WO2023112643A1 - ガス発生器 - Google Patents
ガス発生器 Download PDFInfo
- Publication number
- WO2023112643A1 WO2023112643A1 PCT/JP2022/043639 JP2022043639W WO2023112643A1 WO 2023112643 A1 WO2023112643 A1 WO 2023112643A1 JP 2022043639 W JP2022043639 W JP 2022043639W WO 2023112643 A1 WO2023112643 A1 WO 2023112643A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- holder
- housing
- gas
- igniter
- diameter
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 claims description 27
- 239000002184 metal Substances 0.000 claims description 27
- 229920005989 resin Polymers 0.000 claims description 14
- 239000011347 resin Substances 0.000 claims description 14
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- 239000000956 alloy Substances 0.000 claims description 6
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- 239000003795 chemical substances by application Substances 0.000 description 32
- 230000002265 prevention Effects 0.000 description 13
- 238000002485 combustion reaction Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- -1 polybutylene terephthalate Polymers 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 4
- 229910001487 potassium perchlorate Inorganic materials 0.000 description 4
- 239000002893 slag Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- ULRPISSMEBPJLN-UHFFFAOYSA-N 2h-tetrazol-5-amine Chemical compound NC1=NN=NN1 ULRPISSMEBPJLN-UHFFFAOYSA-N 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
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- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 229910001120 nichrome Inorganic materials 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 239000004323 potassium nitrate Substances 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- IDCPFAYURAQKDZ-UHFFFAOYSA-N 1-nitroguanidine Chemical compound NC(=N)N[N+]([O-])=O IDCPFAYURAQKDZ-UHFFFAOYSA-N 0.000 description 1
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical class NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 229910002010 basic metal nitrate Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229940116318 copper carbonate Drugs 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- NDEMNVPZDAFUKN-UHFFFAOYSA-N guanidine;nitric acid Chemical compound NC(N)=N.O[N+]([O-])=O.O[N+]([O-])=O NDEMNVPZDAFUKN-UHFFFAOYSA-N 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- WETZJIOEDGMBMA-UHFFFAOYSA-L lead styphnate Chemical compound [Pb+2].[O-]C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C([O-])=C1[N+]([O-])=O WETZJIOEDGMBMA-UHFFFAOYSA-L 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
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- 238000003825 pressing Methods 0.000 description 1
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- 230000001681 protective effect Effects 0.000 description 1
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- 150000003839 salts Chemical class 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 229910000048 titanium hydride Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J7/00—Apparatus for generating gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R21/00—Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
- B60R21/02—Occupant safety arrangements or fittings, e.g. crash pads
- B60R21/16—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags
- B60R21/26—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags characterised by the inflation fluid source or means to control inflation fluid flow
- B60R21/264—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags characterised by the inflation fluid source or means to control inflation fluid flow using instantaneous generation of gas, e.g. pyrotechnic
Definitions
- the present invention relates to a gas generator incorporated in an airbag device as an occupant protection device mounted in an automobile or the like, and more particularly to a so-called cylinder-shaped gas generator having a long cylindrical shape.
- a long cylindrical housing in a cylinder-type gas generator is generally configured such that one end is closed with a closing member and the other end is closed with a holder having an ignition part (see, for example, the following patents Reference 1).
- an object of the present invention is to provide a gas generator that is easier to manufacture than conventional ones.
- the gas generator of the present invention is loaded with a gas generating agent that generates gas by burning, contains a filter through which the gas passes, and ejects the gas at a position corresponding to the filter.
- a fixed cylindrical holder and a closing member fixed to the other end in the axial direction of the housing are provided.
- a tubular first holder capable of fitting an external connector for energizing the igniter;
- the outer diameter of the portion that contacts the inner wall of the housing (hereinafter referred to as the contact portion) is larger than the outer diameter of the other end side of the first holder or the same as the outer diameter of the other end side of the first holder.
- a cylindrical second holder having a diameter, and at least a portion having a diameter smaller than the diameter of the end portion opposite to the second holder side (hereinafter referred to as a small diameter portion) on the outer surface, and was in contact with the second holder.
- a cylindrical third holder arranged inside the housing with respect to the second holder, and corresponding to the contact portion of the second holder on the first holder side.
- the outer side of the housing is subjected to diameter-reduction processing, and together with the second holder, at least the second holder of the first holder is contacted.
- the holder is fixed to the housing by clamping a portion of the third holder that is in contact with the second holder by a portion of the housing whose diameter is reduced.
- a flange is provided on the closing member side of the third holder, and at least at the time of operation, the tip of the flange is attached to the housing. It is preferably in contact with the inner wall.
- the gas generator of the present invention is loaded with a gas generating agent that generates gas by combustion, and includes therein a filter through which the gas passes, and a position corresponding to the filter.
- a long cylindrical housing in which a gas ejection port for ejecting gas is formed;
- An igniter capable of igniting and burning the gas generating agent, and having a cylindrical cup-shaped member on the side of the gas generating agent;
- the contact portion has an outer diameter larger than the outer diameter of the other end side of the first holder or an outer diameter of the other end side of the first holder.
