WO2022213961A1 - 等离子体增强原子层沉积设备及方法 - Google Patents
等离子体增强原子层沉积设备及方法 Download PDFInfo
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- WO2022213961A1 WO2022213961A1 PCT/CN2022/085234 CN2022085234W WO2022213961A1 WO 2022213961 A1 WO2022213961 A1 WO 2022213961A1 CN 2022085234 W CN2022085234 W CN 2022085234W WO 2022213961 A1 WO2022213961 A1 WO 2022213961A1
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- 238000000034 method Methods 0.000 title claims abstract description 338
- 238000000231 atomic layer deposition Methods 0.000 title claims abstract description 59
- 239000007789 gas Substances 0.000 claims abstract description 193
- 239000002243 precursor Substances 0.000 claims abstract description 132
- 239000012495 reaction gas Substances 0.000 claims abstract description 35
- 238000010926 purge Methods 0.000 claims abstract description 25
- 230000001105 regulatory effect Effects 0.000 claims abstract description 22
- 239000012159 carrier gas Substances 0.000 claims description 84
- 238000002156 mixing Methods 0.000 claims description 55
- 238000010790 dilution Methods 0.000 claims description 54
- 239000012895 dilution Substances 0.000 claims description 54
- 238000004140 cleaning Methods 0.000 claims description 48
- 238000002955 isolation Methods 0.000 claims description 26
- 235000012431 wafers Nutrition 0.000 claims description 26
- 238000000605 extraction Methods 0.000 claims description 19
- 238000004891 communication Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 4
- 238000011144 upstream manufacturing Methods 0.000 claims description 4
- 230000001276 controlling effect Effects 0.000 abstract 1
- 239000010408 film Substances 0.000 description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000005137 deposition process Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000007865 diluting Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000002159 abnormal effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- OWKFQWAGPHVFRF-UHFFFAOYSA-N n-(diethylaminosilyl)-n-ethylethanamine Chemical compound CCN(CC)[SiH2]N(CC)CC OWKFQWAGPHVFRF-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 238000012369 In process control Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010965 in-process control Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
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- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
- C23C16/45525—Atomic layer deposition [ALD]
- C23C16/45527—Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations
- C23C16/45536—Use of plasma, radiation or electromagnetic fields
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/4401—Means for minimising impurities, e.g. dust, moisture or residual gas, in the reaction chamber
- C23C16/4405—Cleaning of reactor or parts inside the reactor by using reactive gases
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/4401—Means for minimising impurities, e.g. dust, moisture or residual gas, in the reaction chamber
- C23C16/4408—Means for minimising impurities, e.g. dust, moisture or residual gas, in the reaction chamber by purging residual gases from the reaction chamber or gas lines
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/4412—Details relating to the exhausts, e.g. pumps, filters, scrubbers, particle traps
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
- C23C16/45525—Atomic layer deposition [ALD]
- C23C16/45544—Atomic layer deposition [ALD] characterized by the apparatus
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
- C23C16/45525—Atomic layer deposition [ALD]
- C23C16/45553—Atomic layer deposition [ALD] characterized by the use of precursors specially adapted for ALD
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45561—Gas plumbing upstream of the reaction chamber
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/50—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
- C23C16/505—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using radio frequency discharges
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/52—Controlling or regulating the coating process
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/3244—Gas supply means
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
Definitions
- the present invention relates to the field of semiconductor manufacturing, in particular, to a plasma enhanced atomic layer deposition apparatus and method.
- Atomic Layer Deposition as a method of film deposition, has the advantages of good conformality, precise thickness control and excellent coverage of high aspect ratio pattern structures.
- the plasma enhanced atomic layer deposition (Plasma Enhanced Atomic Layer Deposition, hereinafter referred to as PEALD) can avoid the use of higher process temperature, and the choice of precursors is wider, which is a good supplement to the ALD method.
- both ALD equipment and PEALD equipment have prominent problems of low productivity.
- an existing method is to use two process chambers to process two wafers at the same time.
- two process chambers are also Process repeatability between chambers (including film thickness and thickness uniformity, film densification performance, etc.) puts forward requirements, for example, the difference in film thicknesses deposited simultaneously between two process chambers should be less than a specified threshold (for example, less than 1 Angstrom) .
- the chamber pressure and RF-related parameters of the two process chambers cannot be individually controlled, resulting in limitations in process debugging.
- the above differences cannot be eliminated by individually adjusting the chamber pressure and RF-related parameters (such as RF power, frequency, glow time, etc.) of each process chamber,
- the flexibility of the process debugging means is reduced.
- the two process chambers must perform the plasma reaction step at the same time, so that other steps (precursor feeding, purging, etc.) must also be performed simultaneously, resulting in a single process method and poor process matching between chambers.
- each chamber needs to be equipped with a separate precursor source (such as a source bottle), but this will increase the cost of the precursor source and the complexity of the chamber structure .
- the present invention aims to solve at least one of the technical problems existing in the prior art, and proposes a plasma-enhanced atomic layer deposition apparatus and method, which can individually adjust the chamber pressure and RF-related parameters of each process chamber, so as not only to Process debugging means are added, process matching and process mode diversification are improved, and each chamber does not need to be equipped with a precursor supply device, thereby reducing equipment costs.
- a plasma enhanced atomic layer deposition equipment which includes two process chambers, a precursor supply device, a reaction gas supply device, a radio frequency device and a pressure adjustment device, wherein,
- the precursor supply device is in communication with the gas inlet structure of the two process chambers, and is used for selectively supplying a precursor or a purge gas to at least one of the two process chambers;
- the reaction gas supply device is in communication with the gas inlet structures of the two process chambers, and is used for selectively supplying the reaction gas to at least one of the two process chambers;
- the radio frequency device is connected to the two process chambers for selectively outputting radio frequency power to at least one of the two process chambers;
- the pressure regulating device communicates with the exhaust ports of the two process chambers, and is used to independently control the chamber pressures of the two process chambers.
- the precursor supply device includes a precursor source, an intake line group, a switch line group, and an air extraction device, wherein the precursor source passes through the switch line group and the intake line group. communication, the air intake pipeline group is communicated with the air intake structures of the two process chambers;
- the precursor source is used to provide the precursor or purge gas
- the switching pipeline group is used to selectively communicate the precursor source with the intake pipeline group or the air extraction device;
- the set of intake lines is used to selectively communicate the precursor source with at least one of the two process chambers.
- the intake pipeline group includes a first intake branch and a second intake branch, wherein the outlet ends of the first intake branch and the second intake branch are respectively connected with the two other branches.
