WO2023024488A1 - 一种硬碳复合材料及其制备方法和应用 - Google Patents

一种硬碳复合材料及其制备方法和应用 Download PDF

Info

Publication number
WO2023024488A1
WO2023024488A1 PCT/CN2022/080885 CN2022080885W WO2023024488A1 WO 2023024488 A1 WO2023024488 A1 WO 2023024488A1 CN 2022080885 W CN2022080885 W CN 2022080885W WO 2023024488 A1 WO2023024488 A1 WO 2023024488A1
Authority
WO
WIPO (PCT)
Prior art keywords
hard carbon
composite material
carbon composite
binder
solvent
Prior art date
Application number
PCT/CN2022/080885
Other languages
English (en)
French (fr)
Inventor
赵晓锋
Original Assignee
蜂巢能源科技股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 蜂巢能源科技股份有限公司 filed Critical 蜂巢能源科技股份有限公司
Priority to EP22768602.9A priority Critical patent/EP4164000A1/en
Publication of WO2023024488A1 publication Critical patent/WO2023024488A1/zh

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/10—Solid density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/11—Powder tap density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/90—Other properties not specified above
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • the disclosure relates to the technical field of lithium-ion batteries, in particular, to a hard carbon composite material and its preparation method and application.
  • Hard carbon is pyrolytic carbon of high molecular polymer, which is difficult to be graphitized. It has an interlaced layered structure, so that lithium ions can be intercalated and extracted from all angles, thus greatly improving the speed of charge and discharge; and graphite Compared with other materials, its low-temperature performance and rate performance are also significantly improved.
  • hard carbon materials generally have low specific capacity and low initial efficiency.
  • hard carbon materials often have shortcomings such as high electrode potential, potential hysteresis, and high initial irreversibility, which limits their large-scale application. Doping modification is one of the measures to increase the specific capacity of the material and reduce the impedance, but the hard carbon modified materials in the prior art have a small rate increase, a high voltage platform, low initial efficiency, and the cycle performance needs to be improved. question.
  • the present disclosure provides a hard carbon composite material, the hard carbon composite material has a core-shell structure, the inner core of the hard carbon composite material includes hard carbon doped with nitrogen, and the outer shell of the hard carbon composite material includes phosphorous compound of;
  • the mass of the inner core is 1%-10% of the mass of the shell.
  • the inner core and the outer shell are connected by a chemical bond.
  • the particle size of the hard carbon composite material is 5-20 ⁇ m.
  • the inner core is prepared from a resinous raw material, a nitrogen source, an additive and a solvent A in a mass ratio of 100:(1-10):(0.5-2):(100-500).
  • the nitrogen source includes at least one of ammonia water, aniline and pyrrole.
  • the additive includes at least one of sodium bicarbonate, ammonium bicarbonate, sodium carbonate and ammonium carbonate.
  • the resinous material includes at least one of phenolic resin, epoxy resin and furfural resin.
  • the solvent A includes ethanol and water.
  • the shell is prepared from an alkaline phosphorus salt compound, a binder and a solvent B in a mass ratio of 100:(5-20):(1000-5000).
  • the basic phosphorus salt compound includes at least one of melamine cyanurate, pentaerythritol melamine phosphate, ammonium polyphosphate and melamine pyrophosphate.
  • the solvent B includes at least one of ethanol, cyclohexane, carbon tetrachloride, benzene, toluene, N-methylpyrrolidone and acetone.
  • the binder includes at least one of polyvinylidene fluoride, styrene-butadiene rubber, LA132 binder, LA133 binder and LA136D binder.
  • the preparation method of described hard carbon composite material comprises the following steps:
  • the preparation method of the core precursor material includes: grinding and drying the mixture of resinous raw materials, nitrogen sources, additives and solvent A, and heat-treating the dried product in an atmosphere containing oxygen.
  • the temperature of the heat treatment is 100-300° C.
  • the time of the heat treatment is 1-24 hours.
  • the grinding is ball milling, and the time of the ball milling is 1-24 hours.
  • the temperature of the carbonization treatment is 900-1400° C., and the time of the carbonization treatment is 1-24 hours.
  • the carbonization treatment before the carbonization treatment, it further includes drying the mixture of the basic phosphorus salt compound, the binder, the solvent B and the core precursor material.
  • the drying treatment is spray drying.
  • the preparation method of the mixture of the basic phosphorus salt compound, the binder, the solvent B and the core precursor material specifically includes the following steps: mixing the basic phosphorus salt compound, the binder and the solvent B is dispersed to obtain a mixed slurry, and then the mixed slurry is mixed with the core precursor material;
  • the dispersion speed of the dispersion treatment is 1-100 m/s, and the dispersion time of the dispersion treatment is 10-120 minutes.
  • the solid content of the mixed slurry is 1%-5%.
  • a negative electrode includes the hard carbon composite material.
  • a lithium ion battery includes the negative electrode.
  • FIG. 1 is an SEM image of the hard carbon composite material prepared in Example 1 of the present disclosure.
  • One embodiment provides a hard carbon composite material, the hard carbon composite material has a core-shell structure, the inner core of the hard carbon composite material includes hard carbon doped with nitrogen, and the outer shell of the hard carbon composite material includes Phosphorus compounds;
  • the mass of the inner core is 1%-10% of the mass of the shell.
  • the inner shell of the hard carbon composite material in this embodiment is doped with nitrogen to increase the electrical conductivity of the composite material, and the porous structure can store more lithium ions to increase the specific capacity, and the porous structure can also store more electrolyte. cycle and its rate capability.
  • the shell is doped with phosphorus-containing compounds, relying on the high specific capacity of phosphorus itself to improve the specific capacity and first-time efficiency of the material. surface area. That is, the electrochemical performance of the composite material can be further improved through the combination of the core-shell structure.
