ZA806160B - Improved hydroformylation process using stable rhodium catalyst - Google Patents

Improved hydroformylation process using stable rhodium catalyst

Info

Publication number
ZA806160B
ZA806160B ZA00806160A ZA806160A ZA806160B ZA 806160 B ZA806160 B ZA 806160B ZA 00806160 A ZA00806160 A ZA 00806160A ZA 806160 A ZA806160 A ZA 806160A ZA 806160 B ZA806160 B ZA 806160B
Authority
ZA
South Africa
Prior art keywords
rhodium catalyst
hydroformylation process
improved hydroformylation
stable rhodium
stable
Prior art date
Application number
ZA00806160A
Other languages
English (en)
Inventor
E Billig
D Bunning
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of ZA806160B publication Critical patent/ZA806160B/xx

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
ZA00806160A 1979-10-26 1980-10-06 Improved hydroformylation process using stable rhodium catalyst ZA806160B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/088,827 US4283562A (en) 1979-10-26 1979-10-26 Hydroformylation process using stable rhodium catalyst

Publications (1)

Publication Number Publication Date
ZA806160B true ZA806160B (en) 1981-09-30

Family

ID=22213740

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA00806160A ZA806160B (en) 1979-10-26 1980-10-06 Improved hydroformylation process using stable rhodium catalyst

Country Status (14)

Country Link
US (1) US4283562A (xx)
EP (1) EP0028378B1 (xx)
JP (1) JPS5671032A (xx)
KR (1) KR840000212B1 (xx)
AU (1) AU538456B2 (xx)
BR (1) BR8006845A (xx)
CA (1) CA1137998A (xx)
DE (1) DE3069950D1 (xx)
IN (1) IN154537B (xx)
MX (1) MX155379A (xx)
PL (1) PL129099B1 (xx)
SU (1) SU1678201A3 (xx)
YU (1) YU42711B (xx)
ZA (1) ZA806160B (xx)

