ZA200301582B - Method for producing epoxides by oxidising olefins. - Google Patents
Method for producing epoxides by oxidising olefins. Download PDFInfo
- Publication number
- ZA200301582B ZA200301582B ZA200301582A ZA200301582A ZA200301582B ZA 200301582 B ZA200301582 B ZA 200301582B ZA 200301582 A ZA200301582 A ZA 200301582A ZA 200301582 A ZA200301582 A ZA 200301582A ZA 200301582 B ZA200301582 B ZA 200301582B
- Authority
- ZA
- South Africa
- Prior art keywords
- ozone
- flow reactor
- mbar
- carbon atoms
- reaction
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 19
- 150000002118 epoxides Chemical class 0.000 title claims abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 238000000034 method Methods 0.000 claims abstract description 33
- 238000006243 chemical reaction Methods 0.000 claims abstract description 28
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 17
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 9
- 238000010574 gas phase reaction Methods 0.000 claims abstract description 4
- 150000001993 dienes Chemical class 0.000 claims abstract description 3
- 230000003647 oxidation Effects 0.000 claims description 12
- 238000007254 oxidation reaction Methods 0.000 claims description 12
- 239000012159 carrier gas Substances 0.000 claims description 7
- 239000007789 gas Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 claims description 2
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 abstract description 6
- 150000005673 monoalkenes Chemical class 0.000 abstract description 3
- 230000001590 oxidative effect Effects 0.000 abstract description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 11
- 229940095050 propylene Drugs 0.000 description 10
- 150000002924 oxiranes Chemical class 0.000 description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 9
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- -1 olefin glycols Chemical class 0.000 description 2
- 230000036647 reaction Effects 0.000 description 2
- GELKGHVAFRCJNA-UHFFFAOYSA-N 2,2-Dimethyloxirane Chemical compound CC1(C)CO1 GELKGHVAFRCJNA-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10044538A DE10044538A1 (de) | 2000-09-05 | 2000-09-05 | Verfahren zur Herstellung von Epoxiden durch Oxidation von Olefinen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200301582B true ZA200301582B (en) | 2004-03-10 |
Family
ID=7655566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200301582A ZA200301582B (en) | 2000-09-05 | 2003-02-26 | Method for producing epoxides by oxidising olefins. |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6812357B2 (es) |
| EP (1) | EP1299367B1 (es) |
| CN (1) | CN1216875C (es) |
| AT (1) | ATE255095T1 (es) |
| AU (1) | AU2001285929A1 (es) |
| BR (1) | BR0113787B1 (es) |
| CA (1) | CA2419591A1 (es) |
| DE (2) | DE10044538A1 (es) |
| ES (1) | ES2210187T3 (es) |
| NO (1) | NO20030997L (es) |
| PT (1) | PT1299367E (es) |
| RU (1) | RU2242470C2 (es) |
| TR (1) | TR200302075T4 (es) |
| WO (1) | WO2002020502A1 (es) |
| ZA (1) | ZA200301582B (es) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7648719B2 (en) | 2001-12-04 | 2010-01-19 | Peter Kolta | Method for oxygen treatment of unsaturated carbon compounds, novel epoxy-structured material obtained by the method, apparatus for carrying out the method and a therapeutic composition using the material |
| DE102007039874B9 (de) * | 2007-08-20 | 2010-12-09 | Zylum Beteiligungsgesellschaft Mbh & Co. Patente Ii Kg | Verfahren zur Herstellung von Epoxiden durch Oxidation von Olefinen in der homogenen Gasphase |