- a cylindrical second holder having the same diameter as the second holder, and at least a portion having a diameter smaller than the diameter of the end portion opposite to the second holder side (hereinafter referred to as a small diameter portion) on the outer surface, and
- a flange portion is provided on the closing member side, and is attached to the second holder so that the tip portion of the flange portion contacts the inner wall of the housing in a state of contact with the second holder and at least during operation.
- a cylindrical third holder disposed on the inner side of the housing, a portion of the contact portion of the second holder corresponding to the portion on the first holder side;
- the diameter of the housing is reduced from the outside of the housing at a location corresponding to the small diameter portion, and at least a portion of the first holder that is in contact with the second holder is subjected to diameter reduction of the housing together with the second holder.
- the first holder and the second holder are fixed to the housing by being clamped by the machined portions, and the third holder presses the inside into the cup-shaped member of the igniter to ignite the ignition. It may be characterized by being fixed to the vessel.
- the surface of the third holder on the side of the gas generating agent formed around the tip of the igniter and the tip of the igniter It is preferable that the surface of the third holder on the side of the gas generating agent is formed so as to be flush with the surface of the third holder.
- the second holder includes a fitting portion for fitting and holding the igniter inside, and an open end portion on the other end side. and a crimped portion for crimping and fixing the igniter, wherein the third holder is preferably formed so as to cover the crimped portion.
- the first holder and the third holder are made of resin, and the second holder is made of metal or alloy.
- FIG. 3 is a schematic diagram (partially omitted) showing the internal structure of a gas generator according to a second embodiment of the present invention, partly shown in cross section.
- FIG. 3 is a schematic diagram (partially omitted) showing the internal structure of a gas generator according to a third embodiment of the present invention, partly represented in cross section.
- FIG. 10 is a schematic diagram (partially omitted) showing the internal structure of a gas generator according to a fourth embodiment of the present invention, partly shown in cross section.
- the gas generator 100 has an elongated, substantially cylindrical outer shape, and includes a housing 10, a first holder 20, a second holder 25, and a third holder 53 attached near one open end of the housing 10. and a closure member 12 attached to the other end of housing 10 to close the other open end of housing 10 .
- the first holder 20 , the second holder 25 , and the third holder 53 constitute a holder that holds the igniter 50 .
- the housing 10 is a long cylindrical member having peripheral walls 10a, 10b, 10c, 10d, and 10e and openings at both ends in the axial direction.
- the closing member 12 has annular grooves 13 and 14 formed by reducing the diameter of the peripheral surface of a bottomed tubular member having a predetermined thickness by caulking (an example of a diameter-reducing method), which will be described later. It is formed in a substantially pot shape having an internal space 12a.
- the annular grooves 13 and 14 formed by this caulking are formed on the peripheral surface of the closing member 12 so as to extend in the circumferential direction.
- a gas ejection port 11 is provided in the peripheral wall near the end of the housing 10 on the side where the closing member 12 is attached.
- the gas ejection port 11 is a hole for ejecting gas generated inside the gas generator 100 to the outside, and is provided in plural along the circumferential direction and the axial direction of the housing 10 .
- the closing member 12 is made of metal such as stainless steel, steel, aluminum alloy, or stainless alloy. Then, as shown in FIG. 1, with a portion of the closing member 12 inserted into one open end of the housing 10, the peripheral wall of the housing 10 at a portion corresponding to a portion of the peripheral surface of the closing member 12 is opened. Closing member 12 is crimped and fixed to housing 10 by forming annular grooves 13 and 14 by reducing (caulking) 10a and 10b radially inward.
- the first holder 20 is a substantially cylindrical member made of resin, and is fitted with a female connector (not shown) for energizing the igniter 50 on the side opposite to the holding position of the igniter 50. 21, an annular groove 22 formed on the outer peripheral surface so as to extend in the circumferential direction, and a flange 26 formed at the end of the annular groove 22 on the second holder 25 side.
- the flange portion 26 is formed with an outer diameter smaller than the outer diameter of the annular portion 27 of the second holder 25 .
- the annular portion 27 has a portion (contact portion) on its outer periphery that contacts the inner wall of the housing.
- the peripheral wall 10e of the housing 10 at a portion corresponding to the flange portion 26 provided on the outer peripheral surface of the first holder 20 is contracted (crimped) radially inward to engage the flange portion 26.
- the first holder 20 is caulked and fixed to 10 .
- the end portion of the second holder 25 on the first holder 20 side is inserted inside the first holder 20 . Accordingly, when the peripheral wall 10 e of the housing 10 is contracted radially inward, the flange portion 26 is sandwiched between the end of the second holder 25 on the first holder 20 side and the inner wall of the peripheral wall 10 e of the housing 10 . , and the first holder 20 can be fixed to the housing 10 more firmly.
- a simple end portion (without a radially protruding flange) continuous from the surface of the annular groove portion 22 is used as the end portion of the second holder 25. 1 holder 20 side and the inner wall of the peripheral wall 10 e of the housing 10 may be sandwiched.
- thermosetting resins represented by epoxy resins, etc.
- polybutylene terephthalate resin polyethylene terephthalate resin
- polyamide resin for example, nylon 6, nylon 66, etc.