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US4450299A (en) * 1980-10-01 1984-05-22 Exxon Research And Engineering Co. Homogeneous hydroformylation catalysis with silyl substituted alkyl diaryl phosphine metal complexes
US4687874A (en) * 1980-02-12 1987-08-18 Exxon Research And Engineering Company Selective hydroformylation process using alkyl diaryl phosphine rhodium carbonyl hydride catalysts
US4687866A (en) * 1980-02-12 1987-08-18 Exxon Research And Engineering Company Ligand exchange process for producing alkyl diaryl phosphine rhodium carbonyl hydrides
US4491675A (en) * 1981-08-17 1985-01-01 Union Carbide Corporation Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands
US4522933A (en) * 1981-08-17 1985-06-11 Union Carbide Corporation Hydroformylation catalyst containing bisphosphine monooxide ligands
US4593011A (en) * 1981-08-17 1986-06-03 Union Carbide Corporation Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands
US4400548A (en) * 1981-08-17 1983-08-23 Union Carbide Corporation Hydroformylation process using bisphosphine monooxide ligands
IT1140319B (it) * 1981-12-04 1986-09-24 Consiglio Nazionale Ricerche Catalizzatori contenenti fosfine steroidali chirale precessi catalitici asimmetrici che li impiegano
US4668809A (en) * 1982-05-03 1987-05-26 Exxon Research And Engineering Transition metal complex catalysts
US4595753A (en) * 1982-05-03 1986-06-17 Exxon Research And Engineering Co. Heterocycle-substituted alkyl diaryl phosphine rhodium caronyl hydride complex hydroformylation catalyst compositions
DE3372361D1 (en) * 1982-06-11 1987-08-13 Davy Mckee London Hydroformylation process
US4668823A (en) * 1983-12-30 1987-05-26 Union Carbide Corporation Process for the preparation of bulky alkyldiarylphosphines and unsymmetrical aryldialkyl phosphines
US4599206A (en) 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US5110990A (en) * 1984-03-30 1992-05-05 Union Carbide Chemicals & Plastics Technology Corporation Process for recovery of phosphorus ligand from vaporized aldehyde
US4737588A (en) * 1984-12-28 1988-04-12 Union Carbide Corporation Transition metal complex catalyzed reactions
US4593127A (en) * 1985-01-11 1986-06-03 Union Carbide Corporation Hydroformylation process
US4625068A (en) * 1985-03-20 1986-11-25 Exxon Chemical Patents Inc. Rhodium catalyzed hydroformylation of internal olefins
US4642388A (en) * 1985-08-30 1987-02-10 Exxon Chemical Patents Inc. Rhodium catalyzed hydroformylation of alpha-substituted alpha-olefins
US5053551A (en) * 1986-07-01 1991-10-01 Davy Mckee (London) Limited Process for the production of aldehydes by hydroformylation
US4716250A (en) * 1986-07-10 1987-12-29 Union Carbide Corporation Hydroformylation using low volatile/organic soluble phosphine ligands
US4731486A (en) * 1986-11-18 1988-03-15 Union Carbide Corporation Hydroformylation using low volatile phosphine ligands
US5113022A (en) * 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
US5059710A (en) * 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes
JPH031927U (xx) * 1989-05-26 1991-01-10
US5001274A (en) * 1989-06-23 1991-03-19 Union Carbide Chemicals And Plastics Company Inc. Hydroformylation process
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
US5763679A (en) * 1995-12-06 1998-06-09 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US6265619B1 (en) 1996-01-17 2001-07-24 Exxon Chemical Patents Inc. Oxygenates and processes for their manufacture
US5892119A (en) * 1996-11-26 1999-04-06 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
JP3864669B2 (ja) * 2000-05-08 2007-01-10 三菱化学株式会社 ヒドロホルミル化方法
CN1997616B (zh) * 2003-07-03 2011-01-19 陶氏技术投资有限责任公司 配体降解产物的最小化,或其向有用的膦配体的转化
DE10349343A1 (de) * 2003-10-23 2005-06-02 Basf Ag Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden
DE10352261B4 (de) * 2003-11-08 2006-08-24 Celanese Chemicals Europe Gmbh Verfahren zur Herstellung von TCD-Dialdehyd
EP1776328B1 (en) * 2004-08-02 2018-04-18 Dow Technology Investments LLC Stabilization of a hydroformylation process
PL1863747T3 (pl) 2005-03-16 2017-06-30 Perstorp Specialty Chemicals Ab Sposób hydroformylowania o ulepszonej izo-selektywności
BRPI0905700A2 (pt) 2008-01-15 2015-07-14 Dow Global Technologies Inc Composição, catalisador complexo ou composição precursora de catalisador complexo, solução de catalisador complexo ou solução de precursor de catalisador complexo, processo de hidroformilação e classe de compostos de triorganofina não ionicos
DE102009004655B4 (de) 2009-01-15 2013-02-14 Oxea Gmbh Verfahren zur Herstellung von Aldehyden
DE102009016651B4 (de) 2009-04-07 2011-11-17 Oxea Gmbh Verfahren zur Herstellung von Aldehyden
DE102009016652A1 (de) 2009-04-07 2010-10-14 Oxea Gmbh Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrags
IN2014CN02246A (xx) 2011-09-30 2015-06-12 Dow Technology Investments Llc
US9067876B2 (en) 2011-12-20 2015-06-30 Dow Technology Investments Llc Hydroformylation process
US8710276B2 (en) * 2012-05-24 2014-04-29 Lg Chem, Ltd. Catalyst compositions for hydroformylation reaction and hydroformylation process using the same
DE102012105878A1 (de) 2012-07-02 2014-01-02 Oxea Gmbh Verfahren zur Herstellung von Isopentanderivaten
DE102012013968A1 (de) 2012-07-13 2014-04-03 Oxea Gmbh Carbonsäureester der Isononansäure ausgehend von 2-Ethylhexanol, Verfahren zu ihrer Herstellung sowie ihre Verwendung
DE102012014395B3 (de) 2012-07-13 2013-08-22 Oxea Gmbh Isononylamine ausgehend von 2-Ethylhexanol, Verfahren zu ihrer Herstellung sowie ihre Verwendung
DE102012014396B4 (de) 2012-07-13 2018-01-11 Oxea Gmbh Verfahren zur Herstellung eines Vinylestergemisches aus einem Gemisch stellungsisomerer aliphatischer Isononansäuren ausgehend von 2-Ethylhexanol
DE102012013969B4 (de) 2012-07-13 2017-09-14 Oxea Gmbh Verfahren zur Herstellung eines Gemisches stellungsisomerer aliphatischer Isononansäuren ausgehend von 2-Ethylhexanol
CN104248860A (zh) 2013-06-27 2014-12-31 陶氏技术投资有限责任公司 热管理方法
DE102013113724A1 (de) 2013-12-09 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von Pentanderivaten und Derivaten alpha, beta-ungesättigter Decenale aus Propylen
US10766839B2 (en) 2016-02-11 2020-09-08 Dow Technology Investments Llc Process for converting olefins to alcohols, ethers, or combinations thereof
TWI788364B (zh) 2017-06-23 2023-01-01 美商陶氏科技投資有限公司 氫甲醯化反應製程
CN112088153A (zh) 2018-05-30 2020-12-15 陶氏技术投资有限责任公司 控制加氢甲酰化过程的方法
CN112055614A (zh) 2018-05-30 2020-12-08 陶氏技术投资有限责任公司 包括单膦、四膦配位体的组合的催化剂组合物和使用其的加氢甲酰化过程
CA3100778A1 (en) 2018-05-30 2019-12-05 Dow Technology Investments Llc Methods for slowing deactivation of a catalyst and/or slowing tetraphosphine ligand usage in hydroformylation processes
CN113698280B (zh) * 2020-05-21 2023-10-13 中国石油化工股份有限公司 一种烯烃加氢甲酰化方法
CN114515606B (zh) * 2020-11-20 2023-12-19 万华化学集团股份有限公司 一种氢甲酰化反应催化剂组合物及其应用
CA3202991A1 (en) 2020-12-22 2022-06-30 Jason F. GILES Hydroformylation reaction processes

