WO2024052773A1 - 半導体装置、およびその作製方法 - Google Patents

半導体装置、およびその作製方法 Download PDF

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Publication number
WO2024052773A1
WO2024052773A1 PCT/IB2023/058643 IB2023058643W WO2024052773A1 WO 2024052773 A1 WO2024052773 A1 WO 2024052773A1 IB 2023058643 W IB2023058643 W IB 2023058643W WO 2024052773 A1 WO2024052773 A1 WO 2024052773A1
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Prior art keywords
layer
semiconductor
semiconductor layer
film
insulating layer
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Ceased
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PCT/IB2023/058643
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English (en)
French (fr)
Japanese (ja)
Inventor
神長正美
島行徳
中田昌孝
吉住健輔
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Semiconductor Energy Laboratory Co Ltd
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Semiconductor Energy Laboratory Co Ltd
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Priority to US19/103,839 priority Critical patent/US20250393256A1/en
Priority to JP2024545076A priority patent/JPWO2024052773A1/ja
Priority to KR1020257010214A priority patent/KR20250065841A/ko
Priority to CN202380060639.6A priority patent/CN119769196A/zh
Publication of WO2024052773A1 publication Critical patent/WO2024052773A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/136Liquid crystal cells structurally associated with a semi-conducting layer or substrate, e.g. cells forming part of an integrated circuit
    • G02F1/1362Active matrix addressed cells
    • G02F1/1368Active matrix addressed cells in which the switching element is a three-electrode device
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/67Thin-film transistors [TFT]
    • H10D30/6757Thin-film transistors [TFT] characterised by the structure of the channel, e.g. transverse or longitudinal shape or doping profile
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/01Manufacture or treatment
    • H10D30/021Manufacture or treatment of FETs having insulated gates [IGFET]
    • H10D30/031Manufacture or treatment of FETs having insulated gates [IGFET] of thin-film transistors [TFT]
    • H10D30/0318Manufacture or treatment of FETs having insulated gates [IGFET] of thin-film transistors [TFT] of vertical TFTs
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/01Manufacture or treatment
    • H10D30/021Manufacture or treatment of FETs having insulated gates [IGFET]
    • H10D30/031Manufacture or treatment of FETs having insulated gates [IGFET] of thin-film transistors [TFT]
    • H10D30/0321Manufacture or treatment of FETs having insulated gates [IGFET] of thin-film transistors [TFT] comprising silicon, e.g. amorphous silicon or polysilicon
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/67Thin-film transistors [TFT]
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/67Thin-film transistors [TFT]
    • H10D30/6728Vertical TFTs
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/67Thin-film transistors [TFT]
    • H10D30/674Thin-film transistors [TFT] characterised by the active materials
    • H10D30/6741Group IV materials, e.g. germanium or silicon carbide
    • H10D30/6743Silicon
    • H10D30/6745Polycrystalline or microcrystalline silicon
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D84/00Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D84/00Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
    • H10D84/01Manufacture or treatment
    • H10D84/0123Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
    • H10D84/0126Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D84/00Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
    • H10D84/01Manufacture or treatment
    • H10D84/02Manufacture or treatment characterised by using material-based technologies
    • H10D84/03Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology
    • H10D84/038Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology using silicon technology, e.g. SiGe
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/10OLEDs or polymer light-emitting diodes [PLED]
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/10OLED displays
    • H10K59/12Active-matrix OLED [AMOLED] displays
    • H10K59/121Active-matrix OLED [AMOLED] displays characterised by the geometry or disposition of pixel elements
    • H10K59/1213Active-matrix OLED [AMOLED] displays characterised by the geometry or disposition of pixel elements the pixel elements being TFTs

Definitions

  • One embodiment of the present invention relates to a semiconductor device and a method for manufacturing the same.
  • One embodiment of the present invention relates to a transistor and a method for manufacturing the same.
  • One embodiment of the present invention relates to a display device including a semiconductor device.
  • one embodiment of the present invention is not limited to the above technical field.
  • the technical fields of one embodiment of the present invention disclosed in this specification etc. include semiconductor devices, display devices, light emitting devices, power storage devices, storage devices, electronic devices, lighting devices, input devices, input/output devices, and driving methods thereof. , or their manufacturing method.
  • Semiconductor devices refer to all devices that can function by utilizing semiconductor characteristics.
  • High-definition display panels mainly use light emitting elements such as organic EL (Electro Luminescence) elements or light emitting diodes (LEDs).
  • Patent Document 1 discloses a high-definition display device using an organic EL device (also referred to as an organic EL element).
  • An object of one embodiment of the present invention is to provide a transistor, a display device, an electronic device, or the like having a novel structure. Another challenge is to provide highly reliable transistors, display devices, electronic devices, and the like.
  • One aspect of the present invention seeks to at least alleviate at least one of the problems of the prior art.
  • One embodiment of the present invention includes a first conductive layer, a second conductive layer, a third conductive layer, a first semiconductor layer, a second semiconductor layer, a third semiconductor layer, a first insulating layer, and a first conductive layer.
  • This is a semiconductor device having two insulating layers.
  • the second semiconductor layer is provided on the first conductive layer
  • the first insulating layer is provided on the second semiconductor layer
  • the second conductive layer is provided on the first insulating layer
  • the third insulating layer is provided on the first insulating layer.
  • a semiconductor layer is provided on the second conductive layer.
  • the first insulating layer has an opening that reaches the second semiconductor layer.
  • the first semiconductor layer has a portion in contact with the third semiconductor layer, a portion inside the opening in contact with the side surface of the first insulating layer, and a portion in contact with the second semiconductor layer.
  • the second insulating layer covers the first semiconductor layer.
  • the third conductive layer has a portion that overlaps with the first semiconductor layer with the second insulating layer interposed therebetween.
  • the first semiconductor layer, the second semiconductor layer, and the third semiconductor layer contain silicon.
  • the second semiconductor layer and the third semiconductor layer contain the same impurity element.
  • the first insulating layer contains hydrogen, nitrogen, and silicon.
  • the first semiconductor layer, the second semiconductor layer, and the third semiconductor layer each contain amorphous silicon.
  • the first semiconductor layer, the second semiconductor layer, and the third semiconductor layer each contain polycrystalline silicon.
  • the second semiconductor layer preferably has a first portion in contact with the first semiconductor layer and a second portion in contact with the first insulating layer.
  • the first portion has a higher concentration of impurity elements than the second portion.
  • the impurity element is preferably one or more selected from phosphorus, arsenic, boron, and aluminum.
  • Another embodiment of the present invention is a method for manufacturing a semiconductor device, in which a first conductive layer and a second semiconductor layer containing an impurity element are sequentially formed on the first conductive layer over an insulating plane. . Subsequently, a first insulating layer is formed to cover the second semiconductor layer. Subsequently, a second conductive layer is formed on the first insulating layer, and a third semiconductor layer containing an impurity element is formed on the second conductive layer in this order. Subsequently, a portion of each of the third semiconductor layer, second conductive layer, and first insulating layer is etched. Subsequently, an opening reaching the second semiconductor layer is formed.
  • a first semiconductor layer is formed in contact with the side surfaces of the third semiconductor layer, the second semiconductor layer, and the first insulating layer.
  • a second insulating layer is formed on the first semiconductor layer, and a third conductive layer is formed on the second insulating layer in this order.
  • the first semiconductor layer, the second semiconductor layer, and the third semiconductor layer contain silicon.
  • Another embodiment of the present invention is a method for manufacturing a semiconductor device, in which a first conductive layer is first formed over an insulating plane, and a second semiconductor layer is formed over the first conductive layer in this order. . Subsequently, a first insulating layer is formed to cover the second semiconductor layer. Subsequently, a second conductive layer is formed on the first insulating layer, and a third semiconductor layer is formed on the second conductive layer in this order. Subsequently, a portion of each of the third semiconductor layer, second conductive layer, and first insulating layer is etched. Subsequently, an opening reaching the second semiconductor layer is formed.
  • an impurity element is added to a portion of the second semiconductor layer that overlaps with the opening and to the third semiconductor layer.
  • a first semiconductor layer is formed in contact with the side surfaces of the third semiconductor layer, the second semiconductor layer, and the first insulating layer.
  • a second insulating layer is formed on the first semiconductor layer, and a third conductive layer is formed on the second insulating layer in this order.
  • the first semiconductor layer, the second semiconductor layer, and the third semiconductor layer contain silicon.
  • any of the above manufacturing methods it is preferable to use one or more selected from phosphorus, arsenic, boron, and aluminum as the impurity element.
  • a transistor that can be miniaturized can be provided.
  • a transistor with good electrical characteristics can be provided.
  • a transistor whose channel length can be reduced can be provided.
  • a transistor that occupies a small area can be provided.
  • a display device that can easily achieve high definition can be provided.
  • a transistor, a display device, an electronic device, and the like having a novel configuration can be provided.
  • highly reliable transistors, display devices, electronic devices, and the like can be provided.
  • at least one of the problems of the prior art can be at least alleviated.
  • FIG. 1A and 1B are configuration examples of semiconductor devices.
  • FIG. 2 shows an example of the configuration of a semiconductor device.
  • FIG. 3A is a circuit diagram of a semiconductor device.
  • 3B and 3C are configuration examples of semiconductor devices.
  • 4A and 4B are configuration examples of semiconductor devices.
  • 5A and 5B are configuration examples of semiconductor devices.
  • 6A to 6F are diagrams illustrating a method for manufacturing a semiconductor device.
  • 7A to 7E are diagrams illustrating a method for manufacturing a semiconductor device.
  • 8A to 8C are diagrams illustrating a method for manufacturing a semiconductor device.
  • 9A to 9C are diagrams illustrating a method for manufacturing a semiconductor device.
  • FIG. 10 shows an example of the configuration of a display device.
  • FIG. 11 shows an example of the configuration of a display device.
  • FIG. 10 shows an example of the configuration of a display device.
  • FIG. 12 shows a configuration example of a display device.
  • FIG. 13 shows an example of the configuration of a display device.
  • FIG. 14 shows a configuration example of a display device.
  • 15A to 15F are diagrams illustrating a method for manufacturing a display device.
  • 16A to 16D are configuration examples of electronic equipment.
  • 17A to 17F are configuration examples of electronic equipment.
  • 18A to 18G are configuration examples of electronic equipment.
  • electrically connected includes a case where the two are connected via "something that has some kind of electrical effect.”
  • something that has some kind of electrical effect is not particularly limited as long as it enables the transmission and reception of electrical signals between connected objects.
  • something that has some kind of electrical action includes electrodes or wiring, switching elements such as transistors, resistance elements, coils, capacitive elements, and other elements with various functions.
  • the upper surface shapes roughly match means that at least a portion of the outlines of the stacked layers overlap. For example, this includes a case where the upper layer and the lower layer are processed using the same mask pattern or partially the same mask pattern. However, strictly speaking, the contours may not overlap, and the upper layer may be located inside the lower layer, or the upper layer may be located outside the lower layer, and in this case, the upper surface shape may be said to be "approximately the same".
  • top shape of a certain component refers to the outline shape of the component in plan view.
  • planar view refers to viewing from the normal direction of the surface on which the component is formed or the surface of the support (for example, a substrate) on which the component is formed.
  • orientation of "upper” and “lower” are basically used in conjunction with the orientation of the drawing.
  • the orientation of "upper” or “lower” in the specification may not correspond to the drawings.
  • the surface on which the laminate is provided formed surface, supporting surface, adhesive surface, flat surface, etc.
  • its direction may be expressed as below, the opposite direction may be expressed as upward, etc.
  • film and the term “layer” can be interchanged with each other.
  • insulating layer may be interchangeable with the term “insulating film.”
  • a display panel which is one aspect of a display device, has a function of displaying (outputting) an image or the like on a display surface. Therefore, the display panel is one type of output device.
  • the substrate of the display panel is equipped with a connector such as FPC (Flexible Printed Circuit) or TCP (Tape Carrier Package), or an IC is attached to the substrate using a COG (Chip On Glass) method.
  • a device on which is mounted may be called a display panel module, display module, or simply display panel.
  • a touch panel which is one aspect of a display device, has the function of displaying an image, etc. on a display surface, and the function of displaying an object such as a finger or stylus touching, pressing, or approaching the display surface. It has a function as a touch sensor for detection. Therefore, a touch panel is one type of input/output device.
  • a touch panel can also be called, for example, a display panel with a touch sensor (or display device) or a display panel with a touch sensor function (or display device).
  • the touch panel can also be configured to include a display panel and a touch sensor panel.
  • the display panel may have a function as a touch sensor inside or on the surface thereof.
  • a touch panel board with a connector or an IC mounted thereon may be referred to as a touch panel module, a display module, or simply a touch panel.
  • a transistor of one embodiment of the present invention includes a semiconductor layer, a gate insulating layer, a gate electrode, a first electrode, and a second electrode.
  • the first electrode functions as one of a source electrode and a drain electrode, and the second electrode functions as the other.
  • the second electrode is provided above the first electrode.
  • An insulating layer functioning as a spacer is provided between the first electrode and the second electrode.
  • the spacer is provided with an opening that reaches the first electrode, and the semiconductor layer is provided in contact with the first electrode, the second electrode, and a side wall (also referred to as a side surface) within the opening of the insulating layer.
  • a gate insulating layer and a gate electrode are provided to cover the semiconductor layer.
  • the semiconductor layer preferably contains an elemental semiconductor such as silicon or germanium. In particular, it is preferable to include silicon. Furthermore, at this time, it is preferable that the first electrode and the second electrode each have a laminated structure of a conductive layer and a layer containing a semiconductor to which an impurity element is added (impurity semiconductor layer). The semiconductor layer is provided so as to be in contact with the impurity semiconductor layers of the first electrode and the second electrode.
  • an element that imparts n-type conductivity such as phosphorus or arsenic, or an element that imparts p-type conductivity, such as boron or aluminum, can be used.
  • the source electrode and the drain electrode are located at different heights, so the current flowing through the semiconductor layer flows in the height direction.
  • the channel length direction has a component in the height direction (vertical direction); therefore, the transistor of one embodiment of the present invention can be a VFET (Vertical Field Effect Transistor), a vertical transistor, a vertical channel transistor, or the like. It can also be called.
  • VFET Vertical Field Effect Transistor
  • the above transistor can have a source electrode, a semiconductor layer, and a drain electrode stacked on top of each other, so it is possible to provide so-called planar transistors (lateral transistors, LFETs (Lateral FETs), etc.) in which the semiconductor layers are arranged on a plane.
  • planar transistors lateral transistors, LFETs (Lateral FETs), etc.
  • the area occupied can be significantly reduced compared to the
  • the channel length of the transistor can be precisely controlled by the thickness of the insulating layer, variations in channel length can be made extremely small compared to planar transistors. Furthermore, by making the insulating layer thinner, a transistor with an extremely short channel length can be manufactured. For example, manufacturing a transistor with a channel length of 2 ⁇ m or less, 1 ⁇ m or less, 500 nm or less, 300 nm or less, 200 nm or less, 100 nm or less, 50 nm or less, 30 nm or less, or 20 nm or less, and 5 nm or more, 7 nm or more, or 10 nm or more. Can be done.
  • the area occupied by the transistors can be reduced compared to display devices using conventional horizontal transistors. It becomes possible to improve the aperture ratio. As a result, it is possible to realize a display device with higher definition, a display device with higher reliability, a display device with lower power consumption, etc. than in the past.
  • FIG. 1A shows a schematic cross-sectional view of a semiconductor device having a transistor 10. Further, FIG. 1B shows a schematic perspective view of a semiconductor device. In FIG. 1B, in order to make the structure of the transistor 10 easier to see, a portion of the front side is cut away.
  • the transistor 10 is provided on a substrate 11.
  • the transistor 10 includes a semiconductor layer 21, an insulating layer 22, a conductive layer 23, an electrode layer 24, and an electrode layer 25.
  • a portion of the insulating layer 22 functions as a gate insulating layer, and a portion of the conductive layer 23 functions as a gate electrode.
  • a portion of the electrode layer 24 functions as one of the source electrode and the drain electrode, and a portion of the electrode layer 25 functions as the other of the source electrode and the drain electrode.
  • the electrode layer 24 has a laminated structure in which a conductive layer 31 and a semiconductor layer 32 are laminated from the substrate 11 side. Further, the electrode layer 25 has a laminated structure in which a conductive layer 33 and a semiconductor layer 34 are laminated from the substrate 11 side.
  • the semiconductor layer 32 and the semiconductor layer 34 each contain the same semiconductor material as the semiconductor layer 21. Further, the semiconductor layer 32 and the semiconductor layer 34 are doped with the same impurity element and exhibit electrical characteristics of an n-type semiconductor or a p-type semiconductor.
  • the semiconductor layer 21, the semiconductor layer 32, and the semiconductor layer 34 contain elemental semiconductors such as silicon and germanium.
  • silicon amorphous silicon, microcrystalline silicon, polycrystalline silicon, or single-crystalline silicon can be used, and in particular, amorphous silicon, microcrystalline silicon, or polycrystalline silicon that can be formed on a large-area glass substrate is used. It is preferable.
  • the transistor 10 can be manufactured using an existing display backplane manufacturing apparatus, so a display device with higher performance than before can be manufactured without making a large capital investment.
  • semiconductor material used for the semiconductor layer is not limited to elemental semiconductors, and compound semiconductors, oxide semiconductors, organic semiconductors, etc. can also be used.
  • examples of impurity elements that impart n-type conductivity include phosphorus, arsenic, and the like.
  • examples of impurity elements that impart p-type conductivity include boron, aluminum, and the like.
  • the conductive layer 31 and the conductive layer 33 contain a conductive material having a lower resistance than the semiconductor layer 32 and the semiconductor layer 34, respectively.
