ZA200700147B - Surface cross-linked superabsorbent polymer particles and methods of making them - Google Patents
Surface cross-linked superabsorbent polymer particles and methods of making them Download PDFInfo
- Publication number
- ZA200700147B ZA200700147B ZA200700147A ZA200700147A ZA200700147B ZA 200700147 B ZA200700147 B ZA 200700147B ZA 200700147 A ZA200700147 A ZA 200700147A ZA 200700147 A ZA200700147 A ZA 200700147A ZA 200700147 B ZA200700147 B ZA 200700147B
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- ZA
- South Africa
- Prior art keywords
- cross
- linking
- polymer particles
- molecules
- superabsorbent polymer
- Prior art date
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- 238000000034 method Methods 0.000 title claims description 60
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- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 229940106135 cellulose Drugs 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000001212 derivatisation Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- SBHCLVQMTBWHCD-UHFFFAOYSA-N icosa-2,4,6,8,10-pentaenoic acid Chemical compound CCCCCCCCCC=CC=CC=CC=CC=CC(O)=O SBHCLVQMTBWHCD-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002504 physiological saline solution Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical group 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- VCQYDZJGTXAFRL-UHFFFAOYSA-N s-phenyl benzenecarbothioate Chemical class C=1C=CC=CC=1C(=O)SC1=CC=CC=C1 VCQYDZJGTXAFRL-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 150000003459 sulfonic acid esters Chemical class 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- SQAIGLXMIMWFEQ-UHFFFAOYSA-N tetrakis(prop-2-enyl) silicate Chemical compound C=CCO[Si](OCC=C)(OCC=C)OCC=C SQAIGLXMIMWFEQ-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- PLCFYBDYBCOLSP-UHFFFAOYSA-N tris(prop-2-enyl) 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound C=CCOC(=O)CC(O)(CC(=O)OCC=C)C(=O)OCC=C PLCFYBDYBCOLSP-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
- A61F13/534—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/28—Treatment by wave energy or particle radiation
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
- A61F2013/530481—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having superabsorbent materials, i.e. highly absorbent polymer gel materials
- A61F2013/530708—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having superabsorbent materials, i.e. highly absorbent polymer gel materials characterized by the absorbency properties
- A61F2013/530737—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having superabsorbent materials, i.e. highly absorbent polymer gel materials characterized by the absorbency properties by the absorbent capacity
- A61F2013/530766—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having superabsorbent materials, i.e. highly absorbent polymer gel materials characterized by the absorbency properties by the absorbent capacity by the cross-link factor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Veterinary Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Vascular Medicine (AREA)
- Heart & Thoracic Surgery (AREA)
- Biomedical Technology (AREA)
- Dispersion Chemistry (AREA)
- Hematology (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04017071A EP1629854B1 (fr) | 2004-07-20 | 2004-07-20 | Particules polymériques superabsorbantes réticulées en surface et leurs procédés de fabrication |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200700147B true ZA200700147B (en) | 2008-05-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200700147A ZA200700147B (en) | 2004-07-20 | 2007-01-04 | Surface cross-linked superabsorbent polymer particles and methods of making them |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US7588777B2 (fr) |
