WO2023208284A1 - Substrat de document de valeur biodégradable - Google Patents
Substrat de document de valeur biodégradable Download PDFInfo
- Publication number
- WO2023208284A1 WO2023208284A1 PCT/DE2023/100304 DE2023100304W WO2023208284A1 WO 2023208284 A1 WO2023208284 A1 WO 2023208284A1 DE 2023100304 W DE2023100304 W DE 2023100304W WO 2023208284 A1 WO2023208284 A1 WO 2023208284A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- biodegradable
- fibers
- paper
- document substrate
- layer
- Prior art date
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 134
- 229920000642 polymer Polymers 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 18
- 229920003043 Cellulose fiber Polymers 0.000 claims abstract description 9
- 239000004627 regenerated cellulose Substances 0.000 claims abstract description 8
- 239000000835 fiber Substances 0.000 claims description 87
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 19
- 229920000742 Cotton Polymers 0.000 claims description 12
- 210000002268 wool Anatomy 0.000 claims description 9
- 229920000331 Polyhydroxybutyrate Polymers 0.000 claims description 6
- 239000004922 lacquer Substances 0.000 claims description 6
- 239000005015 poly(hydroxybutyrate) Substances 0.000 claims description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 6
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 6
- 241000283707 Capra Species 0.000 claims description 3
- 229920001661 Chitosan Polymers 0.000 claims description 3
- 229920001634 Copolyester Polymers 0.000 claims description 3
- 241001494479 Pecora Species 0.000 claims description 3
- 229920001800 Shellac Polymers 0.000 claims description 3
- 241001416177 Vicugna pacos Species 0.000 claims description 3
- 229920001222 biopolymer Polymers 0.000 claims description 3
- 210000000085 cashmere Anatomy 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 210000004209 hair Anatomy 0.000 claims description 3
- 229920005610 lignin Polymers 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- -1 polybutylene adipate terephthalate Polymers 0.000 claims description 3
- 239000004629 polybutylene adipate terephthalate Substances 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 claims description 3
- 229940113147 shellac Drugs 0.000 claims description 3
- 235000013874 shellac Nutrition 0.000 claims description 3
- 239000004208 shellac Substances 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- 241001465754 Metazoa Species 0.000 abstract description 11
- 239000010410 layer Substances 0.000 description 61
- 229920005594 polymer fiber Polymers 0.000 description 17
- 241000196324 Embryophyta Species 0.000 description 13
- 239000000853 adhesive Substances 0.000 description 9
- 230000001070 adhesive effect Effects 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 102000004169 proteins and genes Human genes 0.000 description 6
- 108090000623 proteins and genes Proteins 0.000 description 6
- 240000000907 Musa textilis Species 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 244000198134 Agave sisalana Species 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 244000105624 Arachis hypogaea Species 0.000 description 3
- 240000008564 Boehmeria nivea Species 0.000 description 3
- 244000025254 Cannabis sativa Species 0.000 description 3
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 3
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 3
- 241000700143 Castor fiber Species 0.000 description 3
- 240000000731 Fagus sylvatica Species 0.000 description 3
- 235000010099 Fagus sylvatica Nutrition 0.000 description 3
- 235000008694 Humulus lupulus Nutrition 0.000 description 3
- 244000025221 Humulus lupulus Species 0.000 description 3
- 240000006240 Linum usitatissimum Species 0.000 description 3
- 235000004431 Linum usitatissimum Nutrition 0.000 description 3
- 229920000433 Lyocell Polymers 0.000 description 3
- 235000009108 Urtica dioica Nutrition 0.000 description 3
- 229920002522 Wood fibre Polymers 0.000 description 3
- 240000008042 Zea mays Species 0.000 description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 3
- 229920006021 bio-based polyamide Polymers 0.000 description 3
- 235000009120 camo Nutrition 0.000 description 3
- 235000005607 chanvre indien Nutrition 0.000 description 3
- 235000005822 corn Nutrition 0.000 description 3
- 239000011487 hemp Substances 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- 239000008267 milk Substances 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- 235000020232 peanut Nutrition 0.000 description 3
- 239000002025 wood fiber Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 244000274883 Urtica dioica Species 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000002255 enzymatic effect Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 235000011624 Agave sisalana Nutrition 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 241001456088 Hesperocnide Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229920002988 biodegradable polymer Polymers 0.000 description 1
- 239000004621 biodegradable polymer Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/333—Watermarks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/351—Translucent or partly translucent parts, e.g. windows
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/355—Security threads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/45—Associating two or more layers
- B42D25/465—Associating two or more layers using chemicals or adhesives
- B42D25/47—Associating two or more layers using chemicals or adhesives using adhesives
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
Definitions
- the invention relates to a biodegradable value document substrate, in particular a banknote.
