ZA200101147B - Process and catalysts for upgrading of hydrocarbons boiling in the naphtha range. - Google Patents
Process and catalysts for upgrading of hydrocarbons boiling in the naphtha range. Download PDFInfo
- Publication number
- ZA200101147B ZA200101147B ZA200101147A ZA200101147A ZA200101147B ZA 200101147 B ZA200101147 B ZA 200101147B ZA 200101147 A ZA200101147 A ZA 200101147A ZA 200101147 A ZA200101147 A ZA 200101147A ZA 200101147 B ZA200101147 B ZA 200101147B
- Authority
- ZA
- South Africa
- Prior art keywords
- metal
- catalyst
- group
- process according
- aqueous solution
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 202
- 238000000034 method Methods 0.000 title claims description 100
- 229930195733 hydrocarbon Natural products 0.000 title claims description 31
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 31
- 238000009835 boiling Methods 0.000 title claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 102
- 239000002184 metal Substances 0.000 claims description 102
- 239000000203 mixture Substances 0.000 claims description 54
- 239000010457 zeolite Substances 0.000 claims description 54
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 50
- 229910021536 Zeolite Inorganic materials 0.000 claims description 49
- 238000005470 impregnation Methods 0.000 claims description 46
- 239000007864 aqueous solution Substances 0.000 claims description 44
- 239000000243 solution Substances 0.000 claims description 40
- 229910044991 metal oxide Inorganic materials 0.000 claims description 36
- 150000004706 metal oxides Chemical class 0.000 claims description 36
- 150000003839 salts Chemical class 0.000 claims description 32
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 28
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 27
- 150000001336 alkenes Chemical class 0.000 claims description 24
- 238000001354 calcination Methods 0.000 claims description 23
- 238000001035 drying Methods 0.000 claims description 23
- 238000006317 isomerization reaction Methods 0.000 claims description 21
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 19
- 239000006185 dispersion Substances 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 229910017052 cobalt Inorganic materials 0.000 claims description 17
- 239000010941 cobalt Substances 0.000 claims description 17
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 17
- 229910052750 molybdenum Inorganic materials 0.000 claims description 16
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims description 14
- 229910052717 sulfur Inorganic materials 0.000 claims description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 239000011593 sulfur Substances 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 230000032683 aging Effects 0.000 claims description 7
- 230000003009 desulfurizing effect Effects 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 5
- 239000011733 molybdenum Substances 0.000 claims description 5
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 150000001768 cations Chemical class 0.000 claims description 4
- -1 hydrogen ions Chemical class 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000005336 cracking Methods 0.000 claims description 3
- 229910001657 ferrierite group Inorganic materials 0.000 claims description 3
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229920000620 organic polymer Polymers 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 3
- 206010011416 Croup infectious Diseases 0.000 claims 1
- 201000010549 croup Diseases 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 29
- 239000012153 distilled water Substances 0.000 description 23
- 230000000052 comparative effect Effects 0.000 description 22
- 238000005984 hydrogenation reaction Methods 0.000 description 19
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 18
- 238000004231 fluid catalytic cracking Methods 0.000 description 17
- 238000003756 stirring Methods 0.000 description 16
- 238000006477 desulfuration reaction Methods 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 13
- 230000023556 desulfurization Effects 0.000 description 13
- 239000004215 Carbon black (E152) Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 9
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 6
- 235000010210 aluminium Nutrition 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 4
- 241001372564 Piona Species 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 229940071826 hydroxyethyl cellulose Drugs 0.000 description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 4