| EP (1) | EP1629854B1 (fr) |
| JP (1) | JP2008506528A (fr) |
| KR (1) | KR20070039050A (fr) |
| CN (1) | CN101076358A (fr) |
| AR (1) | AR054672A1 (fr) |
| AT (1) | ATE484298T1 (fr) |
| AU (1) | AU2005274865A1 (fr) |
| BR (1) | BRPI0513537A (fr) |
| CA (1) | CA2573442A1 (fr) |
| DE (1) | DE602004029569D1 (fr) |
| IN (1) | IN2006DE07971A (fr) |
| WO (1) | WO2006020161A2 (fr) |
| ZA (1) | ZA200700147B (fr) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8080705B2 (en) * | 2004-07-28 | 2011-12-20 | The Procter & Gamble Company | Superabsorbent polymers comprising direct covalent bonds between polymer chain segments and method of making them |
| TW200621868A (en) * | 2004-12-10 | 2006-07-01 | Nippon Catalytic Chem Ind | Method for surface-treatment of water absorbent resin |
| EP1757645A1 (fr) * | 2005-08-23 | 2007-02-28 | Nippon Shokubai Co.,Ltd. | Procédé pour la réticulation en surface de particules de polymère super-absorbantes par rayonnement ultraviolet |
| EP1757648A1 (fr) | 2005-08-23 | 2007-02-28 | Nippon Shokubai Co.,Ltd. | Procédé pour la réticulation en surface de particules de polymère super-absorbantes par rayonnement ultraviolet en présence d'acides de Bronsted |
| EP1757643A1 (fr) * | 2005-08-23 | 2007-02-28 | Nippon Shokubai Co.,Ltd. | Procédé pour la réticulation de la surface de particules polymères ultra-absorbantes par rayonnement ultraviolet sous vide |
| WO2008102322A2 (fr) * | 2007-02-22 | 2008-08-28 | The Procter & Gamble Company | Procédé de traitement de surface d'un matériau particulaire au moyen d'un rayonnement électromagnétique |
| US7935860B2 (en) * | 2007-03-23 | 2011-05-03 | Kimberly-Clark Worldwide, Inc. | Absorbent articles comprising high permeability superabsorbent polymer compositions |
| CN101925623B (zh) * | 2008-01-29 | 2013-11-06 | 巴斯夫欧洲公司 | 生产吸水性聚合物颗粒的方法 |
| US8453354B2 (en) | 2009-10-01 | 2013-06-04 | Nike, Inc. | Rigid cantilevered stud |
| DE102010004478A1 (de) | 2010-01-12 | 2011-07-14 | Riesinger, Birgit, 48346 | Neue Technologien zur Verwendung in Wundauflagen mit superabsorbierenden Polymeren |
| EP2447286A1 (fr) * | 2010-11-01 | 2012-05-02 | The Procter & Gamble Company | Procédé utilisant un milieu supercritique pour produire des polymères |
| KR101290740B1 (ko) * | 2010-11-22 | 2013-07-29 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 |
| KR101495779B1 (ko) * | 2010-11-30 | 2015-02-25 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 |
| EP2740449B1 (fr) * | 2012-12-10 | 2019-01-23 | The Procter & Gamble Company | Article absorbant à haute teneur en matériau absorbant |
| KR101604272B1 (ko) | 2013-05-09 | 2016-03-25 | 주식회사 엘지화학 | 고흡수성 수지의 제조방법 |
| WO2014182128A1 (fr) * | 2013-05-09 | 2014-11-13 | 주식회사 엘지화학 | Procede de preparation pour une resine superabsorbante |
| EP2944376B1 (fr) * | 2014-05-13 | 2019-11-13 | The Procter and Gamble Company | Particules de polymère superabsorbant agglomérées |
| CN109311286B (zh) * | 2016-05-31 | 2021-06-25 | 花王株式会社 | 吸收性物品 |
| AU2018221352B2 (en) | 2017-02-16 | 2022-02-17 | Nutrition & Biosciences USA 4, Inc. | Crosslinked dextran and crosslinked dextran-poly alpha-1,3-glucan graft copolymers |
| JP2020533498A (ja) | 2017-09-13 | 2020-11-19 | デュポン・インダストリアル・バイオサイエンシーズ・ユーエスエイ・エルエルシー | 多糖を含む不織ウェブ |
| KR102600854B1 (ko) * | 2017-12-28 | 2023-11-10 | 롯데정밀화학 주식회사 | 셀룰로오스 유도체 입자의 제조방법, 상기 방법에 의해 제조된 셀룰로오스 유도체 입자 및 이를 포함하는 흡수성 물품 |
| KR20200132929A (ko) | 2018-03-13 | 2020-11-25 | 엠제이제이 테크놀로지스 인코포레이티드 | 고흡수성 폴리머 및 이를 제조 및 사용하는 방법 |
