ZA200907134B - Transition metal nano-catalyst, its preparation method and its use in Fischer-Tropsch synthetic reaction - Google Patents

Transition metal nano-catalyst, its preparation method and its use in Fischer-Tropsch synthetic reaction

Info

Publication number
ZA200907134B
ZA200907134B ZA200907134A ZA200907134A ZA200907134B ZA 200907134 B ZA200907134 B ZA 200907134B ZA 200907134 A ZA200907134 A ZA 200907134A ZA 200907134 A ZA200907134 A ZA 200907134A ZA 200907134 B ZA200907134 B ZA 200907134B
Authority
ZA
South Africa
Prior art keywords
fischer
catalyst
preparation
transition metal
metal nano
Prior art date
Application number
ZA200907134A
Other languages
English (en)
Inventor
Yuan Kou
Ning Yan
Chaoxian Xiao
Zhipeng Cai
Yongwang Li
Original Assignee
Synfuels China Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Synfuels China Technology Co Ltd filed Critical Synfuels China Technology Co Ltd
Publication of ZA200907134B publication Critical patent/ZA200907134B/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/648—Fischer-Tropsch-type reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
ZA200907134A 2007-05-08 2009-10-13 Transition metal nano-catalyst, its preparation method and its use in Fischer-Tropsch synthetic reaction ZA200907134B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB200710099011XA CN100493701C (zh) 2007-05-08 2007-05-08 一种进行费托合成反应的方法及其专用催化剂

Publications (1)

Publication Number Publication Date
ZA200907134B true ZA200907134B (en) 2010-07-28

Family

ID=38770300

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA200907134A ZA200907134B (en) 2007-05-08 2009-10-13 Transition metal nano-catalyst, its preparation method and its use in Fischer-Tropsch synthetic reaction

Country Status (7)

Country Link
US (2) US20100179234A1 (zh)
CN (1) CN100493701C (zh)
AU (1) AU2008247186B2 (zh)
CA (1) CA2681319C (zh)
RU (1) RU2430780C2 (zh)
WO (1) WO2008134939A1 (zh)
ZA (1) ZA200907134B (zh)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100493701C (zh) * 2007-05-08 2009-06-03 中科合成油技术有限公司 一种进行费托合成反应的方法及其专用催化剂
CN101259411B (zh) * 2008-04-16 2010-06-09 厦门大学 一种制备柴油馏分碳氢化合物的催化剂及其制备方法
CN100548476C (zh) * 2008-05-19 2009-10-14 中国科学院山西煤炭化学研究所 一种适合于浆态床用纳米催化剂及制法和应用
CN102408908B (zh) * 2010-09-21 2015-06-17 中科合成油技术有限公司 一种由溶剂相费托合成生产线性α-烯烃的方法
CN102794197B (zh) * 2011-05-27 2014-03-12 中国石油化工股份有限公司 加氢催化剂及其制备方法和应用
CN102489312B (zh) * 2011-11-24 2013-06-19 武汉凯迪工程技术研究总院有限公司 基于多孔材料限域的费托合成钴基纳米催化剂及其制备方法
CN102716766B (zh) * 2012-06-15 2015-06-17 武汉凯迪工程技术研究总院有限公司 液相co2甲烷化催化剂、制备方法及其应用
RU2496576C1 (ru) * 2012-09-20 2013-10-27 Сергей Михайлович Левачев Способ модификации поверхности неорганического оксида
RU2537850C1 (ru) * 2013-09-12 2015-01-10 Общество с ограниченной ответственностью "АНИКО" Катализатор и способ получения синтетических углеводородов алифатического ряда из оксида углерода и водорода в его присутствии
CN104607190B (zh) * 2015-01-30 2018-01-16 武汉凯迪工程技术研究总院有限公司 用于费托合成的单分散过渡金属纳米催化剂及其制备方法和应用
CN106635117B (zh) * 2015-10-30 2019-01-08 中国石油化工股份有限公司 一种费托合成反应方法
CN106622058B (zh) * 2015-10-30 2019-04-16 中国石油化工股份有限公司 一种费托合成反应装置和费托合成方法
CN106622056B (zh) * 2015-10-30 2019-02-01 中国石油化工股份有限公司 费托合成反应系统和费托合成方法
RU2628396C2 (ru) * 2015-12-09 2017-08-16 Федеральное государственное бюджетное образовательное учреждение высшего образования "Юго-Западный государственный университет" (ЮЗГУ) Сорбент для очистки водных сред от ионов мышьяка и способ его получения
RU2665575C1 (ru) * 2017-12-28 2018-08-31 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Способ получения металлсодержащих наноразмерных дисперсий
RU2745214C1 (ru) * 2020-08-11 2021-03-22 Федеральное государственное бюджетное образовательное учреждение высшего образования "Тверской государственный технический университет" Катализатор синтеза фишера-тропша и способ его получения
CN112077334A (zh) * 2020-09-03 2020-12-15 南京晓庄学院 一种过渡金属掺杂钌铑合金的制备方法及其应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1095411C (zh) * 1998-05-29 2002-12-04 中国科学院化学研究所 一种金属纳米簇的制备方法
CN100479917C (zh) * 2003-04-07 2009-04-22 新日本制铁株式会社 由合成气制造烃的催化剂及催化剂的制造方法
WO2006100578A2 (en) * 2005-03-25 2006-09-28 Cima Nano Tech Israel Ltd Nano-metal particle-containing polymer composites, methods for producing same, and uses for same
CN100357023C (zh) * 2005-07-28 2007-12-26 中国科学院大连化学物理研究所 一种金属钌纳米线的制备方法
US20070225382A1 (en) * 2005-10-14 2007-09-27 Van Den Berg Robert E Method for producing synthesis gas or a hydrocarbon product
US7682789B2 (en) * 2007-05-04 2010-03-23 Ventana Medical Systems, Inc. Method for quantifying biomolecules conjugated to a nanoparticle
CN100493701C (zh) * 2007-05-08 2009-06-03 中科合成油技术有限公司 一种进行费托合成反应的方法及其专用催化剂
US8075799B2 (en) * 2007-06-05 2011-12-13 South Dakota School Of Mines And Technology Carbon nanoparticle-containing hydrophilic nanofluid with enhanced thermal conductivity
CN101134163B (zh) * 2007-10-11 2010-09-15 北京大学 一种合成甲酸酯的方法及其专用催化剂
US8399527B1 (en) * 2009-03-17 2013-03-19 Louisiana Tech University Research Foundation; A Division Of Louisiana Tech University Foundation, Inc. Bound cobalt nanowires for Fischer-Tropsch synthesis

