ZA200505558B - Coolant based on azole derivatives containing 1,3-Propandiol for fuel cell cooling systems - Google Patents
Coolant based on azole derivatives containing 1,3-Propandiol for fuel cell cooling systems Download PDFInfo
- Publication number
- ZA200505558B ZA200505558B ZA200505558A ZA200505558A ZA200505558B ZA 200505558 B ZA200505558 B ZA 200505558B ZA 200505558 A ZA200505558 A ZA 200505558A ZA 200505558 A ZA200505558 A ZA 200505558A ZA 200505558 B ZA200505558 B ZA 200505558B
- Authority
- ZA
- South Africa
- Prior art keywords
- fuel cell
- propanediol
- cooling systems
- weight
- azole derivatives
- Prior art date
Links
- 239000000446 fuel Substances 0.000 title claims description 34
- 239000002826 coolant Substances 0.000 title claims description 33
- 150000007980 azole derivatives Chemical class 0.000 title claims description 31
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 title claims description 29
- 238000001816 cooling Methods 0.000 title claims description 28
- 239000000203 mixture Substances 0.000 claims description 37
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 28
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 28
- 230000002528 anti-freeze Effects 0.000 claims description 19
- 239000012141 concentrate Substances 0.000 claims description 17
- -1 alkylene glycols Chemical class 0.000 claims description 15
- 229910052717 sulfur Inorganic materials 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 125000004434 sulfur atom Chemical group 0.000 claims description 11
- 150000002148 esters Chemical class 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- LRUDIIUSNGCQKF-UHFFFAOYSA-N 5-methyl-1H-benzotriazole Chemical compound C1=C(C)C=CC2=NNN=C21 LRUDIIUSNGCQKF-UHFFFAOYSA-N 0.000 claims description 7
- 238000010790 dilution Methods 0.000 claims description 5
- 239000012895 dilution Substances 0.000 claims description 5
- 125000005842 heteroatom Chemical group 0.000 claims description 5
- 150000002391 heterocyclic compounds Chemical class 0.000 claims description 5
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 4
- 239000012964 benzotriazole Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 229940035437 1,3-propanediol Drugs 0.000 description 20
- 238000005260 corrosion Methods 0.000 description 11
- 230000007797 corrosion Effects 0.000 description 11
- 239000007788 liquid Substances 0.000 description 6
- 125000004433 nitrogen atom Chemical group N* 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- 150000000177 1,2,3-triazoles Chemical class 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- NBZANZVJRKXVBH-GYDPHNCVSA-N alpha-Cryptoxanthin Natural products O[C@H]1CC(C)(C)C(/C=C/C(=C\C=C\C(=C/C=C/C=C(\C=C\C=C(/C=C/[C@H]2C(C)=CCCC2(C)C)\C)/C)\C)/C)=C(C)C1 NBZANZVJRKXVBH-GYDPHNCVSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- 150000002431 hydrogen Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/20—Antifreeze additives therefor, e.g. for radiator liquids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/10—Liquid materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
- H01M8/04029—Heat exchange using liquids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Thermal Sciences (AREA)
- Combustion & Propulsion (AREA)
- Sustainable Energy (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Manufacturing & Machinery (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10258385A DE10258385A1 (de) | 2002-12-12 | 2002-12-12 | Kühlmittel auf Basis von 1,3-Propandiol enthaltend Azolderivate für Brennstoffzellen-Kühlsysteme |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200505558B true ZA200505558B (en) | 2006-10-25 |
