WO2023042745A1 - 硬化性オルガノポリシロキサン組成物、その硬化により得られる微粘着性のオルガノポリシロキサン粘着剤層および積層体 - Google Patents

硬化性オルガノポリシロキサン組成物、その硬化により得られる微粘着性のオルガノポリシロキサン粘着剤層および積層体 Download PDF

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Publication number
WO2023042745A1
WO2023042745A1 PCT/JP2022/033709 JP2022033709W WO2023042745A1 WO 2023042745 A1 WO2023042745 A1 WO 2023042745A1 JP 2022033709 W JP2022033709 W JP 2022033709W WO 2023042745 A1 WO2023042745 A1 WO 2023042745A1
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Prior art keywords
curing
organopolysiloxane
composition
adhesive layer
curable
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Ceased
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PCT/JP2022/033709
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English (en)
French (fr)
Japanese (ja)
Inventor
優来 横内
智浩 飯村
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Dow Toray Co Ltd
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Dow Toray Co Ltd
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Priority to CN202280062016.8A priority Critical patent/CN117940529A/zh
Priority to KR1020247011800A priority patent/KR20240067916A/ko
Priority to US18/691,861 priority patent/US20240384138A1/en
Priority to JP2023548440A priority patent/JPWO2023042745A1/ja
Publication of WO2023042745A1 publication Critical patent/WO2023042745A1/ja
Anticipated expiration legal-status Critical
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/385—Acrylic polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/10—Adhesives in the form of films or foils without carriers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29—Laminated material
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/35—Heat-activated
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B2037/1253—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives curable adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/02—2 layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B32B2250/244—All polymers belonging to those covered by group B32B27/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/414—Translucent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/748—Releasability
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2310/00—Treatment by energy or chemical effects
    • B32B2310/08—Treatment by energy or chemical effects by wave energy or particle radiation
    • B32B2310/0806—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation
    • B32B2310/0831—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation using UV radiation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/318—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of liquid crystal displays
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/416—Additional features of adhesives in the form of films or foils characterized by the presence of essential components use of irradiation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2483/00—Presence of polysiloxane

Definitions

  • the present invention can be solvent-free or low-solvent as required, and the radical polymerization curing reaction proceeds by heating or irradiation with high energy rays, etc., and has excellent transparency and slightly tacky organopoly
  • the present invention relates to a curable organopolysiloxane composition forming a siloxane pressure-sensitive adhesive layer, a laminate having the organopolysiloxane pressure-sensitive adhesive layer, and a method for producing the same.
  • a curable silicone composition that can form an adhesive layer by curing has excellent heat resistance, cold resistance, electrical insulation, and weather resistance compared to acrylic or rubber-based adhesives and pressure-sensitive adhesive compositions. It is used in a wide range of industrial fields because it forms a pressure-sensitive adhesive layer with water repellency and transparency.
  • the silicone-based pressure-sensitive adhesive layer after curing has excellent heat resistance compared to other organic materials, does not easily discolor even at high temperatures, and has little deterioration in physical properties. It is suitable for use as an adhesive between members, a sealant or a temporary fixing agent in the manufacturing process of semiconductor devices, etc.
  • Such a device has a structure in which a film consisting of multiple layers including an electrode layer and a display layer is sandwiched between transparent substrates. It is expected that the silicone pressure-sensitive adhesive layer, which is excellent in heat and cold resistance, will work effectively in articles and their manufacturing processes.
  • cured silicone pressure-sensitive adhesives are classified into addition reaction curing type, condensation reaction curing type, peroxide curing type and the like according to the curing mechanism.
  • Addition reaction curable silicone pressure-sensitive adhesive compositions are widely used because they cure quickly when left at room temperature or when heated, do not cause turbidity in the pressure-sensitive adhesive layer, are excellent in transparency, and do not generate by-products. From the standpoint of workability and handling workability, it is generally commercialized by dissolving it in an organic solvent, so its use has been limited. Especially in recent years, development of a solvent-free or low-solvent composition is strongly desired in view of the direction of environmental regulations in various countries around the world.
  • Patent Document 1 (in particular, Preparation Example 1, etc.) describes a solvent-free silicone pressure-sensitive adhesive composition containing acrylic group-containing dimethylpolysiloxane, an MQ-type dimethylpolysiloxane resin, and a photopolymerization initiator, and the use thereof. A dicing tape and the like are disclosed.
  • Patent Document 2 discloses a solvent-free addition-type silicone adhesive composition comprising an MQT OH -type resin component and a platinum-based catalyst.
  • these silicone pressure-sensitive adhesive compositions are difficult to cure within a practical curing time unless the temperature is substantially higher than 100° C., and the pressure-sensitive adhesive layer contains a large amount of resin component. It has a problem that it is difficult to apply to applications that require slight adhesion and easy peelability.
  • Patent Document 3 describes a solvent-free UV-curable silicone adhesive containing an organopolysiloxane having a (meth)acrylic functional group, a monofunctional or polyfunctional acrylate monomer, an MQ-type organopolysiloxane resin, and a photopolymerization initiator. Agent compositions and uses such as temporary fixation are disclosed. However, this document does not disclose a composition containing an alkenyl group as a main component, and the composition disclosed in Patent Document 3 only provides a relatively hard pressure-sensitive adhesive layer containing a large amount of resin. Therefore, there is a strong demand for a silicone pressure-sensitive adhesive that has a slightly sticky property derived from the rubber-like viscoelastic properties of the cured product.
  • Patent Document 4 (unpublished at the time of filing), the applicants disclosed a solvent-free/low-solvent silicone containing an organopolysiloxane resin with a relatively small molecular weight and using a photoactive hydrosilylation reaction catalyst.
  • a pressure-sensitive adhesive composition is proposed. However, it does not describe or suggest a radically polymerizable composition, and heating may be required in order to achieve a practical curing time.
  • the present invention has been made to solve the above problems, and it is possible to design a composition having a viscosity that can be applied even if the solvent content is small, and depending on the industrial process, it is widely used for heat curing. It is a curable reactive organopolysiloxane composition that can be used not only for curing processes but also for high-energy ray curing processes such as ultraviolet rays, and that gives cured products with excellent transparency and slightly tackiness, and cured products thereof. It is an object of the present invention to provide an organopolysiloxane adhesive layer. A further object of the present invention is to provide a laminate comprising the organopolysiloxane pressure-sensitive adhesive layer and a method for producing a laminate comprising a step of bonding between substrates.
  • the composition can be designed to have sufficient coatability even with no solvent to low solvent, and depending on the selection of the radical polymerization initiator, heat curing at high temperature or irradiation with high energy rays It is possible to realize room temperature to low temperature curing characteristics by curing or semi-curing, and it is possible to form an organopolysiloxane adhesive layer with excellent transparency and slight adhesiveness. Further, the above-mentioned problems are a laminate having an organopolysiloxane pressure-sensitive adhesive layer according to the present invention, and a method for producing a laminate including a step of applying the curable organopolysiloxane composition onto a substrate and curing or semi-curing it. resolved by
  • the curable organopolysiloxane composition of the present invention can be designed to have a viscosity that allows coating even when the solvent content is low. It can be used not only for heat curing processes that are widely used in general, but also for curing processes by irradiation with high-energy rays such as ultraviolet rays. It is possible to form an organopolysiloxane pressure-sensitive adhesive layer with little haze. Furthermore, according to the present invention, it is possible to provide a method for manufacturing a laminate including a laminate including the organopolysiloxane pressure-sensitive adhesive layer and a step of bonding between substrates.
  • the curable silicone composition of the present invention contains the above components (A) to (C).
  • an organic solvent may be optionally contained, and a photosensitizer and other additives may be contained within a range not contrary to the purpose of the present invention. .
  • a photosensitizer and other additives may be contained within a range not contrary to the purpose of the present invention. .
  • Component (A) is a chain polysiloxane molecule having at least two alkenyl groups in the molecule, and is the main ingredient (base polymer) of this composition.
  • the alkenyl group of the component (A) organopolysiloxane includes, for example, alkenyl groups having 2 to 10 carbon atoms such as vinyl group, allyl group, butenyl group, pentenyl group, hexenyl group and heptenyl group, particularly vinyl group. or a hexenyl group.