- the intake structure of the process chamber is connected, and the intake ends of the first intake branch and the second intake branch are both communicated with the switching pipeline group; and, in the first intake branch A first on-off valve and a second on-off valve are respectively arranged on the second intake branch and the second intake branch.
- the air inlet pipeline group further includes a first dilution branch and a second dilution branch, wherein the air inlet ends of the first dilution branch and the second dilution branch are both connected to the air inlet for supplying the dilution gas.
- the diluent gas source is connected to the first diluting branch, the gas outlet ends of the first diluting branch and the second diluting branch are respectively connected to the first intake branch and the second intake branch;
- a first flow controller and a second flow controller are respectively arranged on the second dilution branch.
- the air intake pipeline group further includes two air mixing structures, both of which have a first air intake end, a second air intake end and an air outlet end, wherein the two air mixing structures
- the first air intake end of the structure is respectively connected with the air outlet ends of the first air intake branch and the second air intake branch; the air outlet ends of the two air mixing structures are respectively connected with the two process
- the air inlet structures of the chamber are in communication; the second air inlet ends of the two gas mixing structures are used for communicating with a balance gas source for providing a balance gas and the reaction gas supply device.
- each of the air-mixing structures includes an air-mixing block and an air-mixing pipeline, wherein the air-mixing block is provided with an air-mixing cavity, and the first air-mixing block is formed on the outer surface of the air-mixing block.
- the air inlet end and the second air inlet end, and an air outlet end is formed on the outer surface of the air mixing block, and the air outlet end is communicated with the air inlet end of the air mixing pipeline, and the air outlet end of the air mixing pipeline
- the gas outlet end used as the gas mixing structure communicates with the gas inlet structure of the process chamber.
- the switching pipeline group includes a first switching branch and a second switching branch, wherein both ends of the first switching branch are respectively communicated with the precursor source and the intake pipeline group. ; both ends of the second switching branch are respectively communicated with the first switching branch and the air extraction device; and, on the first switching branch and the second switching branch, a third shut-off valve and fourth on-off valve.
- the precursor source includes a carrier gas main circuit, a source bottle, a first carrier gas branch and a second carrier gas branch, wherein the inlet end of the carrier gas main circuit is used to provide a carrier gas.
- the carrier gas source is communicated with the carrier gas source, and the gas outlet end of the carrier gas main circuit is communicated with the switching pipeline group; and a fifth on-off valve and a third mass flow controller are arranged on the carrier gas main circuit;
- the inlet end of the first carrier gas branch is communicated with the carrier gas main circuit at the upstream position of the fifth on-off valve, and the gas outlet end of the first carrier gas branch is connected to the source bottle.
- the inlet end is communicated;
- the outlet end of the second carrier gas branch is communicated with the carrier gas main circuit at the downstream position of the fifth on-off valve, and the inlet end of the second carrier gas branch is connected to The gas outlet end of the source bottle is connected; and a sixth on-off valve and a seventh on-off valve are respectively arranged on the first carrier gas branch and the second carrier gas branch;
- the source bottle is used to store the precursor.
- the radio frequency device includes a first matcher, a second matcher, a first radio frequency power supply, and a second radio frequency power supply, wherein the first radio frequency power supply passes through the first matcher and one of the processes.
- the chambers are electrically connected; the second radio frequency power supply is electrically connected with the other one of the process chambers through the second matcher.
- the pressure regulating device includes a first exhaust branch and a second exhaust branch, wherein the intake ends of the first exhaust branch and the second exhaust branch are respectively connected with the two other exhaust branches.
- the exhaust port of the process chamber is in communication, and the outlet ends of the first exhaust branch and the second exhaust branch are both communicated with the air extraction device; and, in the first exhaust branch and the second exhaust branch A first isolation valve and a second isolation valve are respectively arranged on the gas branch; a first flow regulating valve and a second flow regulating valve are respectively arranged on the first exhaust branch and the second exhaust branch.
- the plasma-enhanced atomic layer deposition apparatus further includes a remote plasma cleaning device, a first cleaning pipeline and a second cleaning pipeline, and both of the gas mixing structures further have a third air inlet end, wherein , the inlet ends of the first cleaning pipeline and the second cleaning pipeline are connected with the remote plasma cleaning device; the gas outlet ends of the first cleaning pipeline and the second cleaning pipeline are respectively connected with the two the third inlet end is communicated; and a third isolation valve and a fourth isolation valve are respectively provided on the first cleaning pipeline and the second cleaning pipeline;
- the remote plasma cleaning device is used for providing plasma capable of cleaning the process chamber.
- an embodiment of the present invention also provides a plasma-enhanced atomic layer deposition method, which uses the above-mentioned plasma-enhanced atomic layer deposition apparatus provided by the embodiment of the present invention to simultaneously deposit films on two wafers; the The plasma enhanced atomic layer deposition method includes the following steps:
- the steps S1 to S4 are performed cyclically until the thicknesses of the films deposited on the two wafers reach the target thickness.
- the plasma-enhanced atomic layer deposition apparatus and method provided by the embodiments of the present invention can independently control the chamber pressures of the two process chambers by using the pressure regulating device communicated with the exhaust ports of the two process chambers; and , by using the radio frequency device connected with the two process chambers to selectively output radio frequency power to at least one process chamber of the two process chambers, the radio frequency related parameters of each process chamber can be adjusted individually, thereby not only increasing the
- the process debugging method improves the process matching, and the two process chambers do not need to perform various process steps simultaneously, thereby improving the diversification of process methods, and there is no need to equip each chamber with a precursor supply device, that is, using a precursor
- the supply device communicates with the gas inlet structure of the two process chambers to selectively supply a precursor or a purge gas to at least one of the two process chambers, thereby reducing equipment costs.
- FIG. 1A is a structural diagram of a conventional plasma-enhanced atomic layer deposition apparatus
- FIG. 1B is a flowchart of a deposition method using the plasma-enhanced atomic layer deposition apparatus in FIG. 1A;
- FIG. 2 is a schematic block diagram of a plasma-enhanced atomic layer deposition apparatus provided by an embodiment of the present invention
- FIG. 3 is a structural diagram of a plasma-enhanced atomic layer deposition apparatus provided by an embodiment of the present invention.
- FIG. 4 is an enlarged view of a precursor source used in an embodiment of the present invention.
- FIG. 5 is an enlarged view of the intake pipeline group adopted in the embodiment of the present invention.
- FIG. 6 is a flowchart of a plasma enhanced atomic layer deposition method provided by an embodiment of the present invention.
- FIG. 7 is another flowchart of the plasma enhanced atomic layer deposition method according to an embodiment of the present invention.
