ZA200305586B - Process for the production of linear alpha olefins and ethylene. - Google Patents
Process for the production of linear alpha olefins and ethylene. Download PDFInfo
- Publication number
- ZA200305586B ZA200305586B ZA200305586A ZA200305586A ZA200305586B ZA 200305586 B ZA200305586 B ZA 200305586B ZA 200305586 A ZA200305586 A ZA 200305586A ZA 200305586 A ZA200305586 A ZA 200305586A ZA 200305586 B ZA200305586 B ZA 200305586B
- Authority
- ZA
- South Africa
- Prior art keywords
- hexene
- butene
- metathesis
- catalyst
- isomerized
- Prior art date
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000005977 Ethylene Substances 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims description 39
- 239000004711 α-olefin Substances 0.000 title description 15
- 238000004519 manufacturing process Methods 0.000 title description 6
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims abstract description 153
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims abstract description 48
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims abstract description 42
- 238000006317 isomerization reaction Methods 0.000 claims abstract description 38
- 238000005649 metathesis reaction Methods 0.000 claims abstract description 38
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 claims abstract description 21
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003054 catalyst Substances 0.000 claims description 58
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pentene-2 Natural products CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 claims description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 14
- 150000001336 alkenes Chemical class 0.000 claims description 13
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 11
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 9
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 9
- 230000003197 catalytic effect Effects 0.000 claims description 7
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 7
- 238000005194 fractionation Methods 0.000 claims description 6
- 238000004821 distillation Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 3
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 3
- DYIZHKNUQPHNJY-UHFFFAOYSA-N oxorhenium Chemical compound [Re]=O DYIZHKNUQPHNJY-UHFFFAOYSA-N 0.000 claims description 3
- 229910003449 rhenium oxide Inorganic materials 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 238000004064 recycling Methods 0.000 claims description 2
- -1 pentene olefin Chemical class 0.000 claims 1
- 239000007858 starting material Substances 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 description 31
- 229910052799 carbon Inorganic materials 0.000 description 14
- 239000000047 product Substances 0.000 description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 13
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 11
- 230000000694 effects Effects 0.000 description 8
- 239000000395 magnesium oxide Substances 0.000 description 8
- ZQDPJFUHLCOCRG-UHFFFAOYSA-N 3-hexene Chemical compound CCC=CCC ZQDPJFUHLCOCRG-UHFFFAOYSA-N 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 239000012808 vapor phase Substances 0.000 description 4
- 230000004580 weight loss Effects 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 3
- 238000006384 oligomerization reaction Methods 0.000 description 3
- RYPKRALMXUUNKS-UHFFFAOYSA-N 2-Hexene Natural products CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 229910001038 basic metal oxide Inorganic materials 0.000 description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/107—Alkenes with six carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/04—Ethylene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
- C07C5/25—Migration of carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/28—Molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/30—Tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/32—Manganese, technetium or rhenium