| DE102008028760B9 (de) * | 2008-06-17 | 2010-09-30 | Zylum Beteiligungsgesellschaft Mbh & Co. Patente Ii Kg | Verfahren zur Abtrennung von NOx aus einem epoxidhaltigen Gasstrom |
| DE102012101607A1 (de) | 2012-02-28 | 2013-08-29 | Zylum Beteiligungsgesellschaft Mbh & Co. Patente Ii Kg | Verbessertes Verfahren zur Abtrennung von NOx aus einem epoxidhaltigen Gasstrom |
| CN103288779B (zh) * | 2012-02-29 | 2015-04-29 | 中国石油化工股份有限公司 | 一种烯丙醇氧化的方法 |
| CN103288781B (zh) * | 2012-02-29 | 2015-04-29 | 中国石油化工股份有限公司 | 一种制备环氧氯丙烷的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1219014B (de) | 1958-07-30 | 1966-06-16 | Exxon Research Engineering Co | Verfahren zur Herstellung von Alkylenoxyden durch nichtkatalytische partielle Oxydation von Kohlenwasserstoffen in der Dampfphase |
| US3160639A (en) * | 1960-05-19 | 1964-12-08 | Exxon Research Engineering Co | Preparation of oxygenated compounds by ozone initiated oxidation |
| US5625084A (en) | 1996-01-31 | 1997-04-29 | Arco Chemical Technology, L.P. | Vapor phase oxidation of propylene to propylene oxide |
| US5763630A (en) | 1996-03-18 | 1998-06-09 | Arco Chemical Technology, L.P. | Propylene oxide process using alkaline earth metal compound-supported silver catalysts |
| US5760254A (en) | 1996-07-18 | 1998-06-02 | Arco Chemical Technology, L.P. | Production of oxirane compounds |
| DE19754303A1 (de) | 1997-12-08 | 1999-06-10 | Hoechst Ag | Verfahren zur Herstellung von Propenoxid |
-
2000
- 2000-09-05 DE DE10044538A patent/DE10044538A1/de not_active Withdrawn
-
2001
- 2001-09-05 ES ES01965255T patent/ES2210187T3/es not_active Expired - Lifetime
- 2001-09-05 TR TR2003/02075T patent/TR200302075T4/xx unknown
- 2001-09-05 CN CN01815185XA patent/CN1216875C/zh not_active Expired - Fee Related
- 2001-09-05 WO PCT/EP2001/010231 patent/WO2002020502A1/de active IP Right Grant
- 2001-09-05 BR BRPI0113787-5A patent/BR0113787B1/pt not_active IP Right Cessation
- 2001-09-05 AU AU2001285929A patent/AU2001285929A1/en not_active Abandoned
- 2001-09-05 US US10/363,170 patent/US6812357B2/en not_active Expired - Fee Related
- 2001-09-05 CA CA002419591A patent/CA2419591A1/en not_active Abandoned
- 2001-09-05 DE DE50101047T patent/DE50101047D1/de not_active Expired - Lifetime
- 2001-09-05 RU RU2003105881/04A patent/RU2242470C2/ru not_active IP Right Cessation
- 2001-09-05 PT PT01965255T patent/PT1299367E/pt unknown
- 2001-09-05 EP EP01965255A patent/EP1299367B1/de not_active Expired - Lifetime
- 2001-09-05 AT AT01965255T patent/ATE255095T1/de not_active IP Right Cessation
-
2003
- 2003-02-26 ZA ZA200301582A patent/ZA200301582B/en unknown
- 2003-03-04 NO NO20030997A patent/NO20030997L/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR0113787A (pt) | 2004-09-21 |
| TR200302075T4 (tr) | 2004-01-21 |
| CA2419591A1 (en) | 2002-03-14 |
| ATE255095T1 (de) | 2003-12-15 |
| RU2242470C2 (ru) | 2004-12-20 |
| PT1299367E (pt) | 2004-04-30 |
| NO20030997D0 (no) | 2003-03-04 |
| DE50101047D1 (de) | 2004-01-08 |
| CN1216875C (zh) | 2005-08-31 |
| EP1299367B1 (de) | 2003-11-26 |
| CN1452615A (zh) | 2003-10-29 |
| US6812357B2 (en) | 2004-11-02 |
| EP1299367A1 (de) | 2003-04-09 |
| NO20030997L (no) | 2003-03-04 |
| AU2001285929A1 (en) | 2002-03-22 |
| BR0113787B1 (pt) | 2011-12-27 |
| WO2002020502A1 (de) | 2002-03-14 |
| US20040054202A1 (en) | 2004-03-18 |
| ES2210187T3 (es) | 2004-07-01 |
| DE10044538A1 (de) | 2002-04-04 |
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