  • the bonding position of the alkenyl group of the component (A) includes, for example, the terminal of the molecular chain and/or the side chain of the molecular chain.
  • component (A) preferably has an alkenyl group bonded to a silicon atom at a site other than the terminal of the molecular chain, and the alkenyl group is added to the side chain of the molecular chain.
  • the use of a linear organopolysiloxane having is one of the preferred embodiments of the present invention.
  • the (A) component may contain only a single component, or may be a mixture of two or more different components.
  • the organic groups other than alkenyl groups bonded to silicon atoms include, for example, alkyl groups such as methyl, ethyl, propyl, butyl, pentyl, hexyl and heptyl groups.
  • alkyl groups such as methyl, ethyl, propyl, butyl, pentyl, hexyl and heptyl groups.
  • aryl groups such as phenyl group, tolyl group, xylyl group and naphthyl group; aralkyl groups such as benzyl group and phenethyl group; halogens such as chloromethyl group, 3-chloropropyl group and 3,3,3-trifluoropropyl group alkyl group, etc., and particularly preferably a methyl group or a phenyl group.
  • Component (A) unlike component (B), has a chain polysiloxane molecular structure.
  • the component (A) is preferably linear or partially branched linear (branched), and may partially contain a cyclic or three-dimensional network.
  • it is a linear or branched diorganopolysiloxane whose main chain consists of repeating diorganosiloxane units and whose molecular chain ends are blocked with triorganosiloxy groups.
  • the siloxane units that give the branched organopolysiloxane are the T units or Q units described later.
  • the properties of component (A) at room temperature may be oily or gum-like. From the standpoint of the properties, it is preferable that the component (A) has an oily state at room temperature, and the viscosity of the component (A) at 25° C. is preferably 1 mPa ⁇ s or more and 100,000 mPa ⁇ s or less, which will be described later. It is particularly preferable that the viscosity is 10 mPa ⁇ s or more, 50,000 mPa ⁇ s or less, and 10,000 mPa ⁇ s or less in relation to the vinyl content.
  • the curable organopolysiloxane composition according to the present invention is a solvent type
  • at least part of component (A) has a viscosity exceeding 100,000 mPa ⁇ s at 25°C or Plasticity measured according to the specified method (25°C, 4.2 g spherical sample, 1 kgf load for 3 minutes, read thickness to 1/100 mm, multiply this value by 100) is in the range of 50-200, more preferably in the range of 80-180.
  • the content of alkenyl groups in component (A) is preferably in the range of 0.001 to 10% by mass, preferably in the range of 0.005 to 5.0% by mass, based on the mass of component (A). A range of 01 to 3.0% by mass is more preferable.
  • the content of the vinyl (CH 2 ⁇ CH—) moiety in the aliphatic unsaturated carbon-carbon bond-containing group (hereinafter referred to as “vinyl content”) is in the range of 0.005 to 10.0% by mass. It is particularly preferred to use organosiloxanes in the range of 0.005 to 5.0% by weight.
  • Component (A) contains, as organic groups other than aliphatic unsaturated carbon-carbon bond-containing groups, alkyl groups such as methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group and heptyl group; Aryl groups such as tolyl group, xylyl group and naphthyl group; Aralkyl groups such as benzyl group and phenethyl group; Halogenated alkyl groups such as chloromethyl group, 3-chloropropyl group and 3,3,3-trifluoropropyl group; may contain From an industrial point of view, it is particularly preferred to contain a methyl group.
  • alkyl groups such as methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group and heptyl group
  • Aryl groups such as tolyl group, xylyl group and naphthyl group
  • an organic group other than the aliphatic unsaturated carbon-carbon bond-containing group in the component (A) is preferably a methyl group, and the content of the aryl group or aralkyl group is less than 0.1 mol%, particularly 0.0 mol%, relative to the entire silicon-bonded groups, and substantially Preferably, it does not contain any aryl or aralkyl groups.
  • Such component (A) may be used alone or as a mixture of a plurality of components.
  • (A1) a linear or branched organopolysiloxane having at least two alkenyl groups only at both ends of the molecular chain, and (A2) having at least one or more alkenyl groups at sites other than the ends of the molecular chain and a linear or branched organopolysiloxane having at least 3 or more alkenyl groups in the molecule in a weight ratio of 30:70 to 70:30.
  • These components (A1) and (A2) may also preferably be a mixture of two or more components having different viscosities, siloxane polymerization degrees, or alkenyl group contents.
  • volatile or low-molecular-weight siloxane oligomers octamethyltetrasiloxane (D4), decamethylpentasiloxane (D5), etc.
  • D4 octamethyltetrasiloxane
  • D5 decamethylpentasiloxane
  • the degree can be designed as desired, it may be less than 1% by mass of the entire component (A) and less than 0.1% by mass for each siloxane oligomer, and if necessary, may be reduced to near the detection limit.
  • composition according to the present invention comprises (B1) a monofunctional or polyfunctional vinyl-based monomer, and (B2) an organopolysiloxane compound having an organic group containing at least one acrylic or methacrylic group in the molecule. It may also contain one or more selected radically reactive components.
  • (meth)acrylic acid indicates that both acrylic acid and methacrylic acid are included.
  • (meth)acrylate”, “(meth)acryloxy”, and “(meth)acrylamide” are each meant to include both acrylate and methacrylate, acryloxy and methacryloxy, acrylamide and methacrylamide.
  • component (B) contains carbon-carbon unsaturated double bonds mainly derived from acrylic or methacrylic groups in the molecule, so it is a radical-reactive component. Participates in curing reaction by radical polymerization. Therefore, by using the component (B) in combination, it is possible to adjust the adhesion to the substrate, the crosslink density of the cured product, etc., and depending on the amount of the component used, the composition can be cured or semi-cured. It is possible to adjust the hardness and adhesion to the substrate of the organopolysiloxane pressure-sensitive adhesive layer to have a slightly adhesive property, especially the improvement of the curing speed, the adjustment of the cross-linking density and the adhesion to the substrate. Useful for force adjustment.
  • the amount of the radical-reactive component (B) used is in the range of 0.1 to 49.9 parts by mass with respect to 50 to 99 parts by mass of component (A), and 0.1 to 25 parts by mass. A range is particularly preferred.
  • the sum of components (A) and (B2) must be 50% by mass or more with respect to the total mass of solids, and the content of component (B) must be If the upper limit is exceeded, the organopolysiloxane pressure-sensitive adhesive layer formed by curing the present composition tends to be hard and brittle, and may not be sufficiently used as a slightly sticky pressure-sensitive adhesive layer. Transparency is impaired and turbidity (haze) tends to occur.
  • the adjustment of the curing speed, crosslink density, etc. of the organopolysiloxane pressure-sensitive adhesive layer may be insufficient, and the purpose of a slightly tacky pressure-sensitive adhesive layer may not be achieved. be.
  • the (B1) component is a vinyl-based monomer that is a starting material for an organic resin generally called a vinyl-based resin, and includes methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, lower alkyl (meth)acrylates such as isopropyl (meth)acrylate; glycidyl (meth)acrylate; n-butyl (meth)acrylate, isobutyl (meth)acrylate, tert-butyl (meth)acrylate, n-hexyl (meth)acrylate, Cyclohexyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, isoamyl (meth)acrylate, octyl (meth)acrylate, dodecyl (meth)acrylate, isobornyl (meth)acrylate, stearyl (meth)acrylate, dicyclopentanyl (
  • polyfunctional vinyl monomers can also be used, such as ethylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate, neopentyl glycol di(meth)acrylate.
  • polyethylene glycol di(meth)acrylate 1,4-bis((meth)acryloyloxy)butane, 1,6-bis((meth)acryloyloxy)hexane, 1,9-bis((meth)acryloyloxy)nonane , 1,12-bis((meth)acryloyloxy)dodecane, tris(2-acryloyloxy)ethylisosialate, pentaerythritol tetraacrylate, trimethylolpropane tri(meth)acrylate, pentaerythritol tri(meth)acrylate, tri methylolpropane trioxyethyl (meth)acrylate, tris(2-hydroxyethyl)isocyanurate di(meth)acrylate, tris(2-hydroxyethyl)isocyanurate tri(meth)acrylate, ethylene oxide or propylene oxide of bisphenol A (Meth)acryloyl group-containing mono
  • the preferred component (B1) is an acrylate-based vinyl monomer having one acryloxy group.