- an existing plasma-enhanced atomic layer deposition (Plasma Enhanced Atomic Layer Deposition, hereinafter referred to as PEALD) equipment which includes two process chambers (1a, 1b) that can simultaneously perform deposition processes on wafers , wherein the exhaust gas discharged from the two process chambers (1a, 1b) is merged into the main exhaust pipeline 11, and the exhaust gas is transported to the exhaust device (not shown in the figure) by the main exhaust pipeline 11.
- an isolation valve 12 and a flow regulating valve 13 are also provided on the main exhaust pipeline 11, wherein the isolation valve 12 is used to connect or disconnect the main exhaust pipeline 11; the flow regulating valve 13 is used to adjust the main exhaust pipeline 11.
- the gas flow rate in the gas pipeline 11 can be controlled so as to control the gas pressure in the two process chambers (1a, 1b) at the same time.
- the two process chambers (1a, 1b) are respectively communicated with the gas supply device 16 and the remote plasma cleaning device 17 through their respective gas inlet pipelines, wherein the gas supply device 16 is used to supply the two process chambers (1a) at the same time.
- 1b) Provide process gases (including but not limited to precursors, reactive gases and purge gases); the remote plasma cleaning device 17 is used to accumulate a certain thickness of the films in the two process chambers (1a, 1b), Two process chambers (1a, 1b) are simultaneously supplied with plasma capable of cleaning the process chambers (eg, plasma formed by ionization of NF3 gas).
- the two process chambers (1a, 1b) share a matcher 14 and a radio frequency power supply 15, and the radio frequency power supply 15 simultaneously applies RF power to the two process chambers (1a, 1b) through the matcher 14 to excite the two process chambers (1a, 1b).
- the reactive gases in the process chambers (1a, 1b) form plasma.
- the chamber pressures of the two process chambers (1a, 1b) cannot be individually controlled, resulting in process debugging problems. limitation. For example, when there are differences in film thicknesses deposited between two process chambers, the above differences cannot be eliminated by individually adjusting the chamber pressure of each process chamber, thereby reducing the flexibility of the process debugging means.
- the isolation valve 12 is opened, the two process chambers (1a, 1b) still have the possibility to communicate with each other via the exhaust pipe, so that no real physical isolation is achieved. When debris or particles occur in one process chamber Abnormal conditions such as an increase in the number are likely to adversely affect another process chamber.
- each chamber needs to be equipped with a separate precursor source (such as a source bottle), so as to realize the simultaneous passage of the precursors into the two process chambers (1a, 1b), but this in turn increases the cost of the precursor source and the complexity of the chamber structure.
- a separate precursor source such as a source bottle
- An embodiment of the present invention further provides a plasma enhanced atomic layer deposition equipment, which includes two process chambers (2a, 2b), Precursor supply device 3, reactive gas supply device 6, radio frequency device 8 and pressure regulating device 7, wherein, the two process chambers (2a, 2b) are independent chambers that are physically isolated, and each process chamber has a A gas structure 21, the air intake structure 21 is, for example, a gas distribution device arranged at the top of the chamber to uniformly deliver the process gas to the interior of the chamber; and each process chamber is also provided with a base 22 for The wafer S is mounted on the wafer S, and the temperature of the wafer S is controlled.
- the above-mentioned precursor supply device 3 is connected to the air inlet structure 21 of the two process chambers (2a, 2b) for selectively supplying a precursor or blowing gas to at least one of the two process chambers (2a, 2b) Sweep gas. That is, the two process chambers ( 2a, 2b ) share one precursor supply device 3 .
- the above-mentioned precursors are selected according to the composition and characteristics of the film layer material to be deposited, and the precursors can be delivered into the process chamber in gaseous form with or without the use of a carrier gas.
- the layer material to be deposited is silicon dioxide (SiO2)
- SAM24 bis(diethylamino)silane
- the above-mentioned precursor supply device 3 includes a precursor source 30, an intake pipeline group 5, a switching pipeline group 4 and an air extraction device 10b, wherein the precursor source 30 passes through the switching pipeline group.
- 4 is communicated with the intake pipeline group 5, which is communicated with the intake structures 21 of the two process chambers (2a, 2b); the precursor source 30 is used to provide the above-mentioned precursor or purge gas; the switching pipe
- the road group 4 is used to selectively connect the precursor source 30 with the intake line group 5 or the air extraction device 10b;
- the intake line group 5 is used to selectively connect the precursor source 30 with the two process chambers (2a, 2a, 10b). At least one of 2b) is connected.
- the precursor provided by the precursor source 30 can be delivered to the intake pipeline group 5 , and to the two via the intake pipeline group 5 .
- the switching pipeline group 4 includes a first switching branch 41a and a second switching branch 41b, wherein two ends of the first switching branch 41a are respectively connected to the precursor
- the body source 30 is communicated with the intake pipeline group 5; both ends of the second switching branch 41b are respectively communicated with the first switching branch 41a and the air extraction device 10b; and, in the first switching branch 41a and the second switching branch 41b is provided with a third on-off valve 42a and a fourth on-off valve 42b, respectively.
- the third on-off valve 42a is opened and the fourth on-off valve 42b is closed, the first switching branch 41a is turned on, and the second switching branch 41b is turned off.
- the switching branch 41a flows into the intake pipeline group 5; when the third on-off valve 42a is closed and the fourth on-off valve 42b is opened, the first switching branch 41a is disconnected, and the second switching branch 41b is connected, at this time
- the precursor output from the precursor source 30 flows into the air extraction device 10b through the second switching branch 41b.
- the precursor source 30 includes a main carrier gas circuit 31 , a source bottle 32 , a first carrier gas branch 35 a and a second carrier gas branch 35 b , wherein,
- the inlet end of the carrier gas main circuit 31 (towards the left side in FIG. 4 ) is used to communicate with the carrier gas source (not shown in the figure) that provides the carrier gas C1, and the gas outlet end of the carrier gas main circuit 31 (in the figure 4 toward the right) is communicated with the above-mentioned switching pipeline group 4 (that is, the intake end of the first switching branch 41a shown in FIG.
- valve 33 and the third mass flow controller 34 wherein, the fifth on-off valve 33 is used to connect or disconnect the carrier gas main circuit 31; the third mass flow controller 34 is used to control the carrier gas in the main carrier gas circuit 31.
- the inlet end of the first carrier gas branch 35a is communicated with the main carrier gas circuit 31 at the upstream position of the fifth on-off valve 33, and the outlet end of the first carrier gas branch 35a is communicated with the inlet end of the source bottle 32; and , a sixth on-off valve 36 and a seventh on-off valve 37 are respectively provided on the first carrier gas branch 35a and the second carrier gas branch 35b.