- WO 2004/072378 A1 proposes providing security paper with a protective layer based on a varnish.
- WO 2004/028825 A2 describes the provision of a security paper that is improved against contamination and has increased mechanical strength based on a multilayer substrate which comprises at least one paper layer and a film.
- the present invention is based on the object of overcoming the disadvantages of the prior art and of providing an improved valuable document substrate.
- the valuable document substrate should in particular ensure sustainable and environmentally friendly disposal and at the same time have a high circulation stability.
- the task is solved by the combination of features defined in the independent claim. Further developments of the invention are the subject of the dependent claims.
- Biodegradable value document substrate comprising a biodegradable paper substrate with sustainable fibers, the sustainable fibers being selected from the group consisting of natural fibers, regenerated cellulose fibers, bio-based plant polymer fibers, bio-based animal polymer fibers or a mixture of two or more of the above-mentioned elements.
- Biodegradable value document substrate according to clause 1, whereby natural fibers are selected as sustainable fibers and the natural fibers are based on a mixture comprising cotton fibers and resistant fibers, the resistant fibers preferably being from plants, selected from the group consisting of hemp, flax , fines, abaca, nettle, ramie, hops, sisal or a mixture of two or more of the above-mentioned elements.
- Biodegradable value document substrate according to clause 2, wherein the paper substrate additionally contains bio-based plant polymer fibers as sustainable fibers, the bio-based plant polymer fibers being bio-based polyamide fibers, beech wood fibers, Tencel fibers, castor fibers, polylactate fibers and/or protein fibers, whereby the protein fibers are obtained in particular from corn, peanuts, milk and/or soy.
- bio-based plant polymer fibers being bio-based polyamide fibers, beech wood fibers, Tencel fibers, castor fibers, polylactate fibers and/or protein fibers, whereby the protein fibers are obtained in particular from corn, peanuts, milk and/or soy.
- Biodegradable value document substrate according to clause 2 or 3, wherein the paper substrate additionally contains bio-based animal polymer fibers as sustainable fibers, the bio-based animal polymer fibers being based on sheep's wool, virgin Merino wool, fine cashmere goat hair and/or alpaca wool.
- Biodegradable value document substrate according to clause 2, 3 or 4, wherein the paper substrate additionally contains regenerated cellulose fibers as sustainable fibers.
- Biodegradable value document substrate according to one of clauses 2 to 5, wherein the cotton fibers have an average length and the resistant fibers have an average length, the average length of the resistant fibers being increased by an amount in a range of 10 % to 50% is higher than the average length of the cotton fibers.
- Biodegradable value document substrate according to one of clauses 1 to 6, wherein the paper substrate is a two-layer paper substrate with a first paper layer and a second paper layer, the first paper layer being based on fibers with an average length and the second paper layer being based on fibers based on an average length, the average length of the fibers of the second paper layer being higher by a certain amount than the average length of the fibers of the first paper layer, the certain amount being in particular in a range of 10% to 50%.
- Biodegradable valuable document substrate according to one of clauses 1 to 7, wherein the paper substrate additionally contains biodegradable stabilizers based on biopolymers, in particular chitosan, and/or biodegradable auxiliary substances.