  • Two or more kinds can be used in combination.
  • acrylate or methacrylate compounds having 8 or more carbon atoms in the molecule, preferably 8 to 30 carbon atoms provide low volatility, low viscosity of the composition, and high glass transition temperature of the cured product.
  • a suitable (B1) component is an acrylate-based vinyl monomer having two acryloxy groups, and the viscosity, curability, compatibility with the compound having one acryloxy group, and after curing It can be used alone or in combination of two or more in consideration of the hardness and glass transition temperature of.
  • Diethylene glycol diacrylate, 1,6-bis(acryloyloxy)hexane, trimethylolpropane triacrylate, polydimethylsiloxane with both ends acryloxy functional are preferably used.
  • Component (B2) is an organopolysiloxane compound having an organic group containing at least one acryl or methacryl group in the molecule, and is resinous, chain (including linear and branched), cyclic and Any resin-linear block copolymer composed of resinous blocks and chain blocks can be used.
  • the (B2) component has the general formula (1) at the terminal or side chain of the molecular chain:
  • Z is a divalent organic group that may contain a hetero atom and is bonded to the silicon atom that constitutes the main chain of the polysiloxane *, and is a divalent organic group that may contain a silicon atom, an oxygen atom, a nitrogen atom, or a sulfur atom. may be a valent organic group.
  • Z is an alkylene group having 2 to 22 carbon atoms
  • Z 2 is * -[(CH 2 ) 2 O] m (C n H 2n )-(m is a number ranging from 0 to 3, n is 2 a number in the range of to 10) ⁇ , and -Z 1 -R 2 2 Si-OR 2 2 Si-Z 2 - described later. Any one group selected from divalent linking groups represented by is preferable.
  • the silicon-bonded functional group (R A ) has the general formula (1): is represented by In the formula, each R 1 independently represents a hydrogen atom, a methyl group or a phenyl group, preferably a hydrogen atom or a methyl group. Each R 2 independently represents an alkyl group or an aryl group, and is industrially preferably an alkyl group having 1 to 20 carbon atoms or a phenyl group, particularly preferably a methyl group.
  • Z 1 represents -O(CH 2 ) m - (m is a number ranging from 0 to 3), m is preferably 1 or 2.
  • Z 2 is a divalent organic group represented by —C n H 2n — (where n is a number in the range of 2 to 10) bonded to a silicon atom constituting the main chain of polysiloxane *, and n is 2 to 6 are practically preferred.
  • the silicon-bonded functional group (R A ) represented by the general formula (1) includes a silicon-bonded functional group (R Alk ) containing at least one alkenyl group, and a silicon-bonded hydrogen atom and a silicon-bonded hydrogen atom in the molecule.
  • Method by reacting a hydrosilane compound having an acrylic functional group (e.g., 3-(1,1,3,3-tetramethyldisiloxanyl)propyl methacrylate, etc.) in the presence of a hydrosilylation reaction catalyst It can be introduced intramolecularly.
  • a hydrosilylation reaction catalyst such as dibutylhydroxytoluene (BHT).
  • the (B2) component may contain one or more linear organopolysiloxanes selected from the following components (B2-1-1) and (B2-1-2) below.
  • Component (B2-1-1) is a linear organopolysiloxane having at least one functional group (R A ) in the molecule, represented by the following structural formula.
  • R 1 is independently a C1-C6 alkyl group, C2-C20 alkenyl group, C6-C12 aryl group
  • R A' is independently a C1-C6 alkyl group, C2-C20 alkenyl a C6-C12 aryl group, and a silicon atom-bonded functional group (R A ) including the aforementioned acryl or methacryl groups
  • n1 is a positive number
  • n2 is 0 or a positive number be.
  • at least one of R A' is a silicon atom-bonded functional group (R A ) containing an acryl group or a methacryl group as described above.
  • n1+n2 is a positive number of 0 or more and is not limited, it is preferably in the range of 10 to 5,000, more preferably 10 to 2,000, still more preferably 10 to 1,000.
  • the value of n1+n2 is such that the viscosity of component (C'1) at 25° C. is in the range of 1 to 100,000 mPa ⁇ s, more preferably 10 to 50,000 mPa ⁇ s, and still more preferably 500 to 50,000 mPa ⁇ s. Any number that satisfies the viscosity range of s may be used and is preferred.
  • Component (B2-1-2) is a branched-chain organopolysiloxane having at least one functional group (R A ) in the molecule and containing branched siloxane units, represented by the following average unit formula: be.
  • Component (B2-1-2) is more specifically a branched organopolysiloxane represented by the following siloxane unit formula.
  • R A' R 1 2 SiO 1/2 a (R 1 2 SiO 2/2 ) b1 (RA ' R 1 SiO 2/2 ) b2 (R 1 SiO 3/2 ) c1 (R A' SiO 3 /2 ) c2
  • R 1 and R A′ are the same groups as above
  • R 1 and R A′ are the same groups as above
  • component (B2-1-2) may be a branched organopolysiloxane having methacryloyl group-containing organic groups only on terminal M units represented by the following siloxane unit formula.
  • R A' R 1 2 SiO 1/2 a (R 1 2 SiO 2/2 ) b1 (R 1 SiO 3/2 ) c1
  • R 1 and R A′ are the same groups as described above, and 0 ⁇ a ⁇ 10, 15 ⁇ b1 ⁇ 2000, 0 ⁇ c1 ⁇ 10, and at least one of R A′ is the above acrylic group. or a silicon atom-bonded functional group (R A ) containing a methacrylic group.
  • the viscosity of component (B2-1-2) at 25° C. is preferably 10 to 50,000 mPa ⁇ s, more preferably 100 to 2,000 mPa ⁇ s.
  • Examples of (B2) component widely available in the market include (branched or straight-chain) polydimethylsiloxane containing (meth)acrylic groups at one end; polydimethylsiloxane endblocked with methacryloxypropyl at both ends.
  • the curable organopolysiloxane composition according to the present invention comprises component (A), which is a linear reactive siloxane component, and optionally (B2) an organic group containing at least one acrylic or methacrylic group in the molecule.
  • the ratio of the sum of the weights of the components (A) and (B2) to the total weight of the solid content of the composition (components that form an organopolysiloxane pressure-sensitive adhesive layer upon curing, excluding the organic solvent) is It can be defined as "mass % siloxane of the composition", where the siloxane mass % is at least 50 wt %, preferably in the range of 55-99.5 wt %, more preferably in the range of 60-99.5 wt %
  • the organopolysiloxane pressure-sensitive adhesive layer according to the present invention can be designed to have a transparent appearance, flexibility peculiar to silicone, and slight adhesiveness derived from the viscoelastic properties of the cured product. be.
  • composition according to the present invention may contain an organopolysiloxane resin other than the components (A) and (B2) within the range where the slight tackiness, which is the technical effect of the present invention, can be achieved.
  • organopolysiloxane resin is a component that adjusts adhesive strength, that is, adhesion to a substrate. can be adjusted.
  • a siloxane unit (M unit) represented by R 3 SiO 1/2 (wherein R independently represents a monovalent organic group) in the molecule, and SiO Organopolysiloxane resins containing siloxane units represented by 4/2 (Q units) are exemplified.
  • the molar ratio of M units to Q units may be from 0.5 to 2.0. If this molar ratio is less than 0.5, the adhesion of the cured product to the substrate may be reduced, and if it is greater than 2.0, the cohesive force of the substances constituting the adhesion layer will be reduced. is.
  • the curable organopolysiloxane composition according to the present invention preferably contains little or substantially no organopolysiloxane resin as described above.
  • the mass ratio of the organopolysiloxane resin to the sum of the linear reactive siloxane component (A) and the component (B2) described later is preferably in the range of 0 to 0.1, and the same mass ratio is in the range of 0 to 0.05.