- the sixth on-off valve 36 is used to connect or disconnect the first carrier gas branch 35a
- the seventh on-off valve 37 is used to connect or disconnect the second carrier gas branch 35b.
- the source bottle 32 is used to store the precursor.
- the initial state of the precursor stored in the source bottle 32 may be liquid, solid or gaseous, and during the process, the precursor in the source bottle 32 is output in gaseous form with or without a carrier gas.
- the carrier gas main circuit 31 is connected, and the first carrier gas branch 35a and the second carrier gas branch The circuit 35b is disconnected, and at this time the carrier gas C1 flows to the switching pipeline group 4 via the carrier gas main circuit 31 without passing through the source bottle 32, that is, the precursor in the source bottle 32 is not output.
- the pipeline and process chamber through which the carrier gas C1 flows can be used for purging, and the carrier gas C1 is used as the above-mentioned purging gas at this time.
- the carrier gas main circuit 31 is disconnected, and the first carrier gas branch 35a and the second carrier gas branch 35b are connected
- the carrier gas C1 flows to the source bottle 32 through the front section of the carrier gas main circuit 31 located upstream of the fifth on-off valve 33 and the first carrier gas branch 35a, that is, the carrier gas C1 passes through the source bottle 32 to be able to carry the source bottle 32.
- the precursor in the bottle 32 is output through the second carrier gas branch 35b and the carrier gas main path 31 at the latter stage downstream of the fifth on-off valve 33 .
- the switching pipeline set 4 connects the precursor source 30 with the intake pipeline set 5
- the carrier gas C1 carrying the precursor can be delivered to the intake pipeline set 5, and passes through the intake pipeline set 5 is delivered to at least one of the two process chambers (2a, 2b).
- the fifth on-off valve 33 , the sixth on-off valve 36 and the seventh on-off valve 37 are all quick on-off valves, so as to realize quick on-off of corresponding pipelines.
- other on-off valves may also be used according to different process requirements, which are not particularly limited in the embodiment of the present invention.
- an intermediate pipeline 35c is also connected between the first carrier gas branch 35a and the second carrier gas branch 35b, and a first automatic on-off valve 39c is set on the intermediate pipeline 35c.
- the automatic on-off valve 39c is opened, the intermediate pipeline 35c is connected.
- the carrier gas C1 does not pass through the source bottle 32, and the source bottle
- the precursors in 32 can be output and flow to the switch line group 4 .
- a second automatic on-off valve 39a may be respectively provided and a third automatic on-off valve 39b to realize automatic control of the first carrier gas branch 35a and the second carrier gas branch 35b.
- a first manual valve 38a and a second manual valve 38b may also be provided on the first carrier gas branch 35a and the second carrier gas branch 35b, respectively.
- the above-mentioned settings of the automatic on-off valve and the manual valve are beneficial to improve the flexibility and reliability of the control.
- the first automatic on-off valve 39c, the second automatic on-off valve 39a and the third automatic on-off valve 39b are, for example, pneumatic valves.
- the source bottle 32 also has an injection end, and the injection end is used for the liquid transmission system with the precursor that supplements the liquid state
- the above-mentioned injection end is connected to a liquid transmission system (not shown in the figure), for example, through an injection pipeline 321 , and an eighth on-off valve 322 is provided near the injection end of the injection pipeline 321 .
- the precursor source 30 uses the source bottle 32 and the carrier gas C1 to supply the precursor.
- the embodiment of the present invention is not limited to this. In practical applications, the precursor source Any other gas supply structures, such as gas cabinets, can also be used.
- the intake pipeline group 5 includes a first intake branch 51a and a second intake branch 51b, wherein the first intake branch 51a and the second intake branch 51a
- the air outlet ends of the air intake branches 51b are respectively communicated with the air intake structures 21 of the two process chambers (2a, 2b).
- the two gas mixing structures (55a, 55b) are communicated with the pipelines used to transport the precursor (and/or carrier gas) and other gases (such as dilution gas, balance gas, etc.), using After these gases are separately or mixed, they are respectively passed into the two process chambers (2a, 2b).
- the above-mentioned air mixing structure may not be provided according to the specific situation.
- the air intake structures 21 of the chambers (2a, 2b) communicate with each other.
- the intake ends of the first intake branch 51a and the second intake branch 51b are both communicated with the outlet ends of the switching pipeline group 4 (ie, the first switching branch 41a shown in FIG. 3 ); and, as shown in As shown in FIG. 5, a first on-off valve 52a and a second on-off valve 52b are respectively provided on the first intake branch passage 51a and the second intake branch passage 51b.
- a first on-off valve 52a and a second on-off valve 52b are respectively provided on the first intake branch passage 51a and the second intake branch passage 51b.
- the above two air-mixing structures (55a, 55b) both have a first air inlet end, a second air inlet end and an air outlet end, wherein the two air-mixing structures (55a, 55b)
- the first air intake ends of the two gas mixture structures (55a, 55b) are respectively connected with the air outlet ends of the first air intake branch 51a and the second air intake branch 51b; , 2b)
- the inlet structure 21 is connected; the second inlet ends of the two gas mixing structures (55a, 55b) are used to connect with the balance gas source and the reaction gas supply device 6 for providing the balance gas.
- the second inlet ends of the two gas mixing structures (55a, 55b) are respectively connected to the balance gas source through two balance gas delivery units (18a, 18b), and the two balance gas delivery units (18a, 18b) It is used to deliver the equilibrium gas to the two process chambers (2a, 2b) independently.
- the deposition process is performed by alternately delivering the precursors into the two process chambers (2a, 2b)
- the moment of switching between the two process chambers will cause the process chamber to stop delivering the precursors.
- the intake air volume fluctuates greatly, which causes the chamber pressure to fluctuate greatly, and the stability of the process gas flow field becomes worse. For this reason, it is possible to start to stop the delivery at the moment of switching between the two process chambers.
- the balance gas is delivered in the process chamber of the precursor, and the intake volume of the balance gas is equal to the intake volume of the precursor, so as to avoid the large fluctuation of the chamber pressure caused by the fluctuation of the intake volume. Improve the stability of the process gas flow field.
- the balance gas is, for example, argon (Ar) or other inert gas.
- FIGS 3 and 5 only schematically show two balance gas delivery units (18a, 18b), but do not show the specific structures of the two.
- the on-off valve on the gas pipeline wherein the intake end of the balanced gas intake pipeline is used to connect with the balanced gas source, and the gas outlet of the balanced gas intake pipeline is connected to the corresponding gas mixing structure.
- a flow controller may also be provided on the balance gas intake line to control the gas flow in the balance gas intake line.
