WO2023130708A1 - 一种用于汽车空调压缩机驱动盘的橡胶及其制备方法 - Google Patents

一种用于汽车空调压缩机驱动盘的橡胶及其制备方法 Download PDF

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WO2023130708A1
WO2023130708A1 PCT/CN2022/105582 CN2022105582W WO2023130708A1 WO 2023130708 A1 WO2023130708 A1 WO 2023130708A1 CN 2022105582 W CN2022105582 W CN 2022105582W WO 2023130708 A1 WO2023130708 A1 WO 2023130708A1
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parts
rubber
carbon black
automobile air
accelerator
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PCT/CN2022/105582
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English (en)
French (fr)
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汪德成
陈爱明
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宁国中奕橡塑有限公司
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C08L23/283—Halogenated homo- or copolymers of iso-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

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  • the invention relates to the field of rubber, in particular to a rubber used for a driving disk of an automobile air-conditioning compressor and a preparation method thereof.
  • Automobile air-conditioning compressor is the heart of automobile air-conditioning refrigeration system, which plays the role of compressing and transporting refrigerant vapor.
  • Air-conditioning compressors are divided into different internal working methods: crank-connecting rod type (composed of cranks, connecting rods, pistons, intake and exhaust valves, etc.); Connecting rods, pistons, intake and discharge valves, and rocking plates); swash plate compressors (composed of spindles, swash plates, cylinders, pistons, intake and exhaust valves, etc.) currently have these three types.
  • variable displacement swash plate compressor clutch device is used to transmit the power from the automobile engine to the variable displacement swash plate compressor.
  • the traditional variable displacement swash plate compressor clutch device includes a pulley assembly and a drive plate Assembly, the power of the car engine is transmitted to the drive plate through the pulley, and the drive plate transmits the power to the main shaft through the spline to make the compressor work.
  • the compressor fails or exceeds the torque set by the clutch, the drive plate and the gap The matching pulley is separated, and the compressor stops working.
  • the existing automotive air-conditioning compressor drive plate includes an outer bracket 1 and an inner bracket 2, and a rubber 3 is arranged between the outer bracket and the inner bracket.
  • the working environment of the driving disk of the automobile air-conditioning compressor is a high-temperature environment, and the rubber layer of the driving disk of the automobile air-conditioning compressor is under high temperature and stress for a long time.
  • Existing rubber cannot adapt to such a harsh environment and rapidly ages, resulting in a reduction in the service life of the drive plate of the automotive air-conditioning compressor.
  • the technical problem to be solved by the present invention is to provide a rubber used for the driving disk of the automobile air-conditioning compressor and its preparation method, so as to solve the problem that the rubber used for the driving disk of the automobile air-conditioning compressor in the prior art cannot adapt to the harsh environment and is easy to age The problem.
  • the technical scheme adopted by the present invention to solve the technical problem is: a kind of rubber used for the driving disc of the automobile air-conditioning compressor, which is made of the following raw materials in parts by weight: 80-100 parts of brominated butyl rubber, slightly 0.8-1.2 parts of crystal wax, 52-56 parts of carbon black, 8-10 parts of white carbon black, 1-1.2 parts of anti-aging agent, 6-8 parts of phenolic resin, 4-6 parts of zinc oxide, 0.3-0.5 parts of accelerator DM , 0.3-0.5 parts of accelerator NA-22, 15-45 parts of neoprene, 80-150 parts of aluminum hydroxide, 2-3 parts of 2-mercaptobenzimidazole, N-isopropyl-N'-benzene 2-3 parts of p-phenylenediamine, 0.8-1.2 parts of ETU-80, 1.0-2.0 parts of coupling agent, 0.8-1.5 parts of stearic acid, 1.5-2.5 parts of sulfur powder, 2-deoxy-22 difluoropentofranose 1.0-3.0
  • bromobutyl rubber is bromobutyl BIIR2255, and the microcrystalline wax is microcrystalline wax OK1900.
  • the dioctyl ester is environmentally friendly DOA
  • the carbon black is high wear-resistant carbon black N330.
  • the coupling agent is a silane coupling agent
  • the anti-aging agent is anti-aging agent MB
  • the phenolic resin is SP1055 resin.
  • the coupling agent is si-69.
  • the present invention also provides a method for preparing the rubber used for the driving disc of the automobile air-conditioning compressor.