  • organopolysiloxane resin ie substantially free of organopolysiloxane resin. If the content of the organopolysiloxane resin exceeds the above upper limit, the adhesive strength and adhesive strength derived from the organopolysiloxane resin will increase in the cured organopolysiloxane pressure-sensitive adhesive layer, resulting in a slightly sticky pressure-sensitive adhesive layer. may not be.
  • Component (C) is a radical polymerization initiator, which may be (C1) a photo-radical polymerization initiator, (C2) a thermal radical polymerization initiator, or a combination thereof.
  • the type of component (C), the curing method, and the curing temperature may be appropriately selected according to the curing and adhesion processes of the base material, the heat resistance of the substrate, the need for low energy consumption, and the like. Since the composition according to the present invention has an alkenyl group in component (A), which is the main ingredient, good curability can be achieved by irradiation with high-energy rays and/or heating in the presence of component (C). can be done.
  • the amount of component (C) to be used is 0.1 to 10 parts by mass, and particularly preferably 0.2 to 5 parts by mass, when the mass of component (A) is 30 to 99 parts by mass. .
  • the amount of component (C) used depends on the process and curing time of the pressure-sensitive adhesive layer to which the present composition is applied, the content of alkenyl groups derived from component (A), the dose of high-energy radiation and/or heating. It can be appropriately designed within the above range depending on the conditions.
  • Component (C1) is a photoradical polymerization initiator, and is a component that accelerates the photocuring reaction of the alkenyl groups in component (A) and optionally the thiol compound (E) by irradiation with high-energy rays such as ultraviolet rays.
  • Radical photopolymerization initiators are roughly classified into photocleavage type and hydrogen abstraction type, but the photoradical polymerization initiator used in the composition of the present invention is arbitrarily selected from those known in the art. It can be selected and used, and is not particularly limited. Some photoradical polymerization initiators can accelerate the curing reaction not only under irradiation with high-energy rays such as ultraviolet rays but also under light irradiation in the visible light range.
  • radical photopolymerization initiators include 4-(2-hydroxyethoxy)phenyl(2-hydroxy-2-propyl)ketone, ⁇ -hydroxy- ⁇ , ⁇ '-dimethylacetophenone, 2-methyl-2 ⁇ -ketol compounds such as hydroxypropiophenone and 1-hydroxycyclohexylphenyl ketone; methoxyacetophenone, 2,2-dimethoxy-2-phenylacetophenone, 2,2-diethoxyacetophenone, 2-methyl-1-[4 Acetophenone compounds such as -(methylthio)-phenyl]-2-morpholinopropane-1; benzoin ether compounds such as benzoin ethyl ether, benzoin isopropyl ether, and anisoin methyl ether; ketal compounds such as benzyl dimethyl ketal; aromatic sulfonyl chloride compounds such as naphthalenesulfonyl chloride; photoactive oxime compounds such as 1-phenone-1,1-
  • photoradical polymerization initiators suitable as the component (C1) in the present invention include bis-(2,6-dichlorobenzoyl)phenylphosphine oxide, bis-(2,6-dichlorobenzoyl)-2,5- Dimethylphenylphosphine oxide, bis-(2,6-dichlorobenzoyl)-4-propylphenylphosphine oxide, bis(2,4,6-trimethylbenzoyl)-phenylphosphine oxide, bis(2,6-dimethoxybenzoyl) )-2,4,4-trimethylpentylphosphine oxide, bis(2,6-dichlorobenzoyl)-4-propylphenylphosphine oxide, bis(2,6-dichlorobenzoyl)-2,5-dimethylphenylphosphine bisacylphosphine oxides such as oxide, bis-(2,6-dimethoxybenzoyl)-2,5-dimethylphenylpho
  • acetophenone-based photopolymerization initiator suitable as the component (C1) in the present invention include Omnirad 907, 369, 369E, 379 manufactured by IGM Resins.
  • Commercially available acylphosphine oxide-based photopolymerization initiators include Omnirad TPO, TPO-L, and 819 manufactured by IGM Resins.
  • Commercially available oxime ester photopolymerization initiators include Irgacure OXE01 and OXE02 manufactured by BASF Japan Ltd., N-1919 manufactured by ADEKA Co., Ltd., Adeka Arcles NCI-831, NCI-831E manufactured by Changzhou Yutaka Electronic New Materials Co., Ltd. and TR-PBG-304.
  • Component (C2) is a thermal radical polymerization initiator that generates radical species upon heating to accelerate the thermosetting reaction of the alkenyl groups in component (A) and optionally the thiol compound (E).
  • thermal radical polymerization initiators include azo compounds and organic peroxides.
  • azo compounds 2,2'-azobisisobutyronitrile, 2,2'-azobis(2-methylbutyronitrile), 2,2'-azobis(2,4-dimethylvaleronitrile), 1,1 '-Azobis-1-cyclohexanecarbonitrile, dimethyl-2,2'-azobisisobutyrate, dimethyl-2,2'-azobis (2-methylpropionate), dimethyl-1,1'-azobis (1 -cyclohexanecarboxylate), 4,4′-azobis(4-cyanovaleric acid), 2,2′-azobis(2-amidinopropane) dihydrochloride, 2-tert-butylazo-2-cyanopropane, 2,2 '-Azobis(2-methylpropionamide) dihydrate, 2,2'-azobis(2,4,4-trimethylpentane) and the like.
  • organic peroxides include alkyl peroxides, diacyl peroxides, ester peroxides, and carbonate peroxides.
  • the alkyl peroxides include dicumyl peroxide, di-tert-butyl peroxide, di-tert-butylcumyl peroxide, 2,5-dimethyl-2,5-di(tert-butylperoxy ) hexane, 2,5-dimethyl-2,5-di(tert-butylperoxy)hexyne-3, tert-butylcumyl, 1,3-bis(tert-butylperoxyisopropyl)benzene, 3,6,9- Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane is exemplified.
  • diacyl peroxides include benzoyl peroxide, lauroyl peroxide, and decanoyl peroxide.
  • peroxide esters include 1,1,3,3-tetramethyl butyl peroxy neodecanoate, ⁇ -cumyl peroxy neo decanoate, tert-butyl peroxy neo decanoate, tert-butyl peroxy neoheptanoate, tert-butyl peroxypivalate, tert-hexyl peroxypivalate, 1,1,3,3-tetramethylbutyl peroxy-2-ethylhexanoate, tert-amylperoxyl-2- Ethylhexanoate, tert-butylperoxy-2-ethylhexanoate, tert-butylperoxyisobutyrate, di-tert-butylperoxyhexahydroterephthalate, tert-
  • Peroxycarbonates include di-3-methoxybutylperoxydicarbonate, di(2-ethylhexyl)peroxydicarbonate, diisopropylperoxycarbonate, tert-butylperoxyisopropylcarbonate, di(4-tert-butylcyclohexyl ) peroxydicarbonate, dicetyl peroxydicarbonate, dimyristyl peroxydicarbonate.
  • the present composition can also use (C') a photosensitizer in combination with (C1) a photoradical polymerization initiator.
  • a sensitizer can increase the photon efficiency of the polymerization reaction, making longer wavelength light available for the polymerization reaction compared to the use of the photoinitiator alone. It is known to be particularly effective when the coating thickness is relatively thick or when relatively long wavelength LED light sources are used.
  • Sensitizers include anthracene compounds, phenothiazine compounds, perylene compounds, cyanine compounds, merocyanine compounds, coumarin compounds, benzylidene ketone compounds, (thio)xanthene or (thio)xanthone compounds such as isopropyl Thioxanthone, 2,4-diethylthioxanthone, squalium-based compounds, (thia)pyrylium-based compounds, porphyrin-based compounds, and the like are known, and any photosensitizer may be used in the curable organopolysiloxane composition of the present invention. It can be used for products and adhesive compositions. The amount used is arbitrary, but the mass ratio of the component (C') to the component (C1) is in the range of 0 to 10, and when used, it is selected in the range of 0.01 to 5. is common.
  • the present composition contains the above components (A) and (B), it forms a cured product through a radical polymerization reaction.
  • the present composition when at least part of the component (C) is the photoradical polymerization initiator (C1), the present composition can be cured by irradiation with high-energy rays such as ultraviolet rays.