- the above-mentioned two balance gas delivery units (18a, 18b) can also be directly connected to the gas inlet structures 21 of the two process chambers (2a, 2b), respectively, without passing through the gas mixing structure (55a, 2b). 55b).
- the above-mentioned reaction gas supply device 6 is communicated with the gas inlet structures 21 of the two process chambers (2a, 2b), for simultaneously or respectively supplying the two process chambers (2a, 2b) to the gas inlet structure 21. 2b) Provide reaction gas.
- the plasma including but not limited to free radicals
- the plasma formed by the reactive gas can chemically react with the precursor adsorbed on the wafer S, thereby forming a desired film layer on the surface of the wafer S.
- the layer material to be deposited is silicon dioxide (SiO2), and SAM24 (bis(diethylamino)silane) is used as the precursor, oxygen (O2) can be selected as the reactive gas.
- the reactive gas supply device 6 includes a first reactive gas delivery unit 6a and a second reactive gas delivery unit 6b, which can be connected to two processes through two gas mixing structures (55a, 55b)
- the gas inlet structures 21 of the chambers (2a, 2b) communicate with each other, and are used for independently feeding the reaction gases to the two process chambers (2a, 2b).
- the specific structures include a reaction gas inlet pipeline and a The on-off valve on the reactant gas intake pipeline, wherein the intake end of the reactant gas intake pipeline is used to communicate with the reactant gas source, and the gas outlet end of the reactant gas intake pipeline is communicated with the corresponding gas mixing structure.
- a flow controller can also be provided on the reaction gas inlet line to control the gas flow in the reaction gas inlet line.
- first reaction gas delivery unit 6a and second reaction gas delivery unit 6b can also be directly communicated with the gas inlet structures 21 of the two process chambers (2a, 2b) without passing through the gas mixing structure (55a, 55b).
- each air-mixing structure may have various structures.
- each air-mixing structure includes an air-mixing block 551 and an air-mixing pipeline 552 , wherein the air-mixing block 551 is provided with There is an air mixing chamber (not shown in the figure), and the first air inlet end, the second air inlet end and the air outlet end are formed on the outer surface of the air mixing block 551.
- the air outlet end is connected to the air inlet of the air mixing pipeline 552
- the gas outlet end of the gas mixing pipeline 552 is used as the gas outlet end of the gas mixing structure to communicate with the air inlet structure 21 of the process chamber.
- the number of the gas inlet ends of the gas mixing structure corresponds to the number of process gases that need to be introduced into the process chamber.
- the above-mentioned balance gas and/or reaction gas may also be introduced without going through the above-mentioned gas mixing structure.
- the intake pipeline group 5 further includes a first dilution branch 53a and a second dilution branch 53b, wherein the first dilution branch 53a and the second dilution branch
- the inlet ends of the passages 53b are all communicated with a dilution gas source (not shown in the figure) for providing the dilution gas
- the outlet ends of the first dilution branch 53a and the second dilution branch 53b are respectively connected with the first inlet branch.
- the dilution gas output from the dilution gas source may flow into the first intake branch 51a and the second intake branch 51b via the first dilution branch 53a and the second dilution branch 53b, respectively, and be mixed with the precursor to to dilution.
- the dilution gas is, for example, argon (Ar) or other inert gas.
- the radio frequency device 8 is connected to the two process chambers (2a, 2b) for selectively outputting radio frequency power to at least one of the two process chambers (2a, 2b).
- the radio frequency device 8 includes a first matcher 81a, a second matcher 81b, a first radio frequency power supply 82a and a second radio frequency power supply 82b, wherein the first radio frequency power supply 82a
- One of the process chambers ie, the first process chamber 2a
- the second RF power source 82b is connected to the other of the process chambers (ie, the second process chamber) through the second matcher 81b Chamber 2b) Electrical connection.
- the RF-related parameters (such as RF power, frequency, ignition time, etc.) of the two process chambers (2a, 2b) can be adjusted independently, Thereby, the means of process debugging is increased, and the process matching is improved. Moreover, since the respective radio frequency power sources of the two process chambers (2a, 2b) can be turned on at different times, the two process chambers (2a, 2b) do not need to perform various process steps simultaneously, thereby improving the diversification of process modes.
- each chamber it is not necessary to equip each chamber with a precursor supplying device, and by using the above-mentioned precursor supplying device adopted in this embodiment, the precursor can be supplied to one of the corresponding process chambers at different times, that is, alternately The precursors are delivered to the two process chambers (2a, 2b), thereby meeting the requirements for process matching and reducing equipment costs.
- the two process chambers (2a, 2b) are separately equipped with a matcher and a radio frequency power supply, however, the embodiment of the present invention is not limited to this.
- a matcher and a radio frequency power supply are provided, and the matching device and the radio frequency power supply are selectively connected to one of the process chambers by setting the corresponding switching device, which can also be realized at different times to the two process chambers ( 2a, 2b)
- the radio frequency power is loaded, the two process chambers (2a, 2b) do not need to perform various process steps simultaneously, thereby improving the diversification of process modes.
- the pressure regulating device 7 communicates with the exhaust ports of the two process chambers (2a, 2b), and is used to independently control the chamber pressures of the two process chambers (2a, 2b). In this way, when there is a difference in the thickness of the films deposited in the two process chambers (2a, 2b), the pressure adjustment device 7 can independently adjust the chamber pressure of each process chamber to eliminate the above difference, thereby improving the process debugging means. flexibility.
- the pressure regulating device 7 includes a first exhaust branch 71a and a second exhaust branch 71b, wherein the intake air of the first exhaust branch 71a and the second exhaust branch 71b The ends are respectively connected with the exhaust ports of the two process chambers (2a, 2b), and the outlet ends of the first exhaust branch 71a and the second exhaust branch 71b are both communicated with the air extraction device 10a;
- the exhaust branch 71a and the second exhaust branch 71b are respectively provided with a first isolation valve 72a and a second isolation valve 72b to independently control the first exhaust branch 71a and the second exhaust branch 71b
- the first exhaust branch 71a and the second exhaust branch 71b are also provided with a first flow regulating valve 73a and a second flow regulating valve 73b, respectively, to independently adjust the first exhaust branch The gas flow in the passage 71a and the second exhaust branch passage 71b.
- the physical isolation of the two process chambers (2a, 2b) can be truly achieved, thereby When abnormal conditions such as debris or increased particle count occur in one process chamber, adverse effects on the other process chamber can be avoided. Meanwhile, by disposing the first flow regulating valve 73a and the second flow regulating valve 73b on the first exhaust branch 71a and the second exhaust branch 71b, respectively, the two process chambers (2a, 2b) can be independently controlled.
- each process can be realized by adjusting the first flow control valve 73a and the second flow control valve 73b individually.