- Biodegradable value document substrate according to one of clauses 1 to 8, wherein the value document substrate is a multilayer value document substrate with polymer layer/paper substrate/polymer layer structure or paper substrate/polymer layer/paper substrate structure, the polymer layer being biodegradable and is selected in particular from the group consisting of cellulose, polybutylene adipate terephthalate (BTA copolyester), polylactide (PLA), in particular biaxially oriented polylactide, polyhydroxybutyrate (PHB), or a mixture of two or more of the above-mentioned elements.
- BTA copolyester polybutylene adipate terephthalate
- PLA polylactide
- PHA polyhydroxybutyrate
- PHB polyhydroxybutyrate
- Biodegradable value document substrate according to clause 9, wherein the value document substrate is a multilayer value document substrate with a polymer layer/paper substrate/polymer layer structure and the polymer layer is in each case a film.
- Biodegradable value document substrate according to one of clauses 1 to 8, wherein the biodegradable paper substrate is provided on its two main surfaces with a biodegradable lacquer layer, the biodegradable lacquer layer being in particular from the group consisting of polysugar, lignin, Shellac, tree resin, polyvinylpyrrolidone (PVP), polyalcohol (PVA) or a mixture of two or more of the above-mentioned elements is selected.
- a biodegradable lacquer layer being in particular from the group consisting of polysugar, lignin, Shellac, tree resin, polyvinylpyrrolidone (PVP), polyalcohol (PVA) or a mixture of two or more of the above-mentioned elements is selected.
- Biodegradable valuable document substrate according to one of clauses 1 to 11, wherein the valuable document substrate has a security thread and/or a security strip and/or a security patch based on a biodegradable material and/or mottled fibers based on natural fibers.
- Biodegradable value document substrate according to one of clauses 1 to 12, wherein the value document substrate is a banknote.
- the invention is based on the finding that a sustainable value document substrate can be provided based on a biodegradable paper substrate containing sustainable fibers.
- the valuable document substrate according to the invention preferably consists essentially of sustainable, i.e. biodegradable, components, it being particularly preferred that the valuable document substrate consists exclusively of sustainable components.
- the biodegradable value document substrate according to the invention comprises a biodegradable paper substrate with sustainable fibers, the sustainable fibers being from the group consisting of natural fibers, regenerated cellulose fibers, bio-based plant polymer fibers, bio-based animal polymer fibers or a mixture of two or more rer of the above-mentioned elements are selected.
- the valuable document substrate according to the invention can be disposed of in a sustainable and environmentally friendly manner at the end of the life cycle or recycled.
- the biodegradable paper substrate comprises natural fibers as sustainable fibers, the natural fibers being based on a mixture comprising cotton fibers and resistant fibers and the resistant fibers preferably made from plants selected from the group consisting of hemp, flax, linen, abaca, stinging nettle, Ramie, hops, sisal or a mixture of two or more of the above-mentioned elements can be obtained. It is particularly preferred that the cotton fibers have an average length and the resistant fibers have an average length, the average length of the resistant fibers being higher than the average length of the cotton fibers is. In this way, a biodegradable valuable document substrate can be provided which is particularly advantageous compared to conventional valuable document substrates in terms of tear resistance and tear resistance.
- the paper substrate contains bio-based plant polymer fibers as sustainable fibers, the bio-based plant polymer fibers being bio-based polyamide fibers, beech wood fibers, Tencel fibers, castor fibers, polylactate fibers and/or protein fibers, the protein fibers being made in particular from corn, peanuts, milk and / or soy can be obtained.
- bio-based plant polymer fibers being bio-based polyamide fibers, beech wood fibers, Tencel fibers, castor fibers, polylactate fibers and/or protein fibers, the protein fibers being made in particular from corn, peanuts, milk and / or soy can be obtained.
- the paper substrate contains bio-based animal polymer fibers as sustainable fibers, the bio-based animal polymer fibers being based on sheep's wool, Merino virgin wool, fine cashmere goat hair and/or alpaca wool.
- biodegradable value document substrate can be provided which is particularly advantageous in terms of biodegradability compared to conventional value document substrates.