  • the thermal radical polymerization initiator (C2) when at least part of the component (C) is the thermal radical polymerization initiator (C2), the composition can be cured by heating.
  • heating and high-energy ray irradiation can be selected or combined for curing, and can be appropriately selected according to the desired curing method and sealing process.
  • the composition according to the present invention is a solvent-free to low-solvent type, and at least part of the component (C) is (C1) a photoradical polymerization initiator, and optionally further (C') photosensitizer
  • the agent By including the agent, the environmental load is small, and even for base materials and members with poor heat resistance, rapid curing is possible even at low temperatures including room temperature, and it is compatible with low energy consumption in the field of semiconductors. There are advantages that are also suitable for industrial production processes.
  • at least part of the component (C) is the thermal radical polymerization initiator (C2)
  • C2 thermal radical polymerization initiator
  • the curable organopolysiloxane composition according to the present invention can be designed as a low-solvent or solvent-free composition by selecting its constituent components (especially by selecting a low-viscosity component as component (A) as a whole).
  • component (A) a low-viscosity component
  • (D) It is possible to design a composition that has practically sufficient coatability even for a composition containing a small amount of organic solvent or substantially no organic solvent.
  • the content of the organic solvent is 0 to less than 60% by mass, less than 50% by mass, and substantially within the range of 0 to 30% by mass with respect to 100 parts by mass of the entire composition. is particularly preferred.
  • an organic solvent is permissible in order to improve the wettability of the present composition to a substrate or to be included as a solvent incidental to other components.
  • the type and blending amount of the organic solvent are adjusted in consideration of coating workability and the like, but from the standpoint of solvent-free composition design, it is preferable to use the amount as small as possible.
  • the total amount of component (D), which is a diluent is in the range of 0 to 100 parts by mass, preferably in the range of 0 to 25 parts by mass.
  • the (D) organic solvent includes, for example, aromatic hydrocarbon solvents such as toluene, xylene, and benzene; aliphatic hydrocarbon solvents such as heptane, hexane, octane, and isoparaffin; Ester solvents, diisopropyl ether, ether solvents such as 1,4-dioxane, trichlorethylene, perchlorethylene, chlorinated aliphatic hydrocarbon solvents such as methylene chloride, solvent volatile oils, etc. You may combine two or more types according to wettability etc. to material.
  • aromatic hydrocarbon solvents such as toluene, xylene, and benzene
  • aliphatic hydrocarbon solvents such as heptane, hexane, octane, and isoparaffin
  • Ester solvents diisopropyl ether, ether solvents such as 1,4-dioxane, trichlorethylene, perchlor
  • the composition according to the present invention may further contain (E) a polyfunctional thiol compound having at least two thiol groups (--SH) in the molecule. Since the polyfunctional thiol compound functions as a chain transfer agent to promote radical polymerization, a part of the component (C) according to the present invention is a radical photopolymerization initiator, and the composition is exposed to high energy such as ultraviolet rays. In the case of curing by radiation irradiation, the curing speed and the deep-part curability of the cured product can be improved even when the irradiation dose of high-energy radiation is small.
  • polyfunctional thiol compounds examples include pentaerythritol tetrakis(3-mercaptobutyrate), 1,4-bis(3-mercaptobutyryloxy)butane, 1,3,5-tris(2-(3 sulfanylbutanoyloxy)ethyl)-1,3,5-triazinane-2,4,6-trione, trimethylolpropane tris(3-mercaptobutyrate) and the like.
  • component (E) may be an organopolysiloxane compound having an organic group containing at least two thiol groups in the molecule, and may be a resinous, chain (including linear and branched), cyclic and resin-linear type block copolymers composed of resin blocks and chain blocks.
  • the binding site of the thiol modified group is not particularly limited, and may be either the terminal of the molecular chain or the side chain.
  • linear organopolysiloxane having a thiol modifying group at the side chain site, such as a dimethylsiloxane/2-thiolpropylmethylsiloxane copolymer whose molecular chain end is blocked with a trimethylsiloxy group.
  • component (E) is a thiol group-containing organopolysiloxane compound
  • the compatibility with other constituent components and the uniformity and viscosity of the composition as a whole can be improved, and the intramolecular crosslink density and the like can be adjusted.
  • Component (E) can be used arbitrarily, but the amount used is 0 to 20 parts by mass, and 0 to 10 parts by mass, based on 50 to 99 parts by mass of component (A). Amounts of 0 to 5 parts by weight are particularly preferred.
  • the curable organopolysiloxane composition according to the present invention includes a non-reactive polydimethylsiloxane or polydimethyldiphenylsiloxane that does not contain a carbon-carbon double bond-containing reactive group such as an alkenyl group, an acrylic group, or a methacrylic group. of the organopolysiloxane can be blended, thereby improving the loss coefficient (tan ⁇ ), storage modulus (G') and loss modulus (G'') of the organopolysiloxane pressure-sensitive adhesive layer.
  • the use of hydroxyl-terminated polydimethylsiloxane or polydimethyldiphenylsiloxane can increase the loss factor of the cured layer, and such compositions are within the scope of the present invention.
  • the curable organopolysiloxane composition according to the present invention can optionally contain components other than the above components within a range that does not impair the technical effects of the present invention.
  • adhesion promoters such as phenol, quinone, amine, phosphorus, phosphite, sulfur, or thioether
  • light stabilizers such as triazoles or benzophenones
  • one or more antistatic agents such as cationic surfactants, anionic surfactants, or nonionic surfactants, polymerization inhibitors, and UV absorbers agents and the like.
  • pigments, dyes, and optionally surface-treated inorganic fine particles can also be arbitrarily blended. .
  • the method for preparing the curable organopolysiloxane composition of the present invention is not particularly limited, and is carried out by homogeneously mixing each component.
  • An organic solvent may be added as necessary, and a known stirrer or kneader may be used to mix and prepare.
  • the present composition may have radical polymerizability when heated. is preferred.
  • the curable organopolysiloxane composition of the present invention has a viscosity of 1,000 to 300 at 25° C. in terms of coatability and handling workability as an adhesive or an adhesive-forming composition. ,000 mPa ⁇ s, and the viscosity of the entire composition is preferably in the range of 5,000 to 50,000 mPa ⁇ s. In particular, when the content of the organic solvent is 30% by mass or less based on 100 parts by mass of the composition, the viscosity of the entire composition is preferably in the range of 5,000 to 300,000 mPa s. . Such a composition can realize practically sufficient coatability even if it is a low-solvent type or a solvent-free type.
  • the curable organopolysiloxane composition according to the present invention contains the components (A), (B) and (C), (i) the heat curing reaction and (ii) the light from high energy ray irradiation It can be cured by one or more radical polymerization reactions selected from curing reactions.
  • the state in which the radical polymerization reaction is completed in the organopolysiloxane pressure-sensitive adhesive layer is "cured"
  • the solid state Although an organopolysiloxane adhesive layer is formed, the adhesive layer retains radical polymerization reactivity, and the state in which the curing reaction can proceed further by heating and irradiation with high-energy rays is called “semi-cured.” do.
  • the reaction for forming the semi-cured organopolysiloxane pressure-sensitive adhesive layer and the subsequent reaction for forming the cured organopolysiloxane pressure-sensitive adhesive layer may be the same radical polymerization reaction or different radical polymerization reactions. Two or more radical polymerization reactions may be carried out simultaneously.
  • a semi-cured organopolysiloxane pressure-sensitive adhesive layer may be formed by a heat curing reaction, and then a completely cured organopolysiloxane pressure-sensitive adhesive layer may be formed by irradiation with high-energy rays.
  • the same curing reaction may be stepped to form a semi-cured/cured organopolysiloxane adhesive layer by temporarily interrupting and resuming the radiation.
  • one or more radical polymerization reactions selected from (i) heat-curing reaction and (ii) photo-curing reaction by irradiation with high-energy rays further proceed.
  • the crosslink density of the adhesive layer changes when changing to the "cured" state, and the adhesive force to the substrate can be changed.
  • the "semi-cured" organopolysiloxane pressure-sensitive adhesive layer is brought into contact with a substrate, and cured by allowing the above-mentioned radical polymerization reaction to proceed, so that the completely cured pressure-sensitive adhesive layer becomes It may exhibit stronger adhesion to the substrate and form a stronger bond.