Also Published As

Publication number Publication date
US20100179234A1 (en) 2010-07-15
CN100493701C (zh) 2009-06-03
CN101045206A (zh) 2007-10-03
RU2009143200A (ru) 2011-06-20
CA2681319A1 (en) 2008-11-13
AU2008247186A2 (en) 2009-11-19
AU2008247186B2 (en) 2010-11-04
RU2430780C2 (ru) 2011-10-10
US20140039073A1 (en) 2014-02-06
AU2008247186A1 (en) 2008-11-13
WO2008134939A1 (en) 2008-11-13
CA2681319C (en) 2012-11-13

Similar Documents

Publication Publication Date Title
ZA200907134B (en) Transition metal nano-catalyst, its preparation method and its use in Fischer-Tropsch synthetic reaction
ZA200906057B (en) Promoted carbride-based fischer-tropsch catalyst,method for its preparation and uses thereof
HUS2200015I1 (hu) Szubsztituált 4-aril-1,4-dihidro-1,6-naftiridinamidok és alkalmazásuk
EP2115653A4 (en) FILE CONVERSION IN A RESTRICTED PROCESS
EP2217371A4 (en) CATALYSTS AND RELATED METHODS
ZA201107129B (en) Fischer-tropsch synthesis catalyst,preparation and application thereof
EP2173481A4 (en) CATALYSTS FOR THE FISCHER-TROPSCH SYNTHESIS OF COBALT / PHOSPHORUS ALUMINUM OXIDE AND METHOD OF MANUFACTURING THEREOF
ZA201000419B (en) Catalyst composition, its preparation and use
ZA201106354B (en) Fischer-tropsch catalyst,preparation method and application thereof
HUE065044T2 (hu) Folyamatos katalizátor aktivátor és eljárás
EP2151500A4 (en) BRANCHED A-GLUCAN, THESE PRODUCING A-GLUCOSYLTRANSFERASE, METHOD FOR THE PRODUCTION THEREOF AND USE THEREOF
PL2009122T3 (pl) Stop miedź-cynk, sposób jego wytwarzania i zastosowanie
PL2354161T3 (pl) Przeciwciało anty -NR10 i jego zastosowanie
EP2114843A4 (en) FISCHER-TROPSCH CONVERSION SYSTEM AND METHOD
EP2386664A4 (en) HIGH STRENGTH BRASS ALLOY FOR SLIDING ELEMENTS AND SLIDING ELEMENTS
EP2299893A4 (en) GRILL TOOL, ASSOCIATED PILLOW AND ASSOCIATED PROCESSES
EP2292805A4 (en) BRONZE ALLOY, MANUFACTURING METHOD AND BRONZE ALLOY COMPOSITE GLIDING ELEMENT
SI2354161T1 (sl) Anti-NR10 protitelo in njegova uporaba
TWI341134B (en) Adapative de-interlacer and method thereof
GB0719592D0 (en) Compound, use and method
EP2351613A4 (en) CATALYST AND METHODS OF PRODUCTION AND USE
GB0506263D0 (en) Skin lightening methods, composition and products
EP2167515A4 (en) PROCESS FOR OBTAINING AMINOPHOSPHINE-LIKE LIGANDS AND THEIR USE AS METAL CATALYSTS
GB0607562D0 (en) Method, composition and use
EP2367631A4 (en) CATALYST ACTIVATION IN FISHER-TROPSCH PROCESSES