- the paper substrate contains regenerated cellulose fibers as sustainable fibers, the paper substrate according to a particularly preferred variant consisting essentially or exclusively of regenerated cellulose fibers with regard to the cellulose fibers contained therein.
- a biodegradable valuable document substrate can be provided which is particularly advantageous in terms of the ecological balance due to the use of recycled starting materials compared to conventional valuable document substrates.
- the paper substrate is a two-layer paper substrate with a first paper layer and a second paper layer, the first paper layer being based on fibers with an average length and the second paper layer being based on fibers with an average length, the average length of the fibers being the second paper layer is higher by a certain amount than the average length of the fibers of the first paper layer, the certain amount being in particular re is in a range of 10% to 50%.
- a biodegradable value document substrate with improved mechanical resistance can be provided, which can also be provided with areas with a watermark quality in which predominantly short fibers are contained compared to the remaining areas.
- the multi-layer paper substrate can be provided, for example, according to the manufacturing process described in WO 2006/099971 A2. Alternatively, the production can be carried out in such a way that a paper layer based on long fibers is applied by spraying onto a paper layer based on short fibers.
- the paper substrate additionally contains biodegradable stabilizers based on biopolymers, in particular chitosan, and/or biodegradable auxiliary substances.
- biodegradable stabilizers based on biopolymers, in particular chitosan, and/or biodegradable auxiliary substances.
- the valuable document substrate is a multilayer valuable document substrate with a polymer layer/paper substrate/polymer layer structure or paper substrate/polymer layer/paper substrate structure, the polymer layer being biodegradable and in particular from the group consisting of cellulose, polybutylene adipate terephthalate (BTA -copolyester), polylactide (PLA), in particular biaxially oriented polylactide, polyhydroxybutyrate (PHB), or a mixture of two or more of the above-mentioned elements.
- BTA -copolyester polylactide
- PHA polyhydroxybutyrate
- the valuable document substrate has both improved mechanical strength and extremely advantageous resistance to contamination as well as environmentally friendly, biodegradability on.
- the valuable document substrate is a multilayer valuable document substrate with a polymer layer/paper substrate/polymer layer structure, the polymer layer being a film in each case.
- a valuable document substrate with a polymer layer/paper substrate/polymer layer structure, which is also referred to as a film composite substrate, is known from WO 2004/028825 A2.
- the valuable document substrate according to the invention is designed in such a way that the biodegradable paper substrate is provided with a biodegradable lacquer layer on its two main surfaces, the biodegradable lacquer layer being in particular from the group consisting of polysugar, lignin, shellac, tree resin, polyvinylpyrrolidone (PVP), polyalcohol (PVA) or a mixture of two or more of the above-mentioned elements.
- PVP polyvinylpyrrolidone
- PVA polyalcohol
- the valuable document substrate according to the invention is designed such that it has a security thread and/or a security strip and/or a security patch based on a biodegradable material and/or mottled fibers based on natural fibers. In this way, a valuable document substrate that is particularly advantageous in terms of recyclability can be provided.
- the valuable document substrate according to the invention is in particular a banknote or a security paper suitable for the production of banknotes. Further exemplary embodiments and advantages of the invention are explained below with reference to the figures, in the representation of which a reproduction true to scale and proportion was omitted in order to increase clarity.
- Figure 1 shows a value document substrate according to a first exemplary embodiment in a top view
- Figure 2 shows a value document substrate according to a second exemplary embodiment in a top view
- Figure 3 shows a section along the line A-B of the value document substrate shown in Figure 2;
- Figure 4 shows a value document substrate according to a third exemplary embodiment in a top view
- Figure 5 shows a section along line AB of the value document substrate shown in Figure 4.
- Figure 6 shows a value document substrate according to a fourth exemplary embodiment in a top view
- Figure 7 shows a section along line AB of the value document substrate shown in Figure 6;
- Figure 8 shows a value document substrate according to a fifth exemplary embodiment in a top view;
- Figure 9 shows a section along line AB of the value document substrate shown in Figure 8.
