WO2023282160A1 - 香料組成物 - Google Patents
香料組成物 Download PDFInfo
- Publication number
- WO2023282160A1 WO2023282160A1 PCT/JP2022/026111 JP2022026111W WO2023282160A1 WO 2023282160 A1 WO2023282160 A1 WO 2023282160A1 JP 2022026111 W JP2022026111 W JP 2022026111W WO 2023282160 A1 WO2023282160 A1 WO 2023282160A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- oil
- component group
- methyl
- ethyl
- fragrance
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 83
- 239000002304 perfume Substances 0.000 title claims abstract description 28
- 230000035807 sensation Effects 0.000 claims abstract description 19
- 239000003205 fragrance Substances 0.000 claims description 70
- 125000003118 aryl group Chemical group 0.000 claims description 24
- -1 L-hydroxycitronellal Chemical compound 0.000 claims description 19
- 230000000694 effects Effects 0.000 claims description 17
- KOCVACNWDMSLBM-UHFFFAOYSA-N 4-(Ethoxymethyl)-2-methoxyphenol Chemical compound CCOCC1=CC=C(O)C(OC)=C1 KOCVACNWDMSLBM-UHFFFAOYSA-N 0.000 claims description 14
- 239000001525 mentha piperita l. herb oil Substances 0.000 claims description 13
- 235000019477 peppermint oil Nutrition 0.000 claims description 13
- XHXUANMFYXWVNG-ADEWGFFLSA-N (-)-Menthyl acetate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(C)=O XHXUANMFYXWVNG-ADEWGFFLSA-N 0.000 claims description 12
- OALYTRUKMRCXNH-UHFFFAOYSA-N 5-pentyloxolan-2-one Chemical compound CCCCCC1CCC(=O)O1 OALYTRUKMRCXNH-UHFFFAOYSA-N 0.000 claims description 12
- WTWBUQJHJGUZCY-UHFFFAOYSA-N cuminaldehyde Chemical compound CC(C)C1=CC=C(C=O)C=C1 WTWBUQJHJGUZCY-UHFFFAOYSA-N 0.000 claims description 12
- ZYTMANIQRDEHIO-KXUCPTDWSA-N isopulegol Chemical compound C[C@@H]1CC[C@@H](C(C)=C)[C@H](O)C1 ZYTMANIQRDEHIO-KXUCPTDWSA-N 0.000 claims description 12
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims description 12
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 claims description 12
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 claims description 12
- 238000010792 warming Methods 0.000 claims description 12
- NPNUFJAVOOONJE-ZIAGYGMSSA-N β-(E)-Caryophyllene Chemical compound C1CC(C)=CCCC(=C)[C@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-ZIAGYGMSSA-N 0.000 claims description 12
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 claims description 9
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 claims description 9
- VLDFMKOUUQYFGF-UHFFFAOYSA-N 4-(butoxymethyl)-2-methoxyphenol Chemical compound CCCCOCC1=CC=C(O)C(OC)=C1 VLDFMKOUUQYFGF-UHFFFAOYSA-N 0.000 claims description 8
- 230000035597 cooling sensation Effects 0.000 claims description 8
- 230000000638 stimulation Effects 0.000 claims description 8
- 229940078465 vanillyl butyl ether Drugs 0.000 claims description 8
- WBNJCBPWAMSDMR-YFVJMOTDSA-N (2e,6e)-3,7,11-trimethyldodeca-2,6-dienal Chemical compound CC(C)CCC\C(C)=C\CC\C(C)=C\C=O WBNJCBPWAMSDMR-YFVJMOTDSA-N 0.000 claims description 7
- MTVBNJVZZAQKRV-DJTWPOEFSA-N (e)-2-methyl-4-[(1r)-2,2,3-trimethylcyclopent-3-en-1-yl]but-2-en-1-ol Chemical compound OCC(/C)=C/C[C@H]1CC=C(C)C1(C)C MTVBNJVZZAQKRV-DJTWPOEFSA-N 0.000 claims description 7
- BVDMQAQCEBGIJR-UHFFFAOYSA-N 1-(2,2,6-trimethylcyclohexyl)hexan-3-ol Chemical compound CCCC(O)CCC1C(C)CCCC1(C)C BVDMQAQCEBGIJR-UHFFFAOYSA-N 0.000 claims description 7
- RQXTZKGDMNIWJF-UHFFFAOYSA-N 2-butan-2-ylcyclohexan-1-one Chemical compound CCC(C)C1CCCCC1=O RQXTZKGDMNIWJF-UHFFFAOYSA-N 0.000 claims description 7
- ABRIMXGLNHCLIP-VURMDHGXSA-N 5-Cyclohexadecenone Chemical compound O=C1CCCCCCCCCC\C=C/CCC1 ABRIMXGLNHCLIP-VURMDHGXSA-N 0.000 claims description 7
- KTTLFUWDFUJAKG-UHFFFAOYSA-N 5-methyl-5-sulfanylhexan-3-one Chemical compound CCC(=O)CC(C)(C)S KTTLFUWDFUJAKG-UHFFFAOYSA-N 0.000 claims description 7
- RVOKNSFEAOYULQ-UHFFFAOYSA-N 8-Mercapto-p-menthan-3-one Chemical compound CC1CCC(C(C)(C)S)C(=O)C1 RVOKNSFEAOYULQ-UHFFFAOYSA-N 0.000 claims description 7
- HZPKNSYIDSNZKW-UHFFFAOYSA-N Ethyl 2-methylpentanoate Chemical compound CCCC(C)C(=O)OCC HZPKNSYIDSNZKW-UHFFFAOYSA-N 0.000 claims description 7
- XRHCAGNSDHCHFJ-UHFFFAOYSA-N Ethylene brassylate Chemical compound O=C1CCCCCCCCCCCC(=O)OCCO1 XRHCAGNSDHCHFJ-UHFFFAOYSA-N 0.000 claims description 7
- ALHUZKCOMYUFRB-OAHLLOKOSA-N Muscone Chemical compound C[C@@H]1CCCCCCCCCCCCC(=O)C1 ALHUZKCOMYUFRB-OAHLLOKOSA-N 0.000 claims description 7
- 239000001279 citrus aurantifolia swingle expressed oil Substances 0.000 claims description 7
- TUEUDXZEBRMJEV-UWVGGRQHSA-N ethyl (1r,6s)-2,2,6-trimethylcyclohexane-1-carboxylate Chemical compound CCOC(=O)[C@@H]1[C@@H](C)CCCC1(C)C TUEUDXZEBRMJEV-UWVGGRQHSA-N 0.000 claims description 7
- 229940093468 ethylene brassylate Drugs 0.000 claims description 7
- 239000010649 ginger oil Substances 0.000 claims description 7
- ALHUZKCOMYUFRB-UHFFFAOYSA-N muskone Natural products CC1CCCCCCCCCCCCC(=O)C1 ALHUZKCOMYUFRB-UHFFFAOYSA-N 0.000 claims description 7
- 210000003928 nasal cavity Anatomy 0.000 claims description 7
- CZCBTSFUTPZVKJ-UHFFFAOYSA-N rose oxide Chemical compound CC1CCOC(C=C(C)C)C1 CZCBTSFUTPZVKJ-UHFFFAOYSA-N 0.000 claims description 7
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 claims description 6
- NFLGAXVYCFJBMK-RKDXNWHRSA-N (+)-isomenthone Natural products CC(C)[C@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-RKDXNWHRSA-N 0.000 claims description 6