  • the curable organopolysiloxane composition according to the present invention forms a coating film by coating on a substrate, and is selected from (i) heat-curing reaction and (ii) photo-curing reaction by irradiation with high-energy rays.
  • a cured or semi-cured organopolysiloxane pressure-sensitive adhesive layer is formed by one or more radical polymerization reactions.
  • Coating methods include gravure coating, offset coating, offset gravure, roll coating, reverse roll coating, air knife coating, curtain coating, and comma coating.
  • the coating amount can be designed to have a desired thickness according to the application of the adhesive layer and the display device. It may be 900 ⁇ m, and may be 10-800 ⁇ m, but is not limited to these.
  • the temperature is 80 to 200°C, preferably 100°C or higher, and more preferably 100 to 180°C.
  • a slightly sticky cured or semi-cured adhesive layer is obtained by a thermal radical polymerization reaction.
  • the heating time required for curing can be appropriately selected according to the degree of curing, the thickness of the pressure-sensitive adhesive layer and the amount of catalyst used, but it is generally in the range of 0.5 to 90 minutes. may be interrupted or performed step by step to obtain an organopolysiloxane pressure-sensitive adhesive layer in the form of a semi-cured material that retains heat curing reactivity.
  • the heating temperature and heating time may be appropriately selected depending on the heat resistance of the substrate, the sealing process, and the like.
  • the curable organopolysiloxane composition according to the present invention is cured by (ii) a photo-curing reaction by irradiation with high-energy rays
  • usable high-energy rays include ultraviolet rays, gamma rays, X-rays, ⁇ -rays, and electron rays. etc., but ultraviolet rays are preferable from the viewpoint of practicality.
  • High-pressure mercury lamps, medium-pressure mercury lamps, Xe—Hg lamps, deep UV lamps, and the like are suitable as the ultraviolet light source, and ultraviolet irradiation with a wavelength of 280 to 400 nm, preferably 300 to 400 nm, is preferred.
  • Light sources with emission bands may also be used.
  • the irradiation dose of high-energy rays varies depending on the type and amount of (C1) photoradical polymerization initiator and the degree of curing reaction. It is preferably within the range of 2 .
  • Irradiation with high-energy rays may be performed with a substrate interposed therebetween as long as the substrate carrying the pressure-sensitive adhesive layer according to the present invention does not absorb electromagnetic waves in the above wavelength range. That is, if a certain amount of irradiation can be realized, high-energy rays may be irradiated through a base material or a cover material such as a protective film.
  • low temperature means, for example, 100° C. or lower, specifically a temperature range of 15° C. to 100° C., and a temperature of 80° C. or lower can be selected.
  • reaction of the composition of the present invention proceeds in a temperature range of 15 to 100 ° C., it is preferably around room temperature (a temperature range that can be reached without heating or cooling, and 20 to In particular, the temperature range of 25° C. is included), the composition may be left standing, may be cooled to room temperature or lower and 15° C.
  • the time required for the curing reaction can be appropriately designed according to the irradiation dose of high-energy rays such as ultraviolet rays and the temperature. Furthermore, by interrupting the irradiation before reaching a predetermined cumulative irradiation dose, a semi-cured organopolysiloxane pressure-sensitive adhesive layer that retains photocuring reactivity may be obtained.
  • the organopolysiloxane pressure-sensitive adhesive layer obtained by the above curing reaction is slightly sticky, for example, a 180° peeling test method according to JIS Z 0237 for a 2 mm-thick polymethyl methacrylate sheet of a 55 ⁇ m-thick cured product layer. It is possible to design an adhesive layer having an adhesive strength in the range of 5 to 50 gf/25 mm, preferably in the range of 5 to 40 gf/25 mm, measured at a tensile speed of 300 mm/min.
  • the above thickness (55 ⁇ m) is the thickness of the cured layer itself, which serves as a reference for objectively defining the adhesive strength of the cured layer according to the present invention. Needless to say, the thickness is not limited to 55 ⁇ m, and any thickness can be used as a cured layer or pressure-sensitive adhesive layer.
  • the cured product or semi-cured product of the present invention is slightly adhesive and can be used as an organopolysiloxane pressure-sensitive adhesive layer or an elastic pressure-sensitive adhesive member.
  • the surface of the pressure-sensitive adhesive layer or substrate may be subjected to surface treatment such as primer treatment, corona treatment, etching treatment, plasma treatment, or the like. good.
  • the curable organopolysiloxane composition according to the present invention is coated on a release liner, it is cured by heating under the temperature conditions described above, and the release liner is peeled off to form a film-like substrate, tape-like substrate, or After bonding with a sheet-like substrate (hereinafter referred to as "film-like substrate") or coating on a film-like substrate, it is cured by heating under the above temperature conditions, and adheres to the surface of the substrate. agent layer can be formed.
  • Laminates comprising a cured layer obtained by curing the organopolysiloxane composition of the present invention on these film-like substrates, particularly a film-like pressure-sensitive adhesive layer, can be used as adhesive tapes, bandages, low-temperature supports, May be used for transfer films, labels, emblems and decorative or instructional markings.
  • the cured layer formed by curing the organopolysiloxane composition of the present invention may be used in the construction of automobile parts, toys, electronic circuits, or keyboards.
  • cured layers, especially film adhesive layers, formed by curing the organopolysiloxane compositions of the present invention may be used in the construction and application of laminated touch screens or flat panel displays.
  • substrate types include paperboard, cardboard, clay-coated paper, polyolefin-laminated paper, especially polyethylene-laminated paper, synthetic resin film/sheet, natural fiber cloth, synthetic fiber cloth, artificial leather cloth, and metal foil.
  • synthetic resin films and sheets are preferred, and examples of synthetic resins include polyimide, polyethylene, polypropylene, polystyrene, polyvinyl chloride, polyvinylidene chloride, polycarbonate, polyethylene terephthalate, cyclopolyolefin, and nylon.
  • heat-resistant synthetic resin films such as polyimide, polyetheretherketone, polyethylenenaphthalate (PEN), liquid crystal polyarylate, polyamideimide, and polyethersulfone are suitable.
  • transparent substrates specifically transparent materials such as polypropylene, polystyrene, polyvinylidene chloride, polycarbonate, polyethylene terephthalate, and PEN, are suitable.
  • the base material is preferably film-like or sheet-like.
  • the thickness is not particularly limited, and can be designed to have a desired thickness depending on the application.
  • a support film that has been subjected to primer treatment, corona treatment, etching treatment, or plasma treatment may be used.
  • the surface opposite to the surface of the pressure-sensitive adhesive layer of the film-like substrate may be subjected to surface treatment such as anti-scratch, anti-fouling, anti-fingerprint, anti-glare, anti-reflection and anti-static treatments. .
  • the pressure-sensitive adhesive layer according to the present invention may be a single layer or a multiple layer formed by laminating two or more pressure-sensitive adhesive layers depending on the required properties.
  • the multi-layer pressure-sensitive adhesive layer may be formed by laminating pressure-sensitive adhesive films prepared one by one, or by coating the curable organopolysiloxane composition according to the present invention on a film substrate having a release layer or the like. The curing step may be performed multiple times.
  • the pressure-sensitive adhesive layer according to the present invention is expected to function as an elastic pressure-sensitive adhesive member because it has a function of bonding or sticking between members. Furthermore, the pressure-sensitive adhesive layer may be given a role as another functional layer selected from a dielectric layer, a conductive layer, a heat dissipation layer, an insulating layer, a reinforcing layer, and the like. In addition, by performing the above-described curing reaction in multiple stages, when utilizing the change in adhesive force accompanying the change from a semi-cured product to a cured product, it may be used as an easily peelable adhesive layer for temporary fixing. .
  • the cured layer formed by curing the curable organopolysiloxane composition of the present invention is an adhesive layer, particularly an adhesive/pressure-sensitive adhesive film
  • the cured layer is provided with a release layer having release coating capability. It is preferable to handle it as a laminate film adhered to a film substrate in a peelable state.
  • the release layer is sometimes called a release liner, separator, release layer, or release coating layer, and is preferably a release coating such as a silicone-based release agent, a fluorine-based release agent, an alkyd-based release agent, or a fluorosilicone-based release agent.