  • the mass of the inner core is 1% to 10% of the mass of the shell, and can also be selected from 2%, 2.5%, 3%, 3.5%, 4%, 4.5%, 5%, 5.5%, 6%, 6.5%, 7%, 7.5%, 8%, 8.5%, 9% or 9.5%.
  • the inner core and the outer shell are connected by a chemical bond.
  • the core and shell of the hard carbon composite material are connected by chemical bonds, which reduces its impedance, lowers the charge and discharge voltage platform, and indirectly increases the specific capacity of the composite material.
  • the particle size of the hard carbon composite material is 5-20 ⁇ m. In one embodiment, the particle size of the hard carbon composite material includes but is not limited to 6 ⁇ m, 7 ⁇ m, 8 ⁇ m, 9 ⁇ m, 10 ⁇ m, 11 ⁇ m, 12 ⁇ m, 13 ⁇ m, 14 ⁇ m, 15 ⁇ m, 16 ⁇ m, 17 ⁇ m, 18 ⁇ m or 19 ⁇ m.
  • the inner core is prepared from a resinous raw material, a nitrogen source, an additive and a solvent A in a mass ratio of 100:(1-10):(0.5-2):(100-500).
  • the mass ratio of resin raw materials, nitrogen sources, additives and solvent A includes but is not limited to 100:1:0.5:100, 100:3:0.7:200, 100:5:1:300, 100:7:1.5:400 or 100:10:2:500.
  • the nitrogen source includes at least one of ammonia, aniline or pyrrole.
  • the precursor of the nitrogen element doped in the inner shell (that is, the nitrogen source) can be any one or a combination of ammonia water, aniline or pyrrole.
  • the additive includes at least one of sodium bicarbonate, ammonium bicarbonate, sodium carbonate and ammonium carbonate. At least one of sodium bicarbonate, ammonium bicarbonate, sodium carbonate and ammonium carbonate is used as a pore-forming agent, so that the inner core of the hard carbon composite material has a porous structure.
  • the resinous material includes at least one of phenolic resin, epoxy resin and furfural resin. Any one or more of the above-mentioned resin materials is used as a carbon source to provide an inner core skeleton.
  • the solvent A includes ethanol and water.
  • the volume ratio of the ethanol to water is (0.8-1):(0.8-1).
  • the shell is prepared from an alkaline phosphorus salt compound, a binder and a solvent B in a mass ratio of 100:(5-20):(1000-5000).
  • the mass ratio of the basic phosphorus salt compound, the binder and the solvent B can also be selected as 100:5:1000, 100:10:2000, 100:15:3500 or 100:20:5000.
  • the basic phosphorus compound includes at least one of melamine cyanurate, pentaerythritol melamine phosphate, ammonium polyphosphate and melamine pyrophosphate.
  • the solvent B includes at least one of ethanol, cyclohexane, carbon tetrachloride, benzene, toluene, N-methylpyrrolidone and acetone.
  • the solvent B may be one of the above solvents, or a combination of ethanol and cyclohexane, a combination of carbon tetrachloride, toluene and N-methylpyrrolidone, and the like.
  • the binder includes at least one of polyvinylidene fluoride, styrene-butadiene rubber, LA132 binder, LA133 binder and LA136D binder.
  • the binder may be any one of the above, or a combination of polyvinylidene fluoride and styrene-butadiene rubber, or the like.
  • the preparation method of the hard carbon composite material of one embodiment comprises the following steps:
  • the preparation method of the core precursor material includes: grinding and drying the mixture of resinous raw materials, nitrogen sources, additives and solvent A, and heat-treating the dried product in an atmosphere containing oxygen.
  • the preparation method of the hard carbon composite material provided by the present disclosure is simple and easy, and the core precursor material is obtained by grinding, drying and heating the mixture of resin raw materials, nitrogen sources, additives and solvent A in an atmosphere containing oxygen;
  • the core precursor material is mixed with the basic phosphorus salt compound, the binder, and the solvent B to obtain a mixture, and the mixture is further carbonized to obtain a hard carbon composite material.
  • nitrogen is doped inside the resin matrix material to reduce impedance, and phosphorus-containing compounds are coated on its surface to increase the specific capacity of the material, thereby improving the energy density and power performance of the composite material.
  • the temperature of the heat treatment is 100-300° C., and the time of the heat treatment is 1-24 hours.
  • the heat treatment includes but not limited to 110°C, 120°C, 130°C, 140°C, 150°C, 160°C, 170°C, 180°C, 190°C, 200°C, 210°C, 220°C, 230°C, 240°C, 250°C, 260°C, 270°C, 280°C or 290°C.
  • the heat treatment time includes but is not limited to 2h, 3h, 4h, 5h, 6h, 7h, 8h, 9h, 10h, 11h, 12h, 13h, 14h, 15h, 16h, 17h, 20h or 22h.
  • oxygen gas is injected at a flow rate of 4-6 mL/min.
  • the oxygen flow rate includes but not limited to 4.2mL/min, 4.5mL/min, 4.7mL/min, 5mL/min, 5.2mL/min, 5.5mL/min, 5.7mL/min or 6mL/min.
  • the grinding is ball milling, and the time of the ball milling is 1-24 hours.
  • the rotational speed of the ball mill is 40-60 rpm.
  • the time of the ball milling can also be selected from 2h, 3h, 4h, 5h, 6h, 7h, 8h, 9h, 10h, 11h, 12h, 13h, 14h, 15h, 16h, 17h, 18h, 19h, 20h, 21h, 22h or 23h.
  • the rotational speed of the ball mill includes but is not limited to 45 rpm, 50 rpm or 55 rpm.
  • resin raw materials, nitrogen sources, additives, and solvent A are mixed and then transferred to a ball mill for wet ball milling, so that the components are uniformly mixed, and the obtained core structure can be evenly doped with nitrogen elements to improve the electrical conductivity of the composite material .
  • the temperature of the carbonization treatment is 900-1400° C.
  • the time of the carbonization treatment is 1-24 hours.
  • the carbonization treatment temperature includes but not limited to 950°C, 970°C, 1000°C, 1020°C, 1050°C, 1070°C, 1100°C, 1120°C, 1150°C, 1170°C, 1200°C , 1220°C, 1250°C, 1270°C, 1300°C, 1320°C, 1350°C, 1370°C or 1400°C.
  • the carbonization treatment time includes but is not limited to 2h, 3h, 4h, 5h, 6h, 7h, 8h, 9h, 10h, 11h, 12h, 13h, 14h, 15h, 16h, 17h, 18h, 19h, 20h, 21h, 22h or 23h.
  • the carbonization treatment before the carbonization treatment, it further includes drying the mixture of the basic phosphorus salt compound, the binder, the solvent B and the core precursor material. In one embodiment, the drying treatment is spray drying.