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 claims description 6
- 239000001871 (1R,2R,5S)-5-methyl-2-prop-1-en-2-ylcyclohexan-1-ol Substances 0.000 claims description 6
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims description 6
- 229940098795 (3z)- 3-hexenyl acetate Drugs 0.000 claims description 6
- 239000001605 (5-methyl-2-propan-2-ylcyclohexyl) acetate Substances 0.000 claims description 6
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 claims description 6
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims description 6
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 claims description 6
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 claims description 6
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 claims description 6
- XHXUANMFYXWVNG-UHFFFAOYSA-N D-menthyl acetate Natural products CC(C)C1CCC(C)CC1OC(C)=O XHXUANMFYXWVNG-UHFFFAOYSA-N 0.000 claims description 6
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 claims description 6
- ZBJCYZPANVLBRK-UHFFFAOYSA-N Menthone 1,2-glyceryl ketal Chemical compound CC(C)C1CCC(C)CC11OC(CO)CO1 ZBJCYZPANVLBRK-UHFFFAOYSA-N 0.000 claims description 6
- AXMVYSVVTMKQSL-UHFFFAOYSA-N UNPD142122 Natural products OC1=CC=C(C=CC=O)C=C1O AXMVYSVVTMKQSL-UHFFFAOYSA-N 0.000 claims description 6
- UJNOLBSYLSYIBM-WISYIIOYSA-N [(1r,2s,5r)-5-methyl-2-propan-2-ylcyclohexyl] (2r)-2-hydroxypropanoate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(=O)[C@@H](C)O UJNOLBSYLSYIBM-WISYIIOYSA-N 0.000 claims description 6
- NPNUFJAVOOONJE-UHFFFAOYSA-N beta-cariophyllene Natural products C1CC(C)=CCCC(=C)C2CC(C)(C)C21 NPNUFJAVOOONJE-UHFFFAOYSA-N 0.000 claims description 6
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 claims description 6
- 229940116229 borneol Drugs 0.000 claims description 6
- SWUIQEBPZIHZQS-UHFFFAOYSA-N calone Chemical compound O1CC(=O)COC2=CC(C)=CC=C21 SWUIQEBPZIHZQS-UHFFFAOYSA-N 0.000 claims description 6
- NPNUFJAVOOONJE-UONOGXRCSA-N caryophyllene Natural products C1CC(C)=CCCC(=C)[C@@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-UONOGXRCSA-N 0.000 claims description 6
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 claims description 6
- 229940117916 cinnamic aldehyde Drugs 0.000 claims description 6
- NPFVOOAXDOBMCE-PLNGDYQASA-N cis-3-Hexenyl acetate Natural products CC\C=C/CCOC(C)=O NPFVOOAXDOBMCE-PLNGDYQASA-N 0.000 claims description 6
- RRGOKSYVAZDNKR-ARJAWSKDSA-M cis-3-hexenylacetate Chemical compound CC\C=C/CCCC([O-])=O RRGOKSYVAZDNKR-ARJAWSKDSA-M 0.000 claims description 6
- MZLGFRRNMCCNBB-UHFFFAOYSA-N deca-4,7-dienal Chemical compound CCC=CCC=CCCC=O MZLGFRRNMCCNBB-UHFFFAOYSA-N 0.000 claims description 6
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims description 6
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 claims description 6
- 229940093503 ethyl maltol Drugs 0.000 claims description 6
- 229940073505 ethyl vanillin Drugs 0.000 claims description 6
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Natural products CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 claims description 6
- 239000010642 eucalyptus oil Substances 0.000 claims description 6
- 229940044949 eucalyptus oil Drugs 0.000 claims description 6
- OALYTRUKMRCXNH-QMMMGPOBSA-N gamma-Nonalactone Natural products CCCCC[C@H]1CCC(=O)O1 OALYTRUKMRCXNH-QMMMGPOBSA-N 0.000 claims description 6
- UFLHIIWVXFIJGU-UHFFFAOYSA-N hex-3-en-1-ol Natural products CCC=CCCO UFLHIIWVXFIJGU-UHFFFAOYSA-N 0.000 claims description 6
- 229940095045 isopulegol Drugs 0.000 claims description 6
- 229930007744 linalool Natural products 0.000 claims description 6
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 claims description 6
- 239000001683 mentha spicata herb oil Substances 0.000 claims description 6
- 229930007503 menthone Natural products 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- ZYTMANIQRDEHIO-UHFFFAOYSA-N neo-Isopulegol Natural products CC1CCC(C(C)=C)C(O)C1 ZYTMANIQRDEHIO-UHFFFAOYSA-N 0.000 claims description 6
- 229940081310 piperonal Drugs 0.000 claims description 6
- 235000019721 spearmint oil Nutrition 0.000 claims description 6
- NPFVOOAXDOBMCE-UHFFFAOYSA-N trans-3-hexenyl acetate Natural products CCC=CCCOC(C)=O NPFVOOAXDOBMCE-UHFFFAOYSA-N 0.000 claims description 6
- 239000001926 citrus aurantium l. subsp. bergamia wright et arn. oil Substances 0.000 claims description 5
- 230000001965 increasing effect Effects 0.000 claims description 5
- 229960001047 methyl salicylate Drugs 0.000 claims description 3
- 230000008859 change Effects 0.000 abstract description 2
- 238000009472 formulation Methods 0.000 description 14
- 238000001816 cooling Methods 0.000 description 11
- 238000013329 compounding Methods 0.000 description 10
- 239000003599 detergent Substances 0.000 description 10
- 230000002093 peripheral effect Effects 0.000 description 9
- 239000007844 bleaching agent Substances 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 6
- 210000001331 nose Anatomy 0.000 description 5
