ZA200905945B - Amino Phosphine - Google Patents
Amino PhosphineInfo
- Publication number
- ZA200905945B ZA200905945B ZA200905945A ZA200905945A ZA200905945B ZA 200905945 B ZA200905945 B ZA 200905945B ZA 200905945 A ZA200905945 A ZA 200905945A ZA 200905945 A ZA200905945 A ZA 200905945A ZA 200905945 B ZA200905945 B ZA 200905945B
- Authority
- ZA
- South Africa
- Prior art keywords
- amino phosphine
- phosphine
- amino
- Prior art date
Links
- XQJHRCVXRAJIDY-UHFFFAOYSA-N aminophosphine Chemical compound PN XQJHRCVXRAJIDY-UHFFFAOYSA-N 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
- B01J31/188—Amide derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/46—Phosphinous acids [R2POH], [R2P(= O)H]: Thiophosphinous acids including[R2PSH]; [R2P(=S)H]; Aminophosphines [R2PNH2]; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
- B01J2540/20—Non-coordinating groups comprising halogens
- B01J2540/22—Non-coordinating groups comprising halogens comprising fluorine, e.g. trifluoroacetate
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/24—Phosphines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2583007A CA2583007C (en) | 2007-03-29 | 2007-03-29 | Amino phosphine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200905945B true ZA200905945B (en) | 2010-05-26 |
Family
ID=39795526
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200905945A ZA200905945B (en) | 2007-03-29 | 2009-08-27 | Amino Phosphine |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US7994363B2 (es) |
| EP (1) | EP2139906B2 (es) |
| CN (1) | CN101646684B (es) |
| CA (1) | CA2583007C (es) |
| ES (1) | ES2456962T5 (es) |
| WO (1) | WO2008119153A1 (es) |
| ZA (1) | ZA200905945B (es) |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2605077C (en) * | 2007-10-01 | 2014-07-08 | Nova Chemicals Corporation | A co-supported catalyst system |
| CA2605044C (en) * | 2007-10-01 | 2014-12-02 | Nova Chemicals Corporation | Polymerization process using a mixed catalyst system |
| CA2639882C (en) † | 2008-09-29 | 2016-07-12 | Nova Chemicals Corporation | Tetramerization |
| CA2639870A1 (en) * | 2008-09-29 | 2010-03-29 | Nova Chemicals Corporation | Trimerization |
| KR101809226B1 (ko) | 2009-10-16 | 2017-12-14 | 사솔 테크날러지 (프로프라이어터리) 리미티드 | 에틸렌을 포함하는 다성분 탄화수소 스트림으로부터 성분들의 분리 |
| MX359459B (es) | 2009-12-31 | 2018-09-28 | Chevron Phillips Chemical Co Lp | Compuestos fosfinil amidina, complejos metalicos, sistemas catalizadores y su uso para oligomerizar o polimerizar olefinas. |
| CA2701252C (en) * | 2010-04-20 | 2017-01-03 | Nova Chemicals Corporation | Polymer mitigation |
| CA2703435C (en) * | 2010-05-12 | 2017-05-02 | Nova Chemicals Corporation | Oligomerization process using a chromium p-n-p catalyst with added alkyl zinc |
| CA2747501C (en) * | 2011-07-26 | 2018-01-23 | Nova Chemicals Corporation | "bulk" ethylene oligomerization |
| CA2765429C (en) * | 2012-01-25 | 2019-12-31 | Nova Chemicals Corporation | P-n-p ligand |
| KR101846031B1 (ko) * | 2012-03-16 | 2018-04-05 | 에스케이이노베이션 주식회사 | 에틸렌으로부터 1-헥센 및/또는 1-옥텐을 제조하기 위한 촉매계 |