  • the structure may include metal, alloy, conductive oxide, or the like. Thereby, a portion of each of the conductive layer 31 and the conductive layer 33 can be used as a wiring. Further, a conductive layer formed by processing the same conductive film as the conductive layer 31 and the conductive layer 33 may be used as the wiring.
  • the electrode layer 24 is provided on the substrate 11, and an insulating layer 28 is provided covering the electrode layer 24. Further, an electrode layer 25 is provided on the insulating layer 28.
  • the electrode layer 25 and the insulating layer 28 are provided with an opening 20 that reaches the semiconductor layer 32 of the electrode layer 24 . For example, it can be said that the side walls (side surfaces) of the semiconductor layer 34, the conductive layer 33, and the insulating layer 28 located within the opening 20 overlap with the semiconductor layer 32.
  • the shape of the opening 20 in plan view can typically be circular.
  • the shape of the opening 20 is not limited to a circle, and can be made into various shapes.
  • it can be oval, rectangular with rounded corners, etc.
  • it may be a regular polygon including a regular triangle, a square, a regular pentagon, or a polygon other than a regular polygon.
  • a concave polygon such as a star-shaped polygon, is a polygon in which at least one interior angle exceeds 180 degrees, the channel width can be increased.
  • it can be an ellipse, a polygon with rounded corners, a closed curve that is a combination of a straight line and a curved line, etc.
  • the semiconductor layer 21 has a top surface of the semiconductor layer 34, a side surface of the insulating layer 28 located in the opening 20, a side surface of the conductive layer 33, a side surface of the semiconductor layer 34, and a top surface of the semiconductor layer 32 located at the bottom of the opening 20. come into contact with A portion of the semiconductor layer 21 that is in contact with the insulating layer 28 functions as a region where a channel is formed (channel formation region).
  • the same impurity element as the semiconductor layer 32 may be contained in the portion of the semiconductor layer 21 that is in contact with the semiconductor layer 32 and in the vicinity thereof.
  • the same impurity element as the semiconductor layer 34 may be contained in the portion of the semiconductor layer 21 that is in contact with the semiconductor layer 34 and in the vicinity thereof. This is preferable because the contact resistance between the semiconductor layer 32 or 34 and the semiconductor layer 21 is reduced.
  • hydrogen is released from the insulating layer 28 when heated.
  • hydrogen is supplied from the insulating layer 28 to the channel formation region of the semiconductor layer 21 due to heat during the process, and the dangling bonds in the semiconductor layer 21 can be terminated by the hydrogen, thereby improving the reliability of the transistor 10. can be improved.
  • an insulating material such as silicon oxide, silicon oxynitride, silicon nitride oxide, or silicon nitride can be used.
  • an optimal material can be used depending on the material used for the semiconductor layer 21 and its crystallinity. For example, when amorphous silicon is used for the semiconductor layer 21, it is preferable to use silicon nitride oxide or silicon nitride containing hydrogen as the insulating layer 28. Further, when polycrystalline silicon is used for the semiconductor layer 21, it is preferable to use silicon oxide or silicon oxynitride containing hydrogen.
  • the insulating layer 28 can be formed by a film forming method such as a sputtering method or a plasma CVD method.
  • a film forming method such as a sputtering method or a plasma CVD method.
  • a plasma CVD method using a gas containing hydrogen or a hydrogen compound as a film forming gas
  • a film containing a large amount of hydrogen can be obtained. Therefore, a large amount of hydrogen can be supplied to the semiconductor layer 21 due to heat during the process, and the electrical characteristics of the transistor 10 can be stabilized.
  • materials that can be used for the insulating layer 28 are not limited to those mentioned above, and various insulating materials such as oxides, oxynitrides, nitrided oxides, and nitrides containing metal elements such as aluminum, hafnium, and yttrium can be used. Can be used.
  • oxynitride refers to a material containing more oxygen than nitrogen.
  • Oxide nitride refers to a material that contains more nitrogen than oxygen.
  • An insulating layer 22 is provided to cover the insulating layer 28, the electrode layer 25, and the semiconductor layer 21. Further, a conductive layer 23 is provided on the insulating layer 22. A portion of the insulating layer 22 and a portion of the conductive layer 23 have portions provided inside the opening 20.
  • Various conductive materials can be used for the conductive layer 23, the conductive layer 31, and the conductive layer 33.
  • the conductive layer 23, the conductive layer 31, and the conductive layer 33 may be a single layer or may have a laminated structure.
  • a part of the insulating layer 22 functions as a gate insulating layer.
  • silicon oxide, silicon oxynitride, aluminum oxide, aluminum oxynitride, hafnium oxide, hafnium oxynitride, gallium oxide, gallium oxynitride, yttrium oxide, and yttrium oxynitride can be used.
  • a nitride insulating film such as silicon nitride, silicon nitride oxide, aluminum nitride, aluminum nitride oxide, etc. can also be used.
  • the insulating layer 22 may have a laminated structure, for example, a laminated structure including one or more oxide insulating films and one or more nitride insulating films.
  • the semiconductor layer 21 has a portion that is in contact with the side surface of the insulating layer 28 and functions as a channel formation region.
  • the insulating layer 22 has a portion that faces the side surface of the insulating layer 28 with the semiconductor layer 21 interposed therebetween.
  • the conductive layer 23 has a portion that faces the side surface of the insulating layer 28 with the semiconductor layer 21 and the insulating layer 22 interposed therebetween.
  • the interface between the semiconductor layer 21 and the insulating layer 22 and the interface between the insulating layer 22 and the conductive layer 23 each have a portion that is parallel to the side surface of the insulating layer 28.
  • an insulating layer functioning as a planarization layer, an interlayer insulating layer, or a protective layer may be provided to cover the insulating layer 22 and the conductive layer 23.
  • a conductive layer that functions as a wiring that electrically connects to the electrode layer 24, the electrode layer 25, the conductive layer 23, or the like may be provided on the insulating layer.
  • a pixel electrode that constitutes a part of the display element may be provided on the insulating layer.
  • a pixel electrode, an organic layer, a common electrode, etc. that constitute a light emitting element may be provided on the insulating layer.
  • FIG. 2 shows a modification of FIG. 1A.
  • the transistor 10 shown in FIG. 2 differs from the structure shown in FIG. 1A mainly in that the semiconductor layer 32 has a region 32i and a region 32d.
  • the region 32i is a region of the semiconductor layer 32 that is covered with the insulating layer 28. Further, the region 32d is a portion of the semiconductor layer 32 located at the bottom of the opening 20, and is a region not covered by the insulating layer 28.
  • the region 32d is a region to which an impurity element is added
  • the region 32i is a region to which no impurity element is added. Therefore, the region 32d in contact with the semiconductor layer 21 has a higher concentration of impurity elements than the region 32i in contact with the insulating layer 28.
  • EDX energy dispersive X-ray spectroscopy
  • EELS electron energy loss spectroscopy
  • the impurity element is selectively added to the region 32d located at the bottom of the opening 20 of the semiconductor layer 32 by performing an impurity element addition process (also referred to as doping process) after the opening 20 is formed. It can be produced by Details of this step will be explained later in the example of the manufacturing method.
  • one contains an impurity element that imparts n-type conductivity
  • the other contains an impurity element that imparts p-type conductivity.
  • a p-i-n type photodiode can also be manufactured by using a structure containing an element.
  • An inverter circuit is one of the simplest CMOS circuits that uses an n-channel transistor and a p-channel transistor.
  • An example of an inverter circuit is shown in FIG. 3A.
  • the drain of the n-channel transistor 10n and the drain of the p-channel transistor 10p are connected to the output terminal OUT. Further, each gate is connected to an input terminal IN.
  • the potential VSS is applied to the source of the transistor 10n, and the potential VDD is applied to the source of the transistor 10p.
  • Potential VDD is higher than potential VSS.
  • the transistor 10n becomes conductive and the potential VSS is outputted to the output terminal OUT.
  • the transistor 10p becomes conductive and the potential VDD is outputted to the output terminal OUT.
  • FIG. 3B shows a schematic cross-sectional view of the transistor 10n and the transistor 10p.
  • the configuration shown in FIG. 3B shows an example in which the conductive layer 33 and the conductive layer 23 are common to the transistor 10n and the transistor 10p.
  • the transistor 10n includes a conductive layer 31a, a semiconductor layer 32a, a semiconductor layer 21a, a conductive layer 33, a semiconductor layer 34a, an insulating layer 22, and a conductive layer 23.
  • the transistor 10p also includes a conductive layer 31b, a semiconductor layer 32b, a semiconductor layer 21b, a conductive layer 33, a semiconductor layer 34b, an insulating layer 22, and a conductive layer 23.
  • the semiconductor layer 32a included in the transistor 10n has a region 32i and a region 32n.
  • the region 32n and the semiconductor layer 34a contain an impurity element that imparts n-type conductivity, such as phosphorus or arsenic.
  • the semiconductor layer 32b included in the transistor 10p has a region 32i and a region 32p.
  • the region 32p and the semiconductor layer 34b contain an impurity element that imparts p-type conductivity, such as boron or aluminum.
  • the conductive layer 33 is shared between the transistor 10n and the transistor 10p.
  • a semiconductor layer 34a and a semiconductor layer 34b are provided on the conductive layer 33. Although the semiconductor layer 34a and the semiconductor layer 34b are separated on the conductive layer 33 and contain different impurities, they are preferably formed by processing the same film.
  • FIG. 3B shows an example in which the ends of the semiconductor layer 34a and the semiconductor layer 34b are located inside the end of the conductive layer 33.
  • different photomasks may be used for processing the semiconductor layers 34a and 34b and the processing for the conductive layer 33, or processing may be performed using a multi-tone mask such as a halftone mask or a graytone mask. It's okay.
  • FIG. 3C shows an example in which the semiconductor layer 34 is shared by the transistor 10n and the transistor 10p.
  • the semiconductor layer 34 has a region 34n, a region 34p, and a region 34x.
  • the region 34x is a portion located between the transistor 10n and the transistor 10p.
  • the region 34x may be doped with the same impurity element as the region 34n, the same impurity element as the region 34p, both, or both. It doesn't have to be done. That is, the region 34x may have n-type conductivity, p-type conductivity, or may have neither conductivity and may be i-type conductivity. .
  • FIG. 3C shows an example in which the conductive layer 33 and the semiconductor layer 34 have substantially the same upper surface shape. That is, the end of the conductive layer 33 and the end of the semiconductor layer 34 approximately coincide. With such a configuration, some steps can be omitted compared to the example shown in FIG. 3B, so the manufacturing process can be simplified.
  • the semiconductor layer 32a and the semiconductor layer 32b each have a region 32n and a region 32p at the bottom of the opening in the insulating layer 28, but as shown in FIGS. 4A and 4B, Alternatively, an impurity element may also be added to the portion overlapping with the insulating layer 28. That is, the entire semiconductor layer 32a may be an n-type impurity semiconductor, and the entire semiconductor layer 32b may be a p-type impurity semiconductor.
  • FIG. 5A shows an example in which the conductive layer 31 and the conductive layer 23 are common to the transistor 10n and the transistor 10p.
  • FIG. 5A shows an example in which the conductive layer 31 is provided in common between the transistor 10n and the transistor 10p, and the semiconductor layer 32 stacked on the conductive layer 31 is provided individually.
  • the semiconductor layer 32a included in the transistor 10n has a region 32i and a region 32n.
  • the semiconductor layer 32b included in the transistor 10p includes a region 32i and a region 32p.
  • the transistor 10n includes a conductive layer 33a and a semiconductor layer 34a on the insulating layer 28.
  • the transistor 10p includes a conductive layer 33b and a semiconductor layer 34b on the insulating layer 28.
  • the conductive layer 33a and the conductive layer 33b, and the semiconductor layer 34a and the semiconductor layer 34b are provided apart from each other.
  • FIG. 5B shows an example in which the semiconductor layer 32 is shared by the transistor 10n and the transistor 10p.
  • the semiconductor layer 32 has a region 32n, a region 32p, and a region 32x.
  • the region 32x like the region 34x, may be doped with the same impurity element as the region 32n, the same impurity element as the region 32p, or both. or both may not be added. That is, the region 32x may have n-type conductivity, p-type conductivity, or may have neither conductivity and may be i-type conductivity. .
  • the semiconductor layer 32 and the conductive layer 31 have substantially the same top surface shape. Furthermore, it is preferable that the semiconductor layer 34a and the conductive layer 33a, and the semiconductor layer 34b and the conductive layer 33b, have substantially the same upper surface shape as described above.
  • the transistor 10n and the transistor 10p can also be used individually.
  • pin type photodiodes can also be separately manufactured on the same substrate. That is, by configuring one of the semiconductor layers 34 and 32 to contain an impurity element that imparts n-type conductivity, and the other to contain an impurity element that imparts p-type conductivity, the p-i - An n-type photodiode can also be manufactured.
  • thin films (insulating films, semiconductor films, conductive films, etc.) constituting a semiconductor device can be formed using a sputtering method, a chemical vapor deposition (CVD) method, a vacuum evaporation method, or a pulsed laser deposition (PLD) method. ) method, atomic layer deposition (ALD) method, or the like.
  • CVD method include a plasma enhanced CVD (PECVD) method, a thermal CVD method, and the like.
  • PECVD plasma enhanced CVD
  • thermal CVD methods is a metal organic chemical vapor deposition (MOCVD) method.
  • thin films that make up semiconductor devices can be manufactured using spin coating, dip coating, spray coating, inkjet, dispensing, screen printing, offset printing, doctor knife coating, slit coating, roll coating, and curtain coating. It can be formed by a method such as , knife coating or the like.
  • the thin film that constitutes the semiconductor device it is possible to process it using a photolithography method or the like.
  • the thin film may be processed by a nanoimprint method, a sandblasting method, a lift-off method, or the like.
  • an island-shaped thin film may be directly formed by a film forming method using a shielding mask such as a metal mask.
  • One method is to form a resist mask on a thin film to be processed, process the thin film by etching or the like, and then remove the resist mask.
  • the other method is to form a photosensitive thin film and then process the thin film into a desired shape by exposing and developing the film.
  • the light used for exposure can be, for example, i-line (wavelength: 365 nm), g-line (wavelength: 436 nm), h-line (wavelength: 405 nm), or a mixture of these.
  • ultraviolet rays, KrF laser light, ArF laser light, etc. can also be used.
  • exposure may be performed using immersion exposure technology.
  • extreme ultraviolet (EUV) light or X-rays may be used.
  • an electron beam can also be used. It is preferable to use extreme ultraviolet light, X-rays, or electron beams because extremely fine processing becomes possible. Note that when exposure is performed by scanning a beam such as an electron beam, a photomask is not necessary.
  • a dry etching method, wet etching method, sandblasting method, etc. can be used for etching the thin film.
  • 6A to 6F are schematic cross-sectional views corresponding to each step in the method for manufacturing a semiconductor device described below.
  • an example will be shown in which an amorphous silicon film or a microcrystalline silicon film is used as the semiconductor film used for the semiconductor layer.
  • the substrate 11 is prepared.
  • a substrate having at least enough heat resistance to withstand subsequent heat treatment can be used.
  • a substrate having at least enough heat resistance to withstand subsequent heat treatment.
  • a substrate a substrate having at least enough heat resistance to withstand subsequent heat treatment.
  • a semiconductor substrate such as a single crystal semiconductor substrate made of silicon or silicon carbide, a polycrystalline semiconductor substrate, a compound semiconductor substrate such as silicon germanium or gallium nitride, or an SOI substrate can be used.
  • a conductive film that will become the conductive layer 31 is formed on the insulating plane of the substrate 11.
  • the conductive film can be formed by, for example, a sputtering method.
  • the film forming gas includes a deposition gas such as SiH 4 or Si 2 H 6 , and a gas containing an impurity that imparts n-type conductivity (e.g. PH 3 ) or a gas containing an impurity that imparts p-type conductivity (e.g. PH 3 ) or a gas containing an impurity that imparts p-type conductivity ( For example, by using a mixed gas containing B 2 H 6 ), an impurity element is added, and a semiconductor film exhibiting n-type or p-type conductivity can be formed.
  • a deposition gas such as SiH 4 or Si 2 H 6
  • a gas containing an impurity that imparts n-type conductivity e.g. PH 3
  • a gas containing an impurity that imparts p-type conductivity e.g. PH 3
  • a mixed gas containing B 2 H 6 an impurity element is added, and a semiconductor film exhibiting n-type or
  • a deposition gas such as GeH 4 or Ge 2 H 6 gas may be used as the film forming gas.
  • the crystallinity of a semiconductor film can be controlled by conditions such as pressure, gas flow rate, substrate temperature, and power during film formation.
  • a highly crystalline microcrystalline silicon film containing crystal grains with a grain size of 1 nm or more and 100 nm or less is formed by increasing the substrate temperature during film formation (e.g., 100°C or more and 300°C or less). be able to.
  • a resist mask is formed on the semiconductor film, and unnecessary portions of the semiconductor film and the conductive film are removed by etching, thereby forming a conductive layer 31 and a semiconductor layer 32 on the substrate 11 (FIG. 6A). .
  • an insulating layer 28 is formed to cover the conductive layer 31 and the semiconductor layer 32 (FIG. 6B).
  • the insulating layer 28 is preferably formed using a plasma CVD method.
  • a plasma CVD method by forming a film by a plasma CVD method using a gas containing hydrogen or a hydrogen compound as a film forming gas, a film containing a large amount of hydrogen can be obtained.