- 238000009529 body temperature measurement Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 229940041616 menthol Drugs 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 235000007586 terpenes Nutrition 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- 206010016334 Feeling hot Diseases 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000003997 cyclic ketones Chemical class 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000002781 deodorant agent Substances 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- VSMOENVRRABVKN-UHFFFAOYSA-N oct-1-en-3-ol Chemical compound CCCCCC(O)C=C VSMOENVRRABVKN-UHFFFAOYSA-N 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 210000003051 thermoreceptor Anatomy 0.000 description 2
- 108091008689 thermoreceptors Proteins 0.000 description 2
- CRDAMVZIKSXKFV-FBXUGWQNSA-N (2-cis,6-cis)-farnesol Chemical compound CC(C)=CCC\C(C)=C/CC\C(C)=C/CO CRDAMVZIKSXKFV-FBXUGWQNSA-N 0.000 description 1
- 239000000260 (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol Substances 0.000 description 1
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 1
- FVUGZKDGWGKCFE-UHFFFAOYSA-N 1-(2,3,8,8-tetramethyl-1,3,4,5,6,7-hexahydronaphthalen-2-yl)ethanone Chemical compound CC1(C)CCCC2=C1CC(C(C)=O)(C)C(C)C2 FVUGZKDGWGKCFE-UHFFFAOYSA-N 0.000 description 1
- VSMOENVRRABVKN-MRVPVSSYSA-N 1-Octen-3-ol Natural products CCCCC[C@H](O)C=C VSMOENVRRABVKN-MRVPVSSYSA-N 0.000 description 1
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 description 1
- YDXQPTHHAPCTPP-UHFFFAOYSA-N 3-Octen-1-ol Natural products CCCCC=CCCO YDXQPTHHAPCTPP-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- 229940088601 alpha-terpineol Drugs 0.000 description 1
- RWZYAGGXGHYGMB-UHFFFAOYSA-N anthranilic acid Chemical class NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 1
- 150000003934 aromatic aldehydes Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 150000004648 butanoic acid derivatives Chemical class 0.000 description 1
- IRAQOCYXUMOFCW-CXTNEJHOSA-N cedrene Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@H]1C(C)=CC2 IRAQOCYXUMOFCW-CXTNEJHOSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- IRAQOCYXUMOFCW-UHFFFAOYSA-N di-epi-alpha-cedrene Natural products C1C23C(C)CCC3C(C)(C)C1C(C)=CC2 IRAQOCYXUMOFCW-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 229930002886 farnesol Natural products 0.000 description 1
- 229940043259 farnesol Drugs 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000009994 optical bleaching Methods 0.000 description 1
- 238000009896 oxidative bleaching Methods 0.000 description 1
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- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical class OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 108020003175 receptors Proteins 0.000 description 1
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- 239000007787 solid Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- CRDAMVZIKSXKFV-UHFFFAOYSA-N trans-Farnesol Natural products CC(C)=CCCC(C)=CCCC(C)=CCO CRDAMVZIKSXKFV-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Definitions
- the present invention relates to perfume compositions. Specifically, it relates to a perfume composition having sensory stimulation.
- organoleptic fragrance compositions include menthol, peppermint oil, vanillyl butyl ether, ginger oil, etc. (Patent Documents 1 to 3, Non-Patent Document 1 ) have been reported.
- Patent Literatures 1 to 3 and Non-Patent Literature 1 did not describe at all about imparting a warm or cold sensation and raising or lowering the skin temperature by sniffing from the nasal cavity.
- Fragrance compositions used for the purpose of imparting a cool and warm sensation are generally subjectively perceived by skin contact stimulation including the mouth, and do not lower the skin temperature even when in contact with the skin.
- receptors that respond to cold sensation have been cloned and the mechanism of action has been elucidated.
- physical cooling and components represented by menthol commonly activate the thermoreceptors on the skin surface, which excites the cold fibers and creates a sensation that the skin coated with menthol is cold. , it was known that the skin temperature did not drop.
- a similar thermoreceptor has been cloned for warmth, and it is known that a similar mechanism causes the feeling of warmth in the skin.
- the present inventors have investigated the increase or decrease in skin temperature due to non-contact with the skin of aromatic components.
- the inventors have completed the present invention by finding a solution consisting of the following configuration characterized in that
- the present invention includes the following contents.
- a fragrance composition that imparts a cool or warm sensation and lowers or raises skin temperature when sniffed from the nasal cavity.
- FIG. 1 is a diagram for explaining a method of skin temperature measurement.
- FIG. 2 is a graph showing the results of cold feeling: changes from the time when the nose tip skin temperature sample was presented.
- FIG. 3 is a diagram showing results of warmth sensation: change from the time of presenting the nose tip skin temperature sample.
- the fragrance composition of the present invention can impart a warm or cool sensation and raise or lower the skin temperature when sniffed from the nasal cavity.
- the perfume composition of the present invention which mainly imparts a cooling sensation and lowers skin temperature, preferably contains one or more selected from the following aromatic component group A, for example.