Family
ID=32336312
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200505558A ZA200505558B (en) | 2002-12-12 | 2005-07-11 | Coolant based on azole derivatives containing 1,3-Propandiol for fuel cell cooling systems |
Country Status (16)
Country | Link |
---|---|
US (1) | US20060027782A1 (ja) |
EP (1) | EP1572830B1 (ja) |
JP (1) | JP4944381B2 (ja) |
KR (1) | KR101021207B1 (ja) |
CN (1) | CN1726269B (ja) |
AR (1) | AR042449A1 (ja) |
AT (1) | ATE500305T1 (ja) |
AU (1) | AU2003294775B2 (ja) |
BR (1) | BR0317186B1 (ja) |
CA (1) | CA2509597C (ja) |
DE (2) | DE10258385A1 (ja) |
ES (1) | ES2359699T3 (ja) |
MX (1) | MXPA05006019A (ja) |
PL (1) | PL205334B1 (ja) |
WO (1) | WO2004053015A1 (ja) |
ZA (1) | ZA200505558B (ja) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6818146B2 (en) * | 2001-01-16 | 2004-11-16 | Shell Oil Company | Chemical base for engine coolant/antifreeze with improved thermal stability properties |
US8658326B2 (en) | 2004-09-08 | 2014-02-25 | Prestone Products Corporation | Heat transfer system, fluid, and method |
ZA200701537B (en) | 2004-09-08 | 2008-10-29 | Honeywell Int Inc | Treated ion exchange resins, method of making, assemblies and heat transfer systems containing the same, and method of use |
AU2005282491A1 (en) | 2004-09-08 | 2006-03-16 | Honeywell International Inc. | Colorant treated ion exchange resins, method of making, heat transfer systems and assemblies containing the same, and method of use |
KR101207886B1 (ko) | 2004-09-08 | 2012-12-05 | 프레스톤 프로닥츠 코포레이션 | 부식 억제제, 부식 억제 열 전달 유체, 및 이들의 사용 |
EP1809718B1 (en) * | 2004-09-08 | 2013-05-15 | Prestone Products Corporation | Non-conductive colored heat transfer fluids |
US20070202062A1 (en) * | 2006-02-10 | 2007-08-30 | Workman Tanya L | Natural deodorant compositions comprising renewably-based, biodegradable 1,3-propanediol |
FR2958654B1 (fr) * | 2010-04-08 | 2013-08-23 | Dehon S A | Liquide caloporteur |
CA3031521A1 (en) | 2016-07-29 | 2018-02-01 | Ecolab Usa Inc. | Benzotriazole and tolyltriazole derivatives for corrosion mitigation |
BR112019010016B1 (pt) * | 2016-11-23 | 2023-11-14 | Basf Se | Composição de refrigerante, método para produzir composições de refrigerante, e, uso de uma composição de refrigerante |
CA3118778A1 (en) * | 2018-11-06 | 2020-05-14 | Basf Se | New heat transfer liquid for cooling lithium storage batteries |
JP7111588B2 (ja) * | 2018-11-14 | 2022-08-02 | トヨタ自動車株式会社 | 冷却液組成物 |
JP6836210B2 (ja) | 2018-12-26 | 2021-02-24 | 株式会社デンソー | 車両用熱マネジメントシステム、熱輸送媒体、および車両走行用の電池の冷却方法 |
JP2020105942A (ja) * | 2018-12-26 | 2020-07-09 | 株式会社デンソー | 車両用熱マネジメントシステム |
JP2020125384A (ja) * | 2019-02-01 | 2020-08-20 | 株式会社デンソー | 熱輸送媒体および車両用熱マネジメントシステム |
EP3865552A1 (en) | 2020-02-11 | 2021-08-18 | Arteco NV | Heat-transfer fluid with low conductivity comprising an amide inhibitor, methods for its preparation and uses thereof |
EP4117085A1 (en) | 2021-07-07 | 2023-01-11 | Basf Se | Novel coolant with low electrical conductivity |
CN113698917B (zh) * | 2021-08-25 | 2023-11-24 | 统一石油化工有限公司 | 一种氢燃料电池车用冷却液组合物 |
CN113789160B (zh) * | 2021-09-10 | 2023-07-04 | 浙江巨化技术中心有限公司 | 一种包含聚乙二醇硫氮杂化改性体的组合物、及其用于液冷剂的用途以及浸没式液冷系统 |
WO2023111687A1 (en) * | 2021-12-17 | 2023-06-22 | Cci Holdings, Inc. | Heat transfer system with organic, non-ionic inhibitors compatible with flux exposure in fuel cell operations |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1948794A1 (de) * | 1969-09-26 | 1971-04-01 | Rhein Chemie Rheinau Gmbh | 4,5,6,7-Tetrahydrobenzotriazole,Verfahren zu ihrer Herstellung und ihre Verwendung als Korrosionsinhibitoren |