- polypropylene sulfide resin polypropylene oxide resin
- polyacetal resin etc.
- thermoplastic resin represented by When these thermoplastic resins are selected as the raw material, it is preferable that these resin materials contain glass fiber or the like as a filler in order to secure the mechanical strength of the first holder 20 after molding. However, if sufficient mechanical strength can be ensured only by the thermoplastic resin, it is not necessary to add the filler as described above.
- the third holder 53 can also be made of the same raw material as the first holder 20 .
- the fitting portion 21 of the first holder 20 is formed with a female connector.
- This female connector is a portion to which a male connector of a harness for transmitting a signal from collision detection means provided separately from the gas generator 100 is connected.
- a retainer (not shown) is attached to the female connector. This retainer is attached to prevent the cylindrical gas generator 100 from malfunctioning due to electrostatic discharge or the like when the gas generator 100 is transported. The contact with the terminal pin 52 is released by inserting the male connector into the female connector.
- the portion of the second holder 25 that contacts the inner wall of the housing 10 is larger than the outer diameter of the flange portion 26 of the first holder 20, and is made of a metal such as stainless steel or steel, an aluminum alloy, or a stainless alloy. It is a substantially cylindrical member.
- the second holder 25 has a tapered fitting portion 23 into which a portion of the igniter 50 (mainly a main body portion) is inserted and the igniter 50 is fitted. is inserted inside the first holder 20 .
- the igniter 50 is crimped and fixed to the second holder 25 by a crimp portion 24 provided at the open end.
- the second holder 25 is fixed to the housing 10 by forming the peripheral wall 10d described later and the peripheral wall 10e described above in a state in which the second holder 25 is sandwiched between the first holder 20 and the third holder 53.
- the third holder 53 is a substantially cylindrical member made of resin, and includes an annular groove 54 (small diameter portion) for caulking and fixing formed on the outer peripheral surface so as to extend in the circumferential direction, and an end of the squib cup 51 . It has a surface 55 that is flush with or substantially flush with the surface of the part.
- the third holder 53 is fixed to the housing 10 by performing a diameter reduction process (caulking or the like) from the outer periphery of the housing 10 to the inner side at a position corresponding to the annular groove 54 to form the peripheral wall 10d.
- a part of the igniter 50 (mainly the squib cup 51) and the crimped portion 24 are inserted into the third holder 53. As shown in FIG.
- the third holder 53 is also a directional member that directs the flame generated in the igniter 50 toward the gas generating agent 31 during operation.
- the annular groove portion 54 does not necessarily have to have a groove shape. 31 side) is formed so as to include at least a portion with a smaller diameter than the diameter of the end portion (portion near the surface 55).
- one end portion of the housing 10 in the axial direction (that is, the portion near the holders (the first holder 20, the second holder 25, and the third holder 53)) has an ignition means for the gas generating agent 31.
- igniters 50 are arranged.
- the igniter 50 and the holders (first holder 20, second holder 25, third holder 53) for fixing the igniter 50 are ignition means for generating a flame for burning the granular gas generating agent 31, which will be described later. It has a function as
- the igniter 50 is inserted into the fitting portion 23 of the second holder 25 and held together with a third holder 53, which will be described later. More specifically, the igniter 50 includes a base frame through which a pair of terminal pins 52 are inserted and held, and a squib cup 51 (cup-shaped member) mounted on the base frame. A resistor (bridge wire) is attached so as to connect the tips of the terminal pins 52 inserted into the squib cup 51 so as to surround or contact the resistor.
- a nichrome wire or the like is generally used as the resistor, and ZPP (zirconium/potassium perchlorate), ZWPP (zirconium/tungsten/potassium perchlorate), lead tricinate, or the like is generally used as the igniter.
- the squib cup 51 may be filled with a transfer charge as well.
- a predetermined amount of current flows through the resistor via the terminal pin 52 .
- Joule heat is generated in the resistor, and the igniter starts burning upon receiving this heat.
- a high-temperature flame generated by the combustion ruptures the squib cup 51 containing the ignition charge.
- the time from when the current flows through the resistor until the igniter 50 is activated is 2 milliseconds or less when the nichrome wire is used as the resistor.
- the squib cup 51 is generally made of metal or resin. A portion of the peripheral wall portion of the squib cup 51 other than the vicinity of the tip portion is crimped and fixed to the second holder 25 by the crimp portion 24 together with the igniter 50 .
- a gas generating agent 31 In the housing 10, in the space between the igniter 50 and the filter 41, a gas generating agent 31, an AI agent 32, a coil spring 35, and a bypass prevention member 36 are arranged.
- the gas generating agent 31 is an integrally molded product that is ignited by the flame generated by the igniter 50 and burns to generate gas. Also, the gas generating agent 31 is generally formed as a molded body containing fuel, oxidant and additive.
- the fuel for example, a triazole derivative, a tetrazole derivative, a guanidine derivative, an azodicarbonamide derivative, a hydrazine derivative, or a combination thereof is used. Specifically, nitroguanidine, guanidine nitrate, cyanoguanidine, 5-aminotetrazole and the like are preferably used.