- aromatic component group A 2-sec-butylcyclohexanone, L-hydroxycitronellal, menthyl acetate, menthyl lactate, ethyl (1R,6S)-2,2,6-trimethylcyclohexanecarboxylate, borneol, ⁇ -caryophyllene, isopulegol, menthone, menthone glycerin Acetal, menthyl glyceryl ether, linalool, linalyl acetate, L-menthol, methyl salicylate, 7-methyl-2H-1,5-benzodioxepin-3(4H)-one, 5-cyclohexadecenone, peppermint oil, eucalyptus Oil, cis-3-hexenol, cis-3-he
- 2-sec-butylcyclohexanone, L-hydroxycitronellal, and ethyl (1R,6S)-2,2,6-trimethylcyclohexanecarboxylate are preferred.
- the fragrance of these fragrance components when used alone or in combination strongly evokes a particularly refreshing cool feeling, and the effect of lowering the skin temperature is remarkable.
- these aromatic component group A is contained in the fragrance composition of the present invention.
- the amount of these aromatic component group A blended in the perfume composition is preferably 0.1 to 100% by mass, more preferably 1.0 to 100% by mass, in order to exhibit the effects of the present invention. This is the preferred range.
- the fragrance component group A can be divided into the fragrance component group A (1) and the fragrance component group A (2), and one or more of each is preferably contained in the fragrance composition of the present invention.
- (Aroma component group A (1)) Isopulegol, L-menthol, menthyl acetate, menthyl lactate, menthone, menthone glycerin acetal, menthyl glyceryl ether, peppermint oil
- Aroma component group A (2) 2-sec-butylcyclohexanone, L-hydroxycitronellal, ethyl (1R,6S)-2,2,6-trimethylcyclohexanecarboxylate, 5-cyclohexadecenone, borneol, ⁇ -caryophyllene, linalool, linalyl acetate, salicylic acid Methyl, 7-methyl-2H-1,5-benzodioxepin-3(4H)-one, 5-cyclohexadec
- the mass ratio (A1)/(A2) between the content (A1) of the aromatic component group A (1) and the content (A2) of the aromatic component group A (2) is 0.01 or more and 0.30 or less. It is a preferable range to exhibit the effects of the present invention.
- Aromade group B Dihydrofarnesal, (R,E)-2-methyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol, (R)-3 -methylcyclopentadecanone, vanillyl butyl ether, vanillyl ethyl ether, ethylene brassylate, 2-(2-methyl-1-propenyl)-4-methyltetrahydropyran, vanillin, ethyl vanillin, ethyl maltol, piperonal, ⁇ - Nonalactone, cinnamic aldehyde, coumarin, cumin aldehyde, diethyl malonate, ethyl 2-methylvalerate, ginger oil
- aromatic components of group B the following aromatic components are preferable because the fragrance alone and the fragrance when used in combination strongly evoke a particularly pleasant warm feeling, and the effect of raising skin temperature is remarkable and is suitable for use.
- fragrance composition of the present invention It is preferable that one or more of these group B fragrance components are contained in the fragrance composition of the present invention.
- the blending amount of these aromatic component B group in the perfume composition is preferably 0.1 to 100% by mass, more preferably 1.0 to 100% by mass, in order to exhibit the effects of the present invention. This is the preferred range.
- the group B of fragrance components can be divided into group B of fragrance components (1) and group B of fragrance components (2), and one or more of each is preferably contained in the fragrance composition of the present invention.
- the mass ratio (B1)/(B2) between the content (B1) of the aromatic component group B (1) and the content (B2) of the aromatic component group B (2) is 0.01 or more and 0.30 or less. It is a preferable range to exhibit the effects of the present invention.
- the fragrance composition of the present invention can contain, as an additional component, at least one or more fragrance components that enhance cooling sensation and lowering of skin temperature, or enhance warming sensation and raising skin temperature.
- aromatic component group C Specific examples of the aromatic component that enhances cooling sensation and lowering of skin temperature or enhancing warming sensation and raising of skin temperature include the aromatic component group C described below.
- aromatic component group C 5-mercapto-5-methyl-3-hexanone, 4,7-decadienal, 8-mercaptomenthone, 1-(2,2,6-trimethylcyclohexyl)-3-hexanol, bergamot oil
- aromatic components of Group C 5-mercapto-5-methyl-3-hexanone, 4,7-decadienal, 8-mercaptomenthone, and 1-(2,2,6-trimethylcyclohexyl)-3-hexanol are preferred.
- aroma components are preferably used because the aroma alone and the aroma when used in combination strongly evoke a particularly pleasant cold or warm sensation, and have a remarkable effect of raising or lowering skin temperature.
- the amount of the aromatic component C group compounded in the perfume composition is preferably 0.00001 to 30% by mass, more preferably 0.0001 to 20% by mass. This is the preferred range.
- the fragrance composition of the present invention can be prepared by appropriately adding and mixing various compounds, and the order and intervals of blending are not particularly limited.
- the formulation form is also not particularly limited, and can be appropriately selected according to the purpose of use.
- fragrance components or conventional additives as described below are added within a range that does not impair the effects of the present invention, that is, to enhance cooling sensation and lowering of skin temperature or to impart warmth. and can be blended within a quantitative and qualitative range to obtain an increase in skin temperature.
- perfumes examples include hydrocarbons such as ⁇ -pinene, limonene, and cedrene; aliphatic saturated or unsaturated alcohols such as 1-octen-3-ol and nonanol; Saturated or unsaturated chain terpene alcohols; Cyclic terpene alcohols such as ⁇ -terpineol and bornylmethoxycyclohexanol; Sesquiterpene alcohols such as farnesol; Aromatic alcohols such as ⁇ -phenylpropyl alcohol and dimethylbenzylcarbinol; , terpene aldehydes, aromatic aldehydes, aliphatic ketones such as 7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene; Cyclic ketones, cyclic ketones, aliphatic esters, acetates, propionates, butyrates, benzoates, phenyl
- the fragrance composition of the present invention is blended in, for example, fragrance products, detergents, fabric softeners, cleaning agents, kitchen detergents, bleaching agents, aerosol agents, deodorant/fragrant agents, incense, miscellaneous goods, food and drink, and pharmaceuticals.