  • the release layer may be a release layer having an ability, a base material that physically forms fine irregularities on the surface of the base material, or a base material itself that is difficult to adhere to the pressure-sensitive adhesive layer of the present invention.
  • a release layer obtained by curing a fluorosilicone release agent may be used as the release layer.
  • the release layer may be a differential release layer, which is a first release layer and a second release layer having different types of release agents constituting the release layer and different release strengths, and a fluorosilicone-based release agent.
  • a cured product obtained by curing the curable organopolysiloxane composition of the present invention has both viscoelasticity and slight adhesiveness as described above, and is therefore useful as an elastic adhesive member for various electronic devices or electrical devices.
  • it is useful as an electronic material, display device member, or transducer member (including sensors, speakers, actuators, and generators), and the cured product is preferably used as an electronic component or display device member.
  • the film-shaped cured product particularly the substantially transparent pressure-sensitive adhesive film, is suitable as a member for a display panel or a display. It is particularly useful for a so-called touch panel application that can operate a device, particularly an electronic device, by touching with a touch panel.
  • the elastic adhesive layer is particularly useful for film-like or sheet-like members used in sensors, speakers, actuators, etc., where transparency is not required and the adhesive layer itself is required to have a certain degree of stretchability or flexibility. be.
  • the pressure-sensitive adhesive layer obtained by curing the curable organopolysiloxane composition can be designed with low solvent or no solvent, and can realize pressure-sensitive adhesive properties such as slight stickiness or easy peeling. Therefore, it is possible to improve the adhesion to substrates such as display devices. Furthermore, if desired, by using a semi-cured product or a multi-stage curing reaction, for display devices, semiconductors, etc., temporarily used as a functional film (e.g., protective film) on the premise of detachment. There is an advantage that it can be used as an easily peelable adhesive layer.
  • Articles containing an adhesive layer obtained by curing the curable organopolysiloxane composition of the present invention may be adhesive tapes, particularly protective tapes intended for attachment and detachment. , a sheet-like member made of a fiber product such as a woven fabric, a non-woven fabric, or paper, and the adhesion layer.
  • the types of such adhesive tapes are not particularly limited, and include insulating tapes, heat-resistant tapes, solder masking tapes, mica tape binders, temporary fixing tapes (particularly including temporary fixing tapes for silicone rubber parts, etc.), and splicing tapes. (particularly including splicing tapes for silicone release papers).
  • a laminate having a pressure-sensitive adhesive layer obtained by curing the curable organopolysiloxane composition of the present invention may be formed on the film-like substrate described above.
  • a release layer may be provided for the cured adhesion layer.
  • the sheet-like substrate has at least one release layer, and the release layer is in contact with the cured adhesion layer.
  • the pressure-sensitive adhesive layer according to the present invention can be easily peeled off from the sheet-like substrate.
  • the release agent contained in the release layer is not particularly limited, and includes the same release agents as described above.
  • the above-mentioned laminate may be able to handle the pressure-sensitive adhesive layer separated from the film-like substrate alone, or may have two film-like substrates.
  • film substrate a first release layer formed on the film-like substrate; It may comprise a pressure-sensitive adhesive layer formed by coating and curing the curable organopolysiloxane composition on the release layer, and a second release layer laminated on the pressure-sensitive adhesive layer.
  • the laminate of the above embodiment can be obtained, for example, by coating the curable organopolysiloxane composition on one of the release layers formed on the film-like substrate and curing the pressure-sensitive adhesive layer. may be formed, and another release layer may be laminated and formed on the adhesion layer.
  • a step of curing or semi-curing by a curing reaction can be produced by a production method including a step of laminating another substrate on the organopolysiloxane pressure-sensitive adhesive layer formed in step (L1-II).
  • the first substrate used in step (L1-I) is preferably a film-like substrate having a first release layer on its surface
  • the other substrates used in step (L2-III) are A film-like substrate having a second release layer on its surface is preferred.
  • the laminate having the above configuration can be obtained, for example, by sandwiching the above curable silicone composition between the first film-like substrate and the second film-like substrate, heating the composition, and pressing or rolling it to a certain thickness. It may be produced by curing the composition after molding.
  • the first sheet base material may have a first release layer, or the first sheet base material itself may have releasability.
  • the second sheet substrate may have a second release layer, or the second sheet substrate itself may have peelability.
  • the cured adhesion layer is the first release layer and/or the second release layer. It is preferred to contact the layer.
  • the sheet substrate having releasability examples include a sheet substrate made of a material having releasability such as a fluororesin film, or a material having no or low releasability such as a polyolefin film and a material such as silicone or fluororesin.
  • a sheet substrate made of one to which a release agent is added may be mentioned.
  • examples of sheet substrates having a release layer include polyolefin films coated with a release agent such as silicone and fluororesin.
  • the laminate can be used, for example, by peeling off the adhesive layer from the film-like substrate after applying the cured adhesive layer to the adherend.
  • the thickness of the adhesive layer is preferably 5 to 10000 ⁇ m, more preferably 10 ⁇ m or more or 8000 ⁇ m or less, and particularly preferably 20 ⁇ m or more or 5000 ⁇ m.
  • the organopolysiloxane pressure-sensitive adhesive layer obtained by semi-curing the curable organopolysiloxane composition of the present invention can be used as a slightly tacky adhesive layer for producing laminates other than the peelable laminate described above.
  • the organopolysiloxane adhesive layer according to the present invention is a semiconductor (including semiconductor precursors and integrated semiconductor devices such as LSI and MEMS), semiconductor substrates (flexible substrates and stretchable substrates such as wearable devices). including), etc., batteries such as secondary batteries, display panels or displays such as laminated touch screens or flat panel displays, etc.
  • Known methods of using layers such as silicone PSAs, silicone adhesives, and silicone sealants can be used without particular limitation.
  • the method for producing a laminated body such as a semiconductor is not particularly limited as long as an organopolysiloxane adhesive layer is used for adhesion between members, and an already cured or semi-cured organopolysiloxane adhesive layer may be used.
  • an already cured or semi-cured organopolysiloxane adhesive layer may be used.
  • the above-described laminate containing the organopolysiloxane adhesive layer for example, single-sided or double-sided adhesive film
  • the substrate that forms a laminate such as a semiconductor is adhered to the exposed organopolysiloxane adhesive layer, and the laminate such as a semiconductor (precursor for the purpose of protection in the process, including temporary fixing) may be formed.
  • the laminate of semiconductors and the like according to the present invention can be obtained by coating an uncured curable organopolysiloxane composition on or between substrates and curing or semi-curing the composition to obtain organopolysiloxane adhesion.
  • An agent layer may be formed.
  • the laminate according to the present invention is Step (L2A-I): a step of applying the curable organopolysiloxane composition of the present invention onto a first substrate;
  • an organopolysiloxane pressure-sensitive adhesive layer is formed between one base material, and another base material is laminated thereon.
  • the laminate according to the invention is Step (L2B-I): a step of applying the curable organopolysiloxane composition of the present invention onto a first substrate; Step (L2B-II): Step of further laminating another substrate on the curable organopolysiloxane composition applied in Step (L2B-I), and Step (L2B-III): Step (L2B-II ), the uncured curable organopoly between the substrates by one or more curing reactions selected from (i) a heat curing reaction and (ii) a photocuring reaction by irradiation with high energy rays.
  • a laminate manufacturing method comprising a step of curing or semi-curing a siloxane composition.
  • an uncured curable organopolysiloxane composition is placed between the substrates to be laminated, and the curable organopolysiloxane composition is subjected to a curing reaction to form an organopolysiloxane between the substrates. It takes a form in which a polysiloxane adhesive layer is formed.
  • the substrates forming the laminate is a translucent substrate
  • the curable organopolysiloxane composition according to the present invention contains (C1) a photoradical polymerization initiator and is irradiated with high-energy rays.
  • the laminate may be formed by irradiating a high-energy ray that passes through the translucent member base material.