- the oxidizing agent examples include basic metal nitrates such as basic copper nitrate, basic metal carbonates such as basic copper carbonate, perchlorates such as ammonium perchlorate and potassium perchlorate, and alkali metals. , alkaline earth metals, transition metals, nitrates containing cations selected from ammonia, and the like are used. As nitrates, for example, sodium nitrate, potassium nitrate and the like are preferably used. Additives include binders, slag forming agents, combustion modifiers, and the like.
- Suitable binders include cellulose derivatives such as hydroxypropylene methyl cellulose, organic binders such as metal salts of carboxymethyl cellulose and stearates, and inorganic binders such as synthetic hydroxytalcite and acid clay.
- cellulose derivatives such as hydroxypropylene methyl cellulose
- organic binders such as metal salts of carboxymethyl cellulose and stearates
- inorganic binders such as synthetic hydroxytalcite and acid clay.
- silicon nitride, silica, acid clay, etc. can be suitably used.
- Metal oxides, ferrosilicon, activated carbon, graphite and the like can be suitably used as combustion modifiers.
- the bypass prevention member 36 has a bottom surface portion 36a with a weak portion in the center and an outer peripheral wall portion 36b, and is welded and fixed to the housing 10 via a peripheral wall 10c which is also a welded portion.
- This bypass prevention member 36 is also a member that partitions the housing 10 into the filter 41 and the combustion chamber of the gas generating agent 31, and during operation, the fragile portion of the bottom surface portion 36a is broken by the pressure of the generated gas.
- the bypass prevention member 36 is arranged such that the bottom surface portion 36 a is in contact with the end portion of the filter 41 and the outer peripheral wall portion 36 b is in contact with the inner wall of the housing 10 .
- the generated gas can be bypassed from between the inner wall of the housing 10 and the outer peripheral portion of the filter 41 and prevented from leaking out to the gas ejection port 11 . That is, the bypass prevention member 36 can allow the gas generated during operation to flow into the filter 41 side through the ruptured central portion.
- the coil spring 35 is arranged so that one end abuts the tip side (flame injection side) of the igniter 50 . Further, the coil spring 35 is formed in a helical shape expanding in diameter from one end side to the other end side, and presses the gas generating agent 31 toward the bypass prevention member 36 side at the other end side.
- the AI agent 32 is provided in a substantially central portion on the igniter 50 side of the bottom portion 36a of the bypass prevention member 36, and has an auto ignition (AI) function that automatically ignites without depending on the operation of the igniter 50. There is. More specifically, since the AI agent 32 automatically ignites at a temperature lower than that of the gas generating agent 31, a fire or the like should occur in a vehicle or the like equipped with an airbag device or the like incorporating the gas generator 100. In this case, abnormal operation of the gas generator 100 due to external heating can be prevented.
- AI auto ignition
- the filter 41 is composed of a cylindrical member having a substantially cylindrical hollow portion 41a at its center.
- a wire material made of metal such as stainless steel or iron steel, a wire material wound with a mesh material, or a material compacted by pressing is used.
- a knitted wire mesh, a plain-woven wire mesh, or an aggregate of crimp-woven metal wires is used.
- the filter 41 functions as a cooling means for cooling the gas generated in the housing 10 by removing high-temperature heat from the gas when it passes through the filter 41, and also removes slag contained in the gas.
- a filter having a labyrinth-like channel formed by combining metal parts having a substantially cylindrical shape or a mortar shape may be used.
- the course of the working gas can be changed in various directions, so it is possible to cool the gas and remove slag.
- the punching metal means a metal plate in which only openings are provided in a plate-like metal member (that is, no projections are provided around the openings), and the expanded metal is a plate-like metal member with, for example, It is a metal plate that is formed into a mesh by forming openings in the plate-like metal member by making cuts in a zigzag pattern and expanding the cuts. Even when such punched metal or expanded metal is used in place of the above-described knitted wire mesh, the same effects as those described in the above-described embodiment of the present invention can be obtained.
- a filter composed of a laminate is configured by winding a single metal plate member, but the configuration of the filter is limited to this configuration. isn't it. That is, each layer may be composed of separate metal plate-shaped members and combined to form a filter composed of a laminate, or a part of a plurality of layers may be made of a single metal. , and the remaining layer is formed by winding another single metal plate member, and these are combined to form a filter consisting of a laminate. good too.
- the collision is detected by collision detection means separately provided in the vehicle, and the igniter 50 works.
- the igniter 50 is actuated, the combustion of the igniter increases the pressure in the igniter 50 , which ruptures the tip of the squib cup 51 of the igniter 50 , and the flame spreads from the tip of the squib cup 51 of the igniter 50 into the housing 10 . flows out to the gas generating agent 31 side.
- the flame that has flowed in this way ignites and burns the gas generating agent 31 in the housing 10, generating a large amount of gas. Combustion of the gas generating agent 31 increases the pressure in the housing 10, and the generated gas bursts the fragile portion of the bottom surface portion 36a of the bypass prevention member 36 and flows into the hollow portion 41a and the internal space 12a. Thereafter, the generated gas passes through the filter 41 and is ejected from the gas ejection port 11 to the outside of the gas generator 100. Since it passes through the filter 41, the generated gas reaches a predetermined temperature. Cooled. The gas ejected from the gas ejection port 11 is guided inside the airbag to inflate and deploy the airbag.
