WO2022191257A1 - 加飾シート、加飾シート付き表示装置、シート物品、加飾シートの製造方法 - Google Patents
加飾シート、加飾シート付き表示装置、シート物品、加飾シートの製造方法 Download PDFInfo
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- WO2022191257A1 WO2022191257A1 PCT/JP2022/010421 JP2022010421W WO2022191257A1 WO 2022191257 A1 WO2022191257 A1 WO 2022191257A1 JP 2022010421 W JP2022010421 W JP 2022010421W WO 2022191257 A1 WO2022191257 A1 WO 2022191257A1
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- decorative sheet
- decorative
- holes
- layer
- arrangement
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Classifications
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F13/00—Illuminated signs; Luminous advertising
- G09F13/04—Signs, boards or panels, illuminated from behind the insignia
- G09F13/12—Signs, boards or panels, illuminated from behind the insignia using a transparent mirror or other light reflecting surface transparent to transmitted light whereby a sign, symbol, picture or other is visible only when illuminated
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F1/00—Designs or pictures characterised by special or unusual light effects
- B44F1/06—Designs or pictures characterised by special or unusual light effects produced by transmitted light, e.g. transparencies, imitations of glass paintings
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/22—Removing surface-material, e.g. by engraving, by etching
- B44C1/228—Removing surface-material, e.g. by engraving, by etching by laser radiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F9/00—Designs imitating natural patterns
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K35/00—Instruments specially adapted for vehicles; Arrangement of instruments in or on vehicles
- B60K35/20—Output arrangements, i.e. from vehicle to user, associated with vehicle functions or specially adapted therefor
- B60K35/21—Output arrangements, i.e. from vehicle to user, associated with vehicle functions or specially adapted therefor using visual output, e.g. blinking lights or matrix displays
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K35/00—Instruments specially adapted for vehicles; Arrangement of instruments in or on vehicles
- B60K35/20—Output arrangements, i.e. from vehicle to user, associated with vehicle functions or specially adapted therefor
- B60K35/21—Output arrangements, i.e. from vehicle to user, associated with vehicle functions or specially adapted therefor using visual output, e.g. blinking lights or matrix displays
- B60K35/22—Display screens
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K35/00—Instruments specially adapted for vehicles; Arrangement of instruments in or on vehicles
- B60K35/80—Arrangements for controlling instruments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K2360/00—Indexing scheme associated with groups B60K35/00 or B60K37/00 relating to details of instruments or dashboards
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- B60K2360/68—Features of instruments
- B60K2360/693—Cover plate features
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133509—Filters, e.g. light shielding masks
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Definitions
- the present disclosure relates to a decorative sheet, a display device with a decorative sheet, a sheet article, and a method for manufacturing a decorative sheet.
- a decorative sheet that is laid over a display device is known.
- the decorative sheet disclosed in JP2001-331132A has a decorated layer.
- the decorated layer is provided with a large number of fine holes through which the image light from the display device can pass.
- the decorative sheet disclosed in JP2001-331132A conceals a display device in a non-display state and further imparts design. On the other hand, the image displayed by the display device can be observed through the decorative sheet.
- a stripe pattern includes a plurality of stripes arranged at a pitch that is observable to the unaided human eye. Each muscle extends linearly in a direction intersecting the array direction.
- the present disclosure aims to suppress the occurrence of striped patterns.
- a decorative sheet includes: Equipped with a decorative layer that displays the design,
- the decorative layer is provided with holes arranged in a plurality of directions,
- the average value AA1 of the arrangement pitch of the holes arranged in the first arrangement direction in which the average value of the arrangement pitch of the holes among the plurality of directions is the smallest is 40 ⁇ m or more and 400 ⁇ m or less,
- Three times the standard deviation ⁇ A1 of the arrangement pitch of the holes arranged in the first arrangement direction is 20 ⁇ m or less
- the ratio of the standard deviation ⁇ A1 ( ⁇ m) to the average value A A1 ( ⁇ m) is 0.0060 or more
- the average value AA2 of the arrangement pitch of the holes arranged in the second arrangement direction in which the average value of the arrangement pitch of the holes is the second smallest among the plurality of directions is 40 ⁇ m or more and 400 ⁇ m or less
- Three times the standard deviation ⁇ A2 of the arrangement pitch of the holes arranged in the second arrangement direction is 20 ⁇ m or less
- FIG. 1 is a diagram for explaining an embodiment, and is an exploded perspective view schematically showing an example of a display device with a decorative sheet.