- the independent control of the chamber pressure of the chambers eliminates the above differences, thereby improving the flexibility of the process debugging means, and further improving the process matching of the two process chambers (2a, 2b).
- the pressure regulating device 7 is not limited to the solutions provided by the above embodiments, and other arbitrary structures may also be used in practical applications to realize the independent control of the chamber pressure of each process chamber.
- the above-mentioned air extraction device 10a and air extraction device 10b may be the same air extraction device, that is, the switching pipeline group 4 and the two process chambers (2a, 2b) share the same air extraction device.
- the evacuation device is, for example, a vacuum pump.
- the plasma enhanced atomic layer deposition apparatus further includes a remote plasma cleaning device 9, a first cleaning pipeline 91a and a second cleaning pipeline 91b, and both of the two gas mixing structures (55a, 55b) also have a Three inlet ends, wherein the inlet ends of the first cleaning pipeline 91a and the second cleaning pipeline 91b are both connected to the remote plasma cleaning device 9; the gas outlet ends of the first cleaning pipeline 91a and the second cleaning pipeline 91b They are respectively communicated with the above-mentioned third intake ends of the two air mixing structures (55a, 55b).
- the gas outlet ends of the first cleaning pipeline 91a and the second cleaning pipeline 91b can also be directly communicated with the air intake structures 21 of the two process chambers (2a, 2b).
- a third isolation valve 92a and a fourth isolation valve 92b are respectively provided on the gas outlet ends of the first cleaning pipeline 91a and the second cleaning pipeline 91b; the remote plasma cleaning device 9 is used in the two process chambers ( After the thin films in 2a, 2b) are accumulated to a certain thickness, at least one of the two process chambers (2a, 2b) is supplied with plasma capable of cleaning the process chamber (for example, formed by ionization of NF3 gas). plasma).
- any one process chamber can be cleaned individually, or two process chambers can be cleaned at the same time, so that the flexibility of the cleaning method can be improved.
- the process gas can be prevented from diffusing to the remote plasma cleaning device 9 by closing the third isolation valve 92a and the fourth isolation valve 92b, thereby improving the utilization rate of the process gas and improving the process gas flow field stability.
- an embodiment of the present invention further provides a plasma-enhanced atomic layer deposition method, which uses the above-mentioned plasma-enhanced atomic layer deposition apparatus provided by the embodiment of the present invention to deposit films on two wafers simultaneously.
- the plasma enhanced atomic layer deposition method includes:
- Step S1 the two process chambers (2a, 2b) respectively perform step S11 and step S12, and the two may be performed synchronously or separately at different times.
- step S11 the precursor is introduced into the first process chamber 2a, so that the precursor is adsorbed on the surface of the wafer S;
- step S12 the reactive gas is introduced into the second process chamber 2b, and the radio frequency power is outputted to the second process chamber 2b to excite the reactive gas to form plasma, and the plasma can react with the precursor adsorbed on the surface of the wafer S , to form the desired film layer on the surface of the wafer S.
- the fourth on-off valve 42b, the fifth on-off valve 33 and the second on-off valve 42b are closed.
- the on-off valve 52b is opened, and the third on-off valve 42a, the sixth on-off valve 36, the seventh on-off valve 37 and the first on-off valve 52a are opened at the same time, so that the precursor ( carried by carrier gas C1).
- the time for introducing the precursor into the first process chamber 2a is generally shorter than the process time of step S11.
- the third on-off valve 42a is not kept open all the time in the process of step S11.
- the third on-off valve 42a is opened, and the fourth on-off valve 42b is closed at the same time, at this time, the first process chamber 2a is opened
- the third on-off valve 42a is closed, and the fourth on-off valve 42b is opened at the same time, at this time, the precursor flows into the exhaust gas through the second switching branch 41b Device 10b.
- the third on-off valve 42a can also be kept open during step S11 according to different needs, which is not particularly limited in the embodiment of the present invention.
- the first dilution branch 53a and the second dilution branch 53b are used to simultaneously feed the dilution gas to the two process chambers (2a, 2b); the balance gas delivery unit 18b is used to feed the second process chamber
- the chamber 2b is fed with a balance gas to ensure that the air intakes of the two process chambers (2a, 2b) are equal; the second reaction gas delivery unit 6b is used to feed the reaction gas into the second process chamber 2b, and the second radio frequency is turned on
- the power supply 82b is used to apply radio frequency power to the second process chamber 2b through the second matcher 81b, so as to excite the reaction gas to form plasma.
- Step S2 the two process chambers (2a, 2b) respectively perform step S21 and step S22, and the two may be performed synchronously or separately at different times.
- Both steps S21 and S22 are used for purging the precursor supply device and the two process chambers (2a, 2b) in the plasma enhanced atomic layer deposition apparatus.
- the fourth on-off valve 42b, the fifth on-off valve 33, the first on-off valve 42b, the first on-off valve 42b, the first on-off valve 42b, the The on-off valve 52a, the second on-off valve 52b, the third on-off valve 42a, and the sixth on-off valve 36 and the seventh on-off valve 37 are closed at the same time, so as to realize the corresponding pipeline and the two process chambers (2a, 2b) Purging is performed.
- the first dilution branch 53a and the second dilution branch 53b are used to pass the dilution gas into the two process chambers (2a, 2b) at the same time, which can also play a purging effect;
- the balance gas delivery units (18a, 18b) respectively feed the balance gas to the first process chamber 2a and the second process chamber 2b at the same time, which can also play the role of purging; stop feeding the reaction gas to the second process chamber 2b .
- Step S3 the two process chambers (2a, 2b) respectively perform step S31 and step S32, and the two may be performed synchronously or separately at different times.
- step S31 a reactive gas is introduced into the first process chamber 2a, and radio frequency power is outputted to the first process chamber 2a to excite the reactive gas to form a plasma, and the plasma can interact with the precursor adsorbed on the surface of the wafer S. body reaction to form the desired film layer on the surface of wafer S;
- step S32 the precursor is introduced into the second process chamber 2 b so that the precursor is adsorbed on the surface of the wafer S .
- the fourth on-off valve 42b, the fifth on-off valve 33 and the first on-off valve 42b are closed.
- the on-off valve 52a is opened, and the third on-off valve 42a, the sixth on-off valve 36, the seventh on-off valve 37 and the second on-off valve 52b are opened at the same time, so that the precursor ( carried by carrier gas C1).