  • the laminate according to the present invention is Step (L3-I): a step of applying the curable organopolysiloxane composition of the present invention, which has photo-curing properties when irradiated with high-energy rays, onto a substrate; Step (L3-II): a step of further laminating another substrate on the curable organopolysiloxane composition applied in step (L3-I); Step (L3-III): The laminate precursor formed in the step (L3-II) is irradiated with high-energy rays passing through the translucent substrate, thereby forming an uncured curable organoleptic layer between the substrates.
  • a laminate manufacturing method comprising a step of curing or semi-curing a polysiloxane composition.
  • this method since high-energy rays can be irradiated through a light-transmitting substrate, it is suitable for the process of forming an organopolysiloxane adhesive layer between substrates with particularly low heat resistance.
  • After laminating to form a laminate precursor by irradiating with high energy rays at a low temperature, it is possible to form a large number of laminates at low energy When it is excellent in industrial production efficiency There is
  • the curing method is appropriately selected from a heat curing reaction and a photocuring reaction according to the curing reactivity of the curable organopolysiloxane, the purpose of use of the laminate, heat resistance, and process requirements. and the two curing reactions may be carried out simultaneously or stepwise.
  • the organopolysiloxane adhesive layer in the laminate is in a semi-cured state
  • the laminate is subjected to the same or different curing reaction to complete the curing reaction, and the organopolysiloxane in the laminate is cured.
  • the pressure-sensitive adhesive layer may be converted into a completely cured state.
  • the method for producing the laminate according to the present invention optionally includes (i) a heat curing reaction and (ii) a high-energy beam. may further include a step of curing the semi-cured organopolysiloxane pressure-sensitive adhesive layer by one or more curing reactions selected from photocuring reactions by irradiation of .
  • the organopolysiloxane pressure-sensitive adhesive layer obtained by curing or semi-curing the curable organopolysiloxane composition of the present invention can be used for construction and utilization of laminated touch screens or flat panel displays, as described above.
  • the cured product obtained by curing the curable organopolysiloxane composition of the present invention is an optically transparent silicone-based pressure-sensitive adhesive disclosed in JP-A-2014-522436 or JP-A-2013-512326. It can be used as an agent film or an adhesive layer for manufacturing a display device such as a touch panel.
  • the organopolysiloxane pressure-sensitive adhesive layer according to the present invention can be used without particular limitation as the pressure-sensitive adhesive layer or pressure-sensitive adhesive film described in JP-T-2013-512326.
  • the touch panel according to the present invention includes a base material such as a conductive plastic film having a conductive layer formed on one surface, and the conductive layer formed on the side or the opposite side thereof. It may be a touch panel comprising a cured layer obtained by curing the curable organopolysiloxane composition.
  • the substrate is preferably a sheet-like or film-like substrate, exemplified by a resin film or a glass plate.
  • the conductive plastic film may be a resin film or a glass plate, especially a polyethylene terephthalate film, having an ITO layer formed on one surface thereof.
  • organopolysiloxane pressure-sensitive adhesive layer according to the present invention may be used as an adhesive film for polarizing plates used in the production of display devices such as touch panels, and between the touch panel and the display module described in JP-A-2013-065009. It may be used as a pressure-sensitive adhesive layer for lamination.
  • the use of the curable reactive organopolysiloxane composition of the present invention and the cured product obtained by curing the composition are not limited to those disclosed above, and the cured product obtained by curing the composition is not limited.
  • the organopolysiloxane pressure-sensitive adhesive layer is used for television receivers, computer monitors, personal digital assistant monitors, surveillance monitors, video cameras, digital cameras, mobile phones, personal digital assistants, instrument panel displays for automobiles, and various equipment. ⁇ It can be used for a variety of display devices for displaying characters, symbols, and images, such as instrument panel displays for devices and equipment, automatic ticket vending machines, automatic teller machines, vehicle-mounted display devices, and vehicle-mounted transmissive screens. be.
  • the surface shape of such a display device may be a curved or curved shape instead of a flat surface, and in addition to various flat panel displays (FPD), curved displays used in automobiles (including electric vehicles), aircraft, etc.
  • FPD flat panel displays
  • curved displays used in automobiles (including electric vehicles), aircraft, etc.
  • a curved transmissive screen is exemplified.
  • these display devices display icons for executing functions or programs on screens and displays, notification displays such as e-mail programs, and operation buttons for various devices such as car navigation devices, audio devices, and air conditioners.
  • a touch panel function may be added to enable input operations by touching the icons, notification displays, and operation buttons with a finger.
  • the cured product obtained by curing the composition has excellent adhesiveness and viscoelastic properties, it is a film that is a member for transducers such as membranes for speakers (including for sensors, speakers, actuators, and generators). Alternatively, it can be used as a sheet-like member, and further, it can be used as a sealing layer or an adhesive layer for use in secondary batteries, fuel cells, or solar cell modules.
  • the organopolysiloxane pressure-sensitive adhesive layer according to the present invention has excellent transparency and excellent adhesion to substrates such as various display devices.
  • Apparatuses in particular, display apparatuses for vehicles with a curved screen or curved display, optionally with a touch panel function.
  • JP-A-2017-047767, JP-A-2014-182335, JP-A-2014-063064, JP-A-2013-233852, etc. disclose a vehicle display device having a curved display surface.
  • the pressure-sensitive adhesive layer according to the present invention can be suitably applied or replaced as part or all of the adhesive layer or pressure-sensitive adhesive layer that requires transparency in these documents.
  • the curable organopolysiloxane composition of the present invention and its cured product can be used in other known curved display devices by replacing the currently used adhesive layer or adhesive layer that requires transparency.
  • the transparent film-like substrate provided with the organopolysiloxane pressure-sensitive adhesive layer according to the present invention is used to prevent scratches on the surface of the display, stain prevention, fingerprint adhesion prevention, static electricity prevention, anti-reflection, anti-peeping, etc. may be used for the purpose.
  • composition Solid content of each composition (components forming a cured product excluding (D) organic solvent) relative to the total mass, when the total mass% of the A component is a, and the synthetic mass% of the B2 component is b, the The siloxane weight percent of the composition is defined as a+b2.
  • the composition according to this example does not contain an organopolysiloxane resin component.
  • Viscosity of curable composition Using a rotational viscometer (E-type viscometer VISCONIC EMD manufactured by Tokimec Co., Ltd.), the viscosity (Pa ⁇ s) of the composition and each component at 25° C. was measured.
  • Each composition is coated on a PET film (manufactured by Toray, Lumirror (registered trademark) S10, thickness 50 ⁇ m) so that the thickness after curing is 55 ⁇ m, and a release film (manufactured by Nippa, FSC-6, thickness 50 ⁇ m) on the composition, and then using a UV-LED ultraviolet irradiation device (manufactured by JATEC), from the PET film side, the ultraviolet irradiation amount (illuminance) is 4,000 mJ / cm as an integrated light amount .
  • the composition was cured by irradiation with ultraviolet rays of 365 nm.
  • Table 1 shows the adhesive strength (gf/25 mm) of the test piece measured at a tensile speed of 300 mm/min using the 180° peeling test method according to JIS Z 0237.
  • the compositions of the present invention according to Examples 1 to 4 have viscosities that allow coating without using an organic solvent, and can be easily cured with ultraviolet rays.
  • the composition of the present invention according to Example 5 has a viscosity that enables coating and can be heat-cured in the same manner as in the conventional method by using an organic solvent.
  • the cured product obtained by curing the composition had no turbidity, had a transparent appearance, and had practically low adhesiveness.

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PCT/JP2022/033709 2021-09-14 2022-09-08 硬化性オルガノポリシロキサン組成物、その硬化により得られる微粘着性のオルガノポリシロキサン粘着剤層および積層体 Ceased WO2023042745A1 (ja)

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US18/691,861 US20240384138A1 (en) 2021-09-14 2022-09-08 Curable organopolysiloxane composition, slightly-adhesive organopolysiloxane adhesive agent layer obtained by curing same, and laminate
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WO2024063069A1 (ja) * 2022-09-22 2024-03-28 ダウ・東レ株式会社 紫外線硬化性組成物およびその用途
WO2025146713A1 (ja) * 2024-01-04 2025-07-10 株式会社レゾナック 熱伝導シート、放熱装置、熱伝導シートの製造方法及び接着層形成用組成物

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