  • a conductive film that will become the conductive layer 33 and a semiconductor film that will become the semiconductor layer 34 are formed on the insulating layer 28. Thereafter, a portion of the conductive film and semiconductor film is removed by etching, thereby forming a conductive layer 33 and a semiconductor layer 34 (FIG. 6C).
  • the semiconductor film that will become the semiconductor layer 34 can be formed by the same method as the semiconductor film that will become the semiconductor layer 32 described above.
  • an opening 20 reaching the semiconductor layer 32 is formed in the semiconductor layer 34, the conductive layer 33, and the insulating layer 28 (FIG. 6D).
  • the etching time is insufficient and a defect occurs such as the opening 20 not reaching the top surface of the semiconductor layer 32, the operation as a transistor will not be obtained. must be done reliably.
  • the insulating layer 28 may be formed thicker than the semiconductor layer 32, etc., it is desirable to perform sufficient over-etching in consideration of variations, but the semiconductor layer 32 may disappear. There is a fear. If the semiconductor layer 32 located at the bottom of the opening 20 disappears by etching, normal transistor characteristics cannot be obtained.
  • the etching of the insulating layer 28 should be performed under conditions where the semiconductor layer 32 is difficult to be etched. is preferred.
  • the insulating layer 28 may be a laminated film formed by stacking a plurality of insulating films, and the insulating film located at the lowest position (i.e., the insulating film in contact with the semiconductor layer 32) may be an insulating film that functions as an etching stopper.
  • the semiconductor film that becomes the semiconductor layer 21 can be formed by the same method as the above semiconductor film.
  • the semiconductor film has i-type conductivity, no impurity element is necessary, and there is no need to introduce a gas containing an impurity element into the film forming gas.
  • the insulating layer 22 is formed to cover the semiconductor layer 21, the conductive layer 33, the semiconductor layer 34, the insulating layer 28, etc.
  • the insulating layer 22 can be formed, for example, by a plasma CVD method, a sputtering method, or the like. In particular, it is preferable to use the plasma CVD method because it is possible to form an insulating layer with a relatively uniform thickness even inside the opening 20.
  • a conductive film is formed on the insulating layer 22, and unnecessary portions are removed by etching to form a conductive layer 23 (FIG. 6F).
  • the conductive layer 23 can be formed by the same method as the conductive layer 31 and the like.
  • the transistor 10 illustrated in Configuration Example 1 can be manufactured.
  • FIGS. 7A to 9C are schematic cross-sectional views of each step in the method for manufacturing a semiconductor device described below.
  • a conductive film 31f and a semiconductor film 32f are sequentially formed on the substrate 11 (FIG. 7A).
  • the conductive film 31f is a conductive film that later becomes the conductive layer 31a and the conductive layer 31b.
  • a high melting point material that has heat resistance against subsequent heat treatment and the like.
  • metals such as tungsten, molybdenum, titanium, tantalum, and chromium, or alloys containing one or more of these can be used for the conductive film 31f.
  • An amorphous silicon film can be used as the semiconductor film 32f.
  • the amorphous silicon film can be formed by a sputtering method, a plasma CVD method, or the like, but it is particularly preferable to form a film by a plasma CVD method because a dense film can be formed.
  • the semiconductor film 32f is crystallized to form a semiconductor film 32c containing polycrystalline silicon (FIG. 7B).
  • the semiconductor film 32f can be crystallized using a laser crystallization method using a laser beam, RTA (Rapid Thermal Annealing), a thermal crystallization method using a heat treatment apparatus such as a furnace annealing furnace, or a metal element that promotes crystallization.
  • Thermal crystallization method used, etc. can be mentioned.
  • two or more of the above crystallization methods may be combined. For example, after using a thermal crystallization method using a metal element that promotes crystallization, the crystallinity may be further improved by a laser crystallization method.
  • a solution containing nickel, which is a metal element that promotes crystallization is applied to the semiconductor film 32f, and then hydrogen contained in the semiconductor film 32f is desorbed.
  • a method of successively performing a heat treatment for crystallization (dehydrogenation treatment) and a heat treatment for crystallization is mentioned.
  • the dehydrogenation treatment can be carried out, for example, at 500° C. for 1 hour, and the subsequent heat treatment for crystallization can be carried out at a higher temperature of 550° C. for 4 hours. Thereafter, crystallinity can be improved by irradiating laser light as needed.
  • a continuous oscillation or pulse oscillation gas laser or solid state laser can be used as the laser light.
  • gas lasers include YAG laser, YVO4 laser, YLF laser, YAlO3 laser, glass laser, ruby laser, Ti:sapphire laser, and the like.
  • solid-state lasers include lasers using crystals such as YAG, YVO 4 , TLF, and YAlO 3 doped with Cr, Nd, Er, Ho, Ce, Co, Ti, or Tm.
  • an amorphous silicon film is crystallized using a metal element that promotes crystallization, crystallization can be performed at low temperatures in a short time, and while it has the advantage of aligning the crystal directions, the metal element It has the disadvantage that it remains in the polycrystalline silicon film after chemical conversion. Therefore, in order to remove the metal elements in the polycrystalline silicon film, it is preferable to form an amorphous silicon film that functions as a gettering film on the polycrystalline silicon film and perform heat treatment. At this time, it is preferable to use a relatively low-density amorphous silicon film formed by sputtering rather than a dense film formed by plasma CVD because the gettering effect can be enhanced. The concentration of the metal element in the polycrystalline semiconductor film can be reduced by diffusing the metal element into the amorphous silicon film by heat treatment and then removing the amorphous silicon film by etching.
  • the semiconductor film 32c is not a semiconductor film used for a semiconductor layer in which a channel is formed, so there may be no problem even if the semiconductor film 32c contains a metal element. Therefore, for the semiconductor film 32c, the step of removing the metal element described above does not necessarily need to be performed.
  • an insulating layer 28, a conductive film 33f, and a semiconductor film 34c are formed in this order (FIG. 7D).
  • the conductive film 33f is a conductive film that will become the conductive layer 33 later.
  • As the conductive film 33f it is preferable to use a conductive film with high heat resistance, similarly to the conductive film 31f.
  • the semiconductor film 34c is a semiconductor film containing polycrystalline silicon.
  • the semiconductor film 34c can be formed by crystallizing an amorphous silicon film using the same crystallization process as the semiconductor film 32c.
  • an opening 20a reaching the semiconductor layer 32a and an opening 20b reaching the semiconductor layer 32b are formed in the semiconductor film 34c, the conductive film 33f, and the insulating layer 28 (FIG. 7E).
  • the above-mentioned manufacturing method example 1 can be referred to.
  • a resist mask 42n is formed to cover the opening 20b and a portion of the semiconductor film 34c, but not to cover the opening 20a and its surroundings.
  • an impurity element 41n that imparts n-type conductivity is added (FIG. 8A).
  • the impurity element 41n is added to the semiconductor film 34c located in a region not covered by the resist mask 42n and to the portion located at the bottom of the opening 20a of the semiconductor layer 32a. Thereby, a region 34n in the semiconductor film 34c and a region 32n in the semiconductor layer 32a can be formed.
  • the resist mask 42n is removed.
  • a resist mask 42p is formed to cover the opening 20a and a portion of the semiconductor film 34c, but not to cover the opening 20b and its surroundings.
  • an impurity element 41p that imparts p-type conductivity is added (FIG. 8B).
  • a region 34p in the semiconductor film 34c and a region 32p in the semiconductor layer 32b can be formed.
  • the resist mask 42p is removed.
  • the addition treatment of the impurity element 41n and the impurity element 41p for example, an ion doping method, an ion implantation method, etc. can be used.
  • an ion doping method for example, an ion doping method, an ion implantation method, etc.
  • the process is not limited to this, and the impurity element 41p may be added first.
  • heat treatment may be performed to activate the impurity element. Further, the heat treatment may alleviate damage caused to the semiconductor film 34c, the semiconductor layer 32a, and the semiconductor layer 32b by the addition treatment, and may restore crystallinity.
  • the heat treatment can be performed, for example, at 550° C. for 4 hours.
  • a region 34x is formed in the semiconductor layer 34 between the region 34n and the region 34p.
  • the region 34x is a region covered with both the resist mask 42n and the resist mask 42p, so here, the region 34x is a region to which no impurity element is added.
  • a semiconductor film 21p containing polycrystalline silicon is formed to cover the semiconductor layer 34, the insulating layer 28, the openings 20a, and the openings 20b (FIG. 9A).
  • the semiconductor film 21p can be formed by crystallizing an amorphous silicon film using the same crystallization process as the semiconductor film 32c. Further, since a part of the semiconductor film 21p is used as a semiconductor layer in which a channel is formed, if a metal element that promotes crystallization is used in the crystallization process, a process of removing the metal element may not be performed. preferable.
  • FIG. 9B shows an example in which a portion of the semiconductor layer 34 that is not covered by the semiconductor layer 21a or the semiconductor layer 21b is removed by etching.
  • an impurity element addition process may be performed in order to adjust the threshold voltage of the transistor.
  • an impurity element imparting p-type conductivity or an impurity element imparting n-type conductivity is added.
  • the insulating layer 22 is formed to cover the semiconductor layer 21a, the semiconductor layer 21b, the conductive layer 33, the insulating layer 28, etc. After that, a conductive layer 23 is formed on the insulating layer 22 (FIG. 9C).
  • the transistor 10n and the transistor 10p to which polycrystalline semiconductors are applied can be separately manufactured.
  • This embodiment can be implemented by appropriately combining at least a part of it with other embodiments described in this specification.
  • the display device of this embodiment can be a high-resolution display device or a large-sized display device. Therefore, the display device of this embodiment can be used, for example, on relatively large screens such as television devices, desktop or notebook personal computers, computer monitors, digital signage, and large game machines such as pachinko machines.
  • the present invention can be used in display units of digital cameras, digital video cameras, digital photo frames, mobile phones, portable game machines, personal digital assistants, and sound reproduction devices.
  • the display device of this embodiment can be a high-definition display device. Therefore, the display device of this embodiment can be used, for example, in a display unit of an information terminal (wearable device) such as a wristwatch type or a bracelet type, as well as a device for VR such as a head mounted display (HMD), and glasses. It can be used in the display section of wearable devices that can be worn on the head, such as AR devices.
  • an information terminal such as a wristwatch type or a bracelet type
  • VR head mounted display (HMD)
  • AR devices head mounted display
  • a semiconductor device of one embodiment of the present invention can be used for a display device or a module including the display device.
  • the module having the display device include a module in which a connector such as a flexible printed circuit board (hereinafter referred to as FPC) or TCP (Tape Carrier Package) is attached to the display device, and a COG (Chip On Glass) module.
  • FPC flexible printed circuit board
  • TCP Transmission Carrier Package
  • COG Chip On Glass
  • Examples include a module in which an integrated circuit (IC) is mounted using a COF (Chip On Film) method or the like.
  • FIG. 10 shows a perspective view of the display device 50A.
  • the display device 50A has a configuration in which a substrate 152 and a substrate 151 are bonded together.
  • the substrate 152 is indicated by a broken line.
  • the display device 50A includes a display section 162, a connection section 140, a circuit section 164, wiring 165, and the like.
  • FIG. 10 shows an example in which an IC 173 and an FPC 172 are mounted on the display device 50A. Therefore, the configuration shown in FIG. 10 can also be called a display module that includes the display device 50A, an IC, and an FPC.
  • the connecting section 140 is provided outside the display section 162.
  • the connecting portion 140 can be provided along one side or a plurality of sides of the display portion 162.
  • the connecting portion 140 may be singular or plural.
  • FIG. 10 shows an example in which connection parts 140 are provided so as to surround the four sides of the display part.
  • the connection part 140 the common electrode of the display element and the conductive layer are electrically connected, and a potential can be supplied to the common electrode.
  • the circuit section 164 includes, for example, a scanning line drive circuit (also referred to as a gate driver). Furthermore, the circuit section 164 may include both a scanning line drive circuit and a signal line drive circuit (also referred to as a source driver).
  • a scanning line drive circuit also referred to as a gate driver
  • a signal line drive circuit also referred to as a source driver
  • the wiring 165 has a function of supplying signals and power to the display section 162 and the circuit section 164.
  • the signal and power are input to the wiring 165 from the outside via the FPC 172 or input to the wiring 165 from the IC 173.
  • FIG. 10 shows an example in which the IC 173 is provided on the substrate 151 using a COG method, a COF method, or the like.
  • a COG method a COG method
  • COF method a COF method
  • an IC having one or both of a scanning line drive circuit and a signal line drive circuit can be applied to the IC 173.
  • the display device 50A and the display module may have a configuration in which no IC is provided.
  • the IC may be mounted on the FPC using a COF method or the like.
  • the semiconductor device of one embodiment of the present invention can be applied to, for example, one or both of the display portion 162 and the circuit portion 164 of the display device 50A. Further, the semiconductor device of one embodiment of the present invention can also be applied to the IC 173.
  • the semiconductor device of one embodiment of the present invention when the semiconductor device of one embodiment of the present invention is applied to a pixel circuit of a display device, the area occupied by the pixel circuit can be reduced, and a high-definition display device can be obtained.
  • the semiconductor device of one embodiment of the present invention when the semiconductor device of one embodiment of the present invention is applied to a driver circuit of a display device (for example, one or both of a gate line driver circuit and a source line driver circuit), the area occupied by the driver circuit can be reduced. Therefore, a display device with a narrow frame can be obtained. Further, since the semiconductor device of one embodiment of the present invention has good electrical characteristics, the reliability of the display device can be increased by using it for a display device.
  • the display section 162 is an area for displaying images in the display device 50A, and has a plurality of periodically arranged pixels 210.
  • FIG. 10 shows an enlarged view of one pixel 210.
  • the arrangement of pixels in the display device of this embodiment is not particularly limited, and various methods can be applied.
  • Examples of pixel arrays include stripe array, S-stripe array, matrix array, delta array, Bayer array, and pentile array.
  • the pixel 210 shown in FIG. 10 has a subpixel 210R that emits red light, a subpixel 210G that emits green light, and a subpixel 210B that emits blue light.
  • Various elements can be used as the display element, such as liquid crystal elements and light emitting elements.
  • a display element using a shutter method or optical interference method MEMS (Micro Electro Mechanical Systems) element, a microcapsule method, an electrophoresis method, an electrowetting method, an electronic powder fluid (registered trademark) method, etc. may be used. You can also do it.
  • a QLED (Quantum-dot LED) using a light source and a color conversion technology using a quantum dot material may be used.
  • liquid crystal element examples include a transmissive liquid crystal element, a reflective liquid crystal element, and a transflective liquid crystal element.
  • the light-emitting element examples include self-emitting light-emitting elements such as an LED (Light Emitting Diode), an OLED (Organic LED), and a semiconductor laser.
  • LED Light Emitting Diode
  • OLED Organic LED
  • semiconductor laser a semiconductor laser
  • the LED for example, a mini LED, a micro LED, etc. can be used.
  • Examples of the light-emitting substance included in the light-emitting element include a substance that emits fluorescence (fluorescent material), a substance that emits phosphorescence (phosphorescent material), and a substance that exhibits thermally activated delayed fluorescence (thermally activated delayed fluorescence (TADF). ) materials), and inorganic compounds (quantum dot materials, etc.).
  • the emitted light color of the light emitting element can be infrared, red, green, blue, cyan, magenta, yellow, white, or the like. Furthermore, color purity can be increased by providing a microcavity structure to the light emitting element.
  • the display device of one embodiment of the present invention is a top-emission type that emits light in the opposite direction to the substrate on which the light-emitting element is formed, and a top-emission type that emits light in the opposite direction to the substrate on which the light-emitting element is formed. It may be either a bottom emission type that emits light on both sides (a bottom emission type) or a double emission type that emits light on both sides (dual emission type).
  • FIG. 11 shows part of the area including the FPC 172, part of the circuit part 164, part of the display part 162, part of the connection part 140, and part of the area including the end of the display device 50A.
  • An example of a cross section when cut is shown.
  • a display device 50A shown in FIG. 11 includes transistors 205D1, 205D2, 205R, 205G, 205B, a light emitting element 130R, a light emitting element 130G, a light emitting element 130B, etc. between a substrate 151 and a substrate 152.
  • the light emitting element 130R is a display element included in the subpixel 210R that emits red light
  • the light emitting element 130G is a display element included in the subpixel 210G that emits green light
  • the light emitting element 130B is a display element that emits blue light. This is a display element included in the subpixel 210B.
  • the SBS structure is applied to the display device 50A.
  • materials and configurations can be optimized for each light emitting element, which increases the degree of freedom in selecting materials and configurations, making it easier to improve brightness and reliability.
  • the display device 50A is a top emission type.
  • a transistor or the like can be placed overlapping the light-emitting region of the light-emitting element, so the aperture ratio of the pixel can be increased compared to the bottom-emission type.
  • the transistors 205D1, 205D2, 205R, 205G, and 205B are all formed on the substrate 151. These transistors can be manufactured through the same process.
  • the transistors of one embodiment of the present invention in which silicon is used as a semiconductor are used as the transistors 205D1, 205D2, 205R, 205G, and 205B.
  • the transistors 205R, 205G, and 205B function as drive transistors to control the current flowing to the light emitting element.
  • either an n-type transistor or a p-type transistor can be used. In particular, it is preferable to use a p-type transistor.
  • transistors 205D1 and 205D2 provided in the circuit section 164 are transistors that constitute part of the drive circuit.
  • a CMOS circuit is configured by transistors 205D1 and 205D2.
  • transistors 205D1 and 205D2 are transistors that constitute part of the drive circuit.