| ES2607135T3 (es) | 2012-05-09 | 2017-03-29 | Sasol Technology (Proprietary) Limited | Separación de componentes de una corriente de hidrocarburo multi-componente |
| CA2869701C (en) | 2012-05-09 | 2020-01-07 | Sasol Technology (Proprietary) Limited | A process for oligomerising a hydrocarbon to form at least one co-monomer product |
| SG11201407142WA (en) | 2012-05-09 | 2014-11-27 | Sasol Tech Pty Ltd | Tetramerisation of ethylene |
| US9499456B2 (en) | 2012-05-09 | 2016-11-22 | Sasol Technology (Proprietary) Limited | Tetramerisation of ethylene |
| US8865610B2 (en) | 2012-06-06 | 2014-10-21 | Chevron Phillips Chemical Company Lp | Phosphinyl guanidine compounds, metal salt complexes, catalyst systems, and their use to oligomerize or polymerize olefins |
| CA2800268C (en) | 2012-12-21 | 2020-02-25 | Nova Chemicals Corporation | Continuous ethylene tetramerization process |
| SG11201508464XA (en) | 2013-05-09 | 2015-11-27 | Sasol Tech Pty Ltd | Oligomerisation of ethylene to mixtures of 1-hexene and 1-octene |
| BR112015027067B1 (pt) | 2013-05-09 | 2020-10-06 | Sasol Technology (Pty) Ltd. | Processo para a tetramerização de etileno |
| MY173996A (en) | 2013-05-09 | 2020-03-03 | Sasol Tech Pty Ltd | Oligomerisation of ethylene to mixtures of 1-hexene and 1-octene |
| CA2835683C (en) | 2013-12-05 | 2021-07-06 | Nova Chemicals Corporation | Ethylene oligomerization with mixed ligands |
| CA2837590C (en) | 2013-12-23 | 2020-12-15 | Nova Chemicals Corporation | Continuous ethylene oligomerization with in-situ catalyst preparation |
| CA2847814C (en) * | 2014-03-27 | 2021-09-28 | Nova Chemicals Corporation | Self cleaning reactor system |
| US9175109B1 (en) | 2014-05-20 | 2015-11-03 | Chevron Phillips Chemical Company Lp | Oligomerization processes and polymer compositions produced therefrom |
| EP3171974B1 (en) * | 2014-07-24 | 2018-04-18 | SABIC Global Technologies B.V. | Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene |
| EP3237362B1 (en) | 2014-12-23 | 2019-12-18 | Public Joint Stock Company "Sibur Holding" | Methods of preparing oligomers of an olefin |
| US9505675B2 (en) | 2015-02-09 | 2016-11-29 | Chevron Phillips Chemical Company Lp | Deactivation of a process by-product |
| JP6587051B2 (ja) | 2015-03-24 | 2019-10-09 | セイコーエプソン株式会社 | 超音波センサー及びその製造方法 |
| WO2017010998A1 (en) | 2015-07-14 | 2017-01-19 | Chevron Phillips Chemical Company Lp | Olefin compositions |
| US9732300B2 (en) | 2015-07-23 | 2017-08-15 | Chevron Phillipa Chemical Company LP | Liquid propylene oligomers and methods of making same |
| US10513473B2 (en) | 2015-09-18 | 2019-12-24 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization/trimerization/tetramerization reactor |
| US10519077B2 (en) | 2015-09-18 | 2019-12-31 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization/trimerization/tetramerization reactor |
| US10414699B2 (en) | 2016-05-27 | 2019-09-17 | Chevron Phillips Chemical Company Lp | Process improvements in selective ethylene oligomerizations |
