ZA200701817B - Polymerization inhibitor for stabilizing olefinically unsaturated monomers - Google Patents
Polymerization inhibitor for stabilizing olefinically unsaturated monomers Download PDFInfo
- Publication number
- ZA200701817B ZA200701817B ZA200701817A ZA200701817A ZA200701817B ZA 200701817 B ZA200701817 B ZA 200701817B ZA 200701817 A ZA200701817 A ZA 200701817A ZA 200701817 A ZA200701817 A ZA 200701817A ZA 200701817 B ZA200701817 B ZA 200701817B
- Authority
- ZA
- South Africa
- Prior art keywords
- weight
- substituents
- formula
- polymerization inhibitor
- olefinically unsaturated
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title claims description 46
- 239000000178 monomer Substances 0.000 title claims description 45
- 239000003112 inhibitor Substances 0.000 title claims description 43
- 230000000087 stabilizing effect Effects 0.000 title claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 32
- 125000001424 substituent group Chemical group 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 17
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- -1 cyanohydrin Chemical group 0.000 claims description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 5
- 150000001449 anionic compounds Chemical class 0.000 claims description 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 150000002891 organic anions Chemical class 0.000 claims description 4
- 125000004043 oxo group Chemical group O=* 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 3
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 3
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 claims description 3
- 229940091173 hydantoin Drugs 0.000 claims description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 claims description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 2
- 229910019567 Re Re Inorganic materials 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 238000002360 preparation method Methods 0.000 description 9
- 150000003254 radicals Chemical class 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 7
- 238000000034 method Methods 0.000 description 5
- 238000000746 purification Methods 0.000 description 4
- YLFIGGHWWPSIEG-UHFFFAOYSA-N aminoxyl Chemical compound [O]N YLFIGGHWWPSIEG-UHFFFAOYSA-N 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
- VDVUCLWJZJHFAV-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)N1 VDVUCLWJZJHFAV-UHFFFAOYSA-N 0.000 description 1
- XESZUVZBAMCAEJ-UHFFFAOYSA-N 4-tert-butylcatechol Chemical compound CC(C)(C)C1=CC=C(O)C(O)=C1 XESZUVZBAMCAEJ-UHFFFAOYSA-N 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000005262 alkoxyamine group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methyl-cyclopentane Natural products CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- ODUCDPQEXGNKDN-UHFFFAOYSA-N nitroxyl Chemical class O=N ODUCDPQEXGNKDN-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B63/00—Purification; Separation; Stabilisation; Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006010347A DE102006010347A1 (de) | 2006-03-03 | 2006-03-03 | Polymerisationsinhibitor zur Stabilisierung von olefinisch ungesättigten Monomeren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200701817B true ZA200701817B (en) | 2008-07-30 |
Family