  • the brominated butyl rubber is masticated in an internal mixer, and then 2 deoxygenated 22 difluoropentafranose 1 ketone 35 di Benzoate, microcrystalline wax, carbon black, white carbon black, antioxidant, phenolic resin, magnesium hydroxide, neoprene, aluminum hydroxide, coupling agent, zinc borate, flame retardant FR-320, dioctyl ester , carnauba wax, 2-mercaptobenzimidazole, N-isopropyl-N'-phenyl-p-phenylenediamine, processing aid WB-16, 5-(4-hydroxyphenyl)-2H-pyridine Furan-2-one is mixed, then zinc oxide, stearic acid, sulfur powder, accelerator DM, accelerator NA-22, ETU-80 are added for banburying to obtain a mixed material; the mixed material is added to a flat
  • the rubber used for the driving disc of the automobile air-conditioning compressor of the present invention adds microcrystalline wax, anti-aging agent, phenolic resin, accelerator DM and accelerator NA-22 to the brominated butyl rubber, which greatly improves the high temperature resistance and resistance of the rubber. corrosion performance.
  • Fig. 1 is a structural schematic diagram of a drive plate of an automobile air-conditioning compressor.
  • a kind of rubber used for the drive plate of automobile air-conditioning compressor and its preparation method it is made of the following raw materials by weight: 80 parts of brominated butyl rubber, 0.8 parts of microcrystalline wax, 52 parts of carbon black, white 8 parts of carbon black, 1 part of anti-aging agent, 6 parts of phenolic resin, 4 parts of zinc oxide, 0.3 parts of accelerator DM, 0.3 parts of accelerator NA-22, 15 parts of neoprene, 80 parts of aluminum hydroxide, 2-mercaptan 2 parts of phenylbenzimidazole, 2 parts of N-isopropyl-N′-phenyl-p-phenylenediamine, 0.8 parts of ETU-80, 1.0 parts of coupling agent, 0.8 parts of stearic acid, 1.5 parts of sulfur powder, 2 deoxygenation 22 difluoropentafranose 1 ketone 35 dibenzoate 1.0 parts, flame retardant FR-320 1.5 parts, magnesium hydroxide 2.0 parts, 5-(4-hydroxyphenyl)-2
  • a kind of rubber used for the driving disc of automobile air-conditioning compressor and its preparation method which is made of the following raw materials in parts by weight: 90 parts of bromobutyl rubber, 1 part of microcrystalline wax, 54 parts of carbon black, white 9 parts of carbon black, 1.1 parts of anti-aging agent, 7 parts of phenolic resin, 5 parts of zinc oxide, 0.4 parts of accelerator DM, 0.4 parts of accelerator NA-22, 30 parts of neoprene, 115 parts of aluminum hydroxide, 2-mercaptan 2.5 parts of phenylbenzimidazole, 2.5 parts of N-isopropyl-N′-phenyl-p-phenylenediamine, 1 part of ETU-80, 1.5 parts of coupling agent, 1.15 parts of stearic acid, 2 parts of sulfur powder, 2 deoxygenation 22 difluoropentafranose 1 ketone 35 dibenzoate 2 parts, flame retardant FR-320 2.5 parts, magnesium hydroxide 3.0 parts, 5-(4-hydroxyphenyl)
  • a kind of rubber used for the driving disc of automobile air-conditioning compressor and its preparation method it is made of the following raw materials by weight: 100 parts of brominated butyl rubber, 1.2 parts of microcrystalline wax, 56 parts of carbon black, white 10 parts of carbon black, 1.2 parts of anti-aging agent, 8 parts of phenolic resin, 6 parts of zinc oxide, 0.5 parts of accelerator DM, 0.5 parts of accelerator NA-22, 45 parts of neoprene, 150 parts of aluminum hydroxide, 2-mercaptan 3 parts of phenylbenzimidazole, 3 parts of N-isopropyl-N′-phenyl-p-phenylenediamine, 1.2 parts of ETU-80, 2.0 parts of coupling agent, 1.5 parts of stearic acid, 2.5 parts of sulfur powder, 2 deoxygenation 22 difluoropentafranose 1 ketone 35 dibenzoate 3.0 parts, flame retardant FR-320 3.5 parts, magnesium hydroxide 4.0 parts, 5-(4-hydroxyphenyl)
  • the rubber used for the driving disc of the automobile air-conditioning compressor prepared by embodiment 1, 2 and 3 is carried out the durability test respectively, and the test method is as follows:
  • the rubbers prepared in Examples 1, 2 and 3 for the driving disk of the automobile air-conditioning compressor have no peeling, cracking, damage and other abnormalities. Therefore, it can be proved that the rubber used for the driving disc of the automobile air-conditioning compressor of the present invention has excellent high temperature resistance and corrosion resistance.