| US10414698B2 (en) | 2016-05-27 | 2019-09-17 | Chevron Phillips Chemical Company Lp | Reduced polymer formation for selective ethylene oligomerizations |
| US10329212B2 (en) | 2016-05-27 | 2019-06-25 | Chevron Phillips Chemical Company Lp | Reduced polymer formation for selective ethylene oligomerizations |
| WO2018012792A1 (en) | 2016-07-14 | 2018-01-18 | Sk Innovation Co., Ltd. | Oligomerization of ethylene |
| KR102428767B1 (ko) | 2016-07-14 | 2022-08-04 | 에스케이이노베이션 주식회사 | 에틸렌의 올리고머화 방법 |
| EP3538566A4 (en) | 2016-11-14 | 2021-01-20 | Public Joint Stock Company "Sibur Holding" | CATALYST SYSTEM USED IN OLEFIN OLIGOMERIZATION AND OLEFIN OLIGOMERIZATION PROCESS |
| US10232339B2 (en) | 2017-06-06 | 2019-03-19 | Chevron Phillips Chemical Company Lp | Fouling protection for an oligomerization reactor inlet |
| US10294171B2 (en) | 2017-09-22 | 2019-05-21 | Chevron Phillips Chemical Company Lp | Carbonyl-containing perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes and their use to oligomerize ethylene |
| US10183960B1 (en) | 2017-09-22 | 2019-01-22 | Chevron Phillips Chemical Company Lp | Perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene |
| US10493442B2 (en) | 2017-09-22 | 2019-12-03 | Chevron Phillips Chemical Company Lp | Fluorinated N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene |
| US10464862B2 (en) | 2017-09-28 | 2019-11-05 | Chevron Phillips Chemical Company Lp | Oligomerization reactions using aluminoxanes |
| CN109174191B (zh) * | 2018-09-17 | 2022-01-25 | 天津科技大学 | 一种乙烯选择性齐聚反应的催化剂 |
| EP3907003B1 (en) | 2019-01-15 | 2024-09-04 | China Petroleum & Chemical Corporation | Halogen-containing compound and use thereof as catalyst ligand in ethylene oligomerization |
| CN111434668B (zh) * | 2019-01-15 | 2021-08-03 | 中国石油化工股份有限公司 | 含卤素化合物及用途和催化剂组合物及乙烯齐聚方法和乙烯三聚方法和乙烯四聚方法 |
| WO2020147373A1 (zh) | 2019-01-15 | 2020-07-23 | 中国石油化工股份有限公司 | 含卤素化合物及用途和催化剂组合物及乙烯齐聚方法和乙烯三聚方法和乙烯四聚方法 |
| CN111434670B (zh) * | 2019-01-15 | 2021-07-30 | 中国石油化工股份有限公司 | 含氟化合物及用途和乙烯齐聚催化剂组合物及乙烯齐聚方法和乙烯三聚方法和乙烯四聚方法 |
| FR3108264B1 (fr) | 2020-03-19 | 2022-04-08 | Ifp Energies Now | Installation d’oligomérisation d’éthylène pour produire des alpha-oléfines |
| KR20230038182A (ko) | 2020-06-10 | 2023-03-17 | 셰브론 필립스 케미컬 컴퍼니 엘피 | 촉매 구조 예측 및 설계를 위한 머신 러닝 및 통계 분석 |
| US11267909B2 (en) | 2020-07-15 | 2022-03-08 | Chevron Phillips Chemical Company Lp | Oligomerization catalyst system activation and related ethylene oligomerization processes and reaction systems |
| FR3116738A1 (fr) * | 2020-11-30 | 2022-06-03 | IFP Energies Nouvelles | Nouvelle composition catalytique a base de chrome comprenant un additif ether aromatique et procede associe pour l’oligomerisation de l’ethylene en octene-1 |
| FR3116739A1 (fr) | 2020-11-30 | 2022-06-03 | IFP Energies Nouvelles | Nouvelle composition catalytique a base de chrome comprenant un additif hydrocarbure aromatique et procede associe pour l’oligomerisation de l’ethylene en octene-1 |
| US11859041B2 (en) | 2021-08-16 | 2024-01-02 | Chevron Phillips Chemical Company Lp | Modulating co-monomer selectivity using non-covalent dispersion interactions in group 4 olefin polymerization catalysts |
