ZA200203301B - Asymmetric copper complex and clyclopropanation reaction using the same. - Google Patents

Asymmetric copper complex and clyclopropanation reaction using the same.

Info

Publication number
ZA200203301B
ZA200203301B ZA200203301A ZA200203301A ZA200203301B ZA 200203301 B ZA200203301 B ZA 200203301B ZA 200203301 A ZA200203301 A ZA 200203301A ZA 200203301 A ZA200203301 A ZA 200203301A ZA 200203301 B ZA200203301 B ZA 200203301B
Authority
ZA
South Africa
Prior art keywords
group
same
represent
hydrogen atom
copper complex
Prior art date
Application number
ZA200203301A
Other languages
English (en)
Inventor
Michio Yamamoto
Gohfu Suzukamo
Makoto Itagaki
Original Assignee
Sumitomo Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co filed Critical Sumitomo Chemical Co
Publication of ZA200203301B publication Critical patent/ZA200203301B/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/08—Copper compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/324—Cyclisations via conversion of C-C multiple to single or less multiple bonds, e.g. cycloadditions
    • B01J2231/325—Cyclopropanations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
ZA200203301A 2001-04-27 2002-04-25 Asymmetric copper complex and clyclopropanation reaction using the same. ZA200203301B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001132016 2001-04-27

Publications (1)

Publication Number Publication Date
ZA200203301B true ZA200203301B (en) 2002-12-04

Family

ID=18980097

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA200203301A ZA200203301B (en) 2001-04-27 2002-04-25 Asymmetric copper complex and clyclopropanation reaction using the same.

Country Status (9)

Country Link
US (1) US6858559B2 (enExample)
EP (1) EP1253135B1 (enExample)
KR (1) KR20020083457A (enExample)
CN (1) CN1259322C (enExample)
AT (1) ATE489356T1 (enExample)
DE (1) DE60238367D1 (enExample)
ES (1) ES2354685T3 (enExample)
HU (1) HU229387B1 (enExample)
ZA (1) ZA200203301B (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101097080B1 (ko) * 2003-02-07 2011-12-22 스미또모 가가꾸 가부시끼가이샤 광학 활성 비스옥사졸린 화합물, 그 제조 방법 및 그 용도
KR101113627B1 (ko) * 2003-03-31 2012-02-13 스미또모 가가꾸 가부시끼가이샤 광학활성 구리 촉매 조성물
KR101132998B1 (ko) * 2003-09-19 2012-04-10 스미또모 가가꾸 가부시끼가이샤 광학 활성 시클로프로판 화합물의 제조 방법 및 이에사용된 비대칭 구리 착물
ITMI20041211A1 (it) * 2004-06-16 2004-09-16 Endura Spa Catalizzatori a base di complessi metallici per la sintesi di acido crisantemico otticamente attivo
JP5002916B2 (ja) 2004-07-01 2012-08-15 住友化学株式会社 不斉銅錯体およびそれを用いた光学活性なシクロプロパンカルボン酸エステル化合物の製造方法
CN100569729C (zh) * 2004-07-01 2009-12-16 住友化学株式会社 制备光学活性环丙烷羧酸酯化合物的方法
CN100389117C (zh) * 2004-08-20 2008-05-21 中国科学院上海有机化学研究所 一种具有手性中心的噁唑啉环金属催化剂、合成及用途
CN100348597C (zh) * 2005-12-29 2007-11-14 上海交通大学 5，5’位连接的1, 1’－联苯类轴手性配体的合成方法
PT2341042T (pt) * 2008-09-10 2019-05-21 Sumitomo Chemical Co Método para produzir composto de éster de ácido carboxílico de ciclopropano oticamente ativo, complexo de cobre assimétrico, e composto de saliicilidenoaminoálcool oticamente ativo
CN104926747B (zh) * 2015-06-01 2018-09-21 中国科学院上海有机化学研究所 具有光学活性的环己基噁唑啉配体的合成方法及其用途
CN106045985B (zh) * 2016-06-14 2018-11-09 华中师范大学 一种双噁唑啉类化合物及制备方法和用途
CN109692708A (zh) * 2017-10-24 2019-04-30 沈阳中化农药化工研发有限公司 一种不对称环丙化催化剂及其应用
CN111732508B (zh) * 2019-03-25 2022-11-01 华东师范大学 一种螺环化合物的合成方法
CN114369248B (zh) * 2020-10-15 2022-09-02 中国科学院大连化学物理研究所 一种手性含硅聚酯及其合成方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4033976A (en) * 1975-10-28 1977-07-05 Imc Chemical Group, Inc. Copper-oxazoline complex
HU210648B (en) 1983-09-15 1995-06-28 Jozsef Muskovits Process for preparing cycloproane-carboxylic acid esters
US5298623A (en) 1991-11-08 1994-03-29 Massachusetts Institute Of Technology Cu complexes of bis-oxazolines and their use
US6011169A (en) 1997-07-14 2000-01-04 Sumitomo Chemical Company, Limited Process for producing optically active cyclopropanecaboxylic acid esters
CA2244417C (en) * 1997-08-05 2006-07-18 Sumitomo Chemical Co., Ltd. Optically active bisoxazoline compounds, production and use thereof
GB9725455D0 (en) * 1997-12-02 1998-01-28 Univ Warwick Supported polymerisation catalyst
WO2002066522A1 (de) * 2001-02-17 2002-08-29 Celanese Ventures Gmbh Übergangsmetallverbindung als katalysatorbestandteil, und verwendung zur herstellung von polyolefinen

Also Published As

Publication number Publication date
CN1384105A (zh) 2002-12-11
EP1253135A1 (en) 2002-10-30
ES2354685T3 (es) 2011-03-17
CN1259322C (zh) 2006-06-14
HU0201357D0 (enExample) 2002-06-29
HU229387B1 (en) 2013-11-28
ATE489356T1 (de) 2010-12-15
DE60238367D1 (de) 2011-01-05
EP1253135B1 (en) 2010-11-24
HUP0201357A3 (en) 2004-06-28
US6858559B2 (en) 2005-02-22
KR20020083457A (ko) 2002-11-02
HUP0201357A2 (hu) 2003-01-28
US20020177718A1 (en) 2002-11-28

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