  • the mixture of the basic phosphorus salt compound, the binder, the solvent B and the core precursor material is spray-dried and pulverized, and then carbonized in an inert atmosphere to obtain a hard carbon composite material.
  • the inert atmosphere includes argon, helium, or neon, among others.
  • the preparation method of the mixture of the basic phosphorus salt compound, the binder, the solvent B and the core precursor material specifically includes the following steps: mixing the basic phosphorus salt compound, the binder and the solvent B performs dispersion treatment to obtain a mixed slurry, and then mixes the mixed slurry with the core precursor material.
  • the basic phosphorus salt compound, the binder and the solvent B are dispersed at high speed first, fully mixed, and then mixed with the core precursor material.
  • the dispersion speed of the dispersion treatment is 1-100 m/s, and the dispersion time of the dispersion treatment is 10-120 minutes. Through appropriate dispersion speed and time coordination, it is beneficial to obtain better dispersion effect.
  • the dispersion speed of the dispersion treatment includes but is not limited to 5m/s, 10m/s, 15m/s, 20m/s, 30m/s, 40m/s, 50m/s, 60m/s , 70m/s, 80m/s or 90m/s.
  • the dispersion time of dispersion treatment includes but not limited to 20min, 30min, 40min, 50min, 60min, 70min, 80min, 90min, 100min or 110min.
  • the solid content of the mixed slurry is 1%-5%. In one embodiment, the solid content of the mixed slurry includes but is not limited to 1.5%, 2%, 2.5%, 3%, 3.5%, 4% or 4.5%.
  • One embodiment provides a negative electrode, including the above-mentioned hard carbon composite material.
  • the hard carbon composite material in the present disclosure can be used alone as an anode material for a lithium ion battery, or used in combination with other anode materials to prepare an anode.
  • the disclosed negative electrodes comprising hard carbon composites can impart high specific capacity and first-time efficiency to lithium-ion batteries.
  • One embodiment provides a lithium ion battery, including the above-mentioned negative electrode.
  • the lithium-ion battery has excellent specific capacity, first-time efficiency, rate performance and cycle performance.
  • a preparation method of hard carbon composite material comprising the following steps:
  • the precursor material A is fed with oxygen at a flow rate of 5mL/min in an atmosphere containing oxygen, the temperature is raised to 200°C and heated for 12 hours to obtain the core precursor material;
  • a preparation method of hard carbon composite material comprising the following steps:
  • the precursor material A is fed with oxygen at a flow rate of 5mL/min, and heated at a temperature of 100°C for 24 hours to obtain the core precursor material;
  • a preparation method of hard carbon composite material comprising the following steps:
  • Precursor material A is fed with oxygen at a flow rate of 5mL/min in an atmosphere containing oxygen, and heated at a temperature of 300°C for 1 hour to obtain a core precursor material;
  • Fig. 1 is an SEM image of the hard carbon composite material prepared in Example 1. It can be seen from the figure that the material presents a granular structure with a uniform size distribution, and the particle size is between 5 and 20 ⁇ m.
  • the hard carbon composite materials prepared in Examples 1-3 and Comparative Example 1 were tested for particle size, true density, tap density, specific surface area, ash content and specific capacity.
  • test method refers to GBT-245332009 "Graphite Anode Materials for Lithium-ion Batteries”:
  • the hard carbon composite materials obtained in Examples 1 to 3 and Comparative Example 1 were assembled into button batteries A1, A2, A3, and B1 respectively; the preparation method included: adding a binding agent, a conductive agent, and a solvent to the negative electrode material, Stirring and pulping, coating on copper foil, drying and rolling; the binder used is LA132 binder, the conductive agent is SP, and the negative electrode materials are respectively prepared in Examples 1-3 and Comparative Example 1
  • the hard carbon composite material produced, the solvent is double-distilled water; the amount ratio of negative electrode material, conductive agent SP, LA132 binder and double-distilled water is 95g: 1g: 4g: 220mL, and the negative electrode sheet is prepared;
  • the electrolyte is LiPF 6 , EC and DEC (the volume ratio of EC and DEC is 1:1, and the concentration of LiPF 6 is 1.3mol/L); the metal lithium sheet is used as the counter electrode, and the diaphragm is made of polyethylene (PE), polypropylene (PP) or polypropylene E
  • the charge and discharge voltage range was 0.005V to 2.0V, and the charge and discharge rate It is 0.1C; at the same time, the rate (3C, 0.1C) and cycle performance (0.5C/0.5C, 200 times) of the button battery are tested.
  • the test data is detailed in Table 2:
  • Example 1 Example 2
  • Example 3 Comparative example 1 Particle size (D50, ⁇ m) 12.6 11.1 12.7 9.9 True density (g/cm 3 ) 2.16 2.18 2.20 1.94 Tap density (g/cm 3 ) 1.08 1.05 1.03 0.90 Ash (%) 0.05 0.04 0.06 0.09 First discharge capacity (mAh/g) 598 586 579 395 First time efficiency (%) 89.5 89.4 89.1 83.3 Rate performance (3C/0.1C) 97.5 96.6 97.1 90.3 Cycle performance (capacity retention)/% 98.8 98.7 98.3 94.3
  • the hard carbon materials prepared in Examples 1-3 have high specific capacity and initial efficiency, because the phosphorus compound doped in the hard carbon composite material can increase its specific capacity, and the pore structure formed at the same time accommodates Lithium salt reduces its irreversible capacity and improves the first-time efficiency of its material. At the same time, the nitrogen element contained in the material can increase the electronic conductivity of the material, thereby improving its rate performance and cycle performance.
  • the present disclosure provides a hard carbon composite material and its preparation method and application.
  • the hard carbon composite material cooperates with a hard carbon inner core doped with nitrogen and an outer shell containing a phosphorus compound to enhance the composite material.
  • the specific capacity and power performance; the preparation method of the hard carbon composite material is simple and easy, and the obtained composite material has excellent conductivity, which can improve the cycle performance and rate performance of lithium-ion batteries.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