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  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
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  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

一种用于汽车空调压缩机驱动盘的橡胶及其制备方法，涉及橡胶领域，包括硫磺粉，2脱氧22二氟戊芙兰糖1酮35二安息香酸盐，丁腈橡胶，硼酸锌，促进剂M，炭黑，促进剂TMTD，氯丁胶，氢氧化铝80-150份，2-硫醇基苯并咪唑，N-异丙基-N'-苯基对苯二胺，促进剂CZ，ETU-80，氧化锌，偶联剂，硬脂酸，白炭黑，阻燃剂FR-320，氢氧化镁，5-(4-羟基苯基)-2H-吡喃-2-酮，加工助剂WB-16，巴西棕榈蜡，二辛酯。本发明能够解决现有技术中的用于汽车空调压缩机驱动盘的橡胶无法适应苛刻的环境而易老化的问题。

Description

一种用于汽车空调压缩机驱动盘的橡胶及其制备方法 技术领域
本发明涉及橡胶领域，尤其是一种用于汽车空调压缩机驱动盘的橡胶及其制备方法。
背景技术
汽车空调压缩机是汽车空调制冷系统的心脏，起着压缩和输送制冷剂蒸汽的作用。空调压缩机按内部工作方式不同来分分为：曲柄连杆式(由曲柄，连杆，活塞，进排气阀等组成)；摇盘式压缩机(由主轴，圆锥齿轮，斜形板，连杆，活塞，进排阀和摇板等组成)；斜盘式压缩机(由主轴，斜盘，气缸，活塞，进排阀等组成)目前有这三种。
变排量旋转斜盘式压缩机离合装置用于将来自汽车发动机的动力传递至变排量旋转斜盘压缩机，传统的变排量旋转斜盘压缩机离合装置包括带轮总成和驱动盘总成，汽车发动机的动力通过带轮传递给驱动盘，驱动盘通过花键将动力传递给主轴，使压缩机工作，当压缩机内部出现故障或者超过离合器设定的扭矩时，驱动盘与间隙配合的带轮分离，压缩机停止工作。
现有的汽车空调压缩机驱动盘包括外支架1和内支架2，所述外支架和内支架之间设置橡胶3。汽车空调压缩机驱动盘的工作环境为高温环境且汽车空调压缩机驱动盘的橡胶层长时间处于高温和受力状态。现有的橡胶无法适应这样苛刻的环境而迅速老化，导致汽车空调压缩机驱动盘的使用寿命降低。
发明内容
本发明所要解决的技术问题是提供一种用于汽车空调压缩机驱动盘的橡胶及其制备方法，解决现有技术中的用于汽车空调压缩机驱动盘的橡胶无法适应苛刻的环境而易老化的问题。
本发明解决其技术问题所采用的技术方案是：一种用于汽车空调压缩机驱动盘的橡胶，其是由下述重量份的原料制成的：溴化丁基橡胶80-100份，微晶蜡0.8-1.2份，炭黑52-56份，白炭黑8-10份，防老剂1-1.2份，酚醛树脂6-8份，氧化锌4-6份，促进剂DM 0.3-0.5份，促进剂NA-22 0.3-0.5份，氯丁胶15-45份，氢氧化铝80-150份，2-硫醇基苯并咪唑2-3份，N-异丙基-N′-苯基对苯二胺2-3份，ETU-80 0.8-1.2份，偶联剂1.0-2.0份，硬脂酸0.8-1.5份，硫磺粉1.5-2.5份，2脱氧22二氟戊芙兰糖1酮35二安息香酸盐1.0-3.0份，阻燃剂FR-320 1.5-3.5份，氢氧化镁2.0-4.0份，5-(4-羟基苯基)-2H-吡喃-2-酮10.0-16.0份，硼酸锌20-50份，加工助剂WB-16 4-6份，巴西棕榈蜡0.4-0.6份，二辛酯30-50份。