- the first dilution branch 53a and the second dilution branch 53b to simultaneously introduce dilution gas into the two process chambers (2a, 2b); use the balance gas delivery unit 18a to feed the first process chamber
- the chamber 2a is fed with a balance gas to ensure that the air intakes of the two process chambers (2a, 2b) are equivalent; the first reactive gas delivery unit 6a is used to feed the reactive gas into the first process chamber 2a, and the first radio frequency is turned on
- the power supply 82a is used to apply radio frequency power to the first process chamber 2a through the first matcher 81a, so as to excite the reactive gas to form plasma.
- Step S4 the two process chambers (2a, 2b) respectively perform step S41 and step S42, and the two may be performed synchronously or separately at different times.
- Steps S41 and S42 are the same as the above-mentioned steps S21 and S22, and the description is not repeated here.
- steps S1 to S4 are performed cyclically until the thicknesses of the films deposited on the two wafers reach the target thickness.
- the two process chambers (2a, 2b) do not need to perform various process steps simultaneously, thereby improving the diversification of process modes. Moreover, it is not necessary to equip each chamber with a precursor supplying device, and by using the above-mentioned precursor supplying device adopted in this embodiment, the precursor can be supplied to one of the corresponding process chambers at different times, that is, alternately The precursors are delivered to the two process chambers (2a, 2b), thereby meeting the requirements for process matching and reducing equipment costs.
- Embodiments of the present invention further provide a plasma-enhanced atomic layer deposition method. Specifically, as shown in FIG. 7 , the method includes steps S1' to S4', wherein,
- Step S1' and the two process chambers (2a, 2b) respectively perform step S11' and step S12', which can be performed synchronously or separately at different times.
- step S11' a reactive gas is introduced into the first process chamber 2a, and radio frequency power is outputted to the first process chamber 2a to excite the reactive gas to form plasma, and the plasma can interact with the adsorbed gas on the surface of the wafer S.
- the precursor reacts to form the desired film layer on the surface of the wafer S;
- step S12' the precursor is introduced into the second process chamber 2b, so that the precursor is adsorbed on the surface of the wafer S.
- the fourth on-off valve 42 b , the fifth on-off valve 33 and the The first on-off valve 52a is simultaneously opened, and the third on-off valve 42a, the sixth on-off valve 36, the seventh on-off valve 37 and the second on-off valve 52b are simultaneously opened, so as to realize the separate introduction of the precursor into the second process chamber 2b body (carried by carrier gas C1).
- the first dilution branch 53a and the second dilution branch 53b to simultaneously introduce dilution gas into the two process chambers (2a, 2b); use the balance gas delivery unit 18a to feed the first process chamber
- the chamber 2a is fed with a balance gas to ensure that the air intakes of the two process chambers (2a, 2b) are equivalent; the first reactive gas delivery unit 6a is used to feed the reactive gas into the first process chamber 2a, and the first radio frequency is turned on
- the power supply 82a is used to apply radio frequency power to the first process chamber 2a through the first matcher 81a, so as to excite the reactive gas to form plasma.
- Step S2' the two process chambers (2a, 2b) respectively perform step S21' and step S22', and the two may be performed synchronously or separately at different times.
- step S21' and step S22' are used for purging the precursor supply device and the two process chambers (2a, 2b) in the plasma enhanced atomic layer deposition apparatus.
- the fourth on-off valve 42 b in the process of performing steps S21 ′ and S22 ′, the fourth on-off valve 42 b , the fifth on-off valve 33 , the The first on-off valve 52a, the second on-off valve 52b, the third on-off valve 42a, and the sixth on-off valve 36 and the seventh on-off valve 37 are closed at the same time, so as to realize the corresponding pipeline and the two process chambers ( 2a, 2b) to carry out purging.
- the first dilution branch 53a and the second dilution branch 53b are used to pass the dilution gas into the two process chambers (2a, 2b) at the same time, which can also play a purging effect;
- the balance gas delivery units (18a, 18b) respectively feed the balance gas to the first process chamber 2a and the second process chamber 2b at the same time, which can also play the role of purging; stop feeding the reaction gas to the second process chamber 2b .
- Step S3' the two process chambers (2a, 2b) respectively perform step S31' and step S32', and the two may be performed synchronously or separately at different times.
- step S31' the precursor is introduced into the first process chamber 2a, so that the precursor is adsorbed on the surface of the wafer S;
- step S32 ′ a reactive gas is introduced into the second process chamber 2 b , and radio frequency power is outputted to the second process chamber 2 b to excite the reactive gas to form plasma, and the plasma can interact with the precursor adsorbed on the surface of the wafer S reaction to form the desired film layer on the surface of the wafer S.
- the fourth on-off valve 42 b , the fifth on-off valve 33 and the The second on-off valve 52b is simultaneously opened, and the third on-off valve 42a, the sixth on-off valve 36, the seventh on-off valve 37 and the first on-off valve 52a are simultaneously opened, so as to realize the separate introduction of the precursor into the first process chamber 2a body (carried by carrier gas C1).
- the first dilution branch 53a and the second dilution branch 53b are used to simultaneously feed the dilution gas to the two process chambers (2a, 2b); the balance gas delivery unit 18b is used to feed the second process chamber
- the chamber 2b is fed with a balance gas to ensure that the air intakes of the two process chambers (2a, 2b) are equal; the second reaction gas delivery unit 6b is used to feed the reaction gas into the second process chamber 2b, and the second radio frequency is turned on
- the power supply 82b is used to apply radio frequency power to the second process chamber 2b through the second matcher 81b, so as to excite the reaction gas to form plasma.
- Step S4' the two process chambers (2a, 2b) respectively perform step S41' and step S42', which can be performed synchronously or separately at different times.
- Step S41' and step S42' are the same as the above-mentioned step S21' and step S22', and the description is not repeated here.
- steps S1' to S4' are cyclically performed until the thickness of the film layers deposited on the two wafers reaches the target thickness.
- the plasma enhanced atomic layer deposition apparatus and method can independently control the pressure of the two process chambers by using the pressure regulating device communicated with the exhaust ports of the two process chambers. chamber pressure; and, by selectively outputting radio frequency power to at least one of the two process chambers using a radio frequency device connected to the two process chambers, the radio frequency related parameters of each process chamber can be adjusted individually , which not only increases the process debugging means and improves the process matching, but also the two process chambers do not need to perform various process steps simultaneously, thereby improving the diversification of process methods, and there is no need to equip each chamber with a precursor supply device, That is, the precursor supply device is used to communicate with the gas inlet structures of the two process chambers to selectively supply the precursor or the purge gas to at least one of the two process chambers, thereby reducing equipment costs.