一种硬碳复合材料及其制备方法和应用。硬碳复合材料具有核壳结构，内核包括掺杂有氮元素的硬碳，外壳包括含磷化合物；内核的质量为外壳的质量的1％～10％。硬碳复合材料的内核掺杂氮元素以提升复合材料的导电率；外壳中掺杂含磷化合物，依靠磷元素自身的高比容量提升复合材料的比容量及其首次效率，同时通过外壳含磷化合物的包覆降低内核多孔结构的比表面积，降低硬碳复合材料的整个比表面积。通过内核和外壳的搭配，得到的硬碳复合材料具有优异的电化学性能。

Description

一种硬碳复合材料及其制备方法和应用
相关申请的交叉引用
本申请要求于2021年08月26日提交中国专利局的申请号为2021109907917、名称为“一种硬碳复合材料及其制备方法和应用”的中国专利申请的优先权，其全部内容通过引用结合在本申请中。
技术领域
本公开涉及锂离子电池技术领域，具体而言，涉及一种硬碳复合材料及其制备方法和应用。
背景技术
硬碳是高分子聚合物的热解碳，其难以被石墨化，它具有相互交错的层状结构，从而使锂离子能够从各个角度嵌入和脱出，从而大大提高了充放电的速度；与石墨材料相比，其低温性能和倍率性能也有明显的改善。但是硬碳材料一般比容量偏低，首次效率低，同时硬碳材料也往往存在电极电位过高、电位滞后、首次不可逆高等缺点，使其大规模应用受到限制。而掺杂改性是提升材料比容量、降低阻抗的措施之一，但现有技术中的硬碳改性材料存在倍率提升幅度较小，电压平台高，首次效率低，同时循环性能有待改善的问题。
因此，如何提高硬碳材料的倍率性能、首效和循环性能是目前急需解决的问题。
发明内容
本公开提供一种硬碳复合材料，所述硬碳复合材料具有核壳结构，所述硬碳复合材料的内核包括掺杂有氮元素的硬碳，所述硬碳复合材料的外壳包括含磷的化合物；
所述内核的质量为所述外壳的质量的1％～10％。
在一种实施方式中，所述内核和所述外壳通过化学键相连接。
在一种实施方式中，所述硬碳复合材料的粒径为5～20μm。
在一种实施方式中，所述内核由包括质量比为100:(1～10):(0.5～2):(100～500)的树脂类原料、氮源、添加剂和溶剂A制备得到。
在一种实施方式中，所述氮源包括氨水、苯胺和吡咯中的至少一种。
在一种实施方式中，所述添加剂包括碳酸氢钠、碳酸氢胺、碳酸钠和碳酸铵中的至少一种。
在一种实施方式中，所述树脂类材料包括酚醛树脂、环氧树脂和糠醛树脂中的至少一种。
在一种实施方式中，所述溶剂A包括乙醇和水。
在一种实施方式中，所述外壳由包括质量比为100:(5～20):(1000～5000)的碱性磷盐化合物、粘结剂和溶剂B制备得到。
在一种实施方式中，所述碱性磷盐化合物包括三聚氰胺氰尿酸盐、季戊四醇三聚氰胺磷酸酯、多聚磷酸铵和三聚氰胺焦磷酸盐中的至少一种。
在一种实施方式中，所述溶剂B包括乙醇、环己烷、四氯化碳、苯、甲苯、N-甲基吡咯烷酮和丙酮中的至少一种。
在一种实施方式中，所述粘结剂包括聚偏二氟乙烯、丁苯橡胶、LA132粘结剂、LA133粘结剂和LA136D粘结剂中的至少一种。
所述的硬碳复合材料的制备方法，包括以下步骤：
将碱性磷盐化合物、粘结剂、溶剂B与内核前驱体材料的混合物进行碳化处理；
所述内核前驱体材料的制备方法包括：将树脂类原料、氮源、添加剂和溶剂A的混合物进行研磨和干燥，干燥后的所得物在含有氧气的气氛中进行加热处理。
在一种实施方式中，所述加热处理的温度为100～300℃，所述加热处理的时间为1～24h。
在一种实施方式中，所述研磨为球磨，所述球磨的时间为1～24h。
在一种实施方式中，所述碳化处理的温度为900～1400℃，所述碳化处理的时间为1～24h。
在一种实施方式中，所述碳化处理之前，还包括对所述碱性磷盐化合物、粘结剂、溶剂B与内核前驱体材料的混合物进行干燥处理。
在一种实施方式中，所述干燥处理为喷雾干燥。
在一种实施方式中，所述碱性磷盐化合物、粘结剂、溶剂B与内核前驱体材料的混合物的制备方法具体包括以下步骤：将所述碱性磷盐化合物、粘结剂和溶剂B进行分散处理，得到混合浆料，再将所述混合浆料与所述内核前驱体材料进行混匀；
在一种实施方式中，所述分散处理的分散速度为1～100m/s，所述分散处理的分散时间为10～120min。
在一种实施方式中，所述混合浆料的固含量为1％～5％。
一种负极，包括所述的硬碳复合材料。
一种锂离子电池，包括所述的负极。
附图说明
为了更清楚地说明本公开实施方式的技术方案，下面将对实施方式中所需要使用的附图作简单地介绍，应当理解，以下附图仅示例地表征本公开的实施方式，图中尺寸比例与实施方式的真实比例并不能直接对应，同时以下附图仅示出了本公开的某些实施方式，因此不应被看作是对范围的限定。
图1为本公开实施例1制备得到的硬碳复合材料的SEM图。
具体实施方式
发明内容中实施方式的优点将会在下面的说明书实施方式部分阐明，一部分根据说明书是显而易见的，或者可以通过本公开实施例的部分实施例而获得。
下面结合附图并通过一些实施方式来进一步说明本公开的技术方案。
为了使本公开的目的、技术方案及优点更加清楚明白，以下结合附图及实施例，对本公开进行进一步详细说明。应当理解，此处所描述的实施例仅仅用以解释本公开，并不用于限定本公开。此外，下面所描述的本公开各个实施方式中所涉及的技术特征只要彼此之间未构成冲突就可以相互组合。在不脱离本公开实施例原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也视为本公开实施例的保护范围。
一实施方式提供一种硬碳复合材料，所述硬碳复合材料具有核壳结构，所述硬碳复合材料的内核包括掺杂有氮元素的硬碳，所述硬碳复合材料的外壳包括含磷的化合物；
所述内核的质量为所述外壳的质量的1％～10％。
本实施方式的硬碳复合材料内壳掺杂氮元素以提升复合材料的导电率，并且具备的多孔结构可以存储更多的锂离子，提升比容量，多孔结构还可以存储更多的电解液提升循环及其倍率性能。外壳中掺杂含磷化合物，依靠磷自身的 高比容量提升材料的比容量及其首次效率，同时通过外壳含磷化合物的包覆降低内核多孔结构的比表面积，降低硬碳复合材料的整个比表面积。即通过核壳结构的搭配，可进一步提高复合材料的电化学性能。
一些实施方式中，所述内核的质量为所述外壳的质量的1％～10％，还可以选择2％、2.5％、3％、3.5％、4％、4.5％、5％、5.5％、6％、6.5％、7％、7.5％、8％、8.5％、9％或9.5％。
一些实施方式中，所述内核和所述外壳通过化学键相连接。硬碳复合材料的内核和外壳是通过化学键相连接，降低其阻抗，降低充放电电压平台，间接提升复合材料的比容量。
一些实施方式中，所述硬碳复合材料的粒径为5～20μm。在一种实施方式中，所述硬碳复合材料的粒径包括但不限于为6μm、7μm、8μm、9μm、10μm、11μm、12μm、13μm、14μm、15μm、16μm、17μm、18μm或19μm。