- the pressure in the vicinity of the igniter 50 immediately after the igniter 50 is activated can be increased compared to when there is the empty volume. can.
- the time (TTFG) from the start of operation until the generated gas is ejected from the gas ejection port can be shortened, but also the combustibility of the gas generating agent 31 can be shortened.
- the pressure in the housing 10, which rises with the passage of time can be made sharper in the initial stage than in the conventional case. (Improved Pt performance).
- the directivity of the flame direction of the igniter 50 is given by the third holder 53, and the peripheral wall 10d deformed by the diameter-reduction processing of the housing 10 is used for the gas generated during operation. It can reliably protect against pressure.
- the third holder 53 has a surface 55 that is flush or substantially flush with the surface of the tip of the squib cup 51, the directivity of the flame direction of the igniter 50 is further increased by the third holder 53. The accuracy can be improved, and the peripheral wall 10d can be more accurately protected from the gas pressure generated during operation.
- the end of the first holder 20 on the side of the second holder 25 is sandwiched between the end of the second holder 25 on the side of the first holder 20 and the inner wall of the peripheral wall 10 e of the housing 10 .
- the first holder 20 can be fixed to the housing 10 more firmly. That is, even if the holder is divided into three members (the first holder 20, the second holder 25, and the third holder 53), the housing 10 and the holders (the first holder 20, the second holder 25, and the third holder 53) It is possible to ensure the sealing performance between
- the third holder 53 can be used as a protective member for the crimped portion 24 of the second holder 25.
- the first holder 20 and the third holder 53 are made of resin, and the second holder 25 is made of metal or alloy. , the weight can be reduced as compared with the case where the entire holder is made of metal or alloy. That is, according to the present embodiment, it is possible to provide the gas generator 100 that can be manufactured more easily than conventional gas generators, can be made lighter, and can reliably reduce costs.
- the crimping position is not particularly limited as long as the closing member 12 can be fixed to the housing 10 . Therefore, since it is not necessary to manage the caulking position (accurate positioning, etc.) as much as in the conventional art, the manufacturing process can be simplified.
- the closing member 12 since the closing member 12 is provided with the internal space 12a, the space volume can be increased compared to using a conventional closing member, and the internal pressure during gas generation can be reduced. becomes.
- the first holder 120 is formed in a cylindrical shape so as to have a smaller maximum outer diameter than the first holder 20 of the first embodiment.
- the main difference from the first embodiment is that a peripheral wall 110 e is formed following the outer shape of 120 .
- the first holder 120 is a substantially cylindrical member with a substantially constant outer diameter, and has a flange portion 126 formed at the end on the second holder 125 side. It should be noted that the peripheral wall 110e of the housing 110 at a portion corresponding to the flange portion 126 provided on the outer peripheral surface of the first holder 120 is radially contracted (crimped) to engage with the flange portion 126, whereby the housing The first holder 120 is caulked and fixed to 110 . Further, the end portion of the second holder 125 on the first holder 120 side is inserted inside the first holder 120 .
- the flange portion 126 is sandwiched between the end of the second holder 125 on the first holder 120 side and the inner wall of the peripheral wall 110e of the housing 110. , so that the first holder 120 can be fixed to the housing 110 more firmly. That is, it is possible to ensure the sealing performance between the housing 110 and the holder.
- a simple end portion (without a radially protruding flange) is used as the end portion of the second holder 125 on the first holder 120 side. , and the inner wall of the peripheral wall 110 e of the housing 110 .
- the gas generator 200 can be made lighter than the gas generator 100 .
- the coil spring 235 is provided inside the bypass prevention member 236, and the collar portion 256 is provided on the closing member 212 side of the third holder 253. It is mainly different from the first embodiment.
- the coil spring 235 is arranged so that one end abuts the bottom of the bypass prevention member 236 . Also, the coil spring 235 is formed in a cylindrical shape, and presses the gas generating agent 231 toward the igniter 250 at the other end side.
- the flange 256 is a portion extending from the edge of the third holder 253 on the closing member 212 side, and at least the tip of the flange 256 is exposed to the pressure of the gas generated when the gas generating agent 231 burns. is formed to deform so as to adhere (contact) the inner wall of the housing 210 . Thereby, the peripheral wall 210d of the housing 210 whose diameter is reduced can be protected from the pressure of the gas. Therefore, the third holder 253 having the flange 256 prevents the diameter-reduced peripheral wall 210d of the housing 210 from being directly exposed to the heat of the generated gas, thereby maintaining the strength of the peripheral wall 210d. can be done. Note that the tip of the flange 256 only needs to contact the inner wall of the housing 210 at least during operation, and may or may not contact the inner wall of the housing 210 in the initial state.
- the space where the flame generated by the igniter 250 is difficult to reach (the vicinity of the edge of the third holder 53 in the first embodiment and the vicinity of the corner between the inner wall of the housing 10) exists.