- fragrance products for example, fragrance products, detergents, fabric softeners, cleaning agents, kitchen detergents, bleaching agents, aerosol agents, deodorant/fragrant agents, incense, miscellaneous goods, food and drink, and pharmaceuticals.
- fragrance products for example, fragrance products, detergents, fabric softeners, cleaning agents, kitchen detergents, bleaching agents, aerosol agents, deodorant/fragrant agents, incense, miscellaneous goods, food and drink, and pharmaceuticals.
- Detergents include heavy laundry detergents, light laundry detergents, liquid detergents, laundry soaps, compact detergents, powdered soaps, and the like.
- Softeners include softeners, furniture care, and the like. Examples include cleansers, house cleaners, toilet cleaners, bathroom cleaners, glass cleaners, mold removers, drain cleaners, etc.
- Kitchen detergents include kitchen soap, kitchen synthetic soap, tableware
- bleaching agents include oxidizing bleaching agents (chlorine bleaching agents, oxygen bleaching agents, etc.), reducing bleaching agents (sulfur bleaching agents, etc.), optical bleaching agents, and the like.
- Aerosol agents include spray types and powder sprays, deodorants and fragrances include solid types, gel types, liquid types, etc. Miscellaneous goods include tissue paper, toilet paper, etc. is mentioned.
- the fragrance composition of the present invention When blended into the above product, it may be appropriately determined according to the form and application of the product, and is not particularly limited. 100% by mass, preferably 0.001 to 80% by mass, more preferably 0.01 to 50% by mass. If it is less than 0.0001%, the aroma component is too small and the expected cooling and warming performance cannot be exhibited, and if it exceeds 80% by mass, a sufficient cooling or warming effect can be expected. can be too expensive and create commercial challenges.
- the effect of adjusting the sensible temperature and skin temperature by the fragrance composition of the present invention and the product containing it is within 5 minutes immediately after receiving the olfactory stimulus, preferably within 30 seconds to 4 minutes after the olfactory stimulus. It is preferably 1 to 3 minutes immediately after receiving the olfactory stimulus, and after more than 5 minutes, the warming or cooling effect of the olfactory stimulus weakens and returns to a steady state in a short time. Confirmed to be persistent.
- a fragrance composition that imparts a cool or warm sensation and lowers or raises skin temperature when sniffed from the nasal cavity.
- the fragrance composition according to [1] containing at least one selected from the following fragrance component group A.
- Aroma component group A (1) Isopulegol, L-menthol, menthyl acetate, menthyl lactate, menthone, menthone glycerin acetal, menthyl glyceryl ether, peppermint oil (Aroma component group A (2)) 2-sec-butylcyclohexanone, L-hydroxycitronellal, ethyl (1R,6S)-2,2,6-trimethylcyclohexanecarboxylate, 5-cyclohexadecenone, borneol, ⁇ -caryophyllene, linalool, linalyl acetate, salicylic acid methyl, 7-methyl-2H-1,5-benzodioxepin-3(4H)-one, peppermint oil, eucalyptus oil, cis-3-hexenol, cis-3-hexenyl acetate, spearmint oil, lime oil [4 ]
- the fragrance composition according to
- (Aroma component group B) Dihydrofarnesal, (R,E)-2-methyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol, (R)-3 -methylcyclopentadecanone, vanillyl butyl ether, vanillyl ethyl ether, ethylene brassylate, 2-(2-methyl-1-propenyl)-4-methyltetrahydropyran, vanillin, ethyl vanillin, ethyl maltol, piperonal, ⁇ - Nonalactone, cinnamic aldehyde, coumarin, cumin aldehyde, diethyl malonate, ethyl 2-methylvalerate, ginger oil [5] Content (B1) of aroma component group B (1) below and content of aroma component group B (2) The fragrance composition according to [1] or [4], wherein the mass ratio (B1)/(B2) to the content (B2) is 0.01 or more and 0.
- the fragrance composition according to any one of [1] to [5], containing one or more selected from the following fragrance component C group.
- [10] A product containing 0.0001 to 100% by mass of the fragrance composition according to any one of [1] to [8]. However, products that are applied directly to the skin and products that are applied directly to the mouth are excluded. [11] A method for adjusting sensible temperature and skin temperature by olfactory stimulation with the fragrance composition according to any one of [1] to [8] or the product according to [9] or [10].
- Example 1 A cooling fragrance composition was prepared according to the formulation shown in Table 1. The amount of the compounding component is % by mass.
- Example 2 A cooling fragrance composition was prepared according to the formulation shown in Table 2. The amount of the compounding component is % by mass.
- FIG. 1 shows a simplified diagram of the method of skin temperature measurement.
- the peripheral skin temperature at the time of presentation of the perfume composition was measured with a thermistor-type high-performance thermometer (LT-200SA, Gram Co., Ltd.).
- a thermistor sensor was fixed to the tip of the nose to measure changes in skin temperature at the tip of the nose. Measurements were performed after 20 minutes or more of acclimation in the laboratory at 25°C. After taking a rest period as a control, changes in skin temperature when the samples were presented were measured.
- Experimental participants were first rested for 5 minutes and then exposed to 3.0 g of the sample presented to the tip of their nose for 5 minutes. The sample was presented in a light-shielded vial approximately 10 cm in front of the nasal cavity of the experimental participant. Peripheral skin temperature changes were calculated by comparing the skin temperature at the start of sample presentation with the skin temperature 150 seconds after sample presentation as a reference value.
- Example 3 To the perfume composition of Example 1, 0.001% of 8-mercaptomenthone from group C and 0.1% of 1-(2,2,6-trimethylcyclohexyl)-3-hexanol were added to the perfume composition. As a result of conducting the same test as in 1, the peripheral skin temperature further decreased by 0.2°C and decreased by 1.01°C, and the subjective evaluation score improved by 0.2 to 4.0.
- Example 4 A warming fragrance composition was prepared according to the formulation shown in Table 6. The amount of the compounding component is % by mass.