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Abstract
Description
Claims (12)
- 一种等离子体增强原子层沉积设备,其特征在于,包括两个工艺腔室、前驱体供应装置、反应气体供应装置、射频装置和压力调节装置,其中,所述前驱体供应装置与两个所述工艺腔室的进气结构连通,用于选择性地向两个所述工艺腔室中的至少一者提供前驱体或吹扫气体;所述反应气体供应装置与两个所述工艺腔室的进气结构连通,用于选择性地向两个所述工艺腔室中的至少一者提供反应气体;所述射频装置与两个所述工艺腔室连接,用于选择性地向两个所述工艺腔室中的至少一者输出射频功率;所述压力调节装置与两个所述工艺腔室的排气口连通,用于独立地分别控制两个所述工艺腔室的腔室压力。
- 根据权利要求1所述的等离子体增强原子层沉积设备,其特征在于,所述前驱体供应装置包括前驱体源、进气管路组、切换管路组和抽气装置,其中,所述前驱体源通过所述切换管路组与所述进气管路组连通,所述进气管路组与两个所述工艺腔室的进气结构连通;所述前驱体源用于提供所述前驱体或吹扫气体;所述切换管路组用于选择性地将所述前驱体源与所述进气管路组或者所述抽气装置连通;所述进气管路组用于将所述前驱体源选择性地与两个所述工艺腔室中的至少一者连通。
- 根据权利要求2所述的等离子体增强原子层沉积设备,其特征在于,所述进气管路组包括第一进气支路和第二进气支路,其中,所述第一进气支路和第二进气支路的出气端分别与两个所述工艺腔室的进气结构连通,所述第一进气支路和第二进气支路的进气端均与所述切换管路组连通;并且,在 所述第一进气支路和第二进气支路上分别设置有第一通断阀和第二通断阀。
- 根据权利要求3所述的等离子体增强原子层沉积设备,其特征在于,所述进气管路组还包括第一稀释支路和第二稀释支路,其中,所述第一稀释支路和第二稀释支路的进气端均与用于提供稀释气体的稀释气体源连通,所述第一稀释支路和第二稀释支路的出气端分别与第一进气支路和第二进气支路连通;并且,在所述第一稀释支路和第二稀释支路上分别设置有第一流量控制器和第二流量控制器。
- 根据权利要求3所述的等离子体增强原子层沉积设备,其特征在于,所述进气管路组还包括两个混气结构,两个所述混气结构均具有第一进气端、第二进气端和出气端,其中,两个所述混气结构的所述第一进气端分别与所述第一进气支路和第二进气支路的出气端连通;两个所述混气结构的所述出气端分别与两个所述工艺腔室的进气结构连通;两个所述混气结构的所述第二进气端用于与提供平衡气体的平衡气体源和所述反应气体供应装置连通。
- 根据权利要求5所述的等离子体增强原子层沉积设备,其特征在于,每个所述混气结构均包括混气块和混气管路,其中,所述混气块中设置有混气腔,所述混气块的外表面上形成有所述第一进气端和所述第二进气端,所述混气块的外表面上还形成有出气端,该出气端与所述混气管路的进气端连通,所述混气管路的出气端用作所述混气结构的出气端与所述工艺腔室的进气结构连通。
- 根据权利要求2-6中任意一项所述的等离子体增强原子层沉积设备,其特征在于,所述切换管路组包括第一切换支路和第二切换支路,其中,所述第一切换支路的两端分别与所述前驱体源和所述进气管路组连通;所述第 二切换支路的两端分别与所述第一切换支路和所述抽气装置连通;并且,在所述第一切换支路和第二切换支路上分别设置有第三通断阀和第四通断阀。
- 根据权利要求2-6中任意一项所述的等离子体增强原子层沉积设备,其特征在于,所述前驱体源包括载气主路、源瓶、第一载气支路和第二载气支路,其中,所述载气主路的进气端用于与提供载气的载气气源连通,所述载气主路的出气端与所述切换管路组连通;并且,在所述载气主路上设置有第五通断阀和第三质量流量控制器;所述第一载气支路的进气端与所述载气主路在所述第五通断阀的上游位置处连通,所述第一载气支路的出气端与所述源瓶的进气端连通;所述第二载气支路的出气端与所述载气主路在所述第五通断阀的下游位置处连通,所述第二载气支路的进气端与所述源瓶的出气端连通;并且,在所述第一载气支路和第二载气支路上分别设置有第六通断阀和第七通断阀;所述源瓶用于存储所述前驱体。
- 根据权利要求1所述的等离子体增强原子层沉积设备,其特征在于,所述射频装置包括第一匹配器、第二匹配器、第一射频电源和第二射频电源,其中,所述第一射频电源通过所述第一匹配器与其中一个所述工艺腔室电连接;所述第二射频电源通过所述第二匹配器与其中另一个所述工艺腔室电连接。
- 根据权利要求1所述的等离子体增强原子层沉积设备,其特征在于,所述压力调节装置包括第一排气支路和第二排气支路,其中,所述第一排气支路和第二排气支路的进气端分别与两个所述工艺腔室的排气口连通,所述第一排气支路和第二排气支路的出气端均与抽气装置连通;并且,在所述第一排气支路和第二排气支路上分别设置有第一隔离阀和第二隔离阀;在所述第一排气支路和第二排气支路上还分别设置有第一流量调节阀和第二流量 调节阀。
- 根据权利要求5或6所述的等离子体增强原子层沉积设备,其特征在于,所述等离子体增强原子层沉积设备还包括远程等离子体清洗装置、第一清洗管路和第二清洗管路,两个所述混气结构均还具有第三进气端,其中,所述第一清洗管路和第二清洗管路的进气端均与所述远程等离子体清洗装置连通;所述第一清洗管路和第二清洗管路的出气端分别与两个所述第三进气端连通;并且,在所述第一清洗管路和第二清洗管路上分别设置有第三隔离阀和第四隔离阀;所述远程等离子体清洗装置用于提供能够对所述工艺腔室进行清洗的等离子体。
- 一种等离子体增强原子层沉积方法,其特征在于,采用权利要求1-11中任意一项所述的等离子体增强原子层沉积设备同时在两个晶圆上沉积膜层;所述等离子体增强原子层沉积方法包括以下步骤:S1、向两个所述工艺腔室中的第一工艺腔室通入所述前驱体,以及向两个所述工艺腔室中的第二工艺腔室通入所述反应气体,并向所述第二工艺腔室输出射频功率;S2、对所述前驱体供应装置和两个所述工艺腔室进行吹扫;S3、向所述第二工艺腔室通入所述前驱体,以及向所述第一工艺腔室通入所述反应气体,并向所述第一工艺腔室输出射频功率;S4、对所述前驱体供应装置和两个所述工艺腔室进行吹扫;循环进行所述步骤S1至所述步骤S4,直至两个所述晶圆上沉积的所述膜层的厚度达到目标厚度。
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