- Figure 10 shows a value document substrate according to a sixth exemplary embodiment in a top view
- Figure 11 is a side view of the value document substrate shown in Figure 10.
- Figure 12 shows a cross section through a valuable document substrate according to the invention.
- FIG. 1 illustrates a biodegradable value document substrate 0 according to the invention, in the example a banknote with the denomination 20, according to a first exemplary embodiment in a top view.
- Banknote 0 contains a biodegradable paper substrate based on natural fibers as sustainable fibers.
- the sustainable fibers are a mixture comprising cotton fibers and resistant fibers, namely abaca fibers, with the average length of the abaca fibers being 20% higher than the average length of the cotton fibers.
- Banknote 0 also includes a polylactide (PLA)-based, metallized security thread (indicated by a black, solid line in the figure) and a polylactide (PLA)-based security patch (indicated by a gray area in the figure).
- FIG. 2 shows a document of value 1 according to the invention, in the example a banknote, according to a second exemplary embodiment in a top view.
- the paper layer consists of a mixture based on cotton fibers and fibers from the hemp plant as resistant fibers.
- individual security elements are already embedded in the paper, namely a portrait watermark 2 and a window security thread 3.
- the polylactide (PLA)-based, metallized security thread 3 is, so to speak, woven into the paper so that it is in the areas 3a comes directly to the surface of the paper, while it is completely embedded in the paper mass in the areas shown in dashed lines.
- PLA polylactide
- the paper layer is covered on both sides with a polylactide (PLA)-based film, with a polylactide (PLA)-based hologram strip 8 being applied to one side, namely on the inner side of the film.
- PLA polylactide
- PLA polylactide
- FIG 3 shows a section through the banknote 1 according to the invention along the dash-dotted line AB shown in Figure 2.
- the banknote 1 according to the invention consists of biodegradable paper 4 and biodegradable films 6, which, according to the embodiment shown, were laminated over the entire surface of the surface of the paper 4 using wet adhesive 5. Alternatively, only a film 6 can be applied to one side of the paper 4.
- the upper film 6 was equipped with a holgram strip 8 before being laminated.
- the upper film 6 was laminated onto the paper 4 in such a way that the strip 8 comes to rest inside the substrate composite.
- the imprint 7 was printed using the intaglio printing process.
- Figures 4 and 5 show a value document substrate 9 according to the invention, in the example a banknote, according to a third exemplary embodiment. 5 shows a section through the banknote 9 along the line AB drawn in dash-dotted lines in FIG. 4.
- the banknote 9 consists of a divided, biodegradable paper web 10, the edges 12 of which are preferably designed as deckle edges.
- Biodegradable films 13 were applied to both sides of the paper web using cold lamination and water-crosslinking adhesive.
- area 11 there is no paper layer, but only the adhesive 5 and the foils 13.
- a foil layer is equipped with a highly reflective metal strip 14 on one side.
- the feature substance can be, for example, a luminescent substance that is transparent under normal lighting and which, when irradiated with UV light, emits in the visual spectral range and thus shows an intense color.
- feature substances can also be provided that can be detected individually. Additional coding can be generated via the mixing ratio of the feature substances.
- Figures 6 and 7 show a fourth exemplary embodiment of a banknote 16 according to the invention.
- Figure 7 shows a section through the banknote 16 according to the invention along the line AB drawn in dash-dotted lines in Figure 6.
- Figure 6 shows a top view of three wide strips 17, 18, 19, each of which has a different visual appearance and is incorporated in different layers of the film/paper/film composite substrate.
- FIG. 7 shows the cross section of the banknote 16.
- the biodegradable paper layer 21 is conventionally printed with steel intaglio printing in the form of the strip 17.
- a transparent adhesive layer 20 was applied over this.
- a second, colored layer of adhesive was applied, which results in strip 18.
- the adhesive layers 18, 20 are in turn covered with a biodegradable film 22, on the inside of which there is a hologram strip 19.
- Another biodegradable film 23 was laminated on the back using the transparent adhesive 20.