- Example 5 A warming fragrance composition was prepared according to the formulation shown in Table 7. The amount of the compounding component is % by mass.
- Examples 4 and 5 and Comparative Examples 3 and 4 were determined by the same peripheral skin temperature measurement method and subjective evaluation as in Example 1 using 7 panelists. Peripheral skin temperature and subjective evaluation were measured in the same manner as described above. The results of the tests are shown in FIG. 3 and Table 10. From this, it was confirmed that Examples 4 and 5 containing the warming composition increased the peripheral skin temperature and felt a warming sensation from the scent.
- Example 6 Furthermore, as a result of presenting a scent by adding 0.01% of 5-mercapto-5-methyl-3-hexanone and 5% of lime oil from the perfume compound group C to the perfume composition of Example 4, the peripheral skin temperature further increased. The temperature rose by 0.1°C, and the subjective evaluation score improved by 0.2.
- Cooling fragrance composition A cooling fragrance composition was prepared according to the formulation shown in Table 11. The amount of the compounding component is % by mass.
- Liquid detergent A liquid detergent was prepared according to the formulation shown in Table 12 below.
- Softening agent for clothes A softening agent for clothes was prepared according to the formulation shown in Table 13 below.
- Example 10 Warm fragrance composition A warm fragrance composition was prepared according to the formulation shown in Table 14. The amount of the compounding component is % by mass.
- Fragrance A fragrance was prepared according to the formulation in Table 15 below.
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Abstract
Description
[1]鼻腔から嗅ぐことにより冷感または温感を付与し、且つ皮膚温を降下または上昇させる香料組成物。
本発明の香料組成物は鼻腔から嗅ぐことにより温感または冷感を付与し、且つ皮膚温を上昇または降下させることができる。
(香気成分A群)
2-sec-ブチルシクロヘキサノン、L-ヒドロキシシトロネラール、酢酸メンチル、乳酸メンチル、(1R,6S)-2,2,6-トリメチルシクロヘキサンカルボン酸エチル、ボルネオール、β-カリオフィレン、イソプレゴール、メントン、メントングリセリンアセタール、メンチルグリセリルエーテル、リナロール、酢酸リナリル、L-メントール、サリチル酸メチル、7-メチル-2H-1,5-ベンゾジオキセピン-3(4H)-オン、5-シクロヘキサデセノン、ハッカ油、ユーカリ油、シス-3-ヘキセノール、酢酸シス-3-ヘキセニル、ペパーミント油、スペアミント油、ライム油
(香気成分A群(1))
イソプレゴール、L-メントール、酢酸メンチル、乳酸メンチル、メントン、メントングリセリンアセタール、メンチルグリセリルエーテル、ペパーミント油
(香気成分A群(2))
2-sec-ブチルシクロヘキサノン、L-ヒドロキシシトロネラール、(1R,6S)-2,2,6-トリメチルシクロヘキサンカルボン酸エチル、5-シクロヘキサデセノン、ボルネオール、β-カリオフィレン、リナロール、酢酸リナリル、サリチル酸メチル、7-メチル-2H-1,5-ベンゾジオキセピン-3(4H)-オン、5-シクロヘキサデセノン、ハッカ油、ユーカリ油、シス-3-ヘキセノール、酢酸シス-3-ヘキセニル、スペアミント油、ライム油
(香気成分B群)
ジヒドロファルネサール、(R,E)-2-メチル-4-(2,2,3-トリメチル-3-シクロペンテン-1-イル)-2-ブテン-1-オ-ル、(R)-3-メチルシクロペンタデカノン、バニリルブチルエーテル、バニリルエチルエーテル、エチレンブラシレート、2-(2-メチル-1-プロペニル)-4-メチルテトラヒドロピラン、バニリン、エチルバニリン、エチルマルトール、ピペロナール、γ-ノナラクトン、シンナミックアルデヒド、クマリン、クミンアルデヒド、マロン酸ジエチル、2-メチル吉草酸エチル、ジンジャー油