  • the transistor 205D1, the transistors 205D2, 205R, 205G, and 205B each include a conductive layer 104 that functions as a gate, an insulating layer 106 that functions as a gate insulating layer, and a conductive layer 112a that functions as a source electrode or a drain electrode, respectively. and a conductive layer 112b, a semiconductor layer 108, a semiconductor layer 107 and a semiconductor layer 109 each functioning as a source region or a drain region, and an insulating layer 110.
  • a plurality of layers obtained by processing the same film are given the same hatching pattern.
  • the display device 50A includes the transistor of one embodiment of the present invention in both the display portion 162 and the circuit portion 164.
  • the transistor of one embodiment of the present invention in the display portion 162
  • the pixel size can be reduced and high definition can be achieved.
  • the transistor of one embodiment of the present invention for the circuit portion 164 the area occupied by the circuit portion 164 can be reduced, and the frame can be made narrower.
  • the description in the previous embodiment can be referred to.
  • the transistor included in the display device of this embodiment is not limited to the transistor of one embodiment of the present invention.
  • a transistor according to one embodiment of the present invention and a transistor having another structure may be included in combination.
  • the display device of this embodiment may include, for example, one or more of a planar transistor, a staggered transistor, and an inverted staggered transistor.
  • the transistor included in the display device of this embodiment may be either a top gate type or a bottom gate type.
  • gates may be provided above and below the semiconductor layer in which the channel is formed.
  • the display device of this embodiment includes a transistor (Si transistor) using silicon for a channel formation region.
  • silicon include single crystal silicon, polycrystalline silicon, amorphous silicon, and the like.
  • a transistor having LTPS in a semiconductor layer (hereinafter also referred to as an LTPS transistor) can be used.
  • LTPS transistors have high field effect mobility and good frequency characteristics.
  • a transistor having amorphous silicon in its semiconductor layer can be uniformly formed over a large glass substrate, and therefore has excellent productivity.
  • the display device of this embodiment includes a transistor (OS transistor) in which an oxide semiconductor (OS: Oxide Semiconductor), typified by In-Ga-Zn oxide (also referred to as IGZO), is used in a channel formation region.
  • OS Oxide Semiconductor
  • IGZO In-Ga-Zn oxide
  • a display device may include a transistor whose channel is formed using silicon as a semiconductor and a transistor whose channel is formed using an oxide semiconductor.
  • the transistor included in the circuit portion 164 and the transistor included in the display portion 162 may have the same structure or may have different structures.
  • the plurality of transistors included in the circuit section 164 may all have the same structure, or may have two or more types.
  • the plurality of transistors included in the display section 162 may all have the same structure, or may have two or more types.
  • All the transistors included in the display section 162 may be Si transistors, all the transistors included in the display section 162 may be OS transistors, or some of the transistors included in the display section 162 may be OS transistors and the rest may be Si transistors. good.
  • an LTPS transistor for example, by using both an LTPS transistor and an OS transistor in the display section 162, a display device with low power consumption and high driving ability can be realized. Further, a configuration in which an LTPS transistor and an OS transistor are combined is sometimes referred to as an LTPO. Note that a more preferable example is a configuration in which an OS transistor is used as a transistor that functions as a switch for controlling conduction and non-conduction between wirings, and an LTPS transistor is used as a transistor that controls current. .
  • one of the transistors included in the display section 162 functions as a transistor for controlling the current flowing to the light emitting element, and can also be called a drive transistor.
  • One of the source and drain of the drive transistor is electrically connected to the pixel electrode of the light emitting element. It is preferable to use an LTPS transistor as the drive transistor. Thereby, the current flowing through the light emitting element in the pixel circuit can be increased.
  • the other transistor included in the display section 162 functions as a switch for controlling selection and non-selection of pixels, and can also be called a selection transistor.
  • the gate of the selection transistor is electrically connected to the gate line, and one of the source and drain is electrically connected to the source line (signal line). It is preferable to use an OS transistor as the selection transistor. This allows the pixel gradation to be maintained even if the frame frequency is significantly reduced (for example, 1 fps or less), so power consumption can be reduced by stopping the driver when displaying still images. can.
  • An insulating layer 218 is provided to cover the transistors 205D1, 205D2, 205R, 205G, and 205B, and an insulating layer 235 is provided on the insulating layer 218.
  • the insulating layer 218 preferably functions as a protective layer for the transistor.
  • the insulating layer 218 preferably has one or more inorganic insulating films.
  • the inorganic insulating film include an oxide insulating film, a nitride insulating film, an oxynitride insulating film, and a nitride oxide insulating film. Specific examples of these inorganic insulating films are as described above.
  • the insulating layer 235 preferably has a function as a planarization layer, and is preferably an organic insulating film.
  • examples of materials that can be used for the organic insulating film include acrylic resin, polyimide resin, epoxy resin, polyamide resin, polyimide amide resin, siloxane resin, benzocyclobutene resin, phenol resin, and precursors of these resins.
  • the insulating layer 235 may have a stacked structure of an organic insulating film and an inorganic insulating film. The outermost layer of the insulating layer 235 preferably functions as an etching protection layer.
  • a recess in the insulating layer 235 can be suppressed during processing of the pixel electrodes 111R, 111G, 111B, etc.
  • a recess may be provided in the insulating layer 235 when processing the pixel electrodes 111R, 111G, 111B, etc.
  • Light emitting elements 130R, 130G, and 130B are provided on the insulating layer 235.
  • the light emitting element 130R includes a pixel electrode 111R on the insulating layer 235, an EL layer 113R on the pixel electrode 111R, and a common electrode 115 on the EL layer 113R.
  • the light emitting element 130R shown in FIG. 11 emits red light (R).
  • the EL layer 113R has a light emitting layer that emits red light.
  • the light emitting element 130G includes a pixel electrode 111G, an EL layer 113G, and a common electrode 115.
  • the light emitting element 130G emits green light (G)
  • the EL layer 113G has a light emitting layer that emits green light.
  • the light emitting element 130B has a pixel electrode 111B, an EL layer 113B, and a common electrode 115.
  • the light emitting element 130B emits blue light (B)
  • the EL layer 113B has a light emitting layer that emits blue light.
  • the thickness is not limited to this.
  • the respective film thicknesses of the EL layers 113R, 113G, and 113B may be different.
  • the pixel electrode 111R is electrically connected to the conductive layer 112b of the transistor 205R through openings provided in the insulating layer 106, the insulating layer 218, and the insulating layer 235.
  • the pixel electrode 111G is electrically connected to the conductive layer 112b of the transistor 205G
  • the pixel electrode 111B is electrically connected to the conductive layer 112b of the transistor 205B.
  • the ends of each of the pixel electrodes 111R, 111G, and 111B are covered with an insulating layer 237.
  • the insulating layer 237 functions as a partition (also referred to as a bank, bank, or spacer).
  • the insulating layer 237 can be provided in a single layer structure or a laminated structure using one or both of an inorganic insulating material and an organic insulating material.
  • a material that can be used for the insulating layer 218 and a material that can be used for the insulating layer 235 can be used.
  • the insulating layer 237 can electrically insulate the pixel electrode and the common electrode. Further, the insulating layer 237 can electrically insulate adjacent light emitting elements from each other.
  • the common electrode 115 is a continuous film provided in common to the light emitting elements 130R, 130G, and 130B.
  • a common electrode 115 that the plurality of light emitting elements have in common is electrically connected to a conductive layer 123 provided in the connection portion 140. It is preferable to use a conductive layer formed of the same material and in the same process as the pixel electrodes 111R, 111G, and 111B for the conductive layer 123.
  • a conductive film that transmits visible light is used for the light extraction side of the pixel electrode and the common electrode. Further, it is preferable to use a conductive film that reflects visible light for the electrode on the side from which light is not extracted.
  • a conductive film that transmits visible light may also be used for the electrode on the side from which light is not extracted.
  • the material for forming the pair of electrodes of the light emitting element metals, alloys, electrically conductive compounds, mixtures thereof, and the like can be used as appropriate.
  • the materials include aluminum, magnesium, titanium, chromium, manganese, iron, cobalt, nickel, copper, gallium, zinc, indium, tin, molybdenum, tantalum, tungsten, palladium, gold, platinum, silver, Examples include metals such as yttrium and neodymium, and alloys containing appropriate combinations of these metals.
  • such materials include indium tin oxide (In-Sn oxide, also referred to as ITO), In-Si-Sn oxide (also referred to as ITSO), indium zinc oxide (In-Zn oxide), and In-Si-Sn oxide (also referred to as ITSO).
  • ITO indium tin oxide
  • ITSO indium zinc oxide
  • ITSO indium zinc oxide
  • ITSO In-Si-Sn oxide
  • -W-Zn oxide etc. can be mentioned.
  • such materials include alloys containing aluminum (aluminum alloys) such as alloys of aluminum, nickel, and lanthanum (Al-Ni-La), alloys of silver and magnesium, and alloys of silver, palladium, and copper.
  • Al-Ni-La alloys of aluminum, nickel, and lanthanum
  • Al-Ni-La alloys of silver and magnesium
  • silver, palladium, and copper alloys of silver, palladium, and copper.
  • APC alloys containing silver.
  • such materials include elements belonging to Group 1 or Group 2 of the periodic table of elements (for example, lithium, cesium, calcium, strontium), rare earth metals such as europium and ytterbium, and appropriate combinations of these.
  • elements belonging to Group 1 or Group 2 of the periodic table of elements for example, lithium, cesium, calcium, strontium
  • rare earth metals such as europium and ytterbium
  • Examples include alloys containing carbon dioxide, graphene, and the like.
  • a micro optical resonator (microcavity) structure is applied to the light emitting element. Therefore, one of the pair of electrodes included in the light emitting element is preferably an electrode that is transparent and reflective to visible light (semi-transparent/semi-reflective electrode), and the other is an electrode that is reflective to visible light ( A reflective electrode) is preferable. Since the light emitting element has a microcavity structure, the light emitted from the light emitting layer can resonate between both electrodes, and the light emitted from the light emitting element can be intensified.
  • the light transmittance of the transparent electrode is 40% or more.
  • an electrode having a transmittance of visible light (light with a wavelength of 400 nm or more and less than 750 nm) of 40% or more as the transparent electrode of the light emitting element.
  • the visible light reflectance of the semi-transparent/semi-reflective electrode is 10% or more and 95% or less, preferably 30% or more and 80% or less.
  • the visible light reflectance of the reflective electrode is 40% or more and 100% or less, preferably 70% or more and 100% or less.
  • the resistivity of these electrodes is preferably 1 ⁇ 10 ⁇ 2 ⁇ cm or less.
  • the EL layers 113R, 113G, and 113B are each provided in an island shape.
  • the ends of adjacent EL layers 113R and 113G overlap, the ends of adjacent EL layers 113G and EL layers 113B overlap, and the ends of adjacent EL layers 113G and EL layers 113B overlap, and The end of the EL layer 113R and the end of the EL layer 113B overlap.
  • the ends of adjacent EL layers may overlap each other, as shown in FIG. 11, but the invention is not limited to this. That is, adjacent EL layers do not overlap and may be spaced apart from each other. Furthermore, in the display device, there may be both a portion where adjacent EL layers overlap and a portion where adjacent EL layers do not overlap and are separated.
  • Each of the EL layers 113R, 113G, and 113B has at least a light emitting layer.
  • the light-emitting layer has one or more types of light-emitting substances.
  • the luminescent substance a substance exhibiting a luminescent color such as blue, violet, blue-violet, green, yellow-green, yellow, orange, or red is appropriately used.
  • a substance that emits near-infrared light can also be used as the light-emitting substance.
  • luminescent material examples include fluorescent materials, phosphorescent materials, TADF materials, quantum dot materials, and the like.
  • the light emitting layer may contain one or more types of organic compounds (host material, assist material, etc.) in addition to the light emitting substance (guest material).
  • organic compounds host material, assist material, etc.
  • one or both of a substance with high hole-transporting properties (hole-transporting material) and a substance with high electron-transporting property (electron-transporting material) can be used.
  • a bipolar substance a substance with high electron transporting properties and hole transporting properties, also referred to as a bipolar material
  • TADF material may be used as one or more types of organic compounds.
  • the light-emitting layer preferably includes, for example, a phosphorescent material and a hole-transporting material and an electron-transporting material that are a combination that tends to form an exciplex.
  • ExTET Exciplex-Triplet Energy Transfer
  • a combination that forms an exciplex that emits light that overlaps with the wavelength of the lowest energy absorption band of the light-emitting substance energy transfer becomes smoother and luminescence can be efficiently obtained.
  • high efficiency, low voltage drive, and long life of the light emitting element can be achieved at the same time.
  • the EL layer includes a layer containing a substance with high hole injection properties (hole injection layer), a layer containing a hole transporting material (hole transport layer), and a substance with high electron blocking properties.
  • hole injection layer a layer containing a substance with high hole injection properties
  • hole transport layer a layer containing a hole transporting material
  • hole blocking layer a layer containing a substance with high electron blocking property
  • the EL layer may include one or both of a bipolar material and a TADF material.
  • the light-emitting element can use either a low-molecular compound or a high-molecular compound, and may also contain an inorganic compound.
  • the layers constituting the light emitting element can be formed by a method such as a vapor deposition method (including a vacuum vapor deposition method), a transfer method, a printing method, an inkjet method, a coating method, or the like.
  • a single structure (a structure having only one light emitting unit) or a tandem structure (a structure having a plurality of light emitting units) may be applied to the light emitting element.
  • the light emitting unit has at least one light emitting layer.
  • the tandem structure is a structure in which a plurality of light emitting units are connected in series via a charge generation layer.
  • the charge generation layer has a function of injecting electrons into one of the two light emitting units and injecting holes into the other when a voltage is applied between the pair of electrodes.
  • the EL layer 113R has a structure that has a plurality of light emitting units that emit red light
  • the EL layer 113G has a structure that has a plurality of light emitting units that emit green light
  • the EL layer 113B preferably has a structure including a plurality of light emitting units that emit blue light.
  • a protective layer 131 is provided on the light emitting elements 130R, 130G, and 130B.
  • the protective layer 131 and the substrate 152 are bonded together via an adhesive layer 142.
  • a light shielding layer 117 is provided on the substrate 152.
  • a solid sealing structure or a hollow sealing structure can be applied to seal the light emitting element.
  • the space between substrate 152 and substrate 151 is filled with adhesive layer 142, and a solid sealing structure is applied.
  • the space may be filled with an inert gas (such as nitrogen or argon) and a hollow sealing structure may be applied.
  • the adhesive layer 142 may be provided so as not to overlap the light emitting element.
  • the space may be filled with a resin different from that of the adhesive layer 142 provided in a frame shape.
  • the protective layer 131 is provided at least on the display section 162, and is preferably provided so as to cover the entire display section 162. By providing the protective layer 131 on the light emitting elements 130R, 130G, and 130B, the reliability of the light emitting elements can be improved. It is preferable that the protective layer 131 is provided so as to cover not only the display section 162 but also the connection section 140 and the circuit section 164. Moreover, it is preferable that the protective layer 131 is provided up to the end of the display device 50A. On the other hand, in the connecting portion 204, there is a portion where the protective layer 131 is not provided in order to electrically connect the FPC 172 and the conductive layer 166.
  • the protective layer 131 may have a single layer structure or a laminated structure of two or more layers. Furthermore, the conductivity of the protective layer 131 does not matter. As the protective layer 131, at least one of an insulating film, a semiconductor film, and a conductive film can be used. Since the protective layer 131 includes an inorganic film, it prevents the common electrode 115 from being oxidized, prevents impurities (moisture, oxygen, etc.) from entering the light emitting element, suppresses deterioration of the light emitting element, and improves the performance of the display device. Reliability can be increased.
  • an inorganic insulating film such as an oxide insulating film, a nitride insulating film, an oxynitride insulating film, and a nitride oxide insulating film can be used. Specific examples of these inorganic insulating films are as described above.
  • the protective layer 131 preferably includes a nitride insulating film or a nitride oxide insulating film, and more preferably a nitride insulating film.
  • an inorganic film containing ITO, In-Zn oxide, Ga-Zn oxide, Al-Zn oxide, IGZO, or the like can also be used. It is preferable that the inorganic film has a high resistance, and specifically, it is preferable that the inorganic film has a higher resistance than the common electrode 115.
  • the inorganic film may further contain nitrogen.
  • the protective layer 131 When emitting light from the light emitting element is extracted through the protective layer 131, the protective layer 131 preferably has high transparency to visible light.
  • the protective layer 131 preferably has high transparency to visible light.
  • ITO, IGZO, and aluminum oxide are preferable because they are inorganic materials with high transparency to visible light.
  • the protective layer 131 for example, a laminated structure of an aluminum oxide film and a silicon nitride film on the aluminum oxide film, or a laminated structure of an aluminum oxide film and an IGZO film on the aluminum oxide film can be used. can.
  • the laminated structure it is possible to suppress impurities (water, oxygen, etc.) from entering the EL layer side.
  • the protective layer 131 may include an organic film.
  • the protective layer 131 may include both an organic film and an inorganic film.
  • Examples of the organic film that can be used for the protective layer 131 include an organic insulating film that can be used for the insulating layer 235.
  • a connecting portion 204 is provided in a region of the substrate 151 where the substrate 152 does not overlap.
  • the wiring 165 is electrically connected to the FPC 172 via the conductive layer 166 and the connection layer 242.
  • the wiring 165 has a single-layer structure of a conductive layer obtained by processing the same conductive film as the conductive layer 112b.
  • the conductive layer 166 has a single-layer structure of a conductive layer obtained by processing the same conductive film as the pixel electrodes 111R, 111G, and 111B.
  • the conductive layer 166 is exposed on the upper surface of the connection portion 204. Thereby, the connection portion 204 and the FPC 172 can be electrically connected via the connection layer 242.
