ZA200508859B - Production of hydrocarbons by steam reforming and Fischer-Tropsch reaction - Google Patents
Production of hydrocarbons by steam reforming and Fischer-Tropsch reaction Download PDFInfo
- Publication number
- ZA200508859B ZA200508859B ZA200508859A ZA200508859A ZA200508859B ZA 200508859 B ZA200508859 B ZA 200508859B ZA 200508859 A ZA200508859 A ZA 200508859A ZA 200508859 A ZA200508859 A ZA 200508859A ZA 200508859 B ZA200508859 B ZA 200508859B
- Authority
- ZA
- South Africa
- Prior art keywords
- gas
- reformed gas
- steam
- mixture
- partially
- Prior art date
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims description 101
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 101
- 238000000629 steam reforming Methods 0.000 title claims description 42
- 238000006243 chemical reaction Methods 0.000 title claims description 12
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000007789 gas Substances 0.000 claims description 209
- 239000000203 mixture Substances 0.000 claims description 86
- 239000004215 Carbon black (E152) Substances 0.000 claims description 75
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 64
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 57
- 238000000034 method Methods 0.000 claims description 56
- 230000015572 biosynthetic process Effects 0.000 claims description 55
- 238000003786 synthesis reaction Methods 0.000 claims description 55
- 238000002407 reforming Methods 0.000 claims description 41
- 239000003054 catalyst Substances 0.000 claims description 38
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 32
- 239000001569 carbon dioxide Substances 0.000 claims description 32
- 238000002485 combustion reaction Methods 0.000 claims description 28
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 27
- 239000001301 oxygen Substances 0.000 claims description 27
- 229910052760 oxygen Inorganic materials 0.000 claims description 27
- 229910052739 hydrogen Inorganic materials 0.000 claims description 25
- 239000001257 hydrogen Substances 0.000 claims description 25
- 238000000926 separation method Methods 0.000 claims description 13
- 238000001193 catalytic steam reforming Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 30
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 20
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 20
- 239000007788 liquid Substances 0.000 description 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 229910052759 nickel Inorganic materials 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 230000002745 absorbent Effects 0.000 description 5
- 239000002250 absorbent Substances 0.000 description 5
- 239000003345 natural gas Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- 229910002090 carbon oxide Inorganic materials 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 238000004065 wastewater treatment Methods 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical class CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000002453 autothermal reforming Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000779 depleting effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- -1 ethanol Chemical class 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 239000008236 heating water Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000006057 reforming reaction Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
- B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G70/00—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/34—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
- C10G9/36—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00309—Controlling the temperature by indirect heat exchange with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
- C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/80—Additives
- C10G2300/805—Water
- C10G2300/807—Steam
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Thermal Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0310106 | 2003-05-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200508859B true ZA200508859B (en) | 2007-03-28 |
Family
ID=33397049
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200508859A ZA200508859B (en) | 2003-05-02 | 2005-11-01 | Production of hydrocarbons by steam reforming and Fischer-Tropsch reaction |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7323497B2 (ru) |
| EP (1) | EP1625190A1 (ru) |
| AU (1) | AU2004234588B2 (ru) |
| CA (1) | CA2523219C (ru) |