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US3448157A (en) * 1965-09-27 1969-06-03 Shell Oil Co Hydroformylation of olefins
US3487112A (en) * 1967-04-27 1969-12-30 Monsanto Co Vapor phase hydroformylation process
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US3644446A (en) * 1969-07-01 1972-02-22 Union Oil Co Preparation of rhodium and iridium hydride carbonyl complexes
GB1338237A (en) * 1969-12-22 1973-11-21 Union Carbide Corp Hydroformylation process
IT1005691B (it) * 1973-04-07 1976-09-30 Basf Ag Processo per la preparazione di dialdeidi alifatiche o cicloalifa tiche e oppure dei loro acetali
US4101588A (en) * 1973-04-07 1978-07-18 Basf Aktiengesellschaft Production of bis-(dimethyl) acetals of hexane dialdehydes
FR2351077A1 (fr) * 1976-05-13 1977-12-09 Celanese Corp Procede perfectionne d'hydroformylation des olefines avec un catalyseur complexe au rhodium
ZA78146B (en) * 1977-01-25 1978-12-27 Union Carbide Corp Improved hydroformylation process
US4215077A (en) * 1978-02-09 1980-07-29 Kuraray Co., Ltd. Hydroformylation of olefins

Also Published As

Publication number Publication date
AU538456B2 (en) 1984-08-16
AU6367380A (en) 1981-04-30
CA1137998A (en) 1982-12-21
PL129099B1 (en) 1984-03-31
DE3069950D1 (en) 1985-02-21
EP0028378B1 (en) 1985-01-09
SU1678201A3 (ru) 1991-09-15
PL227478A1 (xx) 1981-07-10
KR830004326A (ko) 1983-07-09
YU272280A (en) 1983-10-31
JPS5671032A (en) 1981-06-13
KR840000212B1 (ko) 1984-02-29
BR8006845A (pt) 1981-04-28
MX155379A (es) 1988-02-26
US4283562A (en) 1981-08-11
JPH02332B2 (xx) 1990-01-08
IN154537B (xx) 1984-11-03
EP0028378A1 (en) 1981-05-13
YU42711B (en) 1988-12-31

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