一些实施方式中，所述内核由包括质量比为100:(1～10):(0.5～2):(100～500)的树脂类原料、氮源、添加剂和溶剂A制备得到。在一种实施方式中，树脂类原料、氮源、添加剂和溶剂A的质量比包括但不限于为100:1:0.5:100、100:3:0.7:200、100:5:1:300、100:7:1.5:400或100:10:2:500。
一些实施方式中，所述氮源包括氨水、苯胺或吡咯中的至少一种。内壳中掺杂的氮元素的前驱体(即氮源)可选择氨水、苯胺或吡咯中的任意一种或者多种的组合。
一些实施方式中，所述添加剂包括碳酸氢钠、碳酸氢胺、碳酸钠和碳酸铵中的至少一种。采用碳酸氢钠、碳酸氢胺、碳酸钠和碳酸铵中的至少一种作为造孔剂，进而使得硬碳复合材料的内核具有多孔结构。
一些实施方式中，所述树脂类材料包括酚醛树脂、环氧树脂和糠醛树脂中的至少一种。采用上述任意一种或多种树脂材料作为碳源，以提供内核骨架。
一些实施方式中，所述溶剂A包括乙醇和水。
一些实施方式中，所述乙醇和水的体积比为(0.8～1)：(0.8～1)。
一些实施方式中，所述外壳由包括质量比为100:(5～20):(1000～5000)的碱性磷盐化合物、粘结剂和溶剂B制备得到。在一种实施方式中，碱性磷盐化合物、粘结剂和溶剂B的质量比还可以选择100:5:1000、100:10:2000、100:15:3500或100:20:5000。
一些实施方式中，所述碱性磷盐化合物包括三聚氰胺氰尿酸盐、季戊四醇三聚氰胺磷酸酯、多聚磷酸铵和三聚氰胺焦磷酸盐中的至少一种。通过采用三聚氰胺氰尿酸盐、季戊四醇三聚氰胺磷酸酯、多聚磷酸铵和三聚氰胺焦磷酸盐中的一种或者多种组合以提供外壳的含磷化合物，提升复合材料的比容量及其首次效率。
一些实施方式中，所述溶剂B包括乙醇、环己烷、四氯化碳、苯、甲苯、N-甲基吡咯烷酮和丙酮中的至少一种。在一种实施方式中，所述溶剂B可以采用上述溶剂中的一种，或者乙醇和环己烷的组合，四氯化碳、甲苯和N-甲基吡咯烷酮的组合等。
一些实施方式中，所述粘结剂包括聚偏二氟乙烯、丁苯橡胶、LA132粘结剂、LA133粘结剂和LA136D粘结剂中的至少一种。在一种实施方式中，所述粘结剂可以采用上述任意一种，或者聚偏二氟乙烯和丁苯橡胶的组合等。
一实施方式的硬碳复合材料的制备方法，包括以下步骤：
将碱性磷盐化合物、粘结剂、溶剂B与内核前驱体材料的混合物进行碳化处理；
所述内核前驱体材料的制备方法包括：将树脂类原料、氮源、添加剂和溶剂A的混合物进行研磨和干燥，干燥后的所得物在含有氧气的气氛中进行加热处理。
本公开提供的硬碳复合材料的制备方法简单易行，通过将树脂类原料、氮源、添加剂和溶剂A的混合物进行研磨、干燥以及在含有氧气的气氛中加热，获得内核前驱体材料；再将内核前驱体材料与碱性磷盐化合物、粘结剂、溶剂B混合，得到混合物，进一步对混合物进行碳化处理，得到硬碳复合材料。通 过上述方法得到的硬碳复合材料，在树脂基体材料内部掺杂氮以降低阻抗，在其表面包覆含磷化合物提升材料比容量，进而提升复合材料的能量密度及其功率性能。
一些实施方式中，所述加热处理的温度为100～300℃，所述加热处理的时间为1～24h。在一种实施方式中，所述加热处理的包括但不限于为110℃、120℃、130℃、140℃、150℃、160℃、170℃、180℃、190℃、200℃、210℃、220℃、230℃、240℃、250℃、260℃、270℃、280℃或290℃。所述加热处理的时间包括但不限于为2h、3h、4h、5h、6h、7h、8h、9h、10h、11h、12h、13h、14h、15h、16h、17h、20h或22h。
一些实施方式中，在加热处理的过程中，以4～6mL/min的流速通入氧气。在一种实施方式中，氧气的通入流速包括但不限于4.2mL/min、4.5mL/min、4.7mL/min、5mL/min、5.2mL/min、5.5mL/min、5.7mL/min或6mL/min。
一些实施方式中，所述研磨为球磨，所述球磨的时间为1～24h。所述球磨的转速为40～60rpm。在一种实施方式中，所述球磨的时间为还可以选择2h、3h、4h、5h、6h、7h、8h、9h、10h、11h、12h、13h、14h、15h、16h、17h、18h、19h、20h、21h、22h或23h。所述球磨的转速包括但不限于为45rpm、50rpm或55rpm。
本公开将树脂类原料、氮源、添加剂和溶剂A混匀后转移到球磨机中进行湿法球磨，使各组分均匀混合，获得的内核结构可均匀掺杂氮元素，提高复合材料的导电性能。
一些实施方式中，所述碳化处理的温度为900～1400℃，所述碳化处理的时间为1～24h。通过采用适宜的碳化温度和时间，进而可获得具有优异导电性能、适宜多孔结构的硬碳复合材料；进而提高锂离子电池的比容量和循环性能。
在一种实施方式中，所述碳化处理的温度包括但不限于为950℃、970℃、1000℃、1020℃、1050℃、1070℃、1100℃、1120℃、1150℃、1170℃、1200℃、1220℃、1250℃、1270℃、1300℃、1320℃、1350℃、1370℃或1400℃。在一种实施方式中，碳化处理的时间包括但不限于为2h、3h、4h、5h、6h、7h、 8h、9h、10h、11h、12h、13h、14h、15h、16h、17h、18h、19h、20h、21h、22h或23h。
在一种实施方式中，所述碳化处理之前，还包括对所述碱性磷盐化合物、粘结剂、溶剂B与内核前驱体材料的混合物进行干燥处理。在一种实施方式中，所述干燥处理为喷雾干燥。
本公开先将碱性磷盐化合物、粘结剂、溶剂B与内核前驱体材料的混合物进行喷雾干燥、粉碎，然后再于惰性气氛下进行碳化处理，得到硬碳复合材料。惰性气氛包括氩气、氦气或氖气等。
在一种实施方式中，所述碱性磷盐化合物、粘结剂、溶剂B与内核前驱体材料的混合物的制备方法具体包括以下步骤：将所述碱性磷盐化合物、粘结剂和溶剂B进行分散处理，得到混合浆料，再将所述混合浆料与所述内核前驱体材料进行混匀。
本公开先将碱性磷盐化合物、粘结剂和溶剂B进行高速分散处理，充分混匀，再与内核前驱体材料进行混匀。
在一种实施方式中，所述分散处理的分散速度为1～100m/s，所述分散处理的分散时间为10～120min。通过适宜的分散速度和时间配合，有利于获得较佳的分散效果。在一种实施方式中，所述分散处理的分散速度包括但不限于为5m/s、10m/s、15m/s、20m/s、30m/s、40m/s、50m/s、60m/s、70m/s、80m/s或90m/s。分散处理的分散时间包括但不限于为20min、30min、40min、50min、60min、70min、80min、90min、100min或110min。