- Figure 8 shows a section of the banknote 24 according to the invention, with different security features being arranged in register in different layers and resulting in the overall information “PATTERN” in combination with a two-color metallic circular ring.
- the circular ring is divided into four segments, with segments 25a being gold-colored and segments 25b being silver-colored.
- the gold and silver color is achieved, for example, by vacuum vapor deposition with copper and aluminum.
- recesses were incorporated into the metal layer in the segments 25b, namely the letter "U” on the one hand and the letter "E” on the other.
- FIG. 9 shows the section of the banknote 24 according to the invention shown in Figure 8 in cross section.
- the banknote is composed of a biodegradable paper layer 28 and two biodegradable film layers 27a, 27b, each of which is laminated on one side of the paper layer.
- a luminescent substance 29 has been introduced into the paper layer 28 in the circular area 26.
- the letters “S” and “T” were printed on the paper layer using intaglio printing, and these are located above area 26.
- the film 27b is also equipped with security features.
- the foil On the side that lies inside the layer structure, the foil was designed with gold and silver-colored metallization, for example made of aluminum and copper, in the form of a segmented circular ring. Cutouts in the shape of the letters “U” and “E” were incorporated into the silver-colored area 25b.
- the letters “M” and “R” were printed on the outer surfaces of the film 27b using the intaglio printing process.
- FIG 10 shows a banknote 30 according to the invention in a top view.
- the banknote is composed of a biodegradable paper layer 31 and two biodegradable film layers 32a, 32b, each of which is laminated on one side of the paper layer.
- FIG 11 shows the banknote 30 shown in Figure 10 in cross section.
- the foils 32a and 32b are designed to be transparent over the entire surface.
- the paper layer 31 has two recesses 33,34 in the form of circles. Of course, any other form is also conceivable.
- the film 32a is printed with the letters “A”, “L” and “V”, which appear as mirror images when viewed from above according to FIG.
- the letters “I” and “D” are printed on the paper layer 31 approximately in the middle of the banknote.
- the printed letters complement each other to form the font "VALID".
- the fields to be placed one above the other in Figure 10 are marked with circles (solid line or dashed line).
- the complementary prints can also be more complex in nature or, with appropriate design, create moire effects and the like.
- Figure 12 shows a banknote 40 according to the invention in cross section.
- the banknote consists of a biodegradable paper layer 41 and a biodegradable film 42, which are laminated together with three different adhesives 43, 44, 45.
- the adhesives may be of different colors or of different types.
- the adhesives 43, 44, 45 have different adhesion properties to one another, so that predetermined breaking points can be specifically incorporated into the composite and manipulations due to irreversible changes can be easily recognized.
- Biodegradable value document substrate comprising a biodegradable paper substrate with sustainable fibers, the sustainable fibers being selected from the group consisting of natural fibers, regenerated cellulose fibers, bio-based plant polymer fibers, bio-based animal polymer fibers or a mixture of two or more of the above-mentioned elements.
- Biodegradable value document substrate wherein natural fibers are selected as sustainable fibers and the natural fibers are based on a mixture comprising cotton fibers and resistant fibers, the resistant fibers preferably being made from plants, selected from the group consisting of hemp, flax, linen, abaca , nettle, ramie, hops, sisal or a mixture of two or more of the above-mentioned elements.
- Biodegradable valuable document substrate according to claim 2 wherein the paper substrate additionally contains bio-based plant polymer fibers as sustainable fibers, the bio-based plant polymer fibers being bio-based polyamide fibers, beech wood fibers, Tencel fibers, castor fibers, polylactate fibers and / or protein fibers, the protein fibers being in particular from corn, Peanut, milk and/or soy are obtained.
- bio-based plant polymer fibers being bio-based polyamide fibers, beech wood fibers, Tencel fibers, castor fibers, polylactate fibers and / or protein fibers, the protein fibers being in particular from corn, Peanut, milk and/or soy are obtained.