ジヒドロファルネサール、(R,E)-2-メチル-4-(2,2,3-トリメチル-3-シクロペンテン-1-イル)-2-ブテン-1-オ-ル、(R)-3-メチルシクロペンタデカノン、バニリルブチルエーテル、バニリルエチルエーテル、エチレンブラシレート、2-(2-メチル-1-プロペニル)-4-メチルテトラヒドロピラン。
(香気成分B群(1))
バニリルブチルエーテル、バニリルエチルエーテル、ジンジャー油
(香気成分B群(2))
ジヒドロファルネサール、(R,E)-2-メチル-4-(2,2,3-トリメチル-3-シクロペンテン-1-イル)-2-ブテン-1-オ-ル、(R)-3-メチルシクロペンタデカノン、エチレンブラシレート、2-(2-メチル-1-プロペニル)-4-メチルテトラヒドロピラン、バニリン、エチルバニリン、エチルマルトール、ピペロナール、γ-ノナラクトン、シンナミックアルデヒド、クマリン、クミンアルデヒド、マロン酸ジエチル、2-メチル吉草酸エチル
(香気成分C群)
5-メルカプト-5-メチル-3-ヘキサノン、4,7-デカジエナール、8-メルカプトメントン、1-(2,2,6-トリメチルシクロヘキシル)-3-ヘキサノール、ベルガモット油
〔1〕鼻腔から嗅ぐことにより冷感または温感を付与し、且つ皮膚温を降下または上昇させる香料組成物。
〔2〕下記香気成分A群から選ばれる少なくとも1種以上を含有する〔1〕に記載の香料組成物。
(香気成分A群)
2-sec-ブチルシクロヘキサノン、L-ヒドロキシシトロネラール、酢酸メンチル、乳酸メンチル、(1R,6S)-2,2,6-トリメチルシクロヘキサンカルボン酸エチル、ボルネオール、β-カリオフィレン、イソプレゴール、メントン、メントングリセリンアセタール、メンチルグリセリルエーテル、リナロール、酢酸リナリル、L-メントール、サリチル酸メチル、7-メチル-2H-1,5-ベンゾジオキセピン-3(4H)-オン、5-シクロヘキサデセノン、ハッカ油、ユーカリ油、シス-3-ヘキセノール、酢酸シス-3-ヘキセニル、ペパーミント油、スペアミント油、ライム油
〔3〕下記香気成分A群(1)の含有量(A1)と下記香気成分A群(2)の含有量(A2)との質量比(A1)/(A2)が0.01以上0.3以下である、〔1〕または〔2〕に記載の香料組成物。
(香気成分A群(1))
イソプレゴール、L-メントール、酢酸メンチル、乳酸メンチル、メントン、メントングリセリンアセタール、メンチルグリセリルエーテル、ペパーミント油
(香気成分A群(2))
2-sec-ブチルシクロヘキサノン、L-ヒドロキシシトロネラール、(1R,6S)-2,2,6-トリメチルシクロヘキサンカルボン酸エチル、5-シクロヘキサデセノン、ボルネオール、β-カリオフィレン、リナロール、酢酸リナリル、サリチル酸メチル、7-メチル-2H-1,5-ベンゾジオキセピン-3(4H)-オン、ハッカ油、ユーカリ油、シス-3-ヘキセノール、酢酸シス-3-ヘキセニル、スペアミント油、ライム油
〔4〕下記香気成分B群から選ばれる少なくとも1種以上を含有する〔1〕に記載の香料組成物。
(香気成分B群)
ジヒドロファルネサール、(R,E)-2-メチル-4-(2,2,3-トリメチル-3-シクロペンテン-1-イル)-2-ブテン-1-オ-ル、(R)-3-メチルシクロペンタデカノン、バニリルブチルエーテル、バニリルエチルエーテル、エチレンブラシレート、2-(2-メチル-1-プロペニル)-4-メチルテトラヒドロピラン、バニリン、エチルバニリン、エチルマルトール、ピペロナール、γ-ノナラクトン、シンナミックアルデヒド、クマリン、クミンアルデヒド、マロン酸ジエチル、2-メチル吉草酸エチル、ジンジャー油
〔5〕下記香気成分B群(1)の含有量(B1)と香気成分B群(2)の含有量(B2)との質量比(B1)/(B2)が0.01以上0.30以下である、〔1〕または〔4〕に記載の香料組成物。
(香気成分B群(1))
バニリルブチルエーテル、バニリルエチルエーテル、ジンジャー油
(香気成分B群(2))
ジヒドロファルネサール、(R,E)-2-メチル-4-(2,2,3-トリメチル-3-シクロペンテン-1-イル)-2-ブテン-1-オ-ル、(R)-3-メチルシクロペンタデカノン、エチレンブラシレート、2-(2-メチル-1-プロペニル)-4-メチルテトラヒドロピラン、バニリン、エチルバニリン、エチルマルトール、ピペロナール、γ-ノナラクトン、シンナミックアルデヒド、クマリン、クミンアルデヒド、マロン酸ジエチル、2-メチル吉草酸エチル
〔6〕下記香気成分C群から選ばれる1種以上を含有する〔1〕乃至〔5〕のいずれか1に記載の香料組成物。
(香気成分C群)
5-メルカプト-5-メチル-3-ヘキサノン、4,7-デカジエナール、8-メルカプトメントン、1-(2,2,6-トリメチルシクロヘキシル)-3-ヘキサノール、ベルガモット油
〔7〕下記香気成分C群から選ばれる1種以上を含有することにより、冷感付与及び皮膚温を降下または温感付与及び皮膚温を上昇させることが強化された、〔1〕乃至〔6〕のいずれか1に記載の香料組成物。
(香気成分C群)
5-メルカプト-5-メチル-3-ヘキサノン、4,7-デカジエナール、8-メルカプトメントン、1-(2,2,6-トリメチルシクロヘキシル)-3-ヘキサノール、ベルガモット油
〔8〕前記香料組成物による嗅覚刺激により体感温度及び皮膚温が調整され、前記調整効果が嗅覚刺激を受けた直後から5分以内で発現及び維持される、〔1〕乃至〔7〕のいずれか1に記載の香料組成物。
〔9〕〔1〕乃至〔8〕のいずれか1に記載の香料組成物を0.0001~100質量%含有する製品。
〔10〕〔1〕乃至〔8〕のいずれか1に記載の香料組成物を0.0001~100質量%含有する製品。ただし、直接的に皮膚に適用する製品および直接的に口中に適用する製品は除く。
〔11〕〔1〕乃至〔8〕のいずれか1に記載の香料組成物または〔9〕もしくは〔10〕に記載の製品による嗅覚刺激により体感温度及び皮膚温を調整する方法。
表1に示した配合処方に従って冷感香料組成物を調製した。配合成分の量は質量%。
表2に示した配合処方に従って冷感香料組成物を調製した。配合成分の量は質量%。
表3に示した配合処方に従って香料組成物を調製した。配合成分の量は質量%。
表4に示した配合処方に従って香料組成物を調製した。配合成分の量は質量%。
末梢皮膚温度変化は、試料呈示開始時の皮膚温度を基準値とし、試料呈示から150秒後の皮膚温度との比較で算出された。
香りの冷温感
5:非常に強く冷感または温感を感じる。
4:強く冷感または温感を感じる。
3:冷感または温感を感じる。
2:やや冷感または温感を感じる。