进一步地，其是由下述重量份的原料制成的：溴化丁基橡胶80份，微晶蜡0.8份，炭黑52份，白炭黑8份，防老剂1份，酚醛树脂6份，氧化锌4份，促进剂DM 0.3份，促进剂NA-22 0.3份，氯丁胶15份，氢氧化铝80份，2-硫醇基苯并咪唑2份，N-异丙基-N′-苯基对苯二胺2份，ETU-80 0.8份，偶联剂1.0份，硬脂酸0.8份，硫磺粉1.5份，2脱氧22二氟戊芙兰糖1酮35二安息香酸盐1.0份，阻燃剂FR-320 1.5份，氢氧化镁2.0份，5-(4-羟基苯基)-2H-吡喃-2-酮10.0份，硼酸锌20份，加工助剂WB-16 4份，巴西棕榈蜡0.4份，二辛酯30份。
进一步地，其是由下述重量份的原料制成的：溴化丁基橡胶90份，微晶蜡1份，炭黑54份，白炭黑9份，防老剂1.1份，酚醛树脂7份，氧化锌5份，促进剂DM 0.4份，促进剂NA-22 0.4份，氯丁胶30份，氢氧化铝115份，2-硫醇基苯并咪唑2.5份，N-异丙基-N′-苯基对苯二胺2.5份，ETU-80 1份，偶联剂1.5份，硬脂酸1.15份，硫磺粉2份，2脱氧22二氟戊芙兰糖1酮35二安息香酸盐2份，阻燃剂FR-320 2.5份，氢氧化镁3.0份，5-(4-羟基苯基)-2H-吡喃-2-酮13份，硼酸锌35份，加工助剂WB-16 5份，巴西棕榈蜡0.5份，二辛酯40份。
进一步地，其是由下述重量份的原料制成的：溴化丁基橡胶100份，微晶蜡1.2份，炭黑56份，白炭黑10份，防老剂1.2份，酚醛树脂8份，氧化锌6份，促进剂DM 0.5份，促进剂NA-22 0.5份，氯丁胶45份，氢氧化铝150份，2- 硫醇基苯并咪唑3份，N-异丙基-N′-苯基对苯二胺3份，ETU-80 1.2份，偶联剂2.0份，硬脂酸1.5份，硫磺粉2.5份，2脱氧22二氟戊芙兰糖1酮35二安息香酸盐3.0份，阻燃剂FR-320 3.5份，氢氧化镁4.0份，5-(4-羟基苯基)-2H-吡喃-2-酮16.0份，硼酸锌50份，加工助剂WB-16 6份，巴西棕榈蜡0.6份，二辛酯50份。
进一步地，所述溴化丁基橡胶为溴化丁基BIIR2255，所述微晶蜡为微晶蜡0K1900。
进一步地，所述二辛酯为环保DOA，所述炭黑为高耐磨炭黑N330。
进一步地，所述偶联剂为硅烷偶联剂，所述防老剂为防老剂MB，所述酚醛树脂为SP1055树脂。
进一步地，所述的偶联剂为si-69。
本发明还提供了一种用于汽车空调压缩机驱动盘的橡胶的制备方法，将溴化丁基橡胶在密炼机中塑炼，再加入2脱氧22二氟戊芙兰糖1酮35二安息香酸盐、微晶蜡、炭黑、白炭黑、防老剂、酚醛树脂、氢氧化镁、氯丁胶、氢氧化铝、偶联剂、硼酸锌、阻燃剂FR-320、二辛酯、巴西棕榈蜡、2-硫醇基苯并咪唑、N-异丙基-N′-苯基对苯二胺、加工助剂WB-16、5-(4-羟基苯基)-2H-吡喃-2-酮进行混炼，接着加入氧化锌、硬脂酸、硫磺粉、促进剂DM、促进剂NA-22、ETU-80进行密炼，得到混合物料；将混合物料加入平板硫化机中进行硫化，得到所述用于汽车空调压缩机驱动盘的橡胶。
本发明具有如下有益效果：
本发明的用于汽车空调压缩机驱动盘的橡胶在溴化丁基橡胶中加入微晶蜡、防老剂、酚醛树脂、促进剂DM和促进剂NA-22，大大提高了橡胶的耐高温和耐腐蚀性能。
附图说明：
图1为汽车空调压缩机驱动盘的结构示意图。
具体实施方式
实施例1：
