (en)
Inventor
Peter Lappe
Lappe Peter
Helmut Springer
Springer Helmut
Original Assignee
Hoechst Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Ag filed Critical Hoechst Ag
Publication of ZA916073B publication Critical patent/ZA916073B/xx

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C01G55/001—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Processing Of Solid Wastes (AREA)
ZA916073A 1990-08-08 1991-08-01 Process for the recovery of rhodium from the residues of the distillation of products of the oxo process ZA916073B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4025074A DE4025074A1 (de) 1990-08-08 1990-08-08 Verfahren zur wiedergewinnung von rhodium aus den rueckstaenden der destillation von produkten der oxosynthese

Publications (1)

Publication Number Publication Date
ZA916073B true ZA916073B (en) 1992-04-29

Family

ID=6411819

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA916073A ZA916073B (en) 1990-08-08 1991-08-01 Process for the recovery of rhodium from the residues of the distillation of products of the oxo process

Country Status (11)

Country Link
US (1) US5151537A (xx)
EP (1) EP0475036B1 (xx)
JP (1) JPH0672115B2 (xx)
KR (1) KR950003422B1 (xx)
AT (1) ATE98611T1 (xx)
AU (1) AU640033B2 (xx)
DE (2) DE4025074A1 (xx)
DK (1) DK0475036T3 (xx)
ES (1) ES2049508T3 (xx)
TW (1) TW204373B (xx)
ZA (1) ZA916073B (xx)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4110212A1 (de) * 1991-03-28 1992-10-01 Hoechst Ag Verfahren zur wiedergewinnung von rhodium aus den rueckstaenden der destillation von produkten oder oxosynthese
TW319771B (xx) * 1994-04-05 1997-11-11 Mitsubishi Chem Corp
CZ283697A3 (cs) * 1996-09-11 1998-04-15 Mitsubishi Chemical Corporation Způsob přípravy roztoku komplexu rhodia a jeho použití
DE10005084C1 (de) * 2000-02-04 2001-09-13 Celanese Chem Europe Gmbh Verfahren zur Wiedergewinnung von Rhodium aus Reaktionsprodukten der Oxosynthese
GB0113079D0 (en) * 2001-05-30 2001-07-18 Kvaerner Process Tech Ltd Process

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4196096A (en) * 1979-02-12 1980-04-01 Eastman Kodak Company Process for regeneration of rhodium hydroformylation catalysts
US4390473A (en) * 1981-06-22 1983-06-28 Eastman Kodak Company Recovery of rhodium and cobalt low pressure oxo catalyst
US4612402A (en) * 1982-03-29 1986-09-16 Allied Corporation Oxidation of olefins using rhodium nitro complex
DE3515396A1 (de) * 1985-04-29 1986-10-30 Hoechst Ag, 6230 Frankfurt Verfahren zur reinigung und rueckgewinnung der bei der carbonylierung von methylacetat und/oder dimethylether anfallenden verunreinigten katalysatorloesung
US4694109A (en) * 1986-06-13 1987-09-15 Eastman Kodak Company Chelate ligands for low pressure hydroformylation catalyst and process employing same
DE3744213A1 (de) * 1987-12-24 1989-07-06 Ruhrchemie Ag Verfahren zur rueckgewinnung von rhodium aus rhodiumkomplexverbindungen enthaltenden waessrigen loesungen
DE3822037A1 (de) * 1988-06-30 1990-01-04 Hoechst Ag Verfahren zur abtrennung und wiedergewinnung von rhodium aus den produkten der oxosynthese
DE3934824A1 (de) * 1989-10-19 1991-04-25 Hoechst Ag Verfahren zur wiedergewinnung von rhodium aus den rueckstaenden der destillation von produkten der oxosynthese
US5099047A (en) * 1989-11-17 1992-03-24 Mitsubishi Kasei Corporation Method for recovering a group viii metal solid complex and hydroformylation method
US5099048A (en) * 1990-09-11 1992-03-24 The University Of North Carolina At Chapel Hill Rhodium-catalyzed olefin dimerization

Also Published As

Publication number Publication date
JPH04230642A (ja) 1992-08-19
DK0475036T3 (da) 1994-01-24
ATE98611T1 (de) 1994-01-15
ES2049508T3 (es) 1994-04-16
DE59100730D1 (de) 1994-01-27
JPH0672115B2 (ja) 1994-09-14
AU8169491A (en) 1992-02-13
AU640033B2 (en) 1993-08-12
EP0475036A1 (de) 1992-03-18
DE4025074A1 (de) 1992-02-13
US5151537A (en) 1992-09-29
KR920004032A (ko) 1992-03-27
KR950003422B1 (ko) 1995-04-12
EP0475036B1 (de) 1993-12-15
TW204373B (xx) 1993-04-21

Similar Documents

Publication Publication Date Title
ZA916073B (en) Process for the recovery of rhodium from the residues of the distillation of products of the oxo process
ZA922066B (en) A process for the recovery of rhodium from the residues of the distillation of products of the oxo synthesis
MY101210A (en) Process for producing fatty acids from lower alcohol ester of fatty acids.
ATE71412T1 (de) Verfahren zur rueckgewinnung von rhodium.
GB822834A (en) A method of processing waste of polyethylene terephthalate by hydrolysis
CA2027514A1 (en) Process for the recovery of rhodium from distillation residues of products of the oxo synthesis
AU4492093A (en) Process for the recovery of rhodium from distillation residues of products of the oxo synthesis
DE3769245D1 (de) Verfahren zur phlegmatisierung von wasserunloeslichen peroxycarbonsaeuren.
ATE8494T1 (de) Verfahren zur entfernung von hydroperoxiden und aldehyden aus allyl-alkyl-aethern.
GB679664A (en) Improvements in or relating to the treatment of terpenes
GB2021630A (en) Catalytic Conversion of Carbonaceous Solids
JPS56164141A (en) Preparation of 2-hydroxyalkyl acrylate or 2-hydroxyalkyl methacrylate
GB930143A (en) Method of and apparatus for the manufacture of aldehydes or ketones
Lappe et al. Process for Recovering Rhodium From the Distillation Residues of Oxysynthesis Products
JPS5219607A (en) Process for recovery of polyhydric alcohols
RO100132B1 (ro) Procedeu de obtinere si purificare a acizilor fenilen-bis-oxi-bis-acetici
GB960905A (en) A process for the purification of monocarboxylic acids prepared from olefins, carbonmonoxide and water
TH12618EX (th) อีเธอร์ที่ปราศจากเอสเทอร์
JPS643152A (en) Production of glycol esters