| KR102452566B1 (ko) * | 2018-04-27 | 2022-10-06 | 주식회사 엘지화학 | 고흡수성 수지 조성물 |
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| US3661875A (en) * | 1970-01-27 | 1972-05-09 | Du Pont | 1-(1-alkenyl)bicyclo(1.1.0)butanes and their polymers |
| US3959569A (en) * | 1970-07-27 | 1976-05-25 | The Dow Chemical Company | Preparation of water-absorbent articles |
| US3860003B2 (en) * | 1973-11-21 | 1990-06-19 | Contractable side portions for disposable diaper | |
| US3935099A (en) * | 1974-04-03 | 1976-01-27 | The United States Of America As Represented By The Secretary Of Agriculture | Method of reducing water content of emulsions, suspensions, and dispersions with highly absorbent starch-containing polymeric compositions |
| JPS51125468A (en) * | 1975-03-27 | 1976-11-01 | Sanyo Chem Ind Ltd | Method of preparing resins of high water absorbency |
| JPS5265597A (en) * | 1975-11-27 | 1977-05-31 | Sumitomo Chem Co Ltd | Preparation of high polimeric materials with improved water absorption |
| JPS5346389A (en) * | 1976-10-07 | 1978-04-25 | Kao Corp | Preparation of self-crosslinking polymer of acrylic alkali metal salt |
| US4062817A (en) * | 1977-04-04 | 1977-12-13 | The B.F. Goodrich Company | Water absorbent polymers comprising unsaturated carboxylic acid, acrylic ester containing alkyl group 10-30 carbon atoms, and another acrylic ester containing alkyl group 2-8 carbon atoms |
| US4286082A (en) * | 1979-04-06 | 1981-08-25 | Nippon Shokubai Kagaku Kogyo & Co., Ltd. | Absorbent resin composition and process for producing same |
| JPS6056724B2 (ja) * | 1980-10-22 | 1985-12-11 | 株式会社クラレ | 吸水性樹脂の製造方法 |
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-
2004
- 2004-07-20 EP EP04017071A patent/EP1629854B1/fr not_active Expired - Lifetime
- 2004-07-20 AT AT04017071T patent/ATE484298T1/de not_active IP Right Cessation
- 2004-07-20 DE DE602004029569T patent/DE602004029569D1/de not_active Expired - Lifetime
-
2005
- 2005-07-15 JP JP2007522607A patent/JP2008506528A/ja not_active Withdrawn
- 2005-07-15 CN CNA2005800214777A patent/CN101076358A/zh active Pending
- 2005-07-15 CA CA002573442A patent/CA2573442A1/fr not_active Abandoned
- 2005-07-15 KR KR1020077001267A patent/KR20070039050A/ko not_active Application Discontinuation
- 2005-07-15 WO PCT/US2005/025343 patent/WO2006020161A2/fr active Application Filing
- 2005-07-15 BR BRPI0513537-0A patent/BRPI0513537A/pt not_active Application Discontinuation
- 2005-07-15 AU AU2005274865A patent/AU2005274865A1/en not_active Abandoned
- 2005-07-18 US US11/183,356 patent/US7588777B2/en not_active Expired - Fee Related
- 2005-07-19 AR ARP050102982A patent/AR054672A1/es not_active Application Discontinuation
-
2006
- 2006-12-28 IN IN7971DE2006 patent/IN2006DE07971A/en unknown
-
2007
- 2007-01-04 ZA ZA200700147A patent/ZA200700147B/en unknown
-
2009
- 2009-08-07 US US12/537,585 patent/US7871640B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US7871640B2 (en) | 2011-01-18 |
| ATE484298T1 (de) | 2010-10-15 |
| JP2008506528A (ja) | 2008-03-06 |
| CA2573442A1 (fr) | 2006-02-23 |
| WO2006020161A2 (fr) | 2006-02-23 |
| IN2006DE07971A (fr) | 2007-04-27 |
| WO2006020161A3 (fr) | 2006-06-01 |
| US20060020053A1 (en) | 2006-01-26 |
| EP1629854A1 (fr) | 2006-03-01 |
| US20090299315A1 (en) | 2009-12-03 |
| CN101076358A (zh) | 2007-11-21 |
| AR054672A1 (es) | 2007-07-11 |
| BRPI0513537A (pt) | 2008-05-06 |
| DE602004029569D1 (de) | 2010-11-25 |
| AU2005274865A1 (en) | 2006-02-23 |
| EP1629854B1 (fr) | 2010-10-13 |
| KR20070039050A (ko) | 2007-04-11 |
| US7588777B2 (en) | 2009-09-15 |
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