  • the display device 50A is a top emission type. Light emitted by the light emitting element is emitted to the substrate 152 side.
  • the substrate 152 is preferably made of a material that is highly transparent to visible light.
  • the pixel electrodes 111R, 111G, and 111B include a material that reflects visible light, and the counter electrode (common electrode 115) includes a material that transmits visible light.
  • the light shielding layer 117 can be provided between adjacent light emitting elements, at the connection portion 140, the circuit portion 164, and the like.
  • a colored layer such as a color filter may be provided on the surface of the substrate 152 on the substrate 151 side or on the protective layer 131.
  • a color filter By providing a color filter overlapping the light emitting element, the color purity of light emitted from the pixel can be increased.
  • various optical members can be arranged on the outside of the substrate 152 (on the surface opposite to the substrate 151).
  • the optical member include a polarizing plate, a retardation plate, a light diffusion layer (such as a diffusion film), an antireflection layer, and a light collecting film.
  • surface protection is provided such as an antistatic film that suppresses the adhesion of dust, a water-repellent film that prevents dirt from adhering, a hard coat film that suppresses the occurrence of scratches due to use, and a shock absorption layer. Layers may be arranged.
  • a glass layer or a silica layer (SiO x layer) as the surface protective layer, since surface contamination and scratches can be suppressed.
  • the surface protective layer DLC (diamond-like carbon), aluminum oxide (AlO x ), polyester material, polycarbonate material, or the like may be used. Note that it is preferable to use a material with high transmittance to visible light for the surface protective layer. Moreover, it is preferable to use a material with high hardness for the surface protective layer.
  • the substrate 151 and the substrate 152 glass, quartz, ceramics, sapphire, resin, metal, alloy, semiconductor, etc. can be used, respectively.
  • a material that transmits the light is used for the substrate on the side from which the light from the light emitting element is extracted. If a flexible material is used for the substrate 151 and the substrate 152, the flexibility of the display device can be increased and a flexible display can be realized. Further, a polarizing plate may be used as at least one of the substrate 151 and the substrate 152.
  • the substrate 151 and the substrate 152 are made of polyester resin such as polyethylene terephthalate (PET) or polyethylene naphthalate (PEN), polyacrylonitrile resin, acrylic resin, polyimide resin, polymethyl methacrylate resin, polycarbonate (PC) resin, or polyether, respectively.
  • PET polyethylene terephthalate
  • PEN polyethylene naphthalate
  • Sulfone (PES) resin polyamide resin (nylon, aramid, etc.), polysiloxane resin, cycloolefin resin, polystyrene resin, polyamideimide resin, polyurethane resin, polyvinyl chloride resin, polyvinylidene chloride resin, polypropylene resin, polytetrafluoroethylene (PTFE) resin, ABS resin, cellulose nanofiber, etc.
  • At least one of the substrate 151 and the substrate 152 may be made of glass having a thickness sufficient to have flexibility.
  • a substrate with high optical isotropy has small birefringence (it can also be said that the amount of birefringence is small).
  • films with high optical isotropy include triacetyl cellulose (TAC, also referred to as cellulose triacetate) film, cycloolefin polymer (COP) film, cycloolefin copolymer (COC) film, and acrylic film.
  • various curable adhesives such as a photo-curable adhesive such as an ultraviolet curable adhesive, a reaction-curable adhesive, a thermosetting adhesive, and an anaerobic adhesive can be used.
  • these adhesives include epoxy resin, acrylic resin, silicone resin, phenol resin, polyimide resin, imide resin, PVC (polyvinyl chloride) resin, PVB (polyvinyl butyral) resin, EVA (ethylene vinyl acetate) resin, and the like.
  • materials with low moisture permeability such as epoxy resin are preferred.
  • a two-liquid mixed type resin may be used.
  • an adhesive sheet or the like may be used.
  • connection layer 242 an anisotropic conductive film (ACF), anisotropic conductive paste (ACP), or the like can be used.
  • ACF anisotropic conductive film
  • ACP anisotropic conductive paste
  • Display device 50B The display device 50B shown in FIG. 12 uses a light emitting element having an EL layer 113 common to subpixels of each color, a colored layer (color filter, etc.), and is a bottom emission type display device. This is mainly different from the display device 50A. Note that in the following description of the display device, description of parts similar to those of the display device described above may be omitted.
  • the light emitted by the light emitting element is emitted to the substrate 151 side.
  • the substrate 151 is preferably made of a material that is highly transparent to visible light. On the other hand, the light transmittance of the material used for the substrate 152 does not matter.
  • a display device 50B shown in FIG. 12 includes transistors 205D, 205R, 205G, and 205B, light emitting elements 130R, 130G, and 130B, a colored layer 132R that transmits red light, and a colored layer 132R that transmits green light between a substrate 151 and a substrate 152.
  • the light emitting element 130R includes a pixel electrode 111R, an EL layer 113 on the pixel electrode 111R, and a common electrode 115 on the EL layer 113.
  • the light emitted from the light emitting element 130R is extracted as red light to the outside of the display device 50B via the colored layer 132R.
  • the light emitting element 130G includes a pixel electrode 111G, an EL layer 113 on the pixel electrode 111G, and a common electrode 115 on the EL layer 113.
  • the light emitted from the light emitting element 130G is extracted as green light to the outside of the display device 50B via the colored layer 132G.
  • the light emitting element 130B has a pixel electrode 111B, an EL layer 113 on the pixel electrode 111B, and a common electrode 115 on the EL layer 113.
  • the light emitted from the light emitting element 130B is extracted as blue light to the outside of the display device 50B via the colored layer 132B.
  • the light emitting elements 130R, 130G, and 130B each share an EL layer 113 and a common electrode 115.
  • a configuration in which a common EL layer 113 is provided for subpixels of each color can reduce the number of manufacturing steps, compared to a configuration in which different EL layers are provided for subpixels of each color.
  • the light emitting elements 130R, 130G, and 130B shown in FIG. 12 emit white light.
  • the white light emitted by the light emitting elements 130R, 130G, and 130B passes through the colored layers 132R, 132G, and 132B, so that light of a desired color can be obtained.
  • a light shielding layer 117 is formed between the substrate 151 and the transistor.
  • a light shielding layer 117 is provided on a substrate 151
  • an insulating layer 153 is provided on the light blocking layer 117
  • transistors 205D1, 205D2, a transistor 205R, a transistor 205G, and a transistor 205B are provided on the insulating layer 153.
  • An example is shown in which the following is provided.
  • a colored layer 132R, a colored layer 132G, and a colored layer 132B are provided on the insulating layer 218, and an insulating layer 235 is provided on the colored layer 132R, the colored layer 132G, and the colored layer 132B.
  • the pixel electrodes 111R, 111G, and 111B are each made of a material that is highly transparent to visible light. It is preferable to use a material that reflects visible light for the common electrode 115. In a bottom emission type display device, a metal or the like with low resistance can be used for the common electrode 115, so it is possible to suppress a voltage drop caused by the resistance of the common electrode 115, and achieve high display quality.
  • the transistor of one embodiment of the present invention can be miniaturized and occupy a small area; therefore, in a display device with a bottom emission structure, the aperture ratio of a pixel can be increased or the size of a pixel can be reduced.
  • each of the white light produced by the EL layer 113 emits light with a predetermined wavelength intensified.
  • a light-emitting element to which a microcavity is applied in this manner will be referred to as a light-emitting element that emits white light if an EL layer that emits white light is applied thereto.
  • the light emitting element that emits white light includes two or more light emitting layers.
  • the light-emitting layers may be selected such that the emission colors of the two light-emitting layers are complementary colors. For example, by making the light emitting color of the first light emitting layer and the light emitting color of the second light emitting layer complementary, it is possible to obtain a configuration in which the light emitting element as a whole emits white light.
  • the light emitting element as a whole may be configured to emit white light by combining the emitted light colors of the three or more light emitting layers.
  • the EL layer 113 preferably has, for example, a light-emitting layer containing a light-emitting substance that emits blue light and a light-emitting layer containing a light-emitting substance that emits visible light with a longer wavelength than blue light.
  • the EL layer 113 preferably includes, for example, a light-emitting layer that emits yellow light and a light-emitting layer that emits blue light.
  • the EL layer 113 preferably includes, for example, a light-emitting layer that emits red light, a light-emitting layer that emits green light, and a light-emitting layer that emits blue light.
  • a tandem structure for the light emitting element that emits white light has a two-stage tandem structure having a light emitting unit that emits yellow light and a light emitting unit that emits blue light, and a light emitting unit that emits red and green light, and a light emitting unit that emits blue light.
  • a three-stage tandem structure, etc. which has a light-emitting unit that emits light of , a light-emitting unit that emits yellow, yellow-green, or green light, a light-emitting unit that emits red light, and a light-emitting unit that emits blue light, etc., is applied. can do.
  • the number of stacked layers and the order of colors of the light-emitting units are: a two-tiered structure of B and Y, a two-tiered structure of B and the light-emitting unit X, a three-tiered structure of B, Y, and B, and a three-tiered structure of B, , B, and the order of the number and color of the light emitting layers in the light emitting unit It may have a two-layer structure, a three-layer structure of G, R, and G, or a three-layer structure of R, G, and R, or the like. Further, another layer may be provided between the two light emitting layers.
  • the light emitting elements 130R, 130G, and 130B shown in FIG. 12 may be configured to emit blue light.
  • the EL layer 113 has one or more light emitting layers that emit blue light.
  • blue light emitted by the light emitting element 130B can be extracted.
  • a color conversion layer is provided between the light emitting element 130R or the light emitting element 130G and the substrate 151, so that the light emitting element 130R or It is possible to convert the blue light emitted by 130G to longer wavelength light and extract red or green light.
  • a colored layer 132R is provided between the color conversion layer and the substrate 151 on the optical path of the light emission of the light emitting element 130R, and a colored layer 132R is provided between the color conversion layer and the substrate 151 on the optical path of the light emission of the light emitting element 130G. It is preferable to provide a colored layer 132G. A part of the light emitted by the light emitting element may be transmitted as is without being converted by the color conversion layer. By extracting the light transmitted through the color conversion layer through the colored layer, the colored layer absorbs light of a color other than the desired color, thereby increasing the color purity of the light exhibited by the subpixel.
  • a display device 50C shown in FIG. 13 is an example of a display device to which an MML (metal maskless) structure is applied.
  • the display device 50C has a light emitting element manufactured without using a fine metal mask.
  • the laminated structure from the substrate 151 to the insulating layer 235 and the laminated structure from the protective layer 131 to the substrate 152 are the same as those of the display device 50A, so their explanation will be omitted.
  • light emitting elements 130R, 130G, and 130B are provided on an insulating layer 235.
  • the light emitting element 130R includes a conductive layer 124R on the insulating layer 235, a conductive layer 126R on the conductive layer 124R, a layer 133R on the conductive layer 126R, a common layer 114 on the layer 133R, and a common electrode on the common layer 114. 115.
  • the light emitting element 130R shown in FIG. 13 emits red light (R).
  • Layer 133R has a light emitting layer that emits red light.
  • the layer 133R and the common layer 114 can be collectively called an EL layer.
  • one or both of the conductive layer 124R and the conductive layer 126R can be called a pixel electrode.
  • the light emitting element 130G includes a conductive layer 124G on the insulating layer 235, a conductive layer 126G on the conductive layer 124G, a layer 133G on the conductive layer 126G, a common layer 114 on the layer 133G, and a conductive layer 126G on the conductive layer 124G.
  • the light emitting element 130G shown in FIG. 13 emits green light (G).
  • Layer 133G has a light emitting layer that emits green light.
  • the light emitting element 130B includes a conductive layer 124B on the insulating layer 235, a conductive layer 126B on the conductive layer 124B, a layer 133B on the conductive layer 126B, a common layer 114 on the layer 133B, and a conductive layer 126B on the conductive layer 124B.
  • the light emitting element 130B shown in FIG. 13 emits blue light (B).
  • Layer 133B has a light emitting layer that emits blue light.
  • a layer provided in an island shape for each light emitting element is referred to as a layer 133B, a layer 133G, or a layer 133R
  • a layer shared by a plurality of light emitting elements is referred to as a layer 133B, a layer 133G, or a layer 133R. It is indicated as a common layer 114.
  • the layers 133R, 133G, and 133B may be referred to as an island-shaped EL layer, an island-shaped EL layer, or the like, without including the common layer 114.
  • the layer 133R, the layer 133G, and the layer 133B are spaced apart from each other.
  • the EL layer in an island shape for each light emitting element, leakage current between adjacent light emitting elements can be suppressed. Thereby, unintended light emission due to crosstalk can be prevented, and a display device with extremely high contrast can be realized.
  • the layers 133R, 133G, and 133B are all shown to have the same thickness, but the thickness is not limited to this.
  • the layers 133R, 133G, and 133B may have different thicknesses.
  • the conductive layer 124R is electrically connected to the conductive layer 112b of the transistor 205R through openings provided in the insulating layer 106, the insulating layer 218, and the insulating layer 235.
  • the conductive layer 124G is electrically connected to the conductive layer 112b of the transistor 205G
  • the conductive layer 124B is electrically connected to the conductive layer 112b of the transistor 205B.
  • the conductive layers 124R, 124G, and 124B are formed to cover the opening provided in the insulating layer 235.
  • a layer 128 is embedded in each of the recesses of the conductive layers 124R, 124G, and 124B.
  • the layer 128 has a function of flattening the recessed portions of the conductive layers 124R, 124G, and 124B.
  • conductive layers 126R, 126G, 126B are provided which are electrically connected to the conductive layers 124R, 124G, 124B. Therefore, the regions overlapping with the recesses of the conductive layers 124R, 124G, and 124B can also be used as light emitting regions, and the aperture ratio of the pixel can be increased. It is preferable to use a conductive layer that functions as a reflective electrode for the conductive layer 124R and the conductive layer 126R.
  • the layer 128 may be an insulating layer or a conductive layer.
  • various inorganic insulating materials, organic insulating materials, and conductive materials can be used as appropriate.
  • layer 128 is preferably formed using an insulating material, and particularly preferably formed using an organic insulating material.
  • an organic insulating material that can be used for the above-described insulating layer 237 can be applied to the layer 128.
  • FIG. 13 shows an example in which the upper surface of the layer 128 has a flat portion
  • the shape of the layer 128 is not particularly limited.
  • the top surface of layer 128 can have at least one of a convex curve, a concave curve, and a flat surface.
  • the height of the top surface of the layer 128 and the height of the top surface of the conductive layer 124R may be the same or approximately the same, or may be different from each other.
  • the height of the top surface of layer 128 may be lower or higher than the height of the top surface of conductive layer 124R.
  • the end of the conductive layer 126R may be aligned with the end of the conductive layer 124R, or may cover the side surface of the end of the conductive layer 124R. It is preferable that each end of the conductive layer 124R and the conductive layer 126R has a tapered shape. Specifically, it is preferable that each end of the conductive layer 124R and the conductive layer 126R has a tapered shape with a taper angle of less than 90°.
  • the layer 133R provided along the side surface of the pixel electrode has an inclined portion. By tapering the side surfaces of the pixel electrode, it is possible to improve the coverage of the EL layer provided along the side surfaces of the pixel electrode.
  • the conductive layers 124G, 126G and the conductive layers 124B, 126B are the same as the conductive layers 124R, 126R, so a detailed explanation will be omitted.
  • the top and side surfaces of the conductive layer 126R are covered with a layer 133R.
  • the top and side surfaces of conductive layer 126G are covered by layer 133G
  • the top and side surfaces of conductive layer 126B are covered by layer 133B. Therefore, the entire region where the conductive layers 126R, 126G, and 126B are provided can be used as the light emitting region of the light emitting elements 130R, 130G, and 130B, so that the aperture ratio of the pixel can be increased.
  • a portion of the upper surface and side surfaces of each of the layers 133R, 133G, and 133B are covered with insulating layers 125 and 127.
  • a common layer 114 is provided on the layer 133R, layer 133G, layer 133B, and insulating layers 125 and 127, and a common electrode 115 is provided on the common layer 114.
  • the common layer 114 and the common electrode 115 are each a continuous film provided in common to a plurality of light emitting elements.
  • the insulating layer 237 shown in FIG. 11 etc. is not provided between the conductive layer 126R and the layer 133R. That is, the display device 50C is not provided with an insulating layer (also referred to as a partition, bank, spacer, etc.) that is in contact with the pixel electrode and covers the upper end of the pixel electrode. Therefore, the interval between adjacent light emitting elements can be made extremely narrow. Therefore, a high-definition or high-resolution display device can be achieved. Further, a mask for forming the insulating layer is not required, and the manufacturing cost of the display device can be reduced.
  • an insulating layer also referred to as a partition, bank, spacer, etc.
  • the layer 133R, the layer 133G, and the layer 133B each have a light emitting layer. It is preferable that the layer 133R, the layer 133G, and the layer 133B each include a light emitting layer and a carrier transport layer (an electron transport layer or a hole transport layer) on the light emitting layer. Alternatively, each of the layers 133R, 133G, and 133B preferably includes a light-emitting layer and a carrier block layer (hole block layer or electron block layer) on the light-emitting layer.
  • each of the layers 133R, 133G, and 133B preferably includes a light-emitting layer, a carrier block layer on the light-emitting layer, and a carrier transport layer on the carrier block layer. Since the surfaces of the layer 133R, layer 133G, and layer 133B are exposed during the manufacturing process of the display device, by providing one or both of the carrier transport layer and the carrier block layer on the light emitting layer, the light emitting layer is placed on the outermost surface. Exposure can be suppressed and damage to the light emitting layer can be reduced. Thereby, the reliability of the light emitting element can be improved.