| WO2023027749A1 (en) * | 2021-08-26 | 2023-03-02 | Saudi Arabian Oil Company | Catalyst systems |
| FR3128710A1 (fr) | 2021-11-02 | 2023-05-05 | IFP Energies Nouvelles | Procédé d’oligomérisation d’éthylène mettant en œuvre une composition catalytique comprenant un précurseur de chrome, un ligand de type PNP et un aluminoxane |
| US11492305B1 (en) | 2021-11-08 | 2022-11-08 | Chevron Phillips Chemical Company, Lp | Chromium phosphinyl hydroisoindole amidine complexes for tetramerization of ethylene |
| US11583843B1 (en) | 2021-11-08 | 2023-02-21 | Chevron Phillips Chemical Company, Lp | Chromium phosphinyl isoindole amidine complexes for tetramerization of ethylene |
| US11505513B1 (en) | 2021-11-08 | 2022-11-22 | Chevron Phillips Chemical Company, Lp | Chromium bicyclic phosphinyl amidine complexes for tetramerization of ethylene |
| CN116328839A (zh) * | 2021-12-24 | 2023-06-27 | 中国石油化工股份有限公司 | 一种负载型乙烯齐聚主催化剂及乙烯齐聚催化剂组合物及应用 |
| CN116328838A (zh) * | 2021-12-24 | 2023-06-27 | 中国石油化工股份有限公司 | 一种金属有机骨架负载型乙烯齐聚催化剂组合物及应用 |
| CN116328837A (zh) * | 2021-12-24 | 2023-06-27 | 中国石油化工股份有限公司 | 一种乙烯齐聚催化剂组合物及应用 |
| CN116328836B (zh) * | 2021-12-24 | 2024-09-20 | 中国石油化工股份有限公司 | 多孔有机聚合物负载型乙烯聚合主催化剂及乙烯聚合催化剂组合物及应用 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5198563A (en) * | 1989-08-10 | 1993-03-30 | Phillips Petroleum Company | Chromium compounds and uses thereof |
| GB0016895D0 (en) | 2000-07-11 | 2000-08-30 | Bp Chem Int Ltd | Olefin oligomerisation |
| CN1308269C (zh) * | 2001-12-20 | 2007-04-04 | Sasol技术股份有限公司 | 使用铬基催化剂的烯烃三聚和寡聚 |
| BRPI0317510B1 (pt) * | 2002-12-20 | 2020-01-07 | Sasol Technology ( Pty) Ltd | Processo de tetramerização de olefinas e sistema catalisador |
| US7297832B2 (en) | 2002-12-20 | 2007-11-20 | Sasol Technology (Pty) Limited | Tetramerization of olefins |
-
2007
- 2007-03-29 CA CA2583007A patent/CA2583007C/en active Active
-
2008
- 2008-03-13 EP EP08733578.2A patent/EP2139906B2/en active Active
- 2008-03-13 WO PCT/CA2008/000474 patent/WO2008119153A1/en active Application Filing
- 2008-03-13 ES ES08733578T patent/ES2456962T5/es active Active
- 2008-03-13 CN CN200880010165.XA patent/CN101646684B/zh active Active
- 2008-03-20 US US12/077,565 patent/US7994363B2/en active Active
-
2009
- 2009-08-27 ZA ZA200905945A patent/ZA200905945B/xx unknown
-
2011
- 2011-06-24 US US13/135,100 patent/US8252956B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2139906B1 (en) | 2014-02-12 |
| EP2139906A4 (en) | 2011-08-03 |
| CN101646684B (zh) | 2014-10-01 |
| US7994363B2 (en) | 2011-08-09 |
| ES2456962T3 (es) | 2014-04-24 |
| US20110257352A1 (en) | 2011-10-20 |
| EP2139906B2 (en) | 2021-09-15 |
| WO2008119153A1 (en) | 2008-10-09 |
| CA2583007C (en) | 2015-03-31 |
| CN101646684A (zh) | 2010-02-10 |
| EP2139906A1 (en) | 2010-01-06 |
| CA2583007A1 (en) | 2008-09-29 |
| US20080242811A1 (en) | 2008-10-02 |
| ES2456962T5 (es) | 2022-02-10 |
| US8252956B2 (en) | 2012-08-28 |
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