- the flange portion 256 the space is eliminated, so the performance of the gas generator itself can be improved.
- the performance of the gas generator itself can be further improved by forming the collar portion 256 into a shape (for example, a mortar shape) that allows the flame to easily reach.
- the collar portion 256 is integrally formed with the third holder 253, the above effects of the collar portion 256 can be achieved without increasing the number of parts.
- the gas generator 400 has the coil spring 335 provided inside the bypass prevention member 336, the collar portion 356 provided on the closing member 312 side of the third holder 353, and the The holder 353 is not fixed to the housing 310, the third holder 353 is fixed to the igniter 350, and only the first holder 320 and the second holder 325 are sandwiched between the peripheral wall 310d and the peripheral wall 310e of the housing 310.
- the main difference from the first embodiment is that the
- the coil spring 335 is arranged so that one end abuts the bottom of the bypass prevention member 336 .
- the coil spring 335 is formed in a cylindrical shape, and presses the gas generating agent 331 toward the igniter 350 at the other end side.
- the third holder 353 has a flange 356 extending from the edge on the closing member 312 side, and a hole 357 (inside the third holder 353) provided in the center.
- the collar portion 356 can have the same effect as the collar portion 256 in the third embodiment.
- the tip of the flange 356 only needs to contact the inner wall of the housing 310 at least during operation, and does not contact the inner wall of the housing 310 in the initial state. may be in contact with each other.
- the hole 357 is press-fitted into the tip of the squib cup (cup-shaped member) 351 of the igniter 350 . Therefore, the third holder 353 is press-fitted and fixed to the igniter 350 .
- the first to third since it is not necessary to form portions such as the annular grooves 54, 154, and 254 of the third holders 53, 153, and 253 of the first to third embodiments, the first to third As compared with the embodiment, complicated formation is not required and cost can be reduced.
- the flange portion (end portion) of the first holder is sandwiched between the end portion of the second holder on the side of the first holder and the inner wall of the diameter-reduced peripheral wall of the housing.
- it is not limited to this. That is, for example, without sandwiching the flange portion (end portion) of the first holder, at least part of the outer periphery of the first holder and the end portion of the second holder on the first holder side or/and the inner wall of the housing, It may be adhered with an adhesive.
- the first holder may be press-fitted inside the housing.
- the method for reducing the diameter of the housing has been described by taking caulking as an example, but any processing method that can reduce the diameter of the housing may be used.
- the outer diameter of the second holder in each of the above embodiments is shown to be larger than the outer diameter of the other end portion of the first holder, it is not limited to this.