- Biodegradable value document substrate according to claim 2 or 3 wherein the paper substrate additionally contains bio-based animal polymer fibers as sustainable fibers, the bio-based animal poly-
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Abstract
L'invention concerne un substrat de document de valeur biodégradable comprenant un substrat de papier biodégradable ayant des fibres durables, les fibres durables étant choisies dans le groupe constitué par des fibres naturelles, des fibres de cellulose régénérée, des fibres polymères végétales d'origine biologique, des fibres polymères animales d'origine biologique, ou un mélange d'au moins deux des éléments susmentionnés.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102022001505.6 | 2022-04-29 | ||
DE102022001505.6A DE102022001505A1 (de) | 2022-04-29 | 2022-04-29 | Biologisch abbaubares Wertdokumentsubstrat |
Publications (1)
Publication Number | Publication Date |
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WO2023208284A1 true WO2023208284A1 (fr) | 2023-11-02 |
Family
ID=86330728
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/DE2023/100304 WO2023208284A1 (fr) | 2022-04-29 | 2023-04-27 | Substrat de document de valeur biodégradable |
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DE (1) | DE102022001505A1 (fr) |
WO (1) | WO2023208284A1 (fr) |
Families Citing this family (1)
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DE102023110082A1 (de) | 2023-04-20 | 2024-10-24 | Giesecke+Devrient Currency Technology Gmbh | Biologisch abbaubares Wertdokumentsubstrat |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004028825A2 (fr) | 2002-09-19 | 2004-04-08 | Giesecke & Devrient Gmbh | Papier de securite |
WO2004072378A1 (fr) | 2003-02-11 | 2004-08-26 | Giesecke & Devrient Gmbh | Papier de securite et procede de production associe |
WO2006099971A2 (fr) | 2005-03-23 | 2006-09-28 | Giesecke & Devrient Gmbh | Papier securise a plusieurs couches |
WO2016034687A1 (fr) * | 2014-09-05 | 2016-03-10 | Oberthur Fiduciaire Sas | Support papier, son procédé de fabrication et document de sécurité fabriqué avec celui-ci |
US20200063368A1 (en) * | 2018-08-23 | 2020-02-27 | Eastman Chemical Company | Paper composition cellulose and cellulose ester for improved texturing |
WO2020050971A2 (fr) * | 2018-08-23 | 2020-03-12 | Eastman Chemical Company | Articles obtenus par voie humide compostables comprenant de la cellulose et des esters de cellulose |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3012365B1 (fr) | 2013-10-30 | 2016-10-07 | Oberthur Fiduciaire Sas | Document de securite |
DE102016015546A1 (de) | 2016-12-27 | 2018-06-28 | Giesecke+Devrient Currency Technology Gmbh | Mehrlagiges Wertdokumentsubstrat |
-
2022
- 2022-04-29 DE DE102022001505.6A patent/DE102022001505A1/de active Pending
-
2023
- 2023-04-27 WO PCT/DE2023/100304 patent/WO2023208284A1/fr unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004028825A2 (fr) | 2002-09-19 | 2004-04-08 | Giesecke & Devrient Gmbh | Papier de securite |
WO2004072378A1 (fr) | 2003-02-11 | 2004-08-26 | Giesecke & Devrient Gmbh | Papier de securite et procede de production associe |
WO2006099971A2 (fr) | 2005-03-23 | 2006-09-28 | Giesecke & Devrient Gmbh | Papier securise a plusieurs couches |
WO2016034687A1 (fr) * | 2014-09-05 | 2016-03-10 | Oberthur Fiduciaire Sas | Support papier, son procédé de fabrication et document de sécurité fabriqué avec celui-ci |
US20200063368A1 (en) * | 2018-08-23 | 2020-02-27 | Eastman Chemical Company | Paper composition cellulose and cellulose ester for improved texturing |
WO2020050971A2 (fr) * | 2018-08-23 | 2020-03-12 | Eastman Chemical Company | Articles obtenus par voie humide compostables comprenant de la cellulose et des esters de cellulose |
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DE102022001505A1 (de) | 2023-11-02 |
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