| EA (1) | EA008048B1 (ru) |
| MY (1) | MY141294A (ru) |
| WO (1) | WO2004096952A1 (ru) |
| ZA (1) | ZA200508859B (ru) |
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| DE102006023248C5 (de) | 2006-05-18 | 2018-01-25 | Air Liquide Global E&C Solutions Germany Gmbh | Verfahren und Anlage zur Herstellung von Synthesegas |
| EP1860063A1 (en) * | 2006-05-22 | 2007-11-28 | Shell Internationale Researchmaatschappij B.V. | Process for preparing a paraffin product |
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| JP5383508B2 (ja) * | 2007-01-19 | 2014-01-08 | ヴェロシス，インク． | マイクロチャネルプロセス技術を用いて天然ガスを分子量の高くなった炭化水素に変換するためのプロセスおよび装置 |
| US20080260631A1 (en) * | 2007-04-18 | 2008-10-23 | H2Gen Innovations, Inc. | Hydrogen production process |
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| WO2010020309A1 (en) * | 2008-08-22 | 2010-02-25 | Haldor Topsøe A/S | Process for production of synthesis gas |
| AU2009302276B2 (en) | 2008-10-10 | 2015-12-03 | Velocys Inc. | Process and apparatus employing microchannel process technology |
| US8617270B2 (en) * | 2008-12-03 | 2013-12-31 | Kellogg Brown & Root Llc | Systems and methods for improving ammonia synthesis efficiency |
| IT1392392B1 (it) | 2008-12-19 | 2012-03-02 | Eni Spa | Processo per la purificazione di una corrente acquosa proveniente dalla reazione di fischer-tropsch |
| US8007761B2 (en) * | 2008-12-24 | 2011-08-30 | Praxair Technology, Inc. | Carbon dioxide emission reduction method |
| IT1392803B1 (it) | 2009-01-30 | 2012-03-23 | Eni Spa | Processo per la purificazione di una corrente acquosa proveniente dalla reazione di fischer-tropsch |
| CN103923895A (zh) | 2009-04-01 | 2014-07-16 | 丹尼斯科美国公司 | 包含具有改变的性质的α-淀粉酶变体的组合物和方法 |
| EP2421794B1 (en) | 2009-04-22 | 2014-09-03 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of hydrogen and carbon monoxide containing gas |
| IT1394057B1 (it) * | 2009-05-06 | 2012-05-25 | Eni Spa | Processo per la purificazione di una corrente acquosa proveniente dalla reazione di fischer-tropsch |
| IT1396196B1 (it) | 2009-10-08 | 2012-11-16 | Eni Spa | Processo per la purificazione di una corrente acquosa proveniente dalla reazione di fischer-tropsch |
| GB0922411D0 (en) * | 2009-12-22 | 2010-02-03 | Johnson Matthey Plc | Conversion of hydrocarbons to carbon dioxide and electrical power |
| US8592492B2 (en) * | 2010-03-08 | 2013-11-26 | Praxair Technology, Inc. | Using fossil fuels to increase biomass-based fuel benefits |
| JP2012007213A (ja) | 2010-06-25 | 2012-01-12 | Mitsubishi Heavy Ind Ltd | 直接還元製鉄法およびそのための還元ガス製造装置 |
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| JP6016486B2 (ja) * | 2012-07-06 | 2016-10-26 | 三菱重工業株式会社 | ガソリンを製造するシステム又は方法 |
| US10005963B2 (en) * | 2012-09-20 | 2018-06-26 | University Of South Florida | Systems and methods for producing liquid fuels from landfill gases |
| GB201219960D0 (en) * | 2012-11-06 | 2012-12-19 | Johnson Matthey Plc | Process |
| US9676623B2 (en) | 2013-03-14 | 2017-06-13 | Velocys, Inc. | Process and apparatus for conducting simultaneous endothermic and exothermic reactions |
| EP2821699A1 (en) | 2013-07-02 | 2015-01-07 | Haldor Topsøe A/S | Mixing of recycle gas with fuel gas to a burner |
| US9701910B2 (en) | 2013-07-31 | 2017-07-11 | Saudi Basic Industries Corporation | Process for the production of olefins through FT based synthesis |
| WO2015015311A2 (en) | 2013-07-31 | 2015-02-05 | Saudi Basic Industries Corporation | A process for the production of olefins through ft based synthesis |
| RU2555043C1 (ru) * | 2013-09-11 | 2015-07-10 | Общество с ограниченной ответственностью "Газохим Техно" | Способ очистки воды, образующейся на стадии синтеза углеводородов в процессе gtl, и способ ее использования |
| EP2886513A1 (en) * | 2013-12-20 | 2015-06-24 | Casale Sa | Process for producing ammonia synthesis gas |
| RU2544656C1 (ru) * | 2013-12-27 | 2015-03-20 | Владимир Владиславович Имшенецкий | Установка для получения синтез-газа для производства углеводородов |
| WO2015145311A1 (en) * | 2014-03-24 | 2015-10-01 | Sasol Technology Proprietary Limited | Fischer-tropsch synthesis |
| WO2015184290A1 (en) * | 2014-05-30 | 2015-12-03 | GI - Gasification International, S.A. | Methods, systems and apparatuses for recycling fischer-tropsch and fischer-tropsch tail gas |
| US10174261B2 (en) * | 2014-05-30 | 2019-01-08 | Sgce Llc | Methods, systems, and apparatuses for utilizing a fischer-tropsch purge stream |