一种用于汽车空调压缩机驱动盘的橡胶及其制备方法，其是由下述重量份的 原料制成的：溴化丁基橡胶80份，微晶蜡0.8份，炭黑52份，白炭黑8份，防老剂1份，酚醛树脂6份，氧化锌4份，促进剂DM 0.3份，促进剂NA-22 0.3份，氯丁胶15份，氢氧化铝80份，2-硫醇基苯并咪唑2份，N-异丙基-N′-苯基对苯二胺2份，ETU-80 0.8份，偶联剂1.0份，硬脂酸0.8份，硫磺粉1.5份，2脱氧22二氟戊芙兰糖1酮35二安息香酸盐1.0份，阻燃剂FR-320 1.5份，氢氧化镁2.0份，5-(4-羟基苯基)-2H-吡喃-2-酮10.0份，硼酸锌20份，加工助剂WB-16 4份，巴西棕榈蜡0.4份，二辛酯30份。
其制备方法如下：
将溴化丁基橡胶80份在密炼机中塑炼，再加入2脱氧22二氟戊芙兰糖1酮35二安息香酸盐1.0份、微晶蜡0.8份、炭黑52份、白炭黑8份、防老剂1份、酚醛树脂6份、氢氧化镁2.0份、氯丁胶15份、氢氧化铝80份、偶联剂1.0份、硼酸锌20份、阻燃剂FR-320 1.5份、二辛酯30份、巴西棕榈蜡0.4份、2-硫醇基苯并咪唑2份、N-异丙基-N′-苯基对苯二胺2份、加工助剂WB-16 4份、5-(4-羟基苯基)-2H-吡喃-2-酮10.0份进行混炼，接着加入氧化锌4份、硬脂酸0.8份、硫磺粉1.5份、促进剂DM0.3份、促进剂NA-22 0.3份、ETU-80 0.8份进行密炼，得到混合物料；将混合物料加入平板硫化机中进行硫化，得到所述用于汽车空调压缩机驱动盘的橡胶。
实施例2：
一种用于汽车空调压缩机驱动盘的橡胶及其制备方法，其是由下述重量份的原料制成的：溴化丁基橡胶90份，微晶蜡1份，炭黑54份，白炭黑9份，防老剂1.1份，酚醛树脂7份，氧化锌5份，促进剂DM 0.4份，促进剂NA-22 0.4份，氯丁胶30份，氢氧化铝115份，2-硫醇基苯并咪唑2.5份，N-异丙基-N′-苯基对苯二胺2.5份，ETU-80 1份，偶联剂1.5份，硬脂酸1.15份，硫磺粉2份，2脱氧22二氟戊芙兰糖1酮35二安息香酸盐2份，阻燃剂FR-320 2.5份，氢氧化镁3.0份，5-(4-羟基苯基)-2H-吡喃-2-酮13份，硼酸锌35份，加工助剂WB-16 5份，巴西棕榈蜡0.5份，二辛酯40份。
其制备方法如下：
将溴化丁基橡胶90份在密炼机中塑炼，再加入2脱氧22二氟戊芙兰糖1酮35二安息香酸盐2份、微晶蜡1份、炭黑54份、白炭黑9份、防老剂1.1 份、酚醛树脂7份、氢氧化镁3.0份、氯丁胶30份、氢氧化铝115份、偶联剂1.5份、硼酸锌35份、阻燃剂FR-320 2.5份、二辛酯40份、巴西棕榈蜡0.5份、2-硫醇基苯并咪唑2.5份、N-异丙基-N′-苯基对苯二胺2.5份、加工助剂WB-16 5份、5-(4-羟基苯基)-2H-吡喃-2-酮13份进行混炼，接着加入氧化锌5份、硬脂酸1.15份、硫磺粉2份、促进剂DM 0.4份、促进剂NA-22 0.4份、ETU-801份进行密炼，得到混合物料；将混合物料加入平板硫化机中进行硫化，得到所述用于汽车空调压缩机驱动盘的橡胶。
实施例3：
一种用于汽车空调压缩机驱动盘的橡胶及其制备方法，其是由下述重量份的原料制成的：溴化丁基橡胶100份，微晶蜡1.2份，炭黑56份，白炭黑10份，防老剂1.2份，酚醛树脂8份，氧化锌6份，促进剂DM 0.5份，促进剂NA-22 0.5份，氯丁胶45份，氢氧化铝150份，2-硫醇基苯并咪唑3份，N-异丙基-N′-苯基对苯二胺3份，ETU-80 1.2份，偶联剂2.0份，硬脂酸1.5份，硫磺粉2.5份，2脱氧22二氟戊芙兰糖1酮35二安息香酸盐3.0份，阻燃剂FR-320 3.5份，氢氧化镁4.0份，5-(4-羟基苯基)-2H-吡喃-2-酮16.0份，硼酸锌50份，加工助剂WB-16 6份，巴西棕榈蜡0.6份，二辛酯50份。