  • the common layer 114 includes, for example, an electron injection layer or a hole injection layer.
  • the common layer 114 may have an electron transport layer and an electron injection layer stacked together, or may have a hole transport layer and a hole injection layer stacked together.
  • the common layer 114 is shared by the light emitting elements 130R, 130G, and 130B.
  • each of the layers 133R, 133G, and 133B are covered with an insulating layer 125.
  • the insulating layer 127 covers each side surface of the layer 133R, layer 133G, and layer 133B with the insulating layer 125 interposed therebetween.
  • the common layer 114 or the common electrode 115
  • the pixel electrode By covering the side surfaces (and part of the top surface) of the layers 133R, 133G, and 133B with at least one of the insulating layer 125 and the insulating layer 127, the common layer 114 (or the common electrode 115) , the pixel electrode, and the side surfaces of the layers 133R, 133G, and 133B, thereby suppressing short-circuiting of the light emitting element. Thereby, the reliability of the light emitting element can be improved.
  • the insulating layer 125 is in contact with each side surface of the layer 133R, layer 133G, and layer 133B. With the structure in which the insulating layer 125 is in contact with the layers 133R, 133G, and 133B, peeling of the layers 133R, 133G, and 133B can be prevented, and the reliability of the light-emitting element can be improved.
  • the insulating layer 127 is provided on the insulating layer 125 so as to fill the recessed portion of the insulating layer 125.
  • the insulating layer 127 covers at least a portion of the side surface of the insulating layer 125.
  • the space between adjacent island-like layers can be filled, so that the surface on which layers (for example, carrier injection layer, common electrode, etc.) to be provided on the island-like layer are formed can be It is possible to reduce unevenness with large height differences and make the surface more flat. Therefore, coverage of the carrier injection layer, the common electrode, etc. can be improved.
  • layers for example, carrier injection layer, common electrode, etc.
  • the common layer 114 and the common electrode 115 are provided on the layer 133R, the layer 133G, the layer 133B, the insulating layer 125, and the insulating layer 127.
  • the stage before providing the insulating layer 125 and the insulating layer 127 there are a region where the pixel electrode and the island-shaped EL layer are provided, a region where the pixel electrode and the island-like EL layer are not provided (a region between the light emitting elements), There is a step caused by this.
  • the step can be flattened, and the coverage of the common layer 114 and the common electrode 115 can be improved. Therefore, connection failures due to disconnection can be suppressed. Further, it is possible to suppress the common electrode 115 from becoming locally thin due to the step difference, thereby preventing an increase in electrical resistance.
  • the upper surface of the insulating layer 127 preferably has a highly flat shape.
  • the upper surface of the insulating layer 127 may have at least one of a flat surface, a convex curved surface, and a concave curved surface.
  • the upper surface of the insulating layer 127 preferably has a smooth convex curved shape with high flatness.
  • the insulating layer 125 can be an insulating layer containing an inorganic material.
  • an inorganic insulating film such as an oxide insulating film, a nitride insulating film, an oxynitride insulating film, and a nitride oxide insulating film can be used. Specific examples of these inorganic insulating films are as described above.
  • the insulating layer 125 may have a single layer structure or a laminated structure. In particular, aluminum oxide is preferable because it has a high etching selectivity with respect to the EL layer and has a function of protecting the EL layer in forming an insulating layer 127 to be described later.
  • the insulating layer 125 has fewer pinholes and has an excellent function of protecting the EL layer. can be formed.
  • the insulating layer 125 may have a stacked structure of a film formed by an ALD method and a film formed by a sputtering method.
  • the insulating layer 125 may have a laminated structure of, for example, an aluminum oxide film formed by an ALD method and a silicon nitride film formed by a sputtering method.
  • the insulating layer 125 preferably has a function as a barrier insulating layer against at least one of water and oxygen. Further, the insulating layer 125 preferably has a function of suppressing diffusion of at least one of water and oxygen. Furthermore, the insulating layer 125 preferably has a function of capturing or fixing (also referred to as gettering) at least one of water and oxygen.
  • barrier insulating layer refers to an insulating layer having barrier properties.
  • barrier property refers to the function of suppressing the diffusion of a corresponding substance (also referred to as low permeability). Alternatively, the function is to capture or fix (also referred to as gettering) the corresponding substance.
  • the insulating layer 125 has a function as a barrier insulating layer or a gettering function, thereby suppressing the intrusion of impurities (typically, at least one of water and oxygen) that can diffuse into each light emitting element from the outside.
  • impurities typically, at least one of water and oxygen
  • the insulating layer 125 has a low impurity concentration. This can prevent impurities from entering the EL layer from the insulating layer 125 and deteriorating the EL layer. Furthermore, by lowering the impurity concentration in the insulating layer 125, barrier properties against at least one of water and oxygen can be improved. For example, it is desirable that the insulating layer 125 has sufficiently low hydrogen concentration and carbon concentration, preferably both.
  • the insulating layer 127 provided on the insulating layer 125 has a function of flattening unevenness with a large height difference in the insulating layer 125 formed between adjacent light emitting elements. In other words, the presence of the insulating layer 127 has the effect of improving the flatness of the surface on which the common electrode 115 is formed.
  • an insulating layer containing an organic material can be suitably used.
  • the organic material it is preferable to use a photosensitive organic resin, and for example, it is preferable to use a photosensitive resin composition containing an acrylic resin.
  • acrylic resin does not refer only to polymethacrylic acid ester or methacrylic resin, but may refer to the entire acrylic polymer in a broad sense.
  • the insulating layer 127 acrylic resin, polyimide resin, epoxy resin, imide resin, polyamide resin, polyimide amide resin, silicone resin, siloxane resin, benzocyclobutene resin, phenol resin, precursors of these resins, etc. are used. It's okay.
  • an organic material such as polyvinyl alcohol (PVA), polyvinyl butyral, polyvinylpyrrolidone, polyethylene glycol, polyglycerin, pullulan, water-soluble cellulose, or alcohol-soluble polyamide resin may be used.
  • PVA polyvinyl alcohol
  • a photoresist may be used as the photosensitive organic resin.
  • the photosensitive organic resin either a positive type material or a negative type material may be used.
  • a material that absorbs visible light may be used for the insulating layer 127. Since the insulating layer 127 absorbs light emitted from the light emitting element, light leakage from the light emitting element to an adjacent light emitting element via the insulating layer 127 (stray light) can be suppressed. Thereby, the display quality of the display device can be improved. Furthermore, since display quality can be improved without using a polarizing plate in the display device, the display device can be made lighter and thinner.
  • Materials that absorb visible light include materials that contain pigments such as black, materials that contain dyes, resin materials that have light absorption properties (such as polyimide), and resin materials that can be used for color filters (color filter materials). ).
  • resin materials that have light absorption properties such as polyimide
  • resin materials that can be used for color filters color filter materials.
  • by mixing color filter materials of three or more colors it is possible to form a black or nearly black resin layer.
  • Display device 50D In the above, an example is shown in which a light emitting element is applied to the display element, but below, a liquid crystal display device in which a liquid crystal element is applied to the display element will be described.
  • liquid crystal element included in the display device.
  • a transmissive liquid crystal element to which VA (Vertical Alignment) mode, FFS (Fringe Field Switching) mode, IPS (In-Plane-Switching) mode, etc. is applied can be used.
  • the liquid crystal element not only a transmissive type but also a reflective or semi-transmissive liquid crystal element may be used.
  • the display device is preferably a normally black type liquid crystal display device.
  • VA Multi-Domain Vertical Alignment
  • PVA Pulned Vertical Alignment
  • ASV Advanced Super View
  • liquid crystal elements to which various modes are applied can be used as the liquid crystal element.
  • TN Transmission Nematic
  • ASM Analy Symmetrically aligned Micro-cell
  • OCB Optically Compensated Fire
  • fringence FLC
  • FLC Fluoroelectric Liquid Crystal
  • AFLC AntiFerroelectric
  • a liquid crystal element to which a liquid crystal mode, an electrically controlled birefringence (ECB) mode, a guest-host mode, or the like is applied can be used.
  • the liquid crystal display device is a display device that controls transmission or non-transmission of light by utilizing polarization and the optical modulation effect of liquid crystal.
  • the optical modulation effect of a liquid crystal is controlled by an electric field (including a lateral electric field, a longitudinal electric field, or an oblique electric field) applied to the liquid crystal.
  • Liquid crystals that can be used in liquid crystal elements include thermotropic liquid crystal, low molecular liquid crystal, polymer liquid crystal, polymer dispersed liquid crystal (PDLC), and polymer network liquid crystal (PNLC). id Crystal) , ferroelectric liquid crystal, antiferroelectric liquid crystal, etc. can be used.
  • liquid crystal materials exhibit a cholesteric phase, a smectic phase, a cubic phase, a chiral nematic phase, an isotropic phase, etc. depending on the conditions. Further, as the liquid crystal material, either a positive type liquid crystal or a negative type liquid crystal may be used, and the optimum liquid crystal material may be used depending on the applied mode or design.
  • the display device 50D shown in FIG. 14 is an FFS mode liquid crystal display device.
  • the substrate 151 and the substrate 152 are bonded together by an adhesive layer 144. Further, a liquid crystal 262 is sealed in a region surrounded by the substrate 151, the substrate 152, and the adhesive layer 144.
  • a polarizing plate 260a is located on the outer surface of the substrate 152, and a polarizing plate 260b is located on the outer surface of the substrate 151.
  • a backlight can be provided outside the polarizing plate 260a or outside the polarizing plate 260b.
  • the substrate 151 is provided with transistors 205D, 205R, 205G, a connecting portion 204, a spacer 224, and the like.
  • the transistor 205D is a transistor provided in the circuit portion 164, and the transistors 205R and 205G are transistors provided in the display portion 162.
  • the conductive layer 112b of the transistors 205R and 205G is electrically connected to the pixel electrode 111 of the liquid crystal element 60.
  • the substrate 152 is provided with colored layers 132R and 132G, a light shielding layer 117, an insulating layer 225, and the like.
  • the transistors 205D, 205R, and 205G each include a conductive layer 112a, a conductive layer 112b, a semiconductor layer 108, a semiconductor layer 107, a semiconductor layer 109, an insulating layer 106, a conductive layer 104, and the like.
  • the conductive layer 112a functions as one of a source electrode and a drain electrode, and the conductive layer 112b functions as the other.
  • the semiconductor layer 107 functions as one of a source region and a drain region, and the semiconductor layer 109 functions as the other.
  • the conductive layer 104 functions as a gate electrode.
  • a portion of the insulating layer 106 functions as a gate insulating layer.
  • the transistors 205D, 205R, and 205G are covered with an insulating layer 218.
  • the insulating layer 218 functions as a protective layer for the transistors 205D, 205R, and 205G.
  • the subpixel included in the display section 162 includes a transistor, a liquid crystal element 60, and a colored layer.
  • a subpixel that emits red light includes a transistor 205R, a liquid crystal element 60, and a colored layer 132R that transmits red light.
  • the subpixel that emits green light includes a transistor 205G, a liquid crystal element 60, and a colored layer 132G that transmits green light.
  • the subpixel that emits blue light similarly includes a transistor, a liquid crystal element 60, and a colored layer that transmits blue light.
  • the liquid crystal element 60 has a common electrode 115, a pixel electrode 111, and a liquid crystal 262.
  • a common electrode 115 is provided on the insulating layer 218, and an insulating layer 214 is provided on the common electrode 115. Further, the pixel electrode 111 is provided on the insulating layer 214.
  • the pixel electrode 111 and the common electrode 115 transmit visible light.
  • the liquid crystal element 60 can be a transmissive liquid crystal element.
  • the alignment of the liquid crystal 262 can be controlled by the voltage applied between the pixel electrode 111 and the common electrode 115, and the optical modulation of light can be controlled. That is, the intensity of light emitted through the polarizing plate 260a can be controlled.
  • the colored layer absorbs incident light outside a specific wavelength range, so that the extracted light becomes, for example, red-colored light.
  • a linearly polarizing plate may be used as the polarizing plate 260a
  • a circularly polarizing plate may also be used.
  • the circularly polarizing plate for example, a stack of a linearly polarizing plate and a quarter wavelength retardation plate can be used.
  • a circularly polarizing plate may also be used as the polarizing plate 260b, or a normal linearly polarizing plate can also be used.
  • a desired contrast can be achieved by adjusting the cell gap, orientation, driving voltage, etc. of the liquid crystal element used in the liquid crystal element 60, depending on the type of polarizing plate applied to the polarizing plate 260a and the polarizing plate 260b.
  • a connecting portion 204 is provided in a region near the end of the substrate 151.
  • the wiring 165 is electrically connected to the FPC 172 via the conductive layer 166 and the connection layer 242.
  • the wiring 165 is connected to the wiring 165 through an opening provided in the insulating layer 110.
  • the wiring 165 is formed using the same material and in the same process as the conductive layer 112a and the semiconductor layer 107, and the conductive layer 166 is formed using the same material and in the same process as the conductive layer 112b. An example of forming is shown below.
  • the pixel electrode 111 has a comb-like shape or a shape provided with slits in a plan view. Furthermore, the pixel electrode 111 is arranged to overlap the common electrode 115. Further, in the region overlapping with the colored layer, there is a portion where the pixel electrode 111 is not arranged on the common electrode 115.
  • both the pixel electrode 111 and the common electrode 115 may have a comb-like upper surface shape.
  • the display device 50D in the liquid crystal element 60, only one of the pixel electrode 111 and the common electrode 115 has a comb-like upper surface shape, so that the pixel electrode 111 and the common electrode 115 are partially separated. This results in overlapping configurations. Thereby, the capacitance between the pixel electrode 111 and the common electrode 115 can be used as a storage capacitance, there is no need to separately provide a capacitive element, and the aperture ratio of the display device can be increased.
  • an insulating layer 225 is provided to cover the colored layers 132R, 132G and the light shielding layer 117.
  • the insulating layer 225 functions as an overcoat that prevents components contained in the colored layers 132R, 132G, etc. from diffusing into the liquid crystal 262. Further, the insulating layer 225 may have a function as a planarization film.
  • the insulating layer 225 can be formed using a light-transmitting organic resin.
  • an alignment film for controlling the alignment of the liquid crystal 262 may be provided on the surfaces of the pixel electrode 111, the insulating layer 214, the insulating layer 225, etc. that are in contact with the liquid crystal 262.
  • the above is a description of the configuration example of the display device.
  • FIG. 15 shows cross-sectional views of three light emitting elements included in the display section 162 and the connection section 140 in each step.
  • a vacuum process such as a vapor deposition method, and a solution process such as a spin coating method or an inkjet method can be used to manufacture a light emitting element.
  • the vapor deposition method include physical vapor deposition methods (PVD method) such as sputtering method, ion plating method, ion beam vapor deposition method, molecular beam vapor deposition method, and vacuum vapor deposition method, and chemical vapor deposition method (CVD method).
  • PVD method physical vapor deposition methods
  • CVD method chemical vapor deposition method
  • the functional layers (hole injection layer, hole transport layer, hole block layer, light emitting layer, electron block layer, electron transport layer, electron injection layer, charge generation layer, etc.) included in the EL layer are formed using the vapor deposition method ( vacuum evaporation method, etc.), coating method (dip coating method, die coating method, bar coating method, spin coating method, spray coating method, etc.), printing method (inkjet method, screen (stencil printing) method, offset (lithographic printing) method, It can be formed by a method such as a flexo (letterpress printing) method, a gravure method, or a microcontact method.
  • the island-like layer (layer containing a light-emitting layer) manufactured by the method for manufacturing a display device described below is not formed using a fine metal mask, but is formed by forming a light-emitting layer over one surface and then It is formed by processing using a lithography method. Therefore, it is possible to realize a high-definition display device or a display device with a high aperture ratio, which has been difficult to realize up to now. Furthermore, since the light-emitting layer can be made separately for each color, a display device with extremely brightness, high contrast, and high display quality can be realized. Furthermore, by providing a sacrificial layer over the light-emitting layer, damage to the light-emitting layer during the manufacturing process of a display device can be reduced, and reliability of the light-emitting element can be improved.
  • a display device is composed of three types of light-emitting elements: a light-emitting element that emits blue light, a light-emitting element that emits green light, and a light-emitting element that emits red light
  • the film formation of the light-emitting layer and the photolithography By repeating the processing three times, three types of island-shaped light emitting layers can be formed.
  • pixel electrodes 111R, 111G, 111B and a conductive layer 123 are formed on a substrate 151 on which transistors 205R, 205G, 205B, etc. (not shown) are provided. ( Figure 15A).
  • a sputtering method or a vacuum evaporation method can be used to form the conductive film that will become the pixel electrode.
  • the pixel electrodes 111R, 111G, and 111B and the conductive layer 123 can be formed by forming a resist mask on the conductive film by a photolithography process and then processing the conductive film.
  • a wet etching method and a dry etching method can be used for processing the conductive film.
  • Film 133Bf which will later become a layer 133B, is formed on the pixel electrodes 111R, 111G, and 111B (FIG. 15A).
  • Film 133Bf (later layer 133B) includes a light-emitting layer that emits blue light.
  • an example will be described in which an island-shaped EL layer of a light-emitting element that emits blue light is first formed, and then an island-shaped EL layer of a light-emitting element that emits light of another color is formed. show.
  • the pixel electrodes of the light emitting elements of the second and subsequent colors may be damaged by the previous step. As a result, the driving voltage of the light-emitting elements of the second and subsequent colors may become higher.
  • the display device of one embodiment of the present invention it is preferable to manufacture the display device from an island-shaped EL layer of a light-emitting element that emits light with the shortest wavelength (for example, a blue light-emitting element).