- 2 is a cross-sectional view of the display device with the decorative sheet of FIG. 1.
- FIG. 3A is a diagram showing an application example of the display device with the decorative sheet of FIG. 1.
- FIG. 3B is a diagram showing an application example of the display device with the decorative sheet of FIG. 1.
- FIG. 3C is a diagram showing an application example of the display device with the decorative sheet of FIG. 1.
- FIG. FIG. 4 is a front view showing the display device with a decorative sheet in FIG. 1, showing a state in which the display device is in a display state.
- FIG. 5 is a plan view showing an example of a pixel array of a display device included in the display device with a decorative sheet of FIG. 1.
- FIG. 6A is a cross-sectional view showing an example of a decorative sheet included in the display device with a decorative sheet of FIG. 1.
- FIG. 6B is a cross-sectional view showing another example of a decorative sheet included in the display device with a decorative sheet of FIG. 1.
- FIG. 6C is a cross-sectional view showing another example of a decorative sheet included in the display device with a decorative sheet of FIG. 1.
- FIG. FIG. 7 is an enlarged plan view showing a decorative sheet that can be included in the display device with a decorative sheet of FIG. 1, and is a diagram showing the arrangement of holes provided in the decorative sheet.
- FIG. 8A and 8B are diagrams showing an example of a manufacturing method of a decorative sheet that can be included in the display device with a decorative sheet of FIG. 1.
- FIG. 9A and 9B are diagrams showing an example of a method for manufacturing a decorative sheet that can be included in the display device with a decorative sheet of FIG. 1.
- FIG. 10 is a diagram showing a sheet article used for manufacturing the decorative sheet of FIG. 1.
- FIG. 11 is a diagram showing a modified example of the laser irradiation device used to manufacture the decorative sheet of FIG.
- FIG. 12 is a cross-sectional view showing another example of the decorative sheet.
- FIG. 13 is a top view schematically showing a decorative sheet manufacturing apparatus.
- FIG. 14A is a cross-sectional view showing another example of the decorative sheet.
- FIG. 14B is a cross-sectional view showing another example of the decorative sheet.
- FIG. 14C is a cross-sectional view showing another example of the decorative sheet.
- FIG. 15A is a cross-sectional view showing another example of the decorative sheet.
- FIG. 15B is a cross-sectional view showing another example of the decorative sheet.
- FIG. 15C is a cross-sectional view showing another example of the decorative sheet.
- FIG. 15D is a cross-sectional view showing another example of the decorative sheet.
- FIG. 16 is a diagram showing a modification of the arrangement of the laser irradiation device used for manufacturing the decorative sheet of FIG.
- FIG. 17 is a cross-sectional view showing another example of the decorative sheet.