在一种实施方式中，所述混合浆料的固含量为1％～5％。在一种实施方式中，所述混合浆料的固含量包括但不限于为1.5％、2％、2.5％、3％、3.5％、、4％或4.5％。
一实施方式提供一种负极，包括如上所述的硬碳复合材料。
本公开中的硬碳复合材料可单独作为锂离子电池负极材料，或者与其他负极材料组合用于制备负极。本公开包含硬碳复合材料的负极可赋予锂离子电池 高的比容量和首次效率。
一实施方式提供一种锂离子电池，包括如上所述的负极。
该锂离子电池具有优异的比容量，首次效率，倍率性能和循环性能。
实施例
以下为本公开典型但非限制性实施例：
实施例1
一种硬碳复合材料的制备方法，包括以下步骤：
(a)将100g酚醛树脂，5g氨水及1g碳酸钠添加到300g的乙醇和去离子水的混合液中，乙醇和去离子水的体积比为1:1，搅拌均匀后转移到球磨机中，以转速为50rpm进行湿法球磨12h，再进行干燥，得到前驱体材料A；
将前驱体材料A在含有氧气的气氛下，以流速为5mL/min通入氧气，升温到200℃并加热12h，得到内核前驱体材料；
(b)称取100g三聚氰胺氰尿酸盐、10g LA133粘结剂及3000gN-甲基吡咯烷酮配置成溶液，之后通过高速分散机进行分散处理，以分散速度为50m/s分散60min，得到混合浆料；
(c)称取500g上述内核前驱体材料添加至上述混合浆料中，搅拌均匀后，喷雾干燥、粉碎，之后在氩气惰性气氛下，温度为1200℃碳化12h，得到硬碳复合材料。
实施例2
一种硬碳复合材料的制备方法，包括以下步骤：
(a)将100g环氧树脂、1g苯胺及0.5g碳酸氢胺添加到100mL乙醇和去离子水的混合液中，乙醇和去离子水的体积比为1:1，搅拌均匀后转移到球磨 机中，并以转速为50rpm进行湿法球磨1h，再进行干燥，得到前驱体材料A；
将前驱体材料A在含有氧气的气氛下，以流速为5mL/min通入氧气，温度为100℃加热24h，得到内核前驱体材料；
(b)称取100g季戊四醇三聚氰胺磷酸酯、5g聚偏二氟乙烯及1000mL四氯化碳配置成溶液，并通过高速分散机进行分散处理，以分散速度为10m/s分散120min，得到混合浆料；
(c)将1000g上述内核驱体材料添加至上述混合浆料中，搅拌均匀后，喷雾干燥、粉碎，之后在惰性气氛下，温度为900℃碳化24h，得到硬碳复合材料。
实施例3
一种硬碳复合材料的制备方法，包括以下步骤：
(a)将100g糠醛树脂、10g噻吩及2g碳酸铵添加到500mL乙醇和去离子水的混合液中，乙醇和去离子水的体积比为1:1，搅拌均匀后转移到球磨机中，并以转速为50rpm进行湿法球磨24h，再进行干燥，得到前驱体材料A；
将前驱体材料A在含有氧气的气氛下，以流速为5mL/min通入氧气，温度为300℃加热1h，得到内核前驱体材料；
(b)称取100g多聚磷酸铵、20g丁苯橡胶及5000mL丙酮配置成溶液，并通过高速分散机进行分散处理，以分散速度为100m/s分散10min，得到混合浆料；
(c)将上述内核前驱体材料添加至上述混合浆料中，搅拌均匀后，喷雾干燥、粉碎，之后在氩气惰性气氛下，温度为1400℃碳化1h，得到硬碳复合 材料。
对比例1
将100g酚醛树脂和25g乙醇混合，搅拌均匀；之后在温度为180℃反应6h，之后采用球磨机研磨成粉末，将粉末放入管式炉中，通入氩气惰性气体，并在1400℃进行热处理2小时，使之裂解、碳化，得到硬碳复合材料。
实验例
1、SEM测试
图1为实施例1制备出的硬碳复合材料的SEM图，由图中可以看出，材料呈现颗粒状结构，大小分布均匀，粒径介于5～20μm之间。
2、内核前驱体材料的物化性能测试
按照国家标准GBT-245332009《锂离子电池石墨类负极材料》测试实施例1～3的内核前驱体材料的比表面积及其孔容分布，结果如表1所示。
表1内核前驱体材料的物化性能
Figure PCTCN2022080885-appb-000001
由表1可以看出，本公开实施例1～3所得的内核前驱体材料在比表面积方面优于对比例1，因为前驱体材料中采用造孔剂提升材料的比表面积及其孔隙率。
3、扣式电池测试：
(1)物化性能及其扣式电池测试：
对实施例1～3和对比例1制备出的硬碳复合材料进行粒径、真密度、振实密度、比表面积、灰分及其比容量测试。
测试方法参照GBT-245332009《锂离子电池石墨类负极材料》：
分别将实施例1～3和对比例1中所得的硬碳复合材料组装成扣式电池A1、A2、A3、B1；其制备方法包括：在负极材料中添加粘结剂、导电剂及溶剂，进行搅拌制浆，涂覆在铜箔上，经过烘干、碾压制得；所用粘结剂为LA132粘结剂，导电剂为SP，负极材料分别为实施例1～3和对比例1制备出的硬碳复合材料，溶剂为二次蒸馏水；负极材料、导电剂SP、LA132粘结剂和二次蒸馏水的用量比为95g：1g：4g：220mL，并制备出负极极片；电解液是LiPF 6、EC和DEC(EC和DEC的体积比为1:1，LiPF 6浓度为1.3mol/L)；金属锂片为对电极，隔膜采用聚乙烯(PE)，聚丙烯(PP)或聚乙丙烯(PEP)复合膜，模拟电池装配在充氩气的手套箱中进行，电化学性能在武汉蓝电CT2001A型电池测试仪上进行，充放电电压范围为0.005V至2.0V，充放电速率为0.1C；同时测试其扣式电池的倍率(3C、0.1C)和循环性能(0.5C/0.5C，200次)。测试数据详见表2：
表2物化参数及性能比较
项目 实施例1 实施例2 实施例3 对比例1
粒径(D50，μm) 12.6 11.1 12.7 9.9
真密度(g/cm 3) 2.16 2.18 2.20 1.94
振实密度(g/cm 3) 1.08 1.05 1.03 0.90
灰分(％) 0.05 0.04 0.06 0.09
首次放电容量(mAh/g) 598 586 579 395
首次效率(％) 89.5 89.4 89.1 83.3
倍率性能(3C/0.1C) 97.5 96.6 97.1 90.3
循环性能(容量保持率)/％ 98.8 98.7 98.3 94.3
由表2可以看出，实施例1～3制备出的硬碳材料具有高的比容量和首次效率，因为硬碳复合材料中掺杂的磷化合物可提高其比容量，同时形成的孔洞结构容纳锂盐降低其不可逆容量，提高其材料的首次效率，同时材料中含有的氮元素可提升材料的电子导电率，从而改善其倍率性能和循环性能。
工业实用性
综上所述，本公开提供了一种硬碳复合材料及其制备方法和应用，该硬碳复合材料通过掺杂有氮元素的硬碳内核和包含含磷化合物的外壳配合，以提升复合材料的比容量和功率性能；硬碳复合材料的制备方法简单易行，得到的复合材料具有优异的导电率，可提高锂离子电池的循环性能和倍率性能。

