AU4492093A - Process for the recovery of rhodium from distillation residues of products of the oxo synthesis - Google Patents
Process for the recovery of rhodium from distillation residues of products of the oxo synthesisInfo
- Publication number
- AU4492093A AU4492093A AU44920/93A AU4492093A AU4492093A AU 4492093 A AU4492093 A AU 4492093A AU 44920/93 A AU44920/93 A AU 44920/93A AU 4492093 A AU4492093 A AU 4492093A AU 4492093 A AU4492093 A AU 4492093A
- Authority
- AU
- Australia
- Prior art keywords
- recovery
- products
- rhodium
- distillation residues
- oxo synthesis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000004821 distillation Methods 0.000 title abstract 2
- 238000011084 recovery Methods 0.000 title abstract 2
- 229910052703 rhodium Inorganic materials 0.000 title abstract 2
- 239000010948 rhodium Substances 0.000 title abstract 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- -1 alkali metal salt Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 229910000510 noble metal Inorganic materials 0.000 abstract 1
- 239000012074 organic phase Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Catalysts (AREA)
Abstract
For the recovery of the rhodium contained in them as soluble compounds, the distillation residues of products of the oxo synthesis are treated with oxygen or an oxygen-containing gas in the presence of an alkali metal salt of a C2- to C5-monocarboxylic acid. The noble metal is then extracted from the organic phase using the aqueous solution of a complex-forming reagent, optionally after it has already been previously extracted with water on its own.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4228724 | 1992-08-28 | ||
DE4228724A DE4228724A1 (en) | 1992-08-28 | 1992-08-28 | Process for the recovery of rhodium from the distillation residues of products of oxosynthesis |
Publications (1)
Publication Number | Publication Date |
---|---|
AU4492093A true AU4492093A (en) | 1994-03-03 |
Family
ID=6466690
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU44920/93A Abandoned AU4492093A (en) | 1992-08-28 | 1993-08-27 | Process for the recovery of rhodium from distillation residues of products of the oxo synthesis |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP0584720B1 (en) |
JP (1) | JPH0767532B2 (en) |
KR (1) | KR100290221B1 (en) |
AT (1) | ATE153026T1 (en) |
AU (1) | AU4492093A (en) |
BR (1) | BR9303432A (en) |
CA (1) | CA2104509A1 (en) |
DE (2) | DE4228724A1 (en) |
ES (1) | ES2103051T3 (en) |
MX (1) | MX9305089A (en) |
TW (1) | TW287114B (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CZ283697A3 (en) * | 1996-09-11 | 1998-04-15 | Mitsubishi Chemical Corporation | Process for preparing solution of rhodium complex and the use thereof |
DE19824534A1 (en) | 1998-06-03 | 1999-12-09 | Basf Ag | Process for the production of butyrolactones |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4248802A (en) * | 1975-06-20 | 1981-02-03 | Rhone-Poulenc Industries | Catalytic hydroformylation of olefins |
DE3347406A1 (en) * | 1983-12-29 | 1985-07-11 | Ruhrchemie Ag, 4200 Oberhausen | METHOD FOR SEPARATING AND RECOVERING RHODIUM FROM OXOSYNTHESIS PRODUCTS |
DE3822037A1 (en) * | 1988-06-30 | 1990-01-04 | Hoechst Ag | METHOD FOR SEPARATING AND RECOVERING RHODIUM FROM OXOSYNTHESIS PRODUCTS |
US4935550A (en) * | 1988-08-12 | 1990-06-19 | Union Carbide Chemicals And Plastics Company Inc. | Catalytic metal recovery from non-polar organic solutions |
DE3934824A1 (en) * | 1989-10-19 | 1991-04-25 | Hoechst Ag | METHOD FOR RECOVERY OF RHODIUM FROM THE RESIDUES OF THE DISTILLATION OF OXOSYNTHESIS PRODUCTS |
-
1992
- 1992-08-28 DE DE4228724A patent/DE4228724A1/en not_active Withdrawn
-
1993
- 1993-07-13 TW TW082105552A patent/TW287114B/zh active
- 1993-08-19 JP JP5205284A patent/JPH0767532B2/en not_active Expired - Fee Related
- 1993-08-19 AT AT93113258T patent/ATE153026T1/en not_active IP Right Cessation
- 1993-08-19 EP EP93113258A patent/EP0584720B1/en not_active Expired - Lifetime
- 1993-08-19 ES ES93113258T patent/ES2103051T3/en not_active Expired - Lifetime
- 1993-08-19 DE DE59306435T patent/DE59306435D1/en not_active Expired - Lifetime
- 1993-08-20 CA CA002104509A patent/CA2104509A1/en not_active Abandoned
- 1993-08-20 MX MX9305089A patent/MX9305089A/en not_active IP Right Cessation
- 1993-08-20 BR BR9303432A patent/BR9303432A/en not_active IP Right Cessation
- 1993-08-20 KR KR1019930016189A patent/KR100290221B1/en not_active IP Right Cessation
- 1993-08-27 AU AU44920/93A patent/AU4492093A/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
TW287114B (en) | 1996-10-01 |
JPH06182232A (en) | 1994-07-05 |
ATE153026T1 (en) | 1997-05-15 |
BR9303432A (en) | 1994-03-15 |
KR940003962A (en) | 1994-03-14 |
CA2104509A1 (en) | 1994-03-01 |
JPH0767532B2 (en) | 1995-07-26 |
DE59306435D1 (en) | 1997-06-19 |
MX9305089A (en) | 1994-02-28 |
EP0584720A1 (en) | 1994-03-02 |
EP0584720B1 (en) | 1997-05-14 |
ES2103051T3 (en) | 1997-08-16 |
DE4228724A1 (en) | 1994-03-03 |
KR100290221B1 (en) | 2001-09-17 |
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