| RU2648331C2 (ru) * | 2014-12-26 | 2018-03-23 | ИНФРА ИксТиЭл ТЕКНОЛОДЖИ ЛИМИТЕД | Способ получения синтетических жидких углеводородов из природного газа |
| DE102015004214A1 (de) * | 2015-03-31 | 2016-10-06 | Linde Aktiengesellschaft | Verfahren zur Erzeugung von Synthesegas aus einem CO2-reichen, kohlenwasserstoffhaltigen Einsatzgas |
| WO2017093130A1 (en) * | 2015-12-04 | 2017-06-08 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of syngas |
| US20190084833A1 (en) * | 2016-02-03 | 2019-03-21 | Epiphany Energy Corporation | Production of liquid hydrocarbons, biofuels and uncontaminated co2 from gaseous feedstock |
| US10260005B2 (en) | 2016-08-05 | 2019-04-16 | Greyrock Technology LLC | Catalysts, related methods and reaction products |
| US20180215618A1 (en) * | 2017-01-27 | 2018-08-02 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Maximizing steam methane reformer combustion efficiency by pre-heating pre-reformed fuel gas |
| CN110636988A (zh) | 2017-05-10 | 2019-12-31 | 托普索公司 | 用于含氧化合物的蒸汽重整的方法以及用于该方法的催化剂 |
| RU2684420C1 (ru) * | 2018-06-14 | 2019-04-09 | Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") | Способ получения синтетической нефти из природного/попутного нефтяного газа и компактная установка для получения синтетической нефти из природного/попутного нефтяного газа |
| BR102018068334B1 (pt) * | 2018-09-11 | 2021-12-07 | Petróleo Brasileiro S.A. - Petrobras | Processo para a preparação de hidrocarbonetos líquidos por processo de fischer- tropsch integrado a unidades de refino |
| WO2020174057A1 (en) * | 2019-02-28 | 2020-09-03 | Haldor Topsøe A/S | Synthesis gas production by steam methane reforming |
| KR20220112282A (ko) * | 2019-12-04 | 2022-08-10 | 토프쉐 에이/에스 | 전열 증기 메탄 개질에 의한 합성 연료 |
| CA3163634A1 (en) * | 2019-12-04 | 2021-06-10 | Topsoe A/S | Biogas conversion to synthesis gas for producing hydrocarbons |
| GB202009969D0 (en) * | 2020-06-30 | 2020-08-12 | Johnson Matthey Plc | Low-carbon hydrogen process |
| EP3992265A1 (de) | 2020-10-30 | 2022-05-04 | Ineratec GmbH | Verfahren und anlage zur produktaufbereitung fischer-tropsch basierter rohprodukte zur produktion von vorformulierten oder normgerechten kraftstoffen |
| EP4357440A1 (de) * | 2022-10-20 | 2024-04-24 | Linde GmbH | Verfahren zur herstellung eines zielprodukts und entsprechende anlage |
| EP4357439A1 (de) * | 2022-10-20 | 2024-04-24 | Linde GmbH | Verfahren zur herstellung eines zielprodukts und entsprechende anlage |
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| FR2372116A1 (fr) * | 1977-03-22 | 1978-06-23 | Banquy David | Procede de production de gaz de synthese |
| US4127389A (en) | 1977-04-04 | 1978-11-28 | Pullman Incorporated | Exchanger reactor |
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| EP0194067B2 (en) | 1985-03-05 | 1994-05-11 | Imperial Chemical Industries Plc | Steam reforming hydrocarbons |
| GB8803766D0 (en) | 1988-02-18 | 1988-03-16 | Ici Plc | Methanol |
| GB9516125D0 (en) | 1995-08-07 | 1995-10-04 | Ici Plc | Heat exchange apparatus and process |
| GB9817526D0 (en) * | 1998-08-13 | 1998-10-07 | Ici Plc | Steam reforming |
| WO2000058242A2 (en) * | 1999-03-30 | 2000-10-05 | Syntroleum Corporation | System and method for converting light hydrocarbons into heavier hydrocarbons with a plurality of synthesis gas subsystems |
| GB0120071D0 (en) | 2001-08-17 | 2001-10-10 | Ici Plc | Steam reforming |
-
2004
- 2004-04-21 AU AU2004234588A patent/AU2004234588B2/en not_active Ceased
- 2004-04-21 WO PCT/GB2004/001677 patent/WO2004096952A1/en active Search and Examination
- 2004-04-21 US US10/555,369 patent/US7323497B2/en not_active Expired - Lifetime
- 2004-04-21 EA EA200501735A patent/EA008048B1/ru not_active IP Right Cessation
- 2004-04-21 CA CA2523219A patent/CA2523219C/en not_active Expired - Lifetime
- 2004-04-21 EP EP04728589A patent/EP1625190A1/en not_active Withdrawn
- 2004-04-28 MY MYPI20041575A patent/MY141294A/en unknown
-
2005
- 2005-11-01 ZA ZA200508859A patent/ZA200508859B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1625190A1 (en) | 2006-02-15 |
| MY141294A (en) | 2010-04-16 |
| US20070010590A1 (en) | 2007-01-11 |
| EA008048B1 (ru) | 2007-02-27 |
| WO2004096952A1 (en) | 2004-11-11 |
| CA2523219A1 (en) | 2004-11-11 |
| US7323497B2 (en) | 2008-01-29 |
| AU2004234588A1 (en) | 2004-11-11 |
| CA2523219C (en) | 2012-06-12 |
| EA200501735A1 (ru) | 2006-06-30 |
| AU2004234588B2 (en) | 2009-04-09 |
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