Claims (10)

  1. 一种硬碳复合材料，其特征在于，所述硬碳复合材料具有核壳结构，所述硬碳复合材料的内核包括掺杂有氮元素的硬碳，所述硬碳复合材料的外壳包括含磷的化合物；
    所述内核的质量为所述外壳的质量的1％～10％。
  2. 根据权利要求1所述的硬碳复合材料，其特征在于，包含以下特征(1)～(2)中的至少一种：
    (1)所述内核和所述外壳通过化学键相连接；
    (2)所述硬碳复合材料的粒径为5～20μm。
  3. 根据权利要求1或2所述的硬碳复合材料，其特征在于，包含以下特征(1)～(5)中的至少一种：
    (1)所述内核由包括质量比为100:(1～10):(0.5～2):(100～500)的树脂类原料、氮源、添加剂和溶剂A制备得到；
    (2)所述氮源包括氨水、苯胺和吡咯中的至少一种；
    (3)所述添加剂包括碳酸氢钠、碳酸氢胺、碳酸钠和碳酸铵中的至少一种；
    (4)所述树脂类材料包括酚醛树脂、环氧树脂和糠醛树脂中的至少一种；
    (5)所述溶剂A包括乙醇和水。
  4. 根据权利要求1～3中任一项所述的硬碳复合材料，其特征在于，包含以下特征(1)～(4)中的至少一种：
    (1)所述外壳由包括质量比为100:(5～20):(1000～5000)的碱性磷盐化合物、粘结剂和溶剂B制备得到；
    (2)所述碱性磷盐化合物包括三聚氰胺氰尿酸盐、季戊四醇三聚氰胺磷酸酯、多聚磷酸铵和三聚氰胺焦磷酸盐中的至少一种；
    (3)所述溶剂B包括乙醇、环己烷、四氯化碳、苯、甲苯、N-甲基吡咯烷酮和丙酮中的至少一种；
    (4)所述粘结剂包括聚偏二氟乙烯、丁苯橡胶、LA132粘结剂、LA133粘结剂和LA136D粘结剂中的至少一种。
  5. 根据权利要求1～4中任一项所述的硬碳复合材料的制备方法，其特征在于，包括以下步骤：
    将碱性磷盐化合物、粘结剂、溶剂B与内核前驱体材料的混合物进行碳化处理；
    所述内核前驱体材料的制备方法包括：将树脂类原料、氮源、添加剂和溶剂A的混合物进行研磨和干燥，干燥后的所得物在含有氧气的气氛中进行加热处理。
  6. 根据权利要求5所述的硬碳复合材料的制备方法，其特征在于，包含以下特征(1)～(2)中的至少一种：
    (1)所述加热处理的温度为100～300℃，所述加热处理的时间为1～24h；
    (2)所述研磨为球磨，所述球磨的时间为1～24h。
  7. 根据权利要求5或6所述的硬碳复合材料的制备方法，其特征在于，包含以下特征(1)～(3)中的至少一种：
    (1)所述碳化处理的温度为900～1400℃，所述碳化处理的时间为1～24h；
    (2)所述碳化处理之前，还包括对所述碱性磷盐化合物、粘结剂、溶剂B与内核前驱体材料的混合物进行干燥处理；
    (3)所述干燥处理为喷雾干燥。
  8. 根据权利要求5～7中任一项所述的硬碳复合材料的制备方法，其特征在于，包含以下特征(1)～(3)中的至少一种：
    (1)所述碱性磷盐化合物、粘结剂、溶剂B与内核前驱体材料的混合物 的制备方法具体包括以下步骤：将所述碱性磷盐化合物、粘结剂和溶剂B进行分散处理，得到混合浆料，再将所述混合浆料与所述内核前驱体材料进行混匀；
    (2)所述分散处理的分散速度为1～100m/s，所述分散处理的分散时间为10～120min；
    (3)所述混合浆料的固含量为1％～5％。
  9. 一种负极，其特征在于，包括权利要求1～4中任一项所述的硬碳复合材料。
  10. 一种锂离子电池，其特征在于，包括权利要求9所述的负极。
PCT/CN2022/080885 2021-08-26 2022-03-15 一种硬碳复合材料及其制备方法和应用 WO2023024488A1 (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP22768602.9A EP4164000A1 (en) 2021-08-26 2022-03-15 Hard carbon composite material, preparation method therefor, and use thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202110990791.7A CN113707863B (zh) 2021-08-26 2021-08-26 一种硬碳复合材料及其制备方法和应用
CN202110990791.7 2021-08-26

Publications (1)

Publication Number Publication Date
WO2023024488A1 true WO2023024488A1 (zh) 2023-03-02

Family

ID=78655491

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2022/080885 WO2023024488A1 (zh) 2021-08-26 2022-03-15 一种硬碳复合材料及其制备方法和应用

Country Status (3)

Country Link
EP (1) EP4164000A1 (zh)
CN (1) CN113707863B (zh)
WO (1) WO2023024488A1 (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117466278A (zh) * 2023-11-01 2024-01-30 东北大学 一种球磨改性硬碳材料的方法及其在钠离子电池负极中的应用