- C07C2523/36—Rhenium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26392401P | 2001-01-25 | 2001-01-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200305586B true ZA200305586B (en) | 2004-09-03 |
Family
ID=23003825
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200305586A ZA200305586B (en) | 2001-01-25 | 2003-07-18 | Process for the production of linear alpha olefins and ethylene. |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6727396B2 (fr) |
| EP (1) | EP1353889B1 (fr) |
| JP (1) | JP4079776B2 (fr) |
| KR (1) | KR100803431B1 (fr) |
| CN (1) | CN100537496C (fr) |
| AT (1) | ATE473954T1 (fr) |
| AU (1) | AU2002236885B2 (fr) |
| BR (1) | BR0206658B1 (fr) |
| CA (1) | CA2435569C (fr) |
| DE (1) | DE60236997D1 (fr) |
| ES (2) | ES2349005T3 (fr) |
| MX (1) | MXPA03006560A (fr) |
| RU (1) | RU2262500C2 (fr) |
| WO (1) | WO2002059066A1 (fr) |
| ZA (1) | ZA200305586B (fr) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6683019B2 (en) | 2001-06-13 | 2004-01-27 | Abb Lummus Global Inc. | Catalyst for the metathesis of olefin(s) |
| US6777582B2 (en) * | 2002-03-07 | 2004-08-17 | Abb Lummus Global Inc. | Process for producing propylene and hexene from C4 olefin streams |
| US20030236175A1 (en) * | 2002-05-29 | 2003-12-25 | Twu Fred Chun-Chien | Process for well fluids base oil via metathesis of alpha-olefins |
| US20030224945A1 (en) * | 2002-05-29 | 2003-12-04 | Twu Fred Chun-Chien | Process for well fluids base oil via metathesis of alpha-olefins |
| CA2512815A1 (fr) * | 2003-01-13 | 2004-07-29 | Cargill, Incorporated | Procede de production de produits chimiques industriels |
| WO2005035469A1 (fr) | 2003-10-02 | 2005-04-21 | Shell Internationale Research Maatschappij B.V. | Production par distillation catalytique de 1-alcenes a partir de courants d'olefines |
| US20060047176A1 (en) * | 2004-08-25 | 2006-03-02 | Gartside Robert J | Butane removal in C4 upgrading processes |
| US20060129013A1 (en) * | 2004-12-09 | 2006-06-15 | Abazajian Armen N | Specific functionalization and scission of linear hydrocarbon chains |
| CN1319917C (zh) * | 2005-04-13 | 2007-06-06 | 吉化集团公司 | 1－己烯一步合成直链混合烯烃的方法及催化剂 |
| US20070225536A1 (en) * | 2006-03-23 | 2007-09-27 | Eugene Frederick Lutz | Olefin conversion process and olefin recovery process |
| JP5570587B2 (ja) | 2008-04-04 | 2014-08-13 | ラムス テクノロジー インク | 直鎖アルファオレフィンを製造するためのシステムおよびプロセス |
| JP5298195B2 (ja) * | 2008-08-12 | 2013-09-25 | ルマス テクノロジー インコーポレイテッド | 統合されたプロピレン生成 |
| MY152067A (en) * | 2008-09-04 | 2014-08-15 | Lummus Technology Inc | Olefin isomerization and metathesis catalyst |
| US8084659B2 (en) * | 2008-10-22 | 2011-12-27 | Lummus Technology, Inc. | Hexene upgrading |
| RU2460713C1 (ru) * | 2008-11-17 | 2012-09-10 | Юоп Ллк | Способ предварительной обработки в установке метатезиса с образованием октена |
| US7982086B2 (en) * | 2009-02-03 | 2011-07-19 | Catalytic Distillation Technologies | Deisobutenizer |
| TWI458538B (zh) * | 2009-04-03 | 2014-11-01 | Lummus Technology Inc | 製造線性α烯烴之系統及方法 |
| US8586813B2 (en) * | 2009-07-21 | 2013-11-19 | Lummus Technology Inc. | Catalyst for metathesis of ethylene and 2-butene and/or double bond isomerization |
| US8362311B2 (en) | 2009-09-30 | 2013-01-29 | Massachusetts Institute Of Technology | Highly Z-selective olefins metathesis |
| CN102040454B (zh) * | 2009-10-13 | 2013-08-14 | 中国石油化工股份有限公司 | 丁烯歧化制己烯的方法 |
| US8324440B2 (en) * | 2010-02-05 | 2012-12-04 | Uop Llc | Support properties of silica supported catalysts and their use in olefin metathesis |
| US8895795B2 (en) * | 2010-02-05 | 2014-11-25 | Uop Llc | Acid washed silica supported catalysts and their use in olefin metathesis |
| US8935891B2 (en) | 2011-06-09 | 2015-01-20 | Uop Llc | Olefin metathesis catalyst containing tungsten fluorine bonds |
| CN103030513B (zh) * | 2011-09-29 | 2014-10-15 | 中国石油化工股份有限公司 | 用于丁烯歧化制己烯的方法 |
| CN103420772B (zh) * | 2012-05-16 | 2015-10-21 | 中国石油化工股份有限公司 | 用于丁烯制己烯的方法 |
| CN103539618B (zh) * | 2012-07-12 | 2015-07-08 | 中国石油化工股份有限公司 | 己烯双键异构化的方法 |
| CN103539617B (zh) * | 2012-07-12 | 2015-06-10 | 中国石油化工股份有限公司 | 流化床烯烃歧化制己烯的方法 |
| BR112015005606B1 (pt) | 2012-09-14 | 2021-03-09 | Lummus Technology Inc | processo para a produção de propileno |