  • the island-shaped EL layers be produced in the order of blue, green, and red, or in the order of blue, red, and green.
  • the state of the interface between the pixel electrode and the EL layer in the blue light emitting element can be maintained in good condition, and the driving voltage of the blue light emitting element can be prevented from increasing. Furthermore, the life of the blue light emitting element can be extended and its reliability can be improved. Note that red and green light emitting elements are less affected by increases in driving voltage than blue light emitting elements, so the driving voltage of the entire display device can be lowered and reliability can be increased.
  • the order in which the island-shaped EL layers are produced is not limited to the above, and may be, for example, in the order of red, green, and blue.
  • the film 133Bf is not formed on the conductive layer 123.
  • the film 133Bf can be formed only in a desired region.
  • a light emitting element can be manufactured through a relatively simple process.
  • the heat resistance temperature of each compound contained in the film 133Bf is preferably 100°C or more and 180°C or less, preferably 120°C or more and 180°C or less, and more preferably 140°C or more and 180°C or less.
  • the reliability of the light emitting element can be improved.
  • the upper limit of temperature allowed in the manufacturing process of a display device can be increased. Therefore, the range of selection of materials and forming methods used in the display device can be expanded, and yield and reliability can be improved.
  • the heat-resistant temperature may be, for example, any one of the glass transition point, softening point, melting point, thermal decomposition temperature, and 5% weight loss temperature, preferably the lowest temperature among these.
  • the film 133Bf can be formed by, for example, a vapor deposition method, specifically, a vacuum vapor deposition method. Further, the film 133Bf may be formed by a method such as a transfer method, a printing method, an inkjet method, or a coating method.
  • a sacrificial layer 118B is formed on the film 133Bf and the conductive layer 123 (FIG. 15A).
  • the sacrificial layer 118B can be formed by forming a resist mask on the film to be the sacrificial layer 118B by a photolithography process and then processing the film.
  • the sacrificial layer 118B is preferably provided so as to cover each end of the pixel electrodes 111R, 111G, and 111B.
  • the end of the layer 133B to be formed in a later step is located outside the end of the pixel electrode 111B. Since the entire upper surface of the pixel electrode 111B can be used as a light emitting region, the aperture ratio of the pixel can be increased. Further, since the end of the layer 133B may be damaged in a step after forming the layer 133B, it is preferable to be located outside the end of the pixel electrode 111B, that is, not to use it as a light emitting region. Thereby, variations in characteristics of the light emitting elements can be suppressed and reliability can be improved.
  • each step after forming the layer 133B can be performed in a state where the pixel electrode 111B is not exposed. If the end of the pixel electrode 111B is exposed, corrosion may occur during an etching process or the like. By suppressing corrosion of the pixel electrode 111B, the yield and characteristics of the light emitting element can be improved.
  • the sacrificial layer 118B is also provided at a position overlapping with the conductive layer 123. This can prevent the conductive layer 123 from being damaged during the manufacturing process of the display device.
  • a film that has high resistance to the processing conditions of the film 133Bf specifically, a film that can increase the etching selectivity with respect to the film 133Bf, is used.
  • the sacrificial layer 118B is formed at a temperature lower than the allowable temperature limit of each compound included in the film 133Bf.
  • the substrate temperature when forming the sacrificial layer 118B is typically 200°C or lower, preferably 150°C or lower, more preferably 120°C or lower, more preferably 100°C or lower, and still more preferably 80°C or lower. It is.
  • the temperature limit of the compound included in the film 133Bf is high because the temperature at which the sacrificial layer 118B is formed can be increased.
  • the substrate temperature when forming the sacrificial layer 118B can be set to 100° C. or higher, 120° C. or higher, or 140° C. or higher.
  • a sputtering method for example, a sputtering method, an ALD method (including a thermal ALD method and a PEALD method), a CVD method, or a vacuum evaporation method can be used.
  • the film may be formed using the wet film forming method described above.
  • the sacrificial layer 118B (if the sacrificial layer 118B has a layered structure, the layer provided in contact with the film 133Bf) is preferably formed using a formation method that causes less damage to the film 133Bf. For example, it is preferable to use an ALD method or a vacuum evaporation method rather than a sputtering method.
  • the sacrificial layer 118B can be processed by a wet etching method or a dry etching method.
  • the sacrificial layer 118B is preferably processed by anisotropic etching.
  • the wet etching method By using the wet etching method, it is possible to reduce damage to the film 133Bf when processing the sacrificial layer 118B, compared to when using the dry etching method.
  • a developer for example, a developer, a tetramethylammonium hydroxide (TMAH) aqueous solution, dilute hydrofluoric acid, oxalic acid, phosphoric acid, acetic acid, nitric acid, or a mixed solution containing two or more of these can be used.
  • TMAH tetramethylammonium hydroxide
  • a mixed acid chemical solution containing water, phosphoric acid, dilute hydrofluoric acid, and nitric acid may be used.
  • the chemical solution used in the wet etching process may be alkaline or acidic.
  • the sacrificial layer 118B for example, one or more of a metal film, an alloy film, a metal oxide film, a semiconductor film, an inorganic insulating film, and an organic insulating film can be used.
  • the sacrificial layer 118B includes, for example, a metal material such as gold, silver, platinum, magnesium, nickel, tungsten, chromium, molybdenum, iron, cobalt, copper, palladium, titanium, aluminum, yttrium, zirconium, and tantalum, or the metal. Alloy materials including materials can be used.
  • the sacrificial layer 118B includes In-Ga-Zn oxide, indium oxide, In-Zn oxide, In-Sn oxide, indium titanium oxide (In-Ti oxide), and indium tin zinc oxide (In-Sn -Zn oxide), indium titanium zinc oxide (In-Ti-Zn oxide), indium gallium tin zinc oxide (In-Ga-Sn-Zn oxide), and indium tin oxide containing silicon. objects can be used.
  • the element M is aluminum, silicon, boron, yttrium, copper, vanadium, beryllium, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, hafnium, tantalum, tungsten
  • M is aluminum, silicon, boron, yttrium, copper, vanadium, beryllium, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, hafnium, tantalum, tungsten
  • a semiconductor material such as silicon or germanium can be used as a material that is highly compatible with semiconductor manufacturing processes.
  • oxides or nitrides of the above semiconductor materials can be used.
  • a nonmetallic material such as carbon or a compound thereof can be used.
  • metals such as titanium, tantalum, tungsten, chromium, and aluminum, or alloys containing one or more of these may be used.
  • oxides containing the above metals, such as titanium oxide or chromium oxide, or nitrides, such as titanium nitride, chromium nitride, or tantalum nitride, can be used.
  • various inorganic insulating films that can be used for the protective layer 131 can be used as the sacrificial layer 118B.
  • an oxide insulating film is preferable because it has higher adhesion to the film 133Bf than a nitride insulating film.
  • an inorganic insulating material such as aluminum oxide, hafnium oxide, silicon oxide, etc. can be used for the sacrificial layer 118B.
  • an aluminum oxide film can be formed using, for example, an ALD method. It is preferable to use the ALD method because damage to the underlying layer (particularly the film 133Bf) can be reduced.
  • an inorganic insulating film for example, an aluminum oxide film
  • an inorganic film for example, an In-Ga-Zn oxide film, a silicon film, or a tungsten film
  • the same inorganic insulating film can be used for both the sacrificial layer 118B and the insulating layer 125 that will be formed later.
  • an aluminum oxide film formed using an ALD method can be used for both the sacrificial layer 118B and the insulating layer 125.
  • the same film forming conditions may be applied to the sacrificial layer 118B and the insulating layer 125, or different film forming conditions may be applied to the sacrificial layer 118B and the insulating layer 125.
  • the sacrificial layer 118B can be an insulating layer with high barrier properties against at least one of water and oxygen.
  • the sacrificial layer 118B is a layer that will be mostly or completely removed in a later step, it is preferably easy to process. Therefore, the sacrificial layer 118B is preferably formed under conditions where the substrate temperature during film formation is lower than that of the insulating layer 125.
  • An organic material may be used for the sacrificial layer 118B.
  • a material that can be dissolved in a solvent that is chemically stable for at least the film located at the top of the film 133Bf may be used.
  • materials that dissolve in water or alcohol can be suitably used.
  • the material be dissolved in a solvent such as water or alcohol, applied by a wet film forming method, and then heat treated to evaporate the solvent. At this time, by performing heat treatment under a reduced pressure atmosphere, the solvent can be removed at low temperature and in a short time, so thermal damage to the film 133Bf can be reduced, which is preferable.
  • the sacrificial layer 118B is made of an organic resin such as polyvinyl alcohol (PVA), polyvinyl butyral, polyvinylpyrrolidone, polyethylene glycol, polyglycerin, pullulan, water-soluble cellulose, alcohol-soluble polyamide resin, or fluororesin such as perfluoropolymer. may also be used.
  • PVA polyvinyl alcohol
  • polyvinyl butyral polyvinylpyrrolidone
  • polyethylene glycol polyglycerin
  • pullulan polyethylene glycol
  • polyglycerin polyglycerin
  • pullulan polyethylene glycol
  • pullulan polyglycerin
  • water-soluble cellulose water-soluble cellulose
  • alcohol-soluble polyamide resin or fluororesin such as perfluoropolymer.
  • an organic film e.g., PVA film
  • an inorganic film e.g., silicon nitride film
  • part of the sacrificial film may remain as a sacrificial layer.
  • the film 133Bf is processed to form a layer 133B (FIG. 15B).
  • the stacked structure of the layer 133B and the sacrificial layer 118B remains on the pixel electrode 111B. Further, the pixel electrode 111R and the pixel electrode 111G are exposed. Further, in a region corresponding to the connection portion 140, the sacrificial layer 118B remains on the conductive layer 123.
  • the processing of the film 133Bf is preferably performed by anisotropic etching.
  • anisotropic dry etching is preferred.
  • wet etching may be used.
  • the steps of forming the film 133Bf, the sacrificial layer 118B, and the same steps as the layer 133B are repeated twice by changing at least the light-emitting substance, so that the layer 133R.
  • a stacked structure of a sacrificial layer 118R is formed, and a stacked structure of a layer 133G and a sacrificial layer 118G is formed on the pixel electrode 111G (FIG. 15C).
  • the layer 133R is formed to include a light emitting layer that emits red light
  • the layer 133G is formed to include a light emitting layer that emits green light.
  • Materials that can be used for the sacrificial layer 118B can be used for the sacrificial layers 118R and 118G, and the same material or different materials may be used for both.
  • the side surfaces of the layers 133B, 133G, and 133R are preferably perpendicular or approximately perpendicular to the surface on which they are formed.
  • the angle between the surface to be formed and these side surfaces be 60 degrees or more and 90 degrees or less.
  • the distance between two adjacent layers 133B, 133G, and 133R formed using the photolithography method is 8 ⁇ m or less, 5 ⁇ m or less, 3 ⁇ m or less, 2 ⁇ m or less, or 1 ⁇ m or less. It can be narrowed down to Here, the distance can be defined as, for example, the distance between two adjacent opposing ends of the layer 133B, the layer 133G, and the layer 133R. In this way, by narrowing the distance between the island-shaped EL layers, a display device with high definition and a large aperture ratio can be provided.
  • an insulating film 125f that will later become the insulating layer 125 is formed so as to cover the pixel electrode, the layer 133B, the layer 133G, the layer 133R, the sacrificial layer 118B, the sacrificial layer 118G, and the sacrificial layer 118R, and on the insulating film 125f.
  • An insulating layer 127 is formed (FIG. 15D).
  • the insulating film 125f it is preferable to form an insulating film having a thickness of 3 nm or more, 5 nm or more, or 10 nm or more, and 200 nm or less, 150 nm or less, 100 nm or less, or 50 nm or less.
  • the insulating film 125f is preferably formed using, for example, an ALD method. It is preferable to use the ALD method because damage to the film can be reduced and a film with high coverage can be formed. As the insulating film 125f, it is preferable to form an aluminum oxide film using the ALD method, for example.
  • the insulating film 125f may be formed using a sputtering method, a CVD method, or a plasma CVD method, which has a faster deposition rate than the ALD method. Thereby, a highly reliable display device can be manufactured with high productivity.
  • the insulating film that becomes the insulating layer 127 is preferably formed by the above-mentioned wet film forming method (for example, spin coating) using, for example, a photosensitive resin composition containing an acrylic resin.
  • a photosensitive resin composition containing an acrylic resin After film formation, it is preferable to perform heat treatment (also referred to as pre-baking) to remove the solvent contained in the insulating film.
  • heat treatment also referred to as pre-baking
  • a part of the insulating film is exposed to light by irradiating visible light or ultraviolet rays.
  • development is performed to remove the exposed area of the insulating film.
  • heat treatment also referred to as post-bake
  • an insulating layer 127 shown in FIG. 15D can be formed.
  • the shape of the insulating layer 127 is not limited to the shape shown in FIG. 15D.
  • the upper surface of the insulating layer 127 may have one or more of a convex curved surface, a concave curved surface, and a flat surface.
  • the insulating layer 127 may cover the side surface of at least one end of the insulating layer 125, the sacrificial layer 118B, the sacrificial layer 118G, and the sacrificial layer 118R.
  • etching is performed using the insulating layer 127 as a mask to remove the insulating film 125f and parts of the sacrificial layers 118B, 118G, and 118R.
  • openings are formed in each of the sacrificial layers 118B, 118G, and 118R, and the upper surfaces of the layers 133G, 133G, 133R, and the conductive layer 123 are exposed.
  • sacrificial layers 118B, 118G, and 118R may remain at positions overlapping with the insulating layer 127 and the insulating layer 125 (see sacrificial layers 119B, 119G, and 119R).
  • the etching process can be performed by dry etching or wet etching. Note that it is preferable if the insulating film 125f is formed using the same material as the sacrificial layers 118B, 118G, and 118R because the etching process can be performed at once.
  • the portions divided into the common layer 114 and the common electrode 115 are created between each light emitting element. It is possible to suppress the occurrence of connection failures caused by , and increases in electrical resistance caused by locally thinner parts. Thereby, the display device of one embodiment of the present invention can improve display quality.
  • a common layer 114 and a common electrode 115 are formed in this order on the insulating layer 127, layer 133B, layer 133G, and layer 133R (FIG. 15F).
  • the common layer 114 can be formed by a method such as a vapor deposition method (including a vacuum vapor deposition method), a transfer method, a printing method, an inkjet method, a coating method, or the like.
  • the common electrode 115 for example, a sputtering method or a vacuum evaporation method can be used. Alternatively, a film formed by vapor deposition and a film formed by sputtering may be stacked.
  • the island-shaped layer 133B, the island-shaped layer 133G, and the island-shaped layer 133R are not formed using a fine metal mask. Since it is formed by forming a film over one surface and then processing it, it is possible to form an island-like layer with a uniform thickness. Then, a high-definition display device or a display device with a high aperture ratio can be realized. Furthermore, even if the definition or aperture ratio is high and the distance between subpixels is extremely short, it is possible to suppress the layers 133B, 133G, and 133R from coming into contact with each other in adjacent subpixels. Therefore, generation of leakage current between subpixels can be suppressed. Thereby, unintended light emission due to crosstalk can be prevented, and a display device with extremely high contrast can be realized.
  • the display device of one embodiment of the present invention can achieve both high definition and high display quality.
  • the above is a description of an example of a method for manufacturing a display device.
  • This embodiment can be implemented by appropriately combining at least a part of it with other embodiments described in this specification.
  • the electronic device of this embodiment includes the display device of one embodiment of the present invention in the display portion.
  • the display device of one embodiment of the present invention can easily achieve high definition and high resolution. Therefore, it can be used in display units of various electronic devices.
  • the semiconductor device of one embodiment of the present invention can also be applied to a device other than a display portion of an electronic device.
  • a device other than a display portion of an electronic device For example, it is preferable to use the semiconductor device of one embodiment of the present invention in a control unit of an electronic device, because it enables lower power consumption.
  • Examples of electronic devices include television devices, desktop or notebook personal computers, computer monitors, digital signage, large game machines such as pachinko machines, and other electronic devices with relatively large screens, as well as digital devices. Examples include cameras, digital video cameras, digital photo frames, mobile phones, portable game machines, personal digital assistants, and sound playback devices.
  • the display device of one embodiment of the present invention can improve definition, so it can be suitably used for electronic devices having a relatively small display portion.
  • electronic devices include wristwatch- and bracelet-type information terminals (wearable devices), VR devices such as head-mounted displays, glasses-type AR devices, and MR devices.
  • wearable devices that can be attached to the body.
  • the display device of one embodiment of the present invention includes HD (number of pixels 1280 x 720), FHD (number of pixels 1920 x 1080), WQHD (number of pixels 2560 x 1440), WQXGA (number of pixels 2560 x 1600), and 4K (number of pixels It is preferable to have an extremely high resolution such as 3840 ⁇ 2160) or 8K (pixel count 7680 ⁇ 4320). In particular, it is preferable to set the resolution to 4K, 8K, or higher.
  • the pixel density (definition) in the display device of one embodiment of the present invention is preferably 100 ppi or more, preferably 300 ppi or more, more preferably 500 ppi or more, more preferably 1000 ppi or more, more preferably 2000 ppi or more, and 3000 ppi or more. More preferably, it is 5000 ppi or more, and even more preferably 7000 ppi or more.
  • the display device can support various screen ratios such as 1:1 (square), 4:3, 16:9, and 16:10.
  • the electronic device of this embodiment includes sensors (force, displacement, position, speed, acceleration, angular velocity, rotation speed, distance, light, liquid, magnetism, temperature, chemical substance, sound, time, hardness, electric field, current, voltage). , power, radiation, flow rate, humidity, tilt, vibration, odor, or infrared radiation).