US4460478A (en) * | 1982-09-30 | 1984-07-17 | Union Carbide Corporation | Orthosilicate ester containing heat transfer fluids |
DE19802490C2 (de) | 1998-01-23 | 2002-01-24 | Xcellsis Gmbh | Verwendung eines Paraffins als Kühlmittel für Brennstoffzellen |
ATE295616T1 (de) | 1998-09-22 | 2005-05-15 | Ballard Power Systems | Kühlsubsystem mit frostschutzmittel |
DE19857398B4 (de) | 1998-12-12 | 2010-07-08 | GM Global Technology Operations, Inc., Detroit | Brennstoffzellensystem, insbesondere für elektromotorisch angetriebene Fahrzeuge |
JP4842420B2 (ja) * | 1999-09-28 | 2011-12-21 | トヨタ自動車株式会社 | 冷却液、冷却液の封入方法および冷却システム |
DE10063951A1 (de) * | 2000-12-20 | 2002-06-27 | Basf Ag | Kühlmittel für Kühlsysteme in Brennstoffzellenantrieben |
US6818146B2 (en) * | 2001-01-16 | 2004-11-16 | Shell Oil Company | Chemical base for engine coolant/antifreeze with improved thermal stability properties |
US7452479B2 (en) * | 2001-02-14 | 2008-11-18 | Shell Oil Company | Chemical base for fuel cell engine heat exchange coolant/antifreeze comprising 1,3-propanediol |
DE10128530A1 (de) | 2001-06-13 | 2002-12-19 | Basf Ag | Kühlmittel für Kühlsysteme in Brennstoffzellenantrieben enthaltend Azolderivate |
DE10201276A1 (de) * | 2002-01-15 | 2003-07-24 | Basf Ag | Verfahren und Vorrichtung zum Entionisieren von Kühlmedien für Brennstoffzellen |
-
2002
- 2002-12-12 DE DE10258385A patent/DE10258385A1/de not_active Withdrawn
-
2003
- 2003-12-03 CN CN2003801059816A patent/CN1726269B/zh not_active Expired - Fee Related
- 2003-12-03 CA CA2509597A patent/CA2509597C/en not_active Expired - Fee Related
- 2003-12-03 US US10/536,806 patent/US20060027782A1/en not_active Abandoned
- 2003-12-03 EP EP03785723A patent/EP1572830B1/de not_active Expired - Lifetime
- 2003-12-03 WO PCT/EP2003/013633 patent/WO2004053015A1/de active Application Filing
- 2003-12-03 KR KR1020057010516A patent/KR101021207B1/ko active IP Right Grant
- 2003-12-03 PL PL377707A patent/PL205334B1/pl not_active IP Right Cessation
- 2003-12-03 BR BRPI0317186-8B1A patent/BR0317186B1/pt not_active IP Right Cessation
- 2003-12-03 MX MXPA05006019A patent/MXPA05006019A/es active IP Right Grant
- 2003-12-03 JP JP2004557982A patent/JP4944381B2/ja not_active Expired - Fee Related
- 2003-12-03 AU AU2003294775A patent/AU2003294775B2/en not_active Ceased
- 2003-12-03 ES ES03785723T patent/ES2359699T3/es not_active Expired - Lifetime
- 2003-12-03 DE DE50313514T patent/DE50313514D1/de not_active Expired - Lifetime
- 2003-12-03 AT AT03785723T patent/ATE500305T1/de active
- 2003-12-12 AR ARP030104591A patent/AR042449A1/es unknown
-
2005
- 2005-07-11 ZA ZA200505558A patent/ZA200505558B/en unknown
Also Published As
Publication number | Publication date |
---|---|
KR101021207B1 (ko) | 2011-03-11 |
ATE500305T1 (de) | 2011-03-15 |
CA2509597C (en) | 2012-11-20 |
CN1726269B (zh) | 2012-11-07 |
EP1572830B1 (de) | 2011-03-02 |
ES2359699T3 (es) | 2011-05-26 |
MXPA05006019A (es) | 2005-08-18 |
AR042449A1 (es) | 2005-06-22 |
PL205334B1 (pl) | 2010-04-30 |
WO2004053015A1 (de) | 2004-06-24 |
KR20050085504A (ko) | 2005-08-29 |
CN1726269A (zh) | 2006-01-25 |
EP1572830A1 (de) | 2005-09-14 |
AU2003294775B2 (en) | 2009-08-27 |
BR0317186B1 (pt) | 2013-08-13 |
US20060027782A1 (en) | 2006-02-09 |
PL377707A1 (pl) | 2006-02-06 |
JP4944381B2 (ja) | 2012-05-30 |
AU2003294775A1 (en) | 2004-06-30 |
DE10258385A1 (de) | 2004-06-24 |
CA2509597A1 (en) | 2004-06-24 |
BR0317186A (pt) | 2005-11-01 |
JP2006510168A (ja) | 2006-03-23 |
DE50313514D1 (de) | 2011-04-14 |
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