- the outer diameter of the second holder may be the same as the outer diameter of the first holder on the other end side.
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Abstract
Description
前記ガス発生剤を着火燃焼させることが可能であって、前記ガス発生剤側に筒状のカップ状部材を有した点火器と、前記点火器の一部が保持され、前記ハウジングの軸方向の一端部に固定されている筒状のホルダと、前記ハウジングの軸方向の他端部に固定されている閉塞部材と、を備え、前記ホルダは、前記ハウジングの一端部側に配設され、前記一端部側において前記点火器に通電させるための外部コネクタを嵌合可能な筒状の第1ホルダと、前記第1ホルダに接触した状態で、前記第1ホルダの前記ハウジングの内部側に配設され、少なくとも前記ハウジングの内壁と接触する部分(以下、接触部分)の外径が、前記第1ホルダの前記他端部側の外径より大きいまたは前記第1ホルダの前記他端部側の外径と同じ径の筒状の第2ホルダと、少なくとも前記第2ホルダ側と反対側の端部の径よりも小さい径の部分(以下、小径部分)を外側面に有しているとともに、前記閉塞部材側に鍔部が設けられており、前記第2ホルダに接触した状態、かつ、少なくとも作動時において前記鍔部の先端部が前記ハウジングの内壁に接触するように、前記第2ホルダに対して前記ハウジングの内部側に配設されている筒状の第3ホルダと、を含み、前記第2ホルダの前記接触部分の前記第1ホルダ側の部分に対応する箇所と、前記第3ホルダの前記小径部分に対応する箇所とにおいて、前記ハウジングの外部側から縮径加工し、前記第2ホルダとともに、少なくとも前記第1ホルダの前記第2ホルダと接触している部分を、前記ハウジングの縮径加工した部分により挟持することによって、前記第1ホルダおよび前記第2ホルダが前記ハウジングに固定されており、前記第3ホルダは、内部を前記点火器の前記カップ状部材に圧入することによって前記点火器に固定されていることを特徴とするものであってもよい。
以下、図1を参照して、本発明の実施の形態に係るシリンダ型のガス発生器の内部構造について説明する。
ガス発生器100は、長尺略円柱状の外形を有しており、ハウジング10と、ハウジング10の一方の開口端付近に取付けられている第1ホルダ20、第2ホルダ25、第3ホルダ53と、ハウジング10の他方の開口端を閉塞するようにハウジング10の他端部に取付けられている閉塞部材12と、を含んでいる。なお、第1ホルダ20、第2ホルダ25、および第3ホルダ53で、点火器50を保持するホルダを構成している。
本実施の形態によれば、ホルダを3つの部材(第1ホルダ20、第2ホルダ25、第3ホルダ53)に分けていることで、複雑な形状を一度に形成せずともよいので、従来よりも製造が容易なガス発生器100を提供できる。
次に、本発明の第2実施形態について、図2を用いて説明する。なお、本実施形態において、第1実施形態と下2桁まで同じ符号の部位は、第1実施形態の部位と同様であるので、説明を省略することがある。また、本実施形態において、特に説明しない部位についても、第1実施形態と同様であるので、説明及び図示を省略することがある。
次に、本発明の第3実施形態について、図3を用いて説明する。なお、本実施形態において、第1実施形態と下2桁まで同じ符号の部位は、第1実施形態の部位と同様であるので、説明を省略することがある。また、本実施形態において、特に説明しない部位についても、第1実施形態と同様であるので、説明及び図示を省略することがある。
次に、本発明の第4実施形態について、図4を用いて説明する。なお、本実施形態において、第1実施形態と下2桁まで同じ符号の部位は、第1実施形態の部位と同様であるので、説明を省略することがある。また、本実施形態において、特に説明しない部位についても、第1実施形態と同様であるので、説明及び図示を省略することがある。
10a、10b、10c、10d、10e、110a、110b、110c、110d、110e、210a、210b、210c、210d、210e、210a、210b、210c、210d、210e 周壁
11、111、211、311 ガス噴出口
12、112、212、312 閉塞部材
12a、112a、212a、312a 内部空間
13、14、22、54、113、114、154、213、214、222、254、313、314、322 環状溝部
20、120、220、320 第1ホルダ
21、23、121、123、221、223、321、323 嵌合部
24、124、224、324 かしめ部
25、125、225、325 第2ホルダ
26、126、226、326 フランジ部
27、127、227、327 環状部
31、131、231、331 ガス発生剤
32、132 AI剤
35、135、235、335 巻きバネ
36、136、236、336 バイパス防止部材
36a、136a、236a、336a 底面部
36b、136b、236b、336b 外周壁部
41、141、241、341 フィルタ
41a、141a、241a、341a 中空部
50、150、250、350 点火器
51、151、251、351 スクイブカップ
52、152、252、352 端子ピン
53、153、253、353 第3ホルダ
55、155、255、355 面
100、200、300、400 ガス発生器
Claims (7)
- 燃焼することによってガスを発生させるガス発生剤が装填され、前記ガスが通過するフィルタを内部に含み、前記フィルタに対応する位置に前記ガスを噴出するガス噴出口が形成されている長尺円筒状のハウジングと、
前記ガス発生剤を着火燃焼させることが可能な点火器と、
前記点火器の一部が保持され、前記ハウジングの軸方向の一端部に固定されている筒状のホルダと、
前記ハウジングの軸方向の他端部に固定されている閉塞部材と、
を備え、
前記ホルダは、
前記ハウジングの一端部側に配設され、前記一端部側において前記点火器に通電させるための外部コネクタを嵌合可能な筒状の第1ホルダと、
前記第1ホルダに接触した状態で、前記第1ホルダの前記ハウジングの内部側に配設され、少なくとも前記ハウジングの内壁と接触する部分(以下、接触部分)の外径が、前記第1ホルダの前記他端部側の外径より大きいまたは前記第1ホルダの前記他端部側の外径と同じ径の筒状の第2ホルダと、
少なくとも前記第2ホルダ側と反対側の端部の径よりも小さい径の部分(以下、小径部分)を外側面に有し、前記第2ホルダに接触した状態で、前記第2ホルダに対して前記ハウジングの内部側に配設されている筒状の第3ホルダと、
を含み、
前記第2ホルダの前記接触部分の前記第1ホルダ側の部分に対応する箇所と、前記第3ホルダの前記小径部分に対応する箇所とにおいて、前記ハウジングの外部側から縮径加工し、前記第2ホルダとともに、少なくとも前記第1ホルダの前記第2ホルダと接触している部分および前記第3ホルダの前記第2ホルダと接触している部分を、前記ハウジングの縮径加工した部分により挟持することによって、前記ホルダが前記ハウジングに固定されていることを特徴とするガス発生器。 - 前記第2ホルダの一端部側の少なくとも一部が前記第1ホルダの内部に嵌挿されており、