- JCCNYMKQOSZNPW-UHFFFAOYSA-N loratadine Chemical compound C1CN(C(=O)OCC)CCC1=C1C2=NC=CC=C2CCC2=CC(Cl)=CC=C21 JCCNYMKQOSZNPW-UHFFFAOYSA-N 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000006069 physical mixture Substances 0.000 description 4
- WOZZOSDBXABUFO-UHFFFAOYSA-N tri(butan-2-yloxy)alumane Chemical compound [Al+3].CCC(C)[O-].CCC(C)[O-].CCC(C)[O-] WOZZOSDBXABUFO-UHFFFAOYSA-N 0.000 description 4
- 238000009472 formulation Methods 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 3
- 235000011007 phosphoric acid Nutrition 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229930192474 thiophene Natural products 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000008247 solid mixture Substances 0.000 description 2
- 240000005343 Azadirachta indica Species 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000013500 Melia azadirachta Nutrition 0.000 description 1
- 241000840267 Moma Species 0.000 description 1
- 101100422881 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) swf-1 gene Proteins 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 235000019568 aromas Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical class [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 244000144985 peep Species 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
- B01J29/66—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing iron group metals, noble metals or copper
- B01J29/68—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
- B01J29/69—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98202744A EP0980908A1 (en) | 1998-08-15 | 1998-08-15 | Process and catalysts for upgrading of hydrocarbons boiling in the naphtha range |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200101147B true ZA200101147B (en) | 2001-08-14 |
Family
ID=8234042
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200101147A ZA200101147B (en) | 1998-08-15 | 2001-02-09 | Process and catalysts for upgrading of hydrocarbons boiling in the naphtha range. |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US6746598B1 (xx) |
| EP (1) | EP0980908A1 (xx) |
| JP (1) | JP2002522625A (xx) |
| KR (1) | KR20010099621A (xx) |
| CN (1) | CN1318095A (xx) |
| AR (1) | AR020178A1 (xx) |
| AU (1) | AU761053B2 (xx) |
| BR (1) | BR9914613A (xx) |
| CA (1) | CA2340707A1 (xx) |
| CZ (1) | CZ2001582A3 (xx) |
| HU (1) | HUP0103220A3 (xx) |
| NO (1) | NO20010748L (xx) |
| PE (1) | PE20001142A1 (xx) |
| PL (1) | PL346129A1 (xx) |
| WO (1) | WO2000009632A1 (xx) |
| ZA (1) | ZA200101147B (xx) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100419288B1 (ko) * | 2001-06-22 | 2004-02-19 | 인천정유 주식회사 | 경질유의 탈방향족화용 촉매의 제조방법 |
| FR2840315B1 (fr) * | 2002-06-03 | 2004-08-20 | Inst Francais Du Petrole | Procede d'hydrodesulfuration de coupes contenant des composes soufres et des olefines en presence d'un catalyseur supporte comprenant des metaux des groupes viii et vib |
| EP1403358A1 (en) * | 2002-09-27 | 2004-03-31 | ENI S.p.A. | Process and catalysts for deep desulphurization of fuels |
| US7141529B2 (en) * | 2003-03-21 | 2006-11-28 | Chevron U.S.A. Inc. | Metal loaded microporous material for hydrocarbon isomerization processes |
| US20050023191A1 (en) * | 2003-08-01 | 2005-02-03 | Shih Stuart S. | Process to manufacture low sulfur fuels |
| US7288181B2 (en) * | 2003-08-01 | 2007-10-30 | Exxonmobil Research And Engineering Company | Producing low sulfur naphtha products through improved olefin isomerization |
| US7763164B1 (en) * | 2006-05-04 | 2010-07-27 | Marathon Petroleum Company Llc | Gasoline sulfur reduction in FCCU cracking |
| CN101357338B (zh) * | 2007-07-30 | 2011-11-30 | 南京大学 | 一种用于FCC石脑油中烯烃骨架异构的Co/Co-MCM-41催化剂 |
| US8263517B2 (en) * | 2007-12-28 | 2012-09-11 | Exxonmobil Research And Engineering Company | Hydroprocessing catalysts with low surface area binders |
| FR2998488B1 (fr) | 2012-11-29 | 2015-02-06 | Ifp Energies Now | Catalyseur d hydrotraitement a partir d alumine gel et methode de preparation d un tel catalyseur |
| CN106622314B (zh) * | 2016-12-15 | 2020-01-07 | 中国海洋石油集团有限公司 | 一种高活性加氢精制催化剂及其制备方法 |
| CN106582738B (zh) * | 2016-12-15 | 2020-01-03 | 中国海洋石油集团有限公司 | 一种加氢精制催化剂及其制备方法 |
| CN108587673B (zh) * | 2018-04-23 | 2020-12-01 | 安徽理工大学 | 一种球磨预处理微晶纤维素热解制备生物油的方法 |
| FR3116826B1 (fr) | 2020-11-27 | 2023-11-03 | Ifp Energies Now | Procede d’hydrodesulfuration mettant en œuvre un catalyseur comprenant un support d’alumine flash |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| NL105779C (xx) | 1959-07-13 | 1900-01-01 | ||
| DE1443121A1 (de) | 1960-09-09 | 1968-10-31 | Shell Int Research | Verfahren zur katalytischen Umwandlung von nicht verzweigten oder schwach verzweigten Kohlenwasserstoffen in Kohlenwasserstoffe mit einer verzweigten oder staerker verzweigten Kohlenstoffkette |