  • the electronic device of this embodiment can have various functions. For example, functions that display various information (still images, videos, text images, etc.) on the display, touch panel functions, calendars, functions that display date or time, etc., functions that execute various software (programs), wireless communication. It can have a function, a function of reading a program or data recorded on a recording medium, etc.
  • FIGS. 16A to 16D An example of a wearable device that can be worn on the head will be described with reference to FIGS. 16A to 16D.
  • These wearable devices have at least one of a function of displaying AR content, a function of displaying VR content, a function of displaying SR content, and a function of displaying MR content.
  • an electronic device has a function of displaying at least one content such as AR, VR, SR, and MR, it becomes possible to enhance the user's immersive feeling.
  • the electronic device 700A shown in FIG. 16A and the electronic device 700B shown in FIG. 16B each include a pair of display panels 751, a pair of casings 721, a communication section (not shown), and a pair of mounting sections 723. It has a control section (not shown), an imaging section (not shown), a pair of optical members 753, a frame 757, and a pair of nose pads 758.
  • a display device of one embodiment of the present invention can be applied to the display panel 751. Therefore, an electronic device capable of extremely high definition display can be achieved.
  • the electronic device 700A and the electronic device 700B can each project the image displayed on the display panel 751 onto the display area 756 of the optical member 753. Since the optical member 753 has translucency, the user can see the image displayed in the display area superimposed on the transmitted image visually recognized through the optical member 753. Therefore, the electronic device 700A and the electronic device 700B are each electronic devices capable of AR display.
  • the electronic device 700A and the electronic device 700B may be provided with a camera capable of capturing an image of the front as an imaging unit. Further, the electronic device 700A and the electronic device 700B are each equipped with an acceleration sensor such as a gyro sensor to detect the direction of the user's head and display an image corresponding to the direction in the display area 756. You can also.
  • an acceleration sensor such as a gyro sensor to detect the direction of the user's head and display an image corresponding to the direction in the display area 756. You can also.
  • the communication unit has a wireless communication device, and can supply video signals and the like through the wireless communication device.
  • a connector to which a cable to which a video signal and a power supply potential are supplied may be connected may be provided.
  • the electronic device 700A and the electronic device 700B are provided with batteries, and can be charged wirelessly and/or by wire.
  • the housing 721 may be provided with a touch sensor module.
  • the touch sensor module has a function of detecting that the outer surface of the housing 721 is touched.
  • the touch sensor module can detect a user's tap operation, slide operation, etc., and execute various processes. For example, a tap operation can be used to pause or restart a video, and a slide operation can be used to fast forward or rewind. Further, by providing a touch sensor module in each of the two housings 721, the range of operations can be expanded.
  • touch sensors can be applied as the touch sensor module.
  • various methods such as a capacitance method, a resistive film method, an infrared method, an electromagnetic induction method, a surface acoustic wave method, an optical method, etc. can be adopted.
  • a photoelectric conversion element When using an optical touch sensor, a photoelectric conversion element can be used as the light receiving element.
  • the active layer of the photoelectric conversion element one or both of an inorganic semiconductor and an organic semiconductor can be used.
  • the electronic device 800A shown in FIG. 16C and the electronic device 800B shown in FIG. 16D each include a pair of display sections 820, a housing 821, a communication section 822, a pair of mounting sections 823, and a control section 824. It has a pair of imaging units 825 and a pair of lenses 832.
  • a display device of one embodiment of the present invention can be applied to the display portion 820. Therefore, an electronic device capable of extremely high definition display can be achieved. This allows the user to feel highly immersive.
  • the display section 820 is provided inside the housing 821 at a position where it can be viewed through the lens 832. Furthermore, by displaying different images on the pair of display units 820, three-dimensional display using parallax can be performed.
  • the electronic device 800A and the electronic device 800B can each be said to be an electronic device for VR.
  • a user wearing the electronic device 800A or the electronic device 800B can view the image displayed on the display unit 820 through the lens 832.
  • the electronic device 800A and the electronic device 800B each have a mechanism that can adjust the left and right positions of the lens 832 and the display unit 820 so that they are in optimal positions according to the position of the user's eyes. It is preferable that you do so. Further, it is preferable to have a mechanism for adjusting the focus by changing the distance between the lens 832 and the display section 820.
  • the mounting portion 823 allows the user to wear the electronic device 800A or the electronic device 800B on the head.
  • the shape is illustrated as a temple (also referred to as a temple) of glasses, but the shape is not limited to this.
  • the mounting portion 823 only needs to be able to be worn by the user, and may have a helmet-shaped or band-shaped shape, for example.
  • the imaging unit 825 has a function of acquiring external information.
  • the data acquired by the imaging unit 825 can be output to the display unit 820.
  • An image sensor can be used for the imaging unit 825.
  • a plurality of cameras may be provided so as to be able to handle a plurality of angles of view such as telephoto and wide angle.
  • a distance measuring sensor (hereinafter also referred to as a detection unit) that can measure the distance to an object may be provided. That is, the imaging unit 825 is one aspect of a detection unit.
  • the detection unit for example, an image sensor or a distance image sensor such as LIDAR (Light Detection and Ranging) can be used. By using the image obtained by the camera and the image obtained by the distance image sensor, more information can be obtained and more precise gesture operations can be performed.
  • LIDAR Light Detection and Ranging
  • the electronic device 800A may have a vibration mechanism that functions as a bone conduction earphone.
  • a configuration having the vibration mechanism can be applied to one or more of the display section 820, the housing 821, and the mounting section 823.
  • the user can enjoy video and audio simply by wearing the electronic device 800A without requiring additional audio equipment such as headphones, earphones, or speakers.
  • the electronic device 800A and the electronic device 800B may each have an input terminal.
  • a cable for supplying a video signal from a video output device or the like and power for charging a battery provided in the electronic device can be connected to the input terminal.
  • An electronic device may have a function of wirelessly communicating with the earphone 750.
  • Earphone 750 includes a communication unit (not shown) and has a wireless communication function.
  • Earphone 750 can receive information (eg, audio data) from an electronic device using a wireless communication function.
  • electronic device 700A shown in FIG. 16A has a function of transmitting information to earphone 750 using a wireless communication function.
  • electronic device 800A shown in FIG. 16C has a function of transmitting information to earphone 750 using a wireless communication function.
  • the electronic device may have an earphone section.
  • Electronic device 700B shown in FIG. 16B includes earphone section 727.
  • the earphone section 727 and the control section can be configured to be connected to each other by wire.
  • a portion of the wiring connecting the earphone section 727 and the control section may be arranged inside the housing 721 or the mounting section 723.
  • the electronic device 800B shown in FIG. 16D has an earphone section 827.
  • the earphone section 827 and the control section 824 can be configured to be connected to each other by wire.
  • a part of the wiring connecting the earphone section 827 and the control section 824 may be arranged inside the housing 821 or the mounting section 823.
  • the earphone section 827 and the mounting section 823 may include magnets. Thereby, the earphone part 827 can be fixed to the mounting part 823 by magnetic force, which is preferable because storage becomes easy.
  • the electronic device may have an audio output terminal to which earphones, headphones, or the like can be connected. Further, the electronic device may have one or both of an audio input terminal and an audio input mechanism.
  • the audio input mechanism for example, a sound collecting device such as a microphone can be used.
  • the electronic device may be provided with a function as a so-called headset.
  • the electronic devices of one embodiment of the present invention include both glasses type (electronic device 700A and electronic device 700B, etc.) and goggle type (electronic device 800A and electronic device 800B, etc.). suitable.
  • An electronic device can transmit information to earphones by wire or wirelessly.
  • An electronic device 6500 shown in FIG. 17A is a portable information terminal that can be used as a smartphone.
  • the electronic device 6500 includes a housing 6501, a display portion 6502, a power button 6503, a button 6504, a speaker 6505, a microphone 6506, a camera 6507, a light source 6508, and the like.
  • the display section 6502 has a touch panel function.
  • a display device of one embodiment of the present invention can be applied to the display portion 6502.
  • FIG. 17B is a schematic cross-sectional view including the end of the housing 6501 on the microphone 6506 side.
  • a light-transmitting protective member 6510 is provided on the display surface side of the housing 6501, and a display panel 6511, an optical member 6512, a touch sensor panel 6513, and a print are placed in a space surrounded by the housing 6501 and the protective member 6510.
  • a board 6517, a battery 6518, and the like are arranged.
  • a display panel 6511, an optical member 6512, and a touch sensor panel 6513 are fixed to the protective member 6510 with an adhesive layer (not shown).
  • a part of the display panel 6511 is folded back, and an FPC 6515 is connected to the folded part.
  • An IC6516 is mounted on the FPC6515.
  • the FPC 6515 is connected to a terminal provided on a printed circuit board 6517.
  • a flexible display of one embodiment of the present invention can be applied to the display panel 6511. Therefore, extremely lightweight electronic equipment can be realized. Furthermore, since the display panel 6511 is extremely thin, a large-capacity battery 6518 can be mounted while suppressing the thickness of the electronic device. Moreover, by folding back a part of the display panel 6511 and arranging the connection part with the FPC 6515 on the back side of the pixel part, an electronic device with a narrow frame can be realized.
  • FIG. 17C shows an example of a television device.
  • a television device 7100 has a display section 7000 built into a housing 7101. Here, a configuration in which a casing 7101 is supported by a stand 7103 is shown.
  • a display device of one embodiment of the present invention can be applied to the display portion 7000.
  • the television device 7100 shown in FIG. 17C can be operated using an operation switch included in the housing 7101 and a separate remote controller 7111.
  • the display section 7000 may include a touch sensor, and the television device 7100 may be operated by touching the display section 7000 with a finger or the like.
  • the remote control device 7111 may have a display unit that displays information output from the remote control device 7111. Using operation keys or a touch panel included in the remote controller 7111, the channel and volume can be controlled, and the video displayed on the display section 7000 can be controlled.
  • the television device 7100 is configured to include a receiver, a modem, and the like.
  • the receiver can receive general television broadcasts. Also, by connecting to a wired or wireless communication network via a modem, information can be communicated in one direction (from the sender to the receiver) or in both directions (between the sender and the receiver, or between the receivers, etc.). is also possible.
  • FIG. 17D shows an example of a notebook personal computer.
  • the notebook personal computer 7200 includes a housing 7211, a keyboard 7212, a pointing device 7213, an external connection port 7214, and the like.
  • a display unit 7000 is incorporated into the housing 7211.
  • a display device of one embodiment of the present invention can be applied to the display portion 7000.
  • FIGS. 17E and 17F An example of digital signage is shown in FIGS. 17E and 17F.
  • the digital signage 7300 shown in FIG. 17E includes a housing 7301, a display section 7000, a speaker 7303, and the like. Furthermore, it can have an LED lamp, an operation key (including a power switch or an operation switch), a connection terminal, various sensors, a microphone, and the like.
  • FIG. 17F shows a digital signage 7400 attached to a cylindrical pillar 7401.
  • Digital signage 7400 includes a display section 7000 provided along the curved surface of pillar 7401.
  • the display device of one embodiment of the present invention can be applied to the display portion 7000.
  • the wider the display section 7000 is, the more information that can be provided at once can be increased. Furthermore, the wider the display section 7000 is, the easier it is to attract people's attention, and for example, the effectiveness of advertising can be increased.
  • a touch panel By applying a touch panel to the display section 7000, not only images or videos can be displayed on the display section 7000, but also the user can operate it intuitively, which is preferable. Further, when used for providing information such as route information or traffic information, usability can be improved by intuitive operation.
  • the digital signage 7300 or the digital signage 7400 can cooperate with an information terminal 7311 or an information terminal 7411 such as a smartphone owned by the user by wireless communication.
  • advertisement information displayed on the display unit 7000 can be displayed on the screen of the information terminal 7311 or the information terminal 7411.
  • the display on the display unit 7000 can be switched.
  • the digital signage 7300 or the digital signage 7400 can execute a game using the screen of the information terminal 7311 or the information terminal 7411 as an operation means (controller). This allows an unspecified number of users to participate in and enjoy the game at the same time.
  • the electronic device shown in FIGS. 18A to 18G includes a housing 9000, a display section 9001, a speaker 9003, an operation key 9005 (including a power switch or an operation switch), a connection terminal 9006, and a sensor 9007 (force, displacement, position, speed). , acceleration, angular velocity, rotation speed, distance, light, liquid, magnetism, temperature, chemical substances, sound, time, hardness, electric field, current, voltage, power, radiation, flow rate, humidity, tilt, vibration, odor, or infrared rays. , detection, or measurement), a microphone 9008, and the like.
  • the display device of one embodiment of the present invention can be applied to the display portion 9001.
  • the electronic devices shown in FIGS. 18A to 18G have various functions. For example, functions that display various information (still images, videos, text images, etc.) on the display, touch panel functions, calendars, functions that display date or time, etc., functions that control processing using various software (programs), It can have a wireless communication function, a function of reading and processing a program or data recorded on a recording medium, and the like. Note that the functions of the electronic device are not limited to these, and can have various functions.
  • the electronic device may have multiple display units.
  • the electronic device may be equipped with a camera, etc., and may have the function of taking still images or videos and saving them on a recording medium (external or built-in to the camera), the function of displaying the taken images on a display unit, etc. .
  • FIGS. 18A to 18G The details of the electronic device shown in FIGS. 18A to 18G will be described below.
  • FIG. 18A is a perspective view showing the mobile information terminal 9101.
  • the mobile information terminal 9101 can be used as, for example, a smartphone.
  • the mobile information terminal 9101 may be provided with a speaker 9003, a connection terminal 9006, a sensor 9007, and the like.
  • the mobile information terminal 9101 can display text and image information on multiple surfaces thereof.
  • FIG. 18A shows an example in which three icons 9050 are displayed.
  • information 9051 indicated by a dashed rectangle can also be displayed on another surface of the display section 9001. Examples of the information 9051 include notification of incoming e-mail, SNS, telephone, etc., title of e-mail or SNS, sender's name, date and time, remaining battery level, radio wave strength, and the like.
  • an icon 9050 or the like may be displayed at the position where the information 9051 is displayed.
  • FIG. 18B is a perspective view showing the mobile information terminal 9102.
  • the mobile information terminal 9102 has a function of displaying information on three or more sides of the display unit 9001.
  • information 9052, information 9053, and information 9054 are displayed on different surfaces.
  • the user can check the information 9053 displayed at a position visible from above the mobile information terminal 9102 while storing the mobile information terminal 9102 in the chest pocket of clothes. The user can check the display without taking out the mobile information terminal 9102 from his pocket and determine, for example, whether to accept a call.
  • FIG. 18C is a perspective view showing the tablet terminal 9103.
  • the tablet terminal 9103 is capable of executing various applications such as mobile phone calls, e-mail, text viewing and creation, music playback, Internet communication, and computer games, for example.
  • the tablet terminal 9103 has a display section 9001, a camera 9002, a microphone 9008, and a speaker 9003 on the front of the housing 9000, an operation key 9005 as an operation button on the left side of the housing 9000, and a connection terminal on the bottom. 9006.
  • FIG. 18D is a perspective view showing a wristwatch-type mobile information terminal 9200.
  • the mobile information terminal 9200 can be used, for example, as a smart watch (registered trademark).
  • the display portion 9001 is provided with a curved display surface, and can perform display along the curved display surface.
  • the mobile information terminal 9200 can also make a hands-free call by mutually communicating with a headset capable of wireless communication, for example.
  • the mobile information terminal 9200 can also perform data transmission and charging with other information terminals through the connection terminal 9006. Note that the charging operation may be performed by wireless power supply.
  • FIGS. 18E and 18G are perspective views showing a foldable portable information terminal 9201. Further, FIG. 18E is a perspective view of the portable information terminal 9201 in an unfolded state, FIG. 18G is a folded state, and FIG. 18F is a perspective view of a state in the middle of changing from one of FIGS. 18E and 18G to the other.
  • the portable information terminal 9201 has excellent portability in the folded state, and has excellent display visibility due to its wide seamless display area in the unfolded state.
  • a display portion 9001 included in a mobile information terminal 9201 is supported by three casings 9000 connected by hinges 9055. For example, the display portion 9001 can be bent with a radius of curvature of 0.1 mm or more and 150 mm or less.
  • This embodiment can be implemented by appropriately combining at least a part of it with other embodiments described in this specification.

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PCT/IB2023/058643 2022-09-08 2023-09-01 半導体装置、およびその作製方法 Ceased WO2024052773A1 (ja)

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JPH03291973A (ja) * 1990-04-09 1991-12-24 Fuji Xerox Co Ltd 薄膜半導体装置
JP2016146422A (ja) * 2015-02-09 2016-08-12 株式会社ジャパンディスプレイ 表示装置
JP2016149552A (ja) * 2015-02-11 2016-08-18 株式会社半導体エネルギー研究所 半導体装置、および半導体装置の作製方法
JP2017167452A (ja) * 2016-03-18 2017-09-21 株式会社ジャパンディスプレイ 表示装置

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KR20250028505A (ko) 2014-09-12 2025-02-28 가부시키가이샤 한도오따이 에네루기 켄큐쇼 표시 장치

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03291973A (ja) * 1990-04-09 1991-12-24 Fuji Xerox Co Ltd 薄膜半導体装置
JP2016146422A (ja) * 2015-02-09 2016-08-12 株式会社ジャパンディスプレイ 表示装置
JP2016149552A (ja) * 2015-02-11 2016-08-18 株式会社半導体エネルギー研究所 半導体装置、および半導体装置の作製方法
JP2017167452A (ja) * 2016-03-18 2017-09-21 株式会社ジャパンディスプレイ 表示装置

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