其制备方法如下：
将溴化丁基橡胶100份在密炼机中塑炼，再加入2脱氧22二氟戊芙兰糖1酮35二安息香酸盐3.0份、微晶蜡1.2份、炭黑56份、白炭黑10份、防老剂1.2份、酚醛树脂8份、氢氧化镁4.0份、氯丁胶45份、氢氧化铝150份、偶联剂2.0份、硼酸锌50份、阻燃剂FR-320 3.5份、二辛酯50份、巴西棕榈蜡0.6份、2-硫醇基苯并咪唑3份、N-异丙基-N′-苯基对苯二胺3份、加工助剂WB-16 6份、5-(4-羟基苯基)-2H-吡喃-2-酮16.0份进行混炼，接着加入氧化锌6份、硬脂酸1.5份、硫磺粉2.5份、促进剂DM 0.5份、促进剂NA-22 0.5份、ETU-80 1.2份进行密炼，得到混合物料；将混合物料加入平板硫化机中进行硫化，得到所述用于汽车空调压缩机驱动盘的橡胶。
将实施例1、2和3制备的用于汽车空调压缩机驱动盘的橡胶分别进行耐久性试验，试验方法如下：
将外支架1固定，使内支架2受力产生轴向位移0.6mm，加在0-49N.m振幅 扭转，在120度高温箱中，测试整个汽车空调压缩机驱动盘的橡胶的耐疲劳性能，测试频率6Hz，扭转次数200万次。
经过耐久性试验，实施例1、2和3制备的用于汽车空调压缩机驱动盘的橡胶均无剥离、龟裂、破损和其他异常。由此能够证明本发明的用于汽车空调压缩机驱动盘的橡胶具有优良的耐高温和耐腐蚀性能。
以上所述，仅是本发明的较佳实施例而已，并非对本发明作任何形式上的限制，任何熟悉本专业的技术人员，在不脱离本发明技术方案范围内，当可利用上述揭示的技术内容做出些许更动或修饰为等同变化的等效实施例，但凡是未脱离本发明技术方案内容，依据本发明的技术实质，在本发明的精神和原则之内，对以上实施例所作的任何简单的修改、等同替换与改进等，均仍属于本发明技术方案的保护范围之内。

Claims (9)

  1. 一种用于汽车空调压缩机驱动盘的橡胶，其特征在于，其是由下述重量份的原料制成的：溴化丁基橡胶80-100份，微晶蜡0.8-1.2份，炭黑52-56份，白炭黑8-10份，防老剂1-1.2份，酚醛树脂6-8份，氧化锌4-6份，促进剂DM 0.3-0.5份，促进剂NA-22 0.3-0.5份，氯丁胶15-45份，氢氧化铝80-150份，2-硫醇基苯并咪唑2-3份，N-异丙基-N′-苯基对苯二胺2-3份，ETU-80 0.8-1.2份，偶联剂1.0-2.0份，硬脂酸0.8-1.5份，硫磺粉1.5-2.5份，2脱氧22二氟戊芙兰糖1酮35二安息香酸盐1.0-3.0份，阻燃剂FR-320 1.5-3.5份，氢氧化镁2.0-4.0份，5-(4-羟基苯基)-2H-吡喃-2-酮10.0-16.0份，硼酸锌20-50份，加工助剂WB-16 4-6份，巴西棕榈蜡0.4-0.6份，二辛酯30-50份。