ID=38283893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200701817A ZA200701817B (en) | 2006-03-03 | 2007-03-01 | Polymerization inhibitor for stabilizing olefinically unsaturated monomers |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US20070208204A1 (ru) |
| EP (1) | EP1834941A3 (ru) |
| JP (1) | JP2007238614A (ru) |
| KR (1) | KR20070090805A (ru) |
| CN (1) | CN101029232A (ru) |
| AR (1) | AR060107A1 (ru) |
| BR (1) | BRPI0700633A (ru) |
| CA (1) | CA2579989A1 (ru) |
| DE (1) | DE102006010347A1 (ru) |
| MX (1) | MX2007002570A (ru) |
| RU (1) | RU2007107471A (ru) |
| SG (1) | SG135166A1 (ru) |
| TW (1) | TW200804229A (ru) |
| ZA (1) | ZA200701817B (ru) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20080046276A (ko) * | 2005-11-07 | 2008-05-26 | 마쯔시다덴기산교 가부시키가이샤 | 와이프 패턴 생성 장치 |
| EP1787989A1 (de) * | 2005-11-17 | 2007-05-23 | Degussa GmbH | Triazinverbindungen mit Aminogruppen- und Carboxygruppen-haltigen Substituenten |
| DE102007052891A1 (de) * | 2007-11-02 | 2009-05-07 | Evonik Degussa Gmbh | Verfahren zur Stabilisierung von olefinisch ungesättigten Monomeren |
| US20100143580A1 (en) * | 2008-05-28 | 2010-06-10 | American Air Liquide, Inc. | Stabilization of Bicycloheptadiene |
| WO2010116794A1 (ja) * | 2009-03-30 | 2010-10-14 | 日本製紙株式会社 | Ｎ－オキシル化合物の回収・再利用方法 |
| DE102009002514A1 (de) * | 2009-04-21 | 2010-10-28 | Evonik Degussa Gmbh | Verfahren zur Herstellung von substituierten 1,4-Chinonmethiden |
| DE102013204950A1 (de) | 2013-03-20 | 2014-09-25 | Evonik Industries Ag | Verfahren und Zusammensetzung zur Inhibierung der Polymerisation von Cyclopentadienverbindungen |
| US9399622B2 (en) * | 2013-12-03 | 2016-07-26 | Ecolab Usa Inc. | Nitroxide hydroxylamine and phenylenediamine combinations as polymerization inhibitors for ethylenically unsaturated monomer processes |
| TW202114976A (zh) * | 2019-10-11 | 2021-04-16 | 美商藝康美國公司 | 醌甲基化物及銨鹽抗聚合劑組合物及方法 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US688939A (en) * | 1900-08-11 | 1901-12-17 | Friedrich Ernst Paul Ehrlich | Apparatus for automatically producing an umlimited number of copies. |
| US2965685A (en) * | 1958-06-24 | 1960-12-20 | Monsanto Chemicals | Polymerization inhibitor |
| GB1124009A (en) * | 1966-04-26 | 1968-08-14 | Bp Chem Int Ltd | Polymerization of chloroprene |
| GB1346774A (en) * | 1970-10-05 | 1974-02-13 | Bp Chem Int Ltd | Stabilisation of acrylonitrile |
| DE3321332A1 (de) * | 1983-06-13 | 1984-12-13 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von polyalkylpiperidylaminen |
| US4670131A (en) * | 1986-01-13 | 1987-06-02 | Exxon Chemical Patents Inc. | Method for controlling fouling of hydrocarbon compositions containing olefinic compounds |
| DE4219459A1 (de) * | 1992-06-13 | 1993-12-16 | Huels Chemische Werke Ag | Verfahren zur Herstellung von 2,2,6,6-Tetramethylpiperidin-N-oxyl und seinen in 4-Stellung substituierten Derivaten |
| DE4239247A1 (de) * | 1992-11-21 | 1994-05-26 | Huels Chemische Werke Ag | Katalysator für ein Verfahren zur Herstellung von 4-Hydroxy-2.2.6.6-tetramethylpiperidin |
| DE4442990A1 (de) * | 1994-12-02 | 1996-06-05 | Huels Chemische Werke Ag | Verfahren zur Herstellung von 4-Amino-2,2,6,6-tetramethylpiperidin |
| DE19532215B4 (de) * | 1995-09-01 | 2009-06-25 | Evonik Degussa Gmbh | Verfahren zur Herstellung von 4-Acylamino-2,2,6,6-tetramethylpiperidinen |
| DE19544599A1 (de) * | 1995-11-30 | 1997-06-05 | Huels Chemische Werke Ag | Kontinuierliches Verfahren zur Herstellung von 4-Amino-2,2,6,6-tetramethylpiperidin |