| CN104275193B (zh) * | 2013-07-09 | 2017-06-20 | 中国石油化工股份有限公司 | 复分解催化剂 |
| CN104275189B (zh) * | 2013-07-09 | 2017-06-20 | 中国石油化工股份有限公司 | 高温烧结型合成气制低碳烯烃的催化剂及其制备方法 |
| JP5863734B2 (ja) * | 2013-09-18 | 2016-02-17 | ラムス テクノロジー インク | 直鎖アルファオレフィンを製造するためのシステムおよびプロセス |
| EP2862629A1 (fr) * | 2013-10-15 | 2015-04-22 | Borealis AG | Catalyseur et procédé de réaction de métathèses d'oléfines |
| JP2014159464A (ja) * | 2014-05-07 | 2014-09-04 | Lummus Technology Inc | 直鎖アルファオレフィンを製造するためのシステムおよびプロセス |
| US20210170367A1 (en) * | 2019-12-05 | 2021-06-10 | Saudi Arabian Oil Company | Metathesis catalysts and methods of producing propene |
| EP3974499A1 (fr) | 2020-09-28 | 2022-03-30 | Indian Oil Corporation Limited | Production d'alpha-oléfines linéaires |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2776974A (en) | 1954-04-07 | 1957-01-08 | Monsanto Chemicals | Di-(lower alkyl) cyclohexylamine salts of 2, 5-dimethylpiperazine-1, 4-dicarbodithioic acid |
| US3485891A (en) * | 1967-05-18 | 1969-12-23 | Phillips Petroleum Co | Conversion of propylene to 5-decene |
| GB1357632A (en) * | 1971-02-22 | 1974-06-26 | Shell Int Research | Process for the manufacture of higher olefins |
| GB1471151A (en) | 1973-05-30 | 1977-04-21 | Shell Int Research | Process for the production of alkenes |
| US4368345A (en) * | 1981-01-07 | 1983-01-11 | Bp Chemicals Limited | Catalyst for disproportionation of olefins |
| US4522936A (en) * | 1983-03-21 | 1985-06-11 | Phillips Petroleum Company | Metathesis catalyst |
| US4709115A (en) * | 1986-05-15 | 1987-11-24 | The Dow Chemical Company | Disproportionation of alkenes |
| US5057638A (en) * | 1990-06-22 | 1991-10-15 | Chevron Research And Technology Company | Process for making 1-hexene from 1-butene |
| EP1373169A1 (fr) * | 2001-01-25 | 2004-01-02 | Basf Aktiengesellschaft | Procede modifie de production d'alpha-olefines superieures |
-
2002
- 2002-01-23 US US10/055,126 patent/US6727396B2/en not_active Expired - Lifetime
- 2002-01-24 MX MXPA03006560A patent/MXPA03006560A/es active IP Right Grant
- 2002-01-24 JP JP2002559371A patent/JP4079776B2/ja not_active Expired - Fee Related
- 2002-01-24 RU RU2003125853/04A patent/RU2262500C2/ru not_active IP Right Cessation
- 2002-01-24 BR BRPI0206658-0A patent/BR0206658B1/pt not_active IP Right Cessation
- 2002-01-24 ES ES02703253T patent/ES2349005T3/es not_active Expired - Lifetime
- 2002-01-24 EP EP02703253A patent/EP1353889B1/fr not_active Expired - Lifetime
- 2002-01-24 CA CA002435569A patent/CA2435569C/fr not_active Expired - Fee Related
- 2002-01-24 CN CNB028071654A patent/CN100537496C/zh not_active Expired - Lifetime
- 2002-01-24 WO PCT/US2002/002352 patent/WO2002059066A1/fr active IP Right Grant
- 2002-01-24 AT AT02703253T patent/ATE473954T1/de not_active IP Right Cessation
- 2002-01-24 DE DE60236997T patent/DE60236997D1/de not_active Expired - Lifetime
- 2002-01-24 KR KR1020037009787A patent/KR100803431B1/ko active IP Right Grant
- 2002-01-24 ES ES08005540.3T patent/ES2441255T3/es not_active Expired - Lifetime
- 2002-01-24 AU AU2002236885A patent/AU2002236885B2/en not_active Ceased
-
2003
- 2003-07-18 ZA ZA200305586A patent/ZA200305586B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2262500C2 (ru) | 2005-10-20 |
| BR0206658B1 (pt) | 2012-09-18 |
| MXPA03006560A (es) | 2003-09-25 |
| CN100537496C (zh) | 2009-09-09 |
| US20020183572A1 (en) | 2002-12-05 |
| JP2004522743A (ja) | 2004-07-29 |
| CA2435569A1 (fr) | 2002-08-01 |
| CN1498197A (zh) | 2004-05-19 |
| DE60236997D1 (de) | 2010-08-26 |
| ES2441255T3 (es) | 2014-02-03 |
| CA2435569C (fr) | 2008-03-25 |
| AU2002236885B2 (en) | 2005-07-28 |
| KR100803431B1 (ko) | 2008-02-13 |
| US6727396B2 (en) | 2004-04-27 |
| JP4079776B2 (ja) | 2008-04-23 |
| ES2349005T3 (es) | 2010-12-21 |
| BR0206658A (pt) | 2004-02-03 |
| ATE473954T1 (de) | 2010-07-15 |
| KR20040004511A (ko) | 2004-01-13 |
| EP1353889A1 (fr) | 2003-10-22 |
| RU2003125853A (ru) | 2005-02-20 |
| WO2002059066A1 (fr) | 2002-08-01 |
| EP1353889B1 (fr) | 2010-07-14 |
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