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113707863B (zh) * 2021-08-26 2023-04-14 蜂巢能源科技有限公司 一种硬碳复合材料及其制备方法和应用
CN114142011B (zh) * 2021-11-29 2023-06-16 蜂巢能源科技有限公司 一种硬碳复合材料及其制备方法和应用
CN114420939B (zh) * 2022-03-31 2022-06-21 河北坤天新能源股份有限公司 一种高倍率球状硬碳复合材料及其制备方法和应用

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101887966A (zh) * 2010-06-18 2010-11-17 深圳市贝特瑞新能源材料股份有限公司 锂离子电池复合硬碳负极材料及其制备方法
CN102820455A (zh) * 2012-08-02 2012-12-12 天津市贝特瑞新能源科技有限公司 一种锂离子电池硬碳负极材料及其制备方法和其应用
CN104752721A (zh) * 2013-12-31 2015-07-01 比亚迪股份有限公司 负极活性材料及其制备方法、使用该负极活性材料的锂离子电池
CN105098185A (zh) * 2014-04-29 2015-11-25 华为技术有限公司 复合负极材料及其制备方法、锂离子二次电池负极极片和锂离子二次电池
CN106505199A (zh) * 2016-11-29 2017-03-15 中航锂电（洛阳）有限公司 一种锂离子电池复合负极材料及其制备方法、锂离子电池
CN112838197A (zh) * 2019-11-25 2021-05-25 华为技术有限公司 负极材料及其制备方法，电池和终端
CN113707863A (zh) * 2021-08-26 2021-11-26 蜂巢能源科技有限公司 一种硬碳复合材料及其制备方法和应用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101916845B (zh) * 2010-08-05 2012-12-05 深圳市贝特瑞新能源材料股份有限公司 适合于动力与储能电池用的硬碳材料及其制备方法
CN106450311B (zh) * 2016-10-14 2019-10-15 焦作聚能能源科技有限公司 一种石墨复合负极材料及其制备方法
CN107706360A (zh) * 2017-07-25 2018-02-16 深圳市沃特玛电池有限公司 一种锂离子电池复合负极材料的制备方法
CN112645300B (zh) * 2019-11-07 2023-02-07 上海杉杉科技有限公司 一种硬碳负极材料、锂离子电池及其制备方法和应用

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101887966A (zh) * 2010-06-18 2010-11-17 深圳市贝特瑞新能源材料股份有限公司 锂离子电池复合硬碳负极材料及其制备方法
CN102820455A (zh) * 2012-08-02 2012-12-12 天津市贝特瑞新能源科技有限公司 一种锂离子电池硬碳负极材料及其制备方法和其应用
CN104752721A (zh) * 2013-12-31 2015-07-01 比亚迪股份有限公司 负极活性材料及其制备方法、使用该负极活性材料的锂离子电池
CN105098185A (zh) * 2014-04-29 2015-11-25 华为技术有限公司 复合负极材料及其制备方法、锂离子二次电池负极极片和锂离子二次电池
CN106505199A (zh) * 2016-11-29 2017-03-15 中航锂电（洛阳）有限公司 一种锂离子电池复合负极材料及其制备方法、锂离子电池
CN112838197A (zh) * 2019-11-25 2021-05-25 华为技术有限公司 负极材料及其制备方法，电池和终端
CN113707863A (zh) * 2021-08-26 2021-11-26 蜂巢能源科技有限公司 一种硬碳复合材料及其制备方法和应用

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117466278A (zh) * 2023-11-01 2024-01-30 东北大学 一种球磨改性硬碳材料的方法及其在钠离子电池负极中的应用
CN117466278B (zh) * 2023-11-01 2024-05-17 东北大学 一种球磨改性硬碳材料的方法及其在钠离子电池负极中的应用

Also Published As

Publication number Publication date
EP4164000A1 (en) 2023-04-12
CN113707863A (zh) 2021-11-26
CN113707863B (zh) 2023-04-14

Similar Documents

Publication Publication Date Title
WO2023024488A1 (zh) 一种硬碳复合材料及其制备方法和应用
CN109004203B (zh) 一种硅碳复合负极材料及其制备方法
Wang et al. A lightweight multifunctional interlayer of sulfur–nitrogen dual-doped graphene for ultrafast, long-life lithium–sulfur batteries
CN107492645B (zh) 一种氧化亚硅-石墨烯复合材料及其制备方法
CN108565446B (zh) 一种多孔氮掺杂碳包覆石墨材料的制备方法
WO2022166059A1 (zh) 一种硼掺杂树脂包覆人造石墨材料
CN107959010B (zh) 一种石墨复合材料及其制备方法
JP2022553657A (ja) コバルトフリー正極材料およびその調製方法、並びにリチウムイオン電池正極およびリチウム電池
CN113764644B (zh) 一种快充复合石墨材料及其制备方法
CN114122372B (zh) 一种锂离子电池所用低膨胀硅碳负极材料及其制备方法
CN113401897B (zh) 一种黑磷基石墨复合锂离子电池负极材料的制备方法
CN113889593A (zh) 一种硬碳包覆软碳复合材料的制备方法
WO2024031867A1 (zh) 氮掺杂石墨烯包覆硅碳复合材料及其制备方法和应用
CN105914394A (zh) 一种低温锂离子电池复合正极材料，低温锂离子电池正极极片及其制备方法，锂离子电池
CN114583093A (zh) 一种高能量密度硬碳复合负极材料的制备方法和应用
Wang et al. Carbon coating of Li 4 Ti 5 O 12-TiO 2 anode by using cetyl trimethyl ammonium bromide as dispersant and phenolic resin as carbon precursor
CN114497508A (zh) 一种功率型人造石墨复合材料及其制备方法
CN114300671A (zh) 一种石墨复合负极材料及其制备方法和应用
CN109638231B (zh) 氧化亚硅复合负极材料及其制备方法和锂离子电池
CN114843483B (zh) 一种硬碳复合材料及其制备方法和应用
CN110970599B (zh) 一种石墨烯基复合负极材料、其制备方法及锂离子电池
CN115172710A (zh) 一种锂离子电池所用氧化铁石墨复合材料及其制备方法
CN115911306B (zh) 一种高能量密度石墨复合材料及其制备方法
CN114520314B (zh) 具有多孔碳包覆层的负极材料、其制备方法和锂离子电池
CN113363454B (zh) 一种锂硫电池正极极片及其制备方法和应用

Legal Events

Date Code Title Description
ENP Entry into the national phase

Ref document number: 2022768602

Country of ref document: EP

Effective date: 20220920

NENP Non-entry into the national phase

Ref country code: DE