| FR2457317A1 (fr) | 1979-05-21 | 1980-12-19 | Inst Francais Du Petrole | Procede et catalyseurs de desulfuration selective de coupes olefiniques |
| JPH0631333B2 (ja) * | 1984-11-22 | 1994-04-27 | 重質油対策技術研究組合 | 炭化水素類の水素化分解方法 |
| US4808560A (en) * | 1985-05-13 | 1989-02-28 | Mobil Oil Corporation | Catalyst for simultaneous desulfurization and dewaxing of residua |
| US4629717A (en) * | 1985-06-11 | 1986-12-16 | Uop Inc. | Phosphorus-modified alumina composite, method of manufacture and use thereof |
| US4628717A (en) | 1985-10-03 | 1986-12-16 | Blum Alvin S | Protective key holder |
| US5043520A (en) * | 1989-12-21 | 1991-08-27 | Shell Oil Company | Concurrent isomerization and disproportionation of olefins |
| EP0448117B1 (en) * | 1990-03-23 | 1994-09-28 | Cosmo Research Institute | Process for producing a catalyst composition for hydrodesulphurization of hydrocarbon oil. |
| JP2547115B2 (ja) * | 1990-03-30 | 1996-10-23 | 財団法人石油産業活性化センター | 炭化水素油用水素化処理触媒組成物ならびにそれを用いる水素化処理方法 |
| US5411658A (en) * | 1991-08-15 | 1995-05-02 | Mobil Oil Corporation | Gasoline upgrading process |
| JP3272384B2 (ja) | 1991-10-24 | 2002-04-08 | 財団法人石油産業活性化センター | 触媒組成物及びその製造方法ならびに該触媒組成物を用いる含硫炭化水素の水素化脱硫方法 |
| AU658937B2 (en) * | 1991-11-19 | 1995-05-04 | Mobil Oil Corporation | Hydrocarbon upgrading process |
| IT1252647B (it) | 1991-12-06 | 1995-06-20 | Eniricerche Spa | Catalizzatore estruso a base di gel di silice ed allumina e procedimento per la sua preparazione |
| US5482617A (en) * | 1993-03-08 | 1996-01-09 | Mobil Oil Corporation | Desulfurization of hydrocarbon streams |
| EP0665280B1 (en) * | 1993-12-30 | 2000-05-10 | Cosmo Oil Company, Ltd | Process for producing a hydrodesulfurization catalyst |
| US5576256A (en) * | 1994-05-23 | 1996-11-19 | Intevep, S.A. | Hydroprocessing scheme for production of premium isomerized light gasoline |
| US5871635A (en) * | 1995-05-09 | 1999-02-16 | Exxon Research And Engineering Company | Hydroprocessing of petroleum fractions with a dual catalyst system |
| US6582590B1 (en) * | 1997-07-15 | 2003-06-24 | Exxonmobil Research And Engineering Company | Multistage hydroprocessing using bulk multimetallic catalyst |
| IT1295300B1 (it) | 1997-10-09 | 1999-05-04 | Agip Petroli | Procedimento per l'idroisomerizzazione di n-paraffine a catena lunga e catalizzatore adatto allo scopo |
| IT1304792B1 (it) * | 1998-12-22 | 2001-03-29 | Agip Petroli | Composizione catalitica per l'upgrading di idrocarburi aventi puntidi ebollizione nell'intervallo della nafta. |
-
1998
- 1998-08-15 EP EP98202744A patent/EP0980908A1/en not_active Withdrawn
-
1999
- 1999-08-03 KR KR1020017001944A patent/KR20010099621A/ko not_active Application Discontinuation
- 1999-08-03 PL PL99346129A patent/PL346129A1/xx unknown
- 1999-08-03 CN CN99810912A patent/CN1318095A/zh active Pending
- 1999-08-03 BR BR9914613-4A patent/BR9914613A/pt not_active IP Right Cessation
- 1999-08-03 AU AU54182/99A patent/AU761053B2/en not_active Ceased
- 1999-08-03 CA CA002340707A patent/CA2340707A1/en not_active Abandoned
- 1999-08-03 HU HU0103220A patent/HUP0103220A3/hu unknown
- 1999-08-03 JP JP2000565069A patent/JP2002522625A/ja active Pending
- 1999-08-03 WO PCT/EP1999/005577 patent/WO2000009632A1/en not_active Application Discontinuation
- 1999-08-03 CZ CZ2001582A patent/CZ2001582A3/cs unknown
- 1999-08-03 US US09/744,978 patent/US6746598B1/en not_active Expired - Fee Related
- 1999-08-11 PE PE1999000810A patent/PE20001142A1/es not_active Application Discontinuation
- 1999-08-12 AR ARP990104045A patent/AR020178A1/es not_active Application Discontinuation
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2001
- 2001-02-09 ZA ZA200101147A patent/ZA200101147B/en unknown
- 2001-02-14 NO NO20010748A patent/NO20010748L/no unknown
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2004
- 2004-04-07 US US10/819,211 patent/US7196029B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0980908A1 (en) | 2000-02-23 |
| US7196029B2 (en) | 2007-03-27 |
| NO20010748D0 (no) | 2001-02-14 |
| CN1318095A (zh) | 2001-10-17 |
| AU5418299A (en) | 2000-03-06 |
| NO20010748L (no) | 2001-04-11 |
| AR020178A1 (es) | 2002-05-02 |
| AU761053B2 (en) | 2003-05-29 |
| US20040192540A1 (en) | 2004-09-30 |
| CA2340707A1 (en) | 2000-02-24 |
| PE20001142A1 (es) | 2000-10-26 |
| PL346129A1 (en) | 2002-01-28 |
| BR9914613A (pt) | 2001-07-03 |
| US6746598B1 (en) | 2004-06-08 |
| HUP0103220A3 (en) | 2003-04-28 |
| WO2000009632A1 (en) | 2000-02-24 |
| JP2002522625A (ja) | 2002-07-23 |
| HUP0103220A2 (hu) | 2001-12-28 |
| KR20010099621A (ko) | 2001-11-09 |
| CZ2001582A3 (cs) | 2002-01-16 |
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