  2. 如权利要求1所述的一种用于汽车空调压缩机驱动盘的橡胶，其特征在于，其是由下述重量份的原料制成的：溴化丁基橡胶80份，微晶蜡0.8份，炭黑52份，白炭黑8份，防老剂1份，酚醛树脂6份，氧化锌4份，促进剂DM 0.3份，促进剂NA-22 0.3份，氯丁胶15份，氢氧化铝80份，2-硫醇基苯并咪唑2份，N-异丙基-N′-苯基对苯二胺2份，ETU-80 0.8份，偶联剂1.0份，硬脂酸0.8份，硫磺粉1.5份，2脱氧22二氟戊芙兰糖1酮35二安息香酸盐1.0份，阻燃剂FR-320 1.5份，氢氧化镁2.0份，5-(4-羟基苯基)-2H-吡喃-2-酮10.0份，硼酸锌20份，加工助剂WB-16 4份，巴西棕榈蜡0.4份，二辛酯30份。
  3. 如权利要求1所述的一种用于汽车空调压缩机驱动盘的橡胶，其特征在于，其是由下述重量份的原料制成的：溴化丁基橡胶90份，微晶蜡1份，炭黑54份，白炭黑9份，防老剂1.1份，酚醛树脂7份，氧化锌5份，促进剂DM 0.4份，促进剂NA-22 0.4份，氯丁胶30份，氢氧化铝115份，2-硫醇基苯并咪唑2.5份，N-异丙基-N′-苯基对苯二胺2.5份，ETU-80 1份，偶联剂1.5份，硬脂酸1.15份，硫磺粉2份，2脱氧22二氟戊芙兰糖1酮35二安息香酸盐2份，阻燃剂FR-320 2.5份，氢氧化镁3.0份，5-(4-羟基苯基)-2H-吡喃-2-酮13份，硼酸锌35份，加工助剂WB-16 5份，巴西棕榈蜡0.5份，二辛酯40份。
  4. 如权利要求1所述的一种用于汽车空调压缩机驱动盘的橡胶，其特征在于，其是由下述重量份的原料制成的：溴化丁基橡胶100份，微晶蜡1.2份，炭黑56份，白炭黑10份，防老剂1.2份，酚醛树脂8份，氧化锌6份，促进剂DM 0.5份，促进剂NA-22 0.5份，氯丁胶45份，氢氧化铝150份，2-硫醇基苯并咪唑3份，N-异丙基-N′-苯基对苯二胺3份，ETU-80 1.2份，偶联剂2.0份，硬脂酸1.5份，硫磺粉2.5份，2脱氧22二氟戊芙兰糖1酮35二安息香酸盐3.0份，阻燃剂FR-320 3.5份，氢氧化镁4.0份，5-(4-羟基苯基)-2H-吡喃-2-酮16.0份，硼酸锌50份，加工助剂WB-16 6份，巴西棕榈蜡0.6份，二辛酯50份。
  5. 如权利要求1-4任一所述的一种用于汽车空调压缩机驱动盘的橡胶，其特征在于，所述溴化丁基橡胶为溴化丁基BIIR2255，所述微晶蜡为微晶蜡0K1900。
  6. 如权利要求1-4任一所述的一种用于汽车空调压缩机驱动盘的橡胶，其特征在于，所述二辛酯为环保DOA，所述炭黑为高耐磨炭黑N330。
  7. 如权利要求1-4任一所述的一种用于汽车空调压缩机驱动盘的橡胶，其特征在于，所述偶联剂为硅烷偶联剂，所述防老剂为防老剂MB，所述酚醛树脂为SP1055树脂。
  8. 如权利要求7任一所述的一种用于汽车空调压缩机驱动盘的橡胶，其特征在于，所述的偶联剂为si-69。
  9. 如权利要求1-8任一所述的一种用于汽车空调压缩机驱动盘的橡胶的制备方法，其特征在于：将溴化丁基橡胶在密炼机中塑炼，再加入2脱氧22二氟戊芙兰糖1酮35二安息香酸盐、微晶蜡、炭黑、白炭黑、防老剂、酚醛树脂、氢氧化镁、氯丁胶、氢氧化铝、偶联剂、硼酸锌、阻燃剂FR-320、二辛酯、巴西棕榈蜡、2-硫醇基苯并咪唑、N-异丙基-N′-苯基对苯二胺、加工助剂WB-16、5-(4-羟基苯基)-2H-吡喃-2-酮进行混炼，接着加入氧化锌、硬脂酸、硫磺粉、促进剂DM、促进剂NA-22、ETU-80进行密炼，得到混合物料；将混合物料加入平板硫化机中进行硫化，得到所述用于汽车空调压缩机驱动盘的橡胶。
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