1:少し冷感または温感を感じる。
0:冷感または温感を感じない。
試験の結果を図2および表5に示す。これより、冷感組成物配合の実施例1および2が末梢皮膚温度を下げ、香りから冷感を感じていることが確認された。
実施例1の香料組成物に、香気成分C群から8-メルカプトメントンを0.001%、かつ1-(2,2,6-トリメチルシクロヘキシル)-3-ヘキサノールを0.1%加えて実施例1と同様の試験を実施した結果、末梢皮膚温度がさらに0.2℃下がり1.01℃低下、主観評価スコアは0.2向上し、4.0となった。
表6に示した配合処方に従って温感香料組成物を調製した。配合成分の量は質量%。
表7に示した配合処方に従って温感香料組成物を調製した。配合成分の量は質量%。
表8に示した配合処方に従って香料組成物を調製した。配合成分の量は質量%。
表9に示した配合処方に従って香料組成物を調製した。配合成分の量は質量%。
試験の結果を図3および表10に示す。これより、温感組成物配合の実施例4および5が末梢皮膚温度を上げ、香りから温感を感じていることが確認された。
さらに、実施例4の香料組成物に香料化合物C群から5-メルカプト-5-メチル-3-ヘキサノンを0.01%かつライム油を5%加えて香りを提示した結果、末梢皮膚温度がさらに0.1℃上がり、主観評価スコアは0.2向上した。
表11に示した配合処方に従って冷感香料組成物を調製した。配合成分の量は質量%。
下記表12の処方に従い、液体洗剤を作製した。
下記表13の処方に従い、衣料用柔軟剤を作成した。
表14に示した配合処方に従って温感香料組成物を調製した。配合成分の量は質量%。
下記表15の処方に従い、芳香剤を作成した。
Claims (11)
- 鼻腔から嗅ぐことにより冷感または温感を付与し、且つ皮膚温を降下または上昇させる香料組成物。
- 下記香気成分A群から選ばれる少なくとも1種以上を含有する請求項1に記載の香料組成物。
(香気成分A群)
2-sec-ブチルシクロヘキサノン、L-ヒドロキシシトロネラール、酢酸メンチル、乳酸メンチル、(1R,6S)-2,2,6-トリメチルシクロヘキサンカルボン酸エチル、ボルネオール、β-カリオフィレン、イソプレゴール、メントン、メントングリセリンアセタール、メンチルグリセリルエーテル、リナロール、酢酸リナリル、L-メントール、サリチル酸メチル、7-メチル-2H-1,5-ベンゾジオキセピン-3(4H)-オン、5-シクロヘキサデセノン、ハッカ油、ユーカリ油、シス-3-ヘキセノール、酢酸シス-3-ヘキセニル、ペパーミント油、スペアミント油、ライム油 - 下記香気成分A群(1)の含有量(A1)と下記香気成分A群(2)の含有量(A2)との質量比(A1)/(A2)が0.01以上0.3以下である、請求項1に記載の香料組成物。
(香気成分A群(1))
イソプレゴール、L-メントール、酢酸メンチル、乳酸メンチル、メントン、メントングリセリンアセタール、メンチルグリセリルエーテル、ペパーミント油
(香気成分A群(2))
2-sec-ブチルシクロヘキサノン、L-ヒドロキシシトロネラール、(1R,6S)-2,2,6-トリメチルシクロヘキサンカルボン酸エチル、5-シクロヘキサデセノン、ボルネオール、β-カリオフィレン、リナロール、酢酸リナリル、サリチル酸メチル、7-メチル-2H-1,5-ベンゾジオキセピン-3(4H)-オン、ハッカ油、ユーカリ油、シス-3-ヘキセノール、酢酸シス-3-ヘキセニル、スペアミント油、ライム油 - 下記香気成分B群から選ばれる少なくとも1種以上を含有する請求項1に記載の香料組成物。
(香気成分B群)
ジヒドロファルネサール、(R,E)-2-メチル-4-(2,2,3-トリメチル-3-シクロペンテン-1-イル)-2-ブテン-1-オ-ル、(R)-3-メチルシクロペンタデカノン、バニリルブチルエーテル、バニリルエチルエーテル、エチレンブラシレート、2-(2-メチル-1-プロペニル)-4-メチルテトラヒドロピラン、バニリン、エチルバニリン、エチルマルトール、ピペロナール、γ-ノナラクトン、シンナミックアルデヒド、クマリン、クミンアルデヒド、マロン酸ジエチル、2-メチル吉草酸エチル、ジンジャー油 - 下記香気成分B群(1)の含有量(B1)と香気成分B群(2)の含有量(B2)との質量比(B1)/(B2)が0.01以上0.30以下である、請求項1に記載の香料組成物。
(香気成分B群(1))
バニリルブチルエーテル、バニリルエチルエーテル、ジンジャー油
(香気成分B群(2))
ジヒドロファルネサール、(R,E)-2-メチル-4-(2,2,3-トリメチル-3-シクロペンテン-1-イル)-2-ブテン-1-オ-ル、(R)-3-メチルシクロペンタデカノン、エチレンブラシレート、2-(2-メチル-1-プロペニル)-4-メチルテトラヒドロピラン、バニリン、エチルバニリン、エチルマルトール、ピペロナール、γ-ノナラクトン、シンナミックアルデヒド、クマリン、クミンアルデヒド、マロン酸ジエチル、2-メチル吉草酸エチル - 下記香気成分C群から選ばれる1種以上を含有する請求項1に記載の香料組成物。
(香気成分C群)
5-メルカプト-5-メチル-3-ヘキサノン、4,7-デカジエナール、8-メルカプトメントン、1-(2,2,6-トリメチルシクロヘキシル)-3-ヘキサノール、ベルガモット油 - 下記香気成分C群から選ばれる1種以上を含有することにより、冷感付与及び皮膚温を降下または温感付与及び皮膚温を上昇させることが強化された、請求項1に記載の香料組成物。
(香気成分C群)
5-メルカプト-5-メチル-3-ヘキサノン、4,7-デカジエナール、8-メルカプトメントン、1-(2,2,6-トリメチルシクロヘキシル)-3-ヘキサノール、ベルガモット油 - 前記香料組成物による嗅覚刺激により体感温度及び皮膚温が調整され、前記調整効果が嗅覚刺激を受けた直後から5分以内で発現及び維持される、請求項1に記載の香料組成物。
- 請求項1乃至8のいずれか1項に記載の香料組成物を0.0001~100質量%含有する製品。
- 請求項1乃至8のいずれか1項に記載の香料組成物を0.0001~100質量%含有する製品。ただし、直接的に皮膚に適用する製品および直接的に口中に適用する製品は除く。
- 請求項1乃至8のいずれか1項に記載の香料組成物または請求項9に記載の製品による嗅覚刺激により体感温度及び皮膚温を調整する方法。
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