前記第1ホルダの他端部は、前記第1ホルダの環状溝部に対応する箇所において縮径加工された部分の前記ハウジングの内壁と、前記ホルダの一端部側の少なくとも一部との間に挟み込まれた状態で、前記ハウジングに固定されていることを特徴とする請求項1に記載のガス発生器。 - 前記第3ホルダの前記閉塞部材側に鍔部が設けられており、
少なくとも作動時において前記鍔部の先端部が前記ハウジングの内壁に接触していることを特徴とする請求項1または2に記載のガス発生器。 - 燃焼することによってガスを発生させるガス発生剤が装填され、前記ガスが通過するフィルタを内部に含み、前記フィルタに対応する位置に前記ガスを噴出するガス噴出口が形成されている長尺円筒状のハウジングと、
前記ガス発生剤を着火燃焼させることが可能であって、前記ガス発生剤側に筒状のカップ状部材を有した点火器と、
前記点火器の一部が保持され、前記ハウジングの軸方向の一端部に固定されている筒状のホルダと、
前記ハウジングの軸方向の他端部に固定されている閉塞部材と、
を備え、
前記ホルダは、
前記ハウジングの一端部側に配設され、前記一端部側において前記点火器に通電させるための外部コネクタを嵌合可能な筒状の第1ホルダと、
前記第1ホルダに接触した状態で、前記第1ホルダの前記ハウジングの内部側に配設され、少なくとも前記ハウジングの内壁と接触する部分(以下、接触部分)の外径が、前記第1ホルダの前記他端部側の外径より大きいまたは前記第1ホルダの前記他端部側の外径と同じ径の筒状の第2ホルダと、
少なくとも前記第2ホルダ側と反対側の端部の径よりも小さい径の部分(以下、小径部分)を外側面に有しているとともに、前記閉塞部材側に鍔部が設けられており、前記第2ホルダに接触した状態、かつ、少なくとも作動時において前記鍔部の先端部が前記ハウジングの内壁に接触するように、前記第2ホルダに対して前記ハウジングの内部側に配設されている筒状の第3ホルダと、
を含み、
前記第2ホルダの前記接触部分の前記第1ホルダ側の部分に対応する箇所と、前記第3ホルダの前記小径部分に対応する箇所とにおいて、前記ハウジングの外部側から縮径加工し、前記第2ホルダとともに、少なくとも前記第1ホルダの前記第2ホルダと接触している部分を、前記ハウジングの縮径加工した部分により挟持することによって、前記第1ホルダおよび前記第2ホルダが前記ハウジングに固定されており、
前記第3ホルダは、内部を前記点火器の前記カップ状部材に圧入することによって前記点火器に固定されていることを特徴とするガス発生器。 - 前記点火器の先端部の周囲に形成された前記第3ホルダの前記ガス発生剤側の面と、前記点火器の先端部の面とが、面一となるように、前記第3ホルダの前記ガス発生剤側の面が形成されていることを特徴とする請求項1~4のいずれか1項に記載のガス発生器。
- 前記第2ホルダは、前記点火器を内部に嵌合して保持する嵌合部と、前記他端部側の開口端部に設けられ、前記点火器をかしめ固定するかしめ部と、を有した筒状部材であり、
前記第3ホルダが、前記かしめ部を覆うように形成されていることを特徴とする請求項1~5のいずれか1項に記載のガス発生器。 - 前記第1ホルダおよび前記第3ホルダが樹脂製であり、
前記第2ホルダが金属製または合金製であることを特徴とする請求項1~6のいずれか1項に記載のガス発生器。
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Citations (10)
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JP2008094259A (ja) * | 2006-10-12 | 2008-04-24 | Nippon Kayaku Co Ltd | ガス発生器 |
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JP2021138190A (ja) * | 2020-03-02 | 2021-09-16 | 日本化薬株式会社 | ガス発生器 |
WO2022138134A1 (ja) * | 2020-12-25 | 2022-06-30 | 日本化薬株式会社 | ガス発生器 |
WO2022196228A1 (ja) * | 2021-03-19 | 2022-09-22 | 日本化薬株式会社 | ガス発生器 |
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2022
- 2022-11-25 WO PCT/JP2022/043639 patent/WO2023112643A1/ja active Application Filing
- 2022-11-25 EP EP22907174.1A patent/EP4450336A1/en active Pending
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JP2008094259A (ja) * | 2006-10-12 | 2008-04-24 | Nippon Kayaku Co Ltd | ガス発生器 |
JP2009137402A (ja) * | 2007-12-05 | 2009-06-25 | Nippon Kayaku Co Ltd | ガス発生器 |
US20100096844A1 (en) * | 2008-10-21 | 2010-04-22 | Autoliv Asp, Inc. | Airbag with ignition distributor |
JP2017081343A (ja) * | 2015-10-27 | 2017-05-18 | 日本化薬株式会社 | ガス発生器 |
WO2017183626A1 (ja) * | 2016-04-18 | 2017-10-26 | 日本化薬株式会社 | ガス発生器 |
JP2017193192A (ja) * | 2016-04-18 | 2017-10-26 | 日本化薬株式会社 | ガス発生器 |
JP6579992B2 (ja) | 2016-04-18 | 2019-09-25 | 日本化薬株式会社 | ガス発生器 |
DE202018104422U1 (de) * | 2018-07-31 | 2019-11-04 | Trw Airbag Systems Gmbh | Gasgenerator, Modul und Fahrzeugsicherheitssystem mit einem Gasgenerator |
JP2021138190A (ja) * | 2020-03-02 | 2021-09-16 | 日本化薬株式会社 | ガス発生器 |
WO2022138134A1 (ja) * | 2020-12-25 | 2022-06-30 | 日本化薬株式会社 | ガス発生器 |
WO2022196228A1 (ja) * | 2021-03-19 | 2022-09-22 | 日本化薬株式会社 | ガス発生器 |
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