| DE19704460A1 (de) * | 1997-02-06 | 1998-08-13 | Huels Chemische Werke Ag | Kontinuierliches Verfahren zur Herstellung von 4-Aminopiperidinen |
| AU723502B2 (en) * | 1997-07-23 | 2000-08-31 | Ciba Specialty Chemicals Holding Inc. | Inhibition of pulp and paper yellowing using nitroxides and other coadditives |
| TWI224995B (en) * | 1998-03-19 | 2004-12-11 | Ciba Sc Holding Ag | Stabilization of wood substrates |
| GB9819600D0 (en) * | 1998-09-08 | 1998-11-04 | Marks A H & Co Ltd | Chemical compositions |
| JP2002524471A (ja) * | 1998-09-09 | 2002-08-06 | ベイカー ヒューズ インコーポレイテッド | ヒンダードヒドロキシルアミンを使用したビニルモノマーの重合禁止剤 |
| AR029410A1 (es) * | 1999-12-02 | 2003-06-25 | Crompton Corp | Metodo para inhibir la polimerizacion prematura de monomeros etilenicamente insaturados y composiciones de los mismos |
| JP3863694B2 (ja) * | 1999-12-24 | 2006-12-27 | 株式会社日本触媒 | ビニル化合物中のｎ−オキシル化合物の安定化方法 |
| US6525146B1 (en) * | 2000-04-03 | 2003-02-25 | Baker Hughes Incorporated | Inhibition of popcorn polymer growth |
| AU2128002A (en) * | 2001-03-16 | 2002-09-19 | Rohm And Haas Company | Transesterification process |
| EP1541566A1 (en) * | 2003-12-08 | 2005-06-15 | SCA Hygiene Products AB | Process for the separation of organic hydroxylamine and nitrosonium compounds and its use in the oxidation of hydroxy compounds |
| DE102004023640A1 (de) * | 2004-05-10 | 2005-12-08 | Degussa Ag | Verfahren zur Herstellung von 4-substituierten 2,2,6,6-Tetramethyl-piperidin-N-oxy- und 2,2,6,6-Tetramethyl-piperidin-N-hydroxy-verbindungen |
| US7030279B1 (en) * | 2004-12-23 | 2006-04-18 | Degussa Ag | Process for transition metal free catalytic aerobic oxidation of alcohols under mild conditions using stable free nitroxyl radicals |
-
2006
- 2006-03-03 DE DE102006010347A patent/DE102006010347A1/de not_active Withdrawn
- 2006-12-28 EP EP06127302A patent/EP1834941A3/de not_active Withdrawn
-
2007
- 2007-02-05 US US11/671,119 patent/US20070208204A1/en not_active Abandoned
- 2007-02-26 TW TW096106499A patent/TW200804229A/zh unknown
- 2007-02-28 RU RU2007107471/04A patent/RU2007107471A/ru not_active Application Discontinuation
- 2007-03-01 ZA ZA200701817A patent/ZA200701817B/en unknown
- 2007-03-01 CA CA002579989A patent/CA2579989A1/en not_active Abandoned
- 2007-03-01 MX MX2007002570A patent/MX2007002570A/es unknown
- 2007-03-02 AR ARP070100857A patent/AR060107A1/es unknown
- 2007-03-02 KR KR1020070020827A patent/KR20070090805A/ko not_active Application Discontinuation
- 2007-03-02 SG SG200701542-3A patent/SG135166A1/en unknown
- 2007-03-02 CN CNA2007100844240A patent/CN101029232A/zh active Pending
- 2007-03-05 JP JP2007054593A patent/JP2007238614A/ja not_active Withdrawn
- 2007-03-05 BR BRPI0700633-0A patent/BRPI0700633A/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JP2007238614A (ja) | 2007-09-20 |
| DE102006010347A1 (de) | 2007-09-06 |
| TW200804229A (en) | 2008-01-16 |
| BRPI0700633A (pt) | 2007-11-06 |
| US20070208204A1 (en) | 2007-09-06 |
| AR060107A1 (es) | 2008-05-28 |
| KR20070090805A (ko) | 2007-09-06 |
| EP1834941A2 (de) | 2007-09-19 |
| CN101029232A (zh) | 2007-09-05 |
| MX2007002570A (es) | 2008-10-30 |
| EP1834941A3 (de) | 2007-09-26 |
| SG135166A1 (en) | 2007-09-28 |
| CA2579989A1 (en) | 2007-09-03 |
| RU2007107471A (ru) | 2008-09-10 |
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