- a decorative sheet includes: Equipped with a decorative layer that displays the design,
- the decorative layer is provided with holes arranged in a plurality of directions,
- the average value AA1 of the arrangement pitch of the holes arranged in the first arrangement direction in which the average value of the arrangement pitch of the holes among the plurality of directions is the smallest is 40 ⁇ m or more and 400 ⁇ m or less,
- Three times the standard deviation ⁇ A1 of the arrangement pitch of the holes arranged in the first arrangement direction is 20 ⁇ m or less
- the ratio of the standard deviation ⁇ A1 ( ⁇ m) to the average value A A1 ( ⁇ m) is 0.0060 or more
- the average value AA2 of the arrangement pitch of the holes arranged in the second arrangement direction in which the average value of the arrangement pitch of the holes is the second smallest among the plurality of directions is 40 ⁇ m or more and 400 ⁇ m or less
- Three times the standard deviation ⁇ A2 of the arrangement pitch of the holes arranged in the second arrangement direction is 20 ⁇ m or less
- the decorative sheet according to one embodiment satisfies the following conditions. 40 ⁇ m ⁇ A A1 ⁇ 400 ⁇ m 40 ⁇ m ⁇ A A2 ⁇ 400 ⁇ m 3 ⁇ A1 ⁇ 20 ⁇ m 3 ⁇ A2 ⁇ 20 ⁇ m 0.0060 ⁇ A1 /A A1 0.0060 ⁇ A2 /A A2
- the ratio of the standard deviation ⁇ D ( ⁇ m) of the diameter of the holes to the average value AD ( ⁇ m) of the diameter of the holes provided in the decorative layer is 0. It may be 080 or less. That is, the following conditions may be satisfied. ⁇ D /A D ⁇ 0.080
- the average value A A1 ( ⁇ m) and the standard deviation ⁇ A1 ( ⁇ m) of the arrangement pitch of the holes arranged in the first arrangement direction, and in the second arrangement direction may satisfy the following conditions.
- the decorative layer may include a design layer displaying a design and a light shielding layer laminated with the design layer.
- the decorative layer may further include a white layer positioned between the design layer and the light shielding layer.
- a decorative sheet includes: Further comprising a base material laminated with the decorative layer, The light shielding layer is located between the base material and the design layer, A width of the hole at a proximal end closer to the substrate may be narrower than a width of the hole at a distal end remote from the substrate.
- the average value AD of the diameters of the holes provided in the decorative layer may be 20 ⁇ m or more and 200 ⁇ m or less.
- the decorative layer may have an aperture ratio of 5% or more and 50% or less.
- the decorative sheet according to one embodiment may have a total light transmittance of 3% or more and 40% or less.
- the decorative layer may have a thickness of 1 ⁇ m or more and 20 ⁇ m or less.
- the decorative sheet according to one embodiment may further include a transparent substrate laminated with the decorative layer.
- the decorative layer may contain one or more selected from wood, natural fiber, natural leather, natural stone, synthetic fiber, synthetic leather, and artificial stone.
- a display device with a decorative sheet includes: a display device; and any of the above-described decorative sheets according to the present disclosure arranged to overlap with the display device.
- the arrangement pitch of pixels displaying the same color included in the display device may be 40 ⁇ m or more and 500 ⁇ m or less.
- a sheet article according to one embodiment includes any of the decorative sheets according to the present disclosure described above.
- the first arrangement direction of the decorative sheet may be inclined with respect to the longitudinal direction of the sheet article
- the second arrangement direction of the decorative sheets may be inclined with respect to the longitudinal direction of the sheet article.
- a sheet article comprises: It is wound around the winding axis, The first arrangement direction of the decorative sheet may be inclined with respect to the winding axis, The second arrangement direction of the decorative sheet may be inclined with respect to the winding axis.
- a method for manufacturing a decorative sheet includes: a step of producing a laminate including a base decorative layer on which a design is formed; While moving the laminate relative to a laser irradiation device having a plurality of irradiation ports, the laminate is intermittently irradiated with laser light from the plurality of irradiation ports to form holes in the decorative base layer. and In the step of forming the holes, the laminate is moved relative to the laser irradiation device in a direction non-parallel to the arrangement direction of the plurality of irradiation ports, and the laminate is moved relative to the laser irradiation device. At least one of the speed and the irradiation time interval of the laser light from the irradiation port is varied.
- the laminate is moved relative to the laser irradiation device in a direction inclined with respect to the arrangement direction of the plurality of irradiation ports. good too.
- the holes in the manufactured decorative sheet are arranged in a plurality of directions, A first arrangement direction in which an average value of arrangement pitches of the holes among the plurality of directions is the smallest may be non-parallel to the inclined direction.
- the second arrangement direction in which the average value of the arrangement pitch of the holes among the plurality of directions is the second smallest may be non-parallel to the inclined direction.
- the arrangement pitch of the holes in the manufactured decorative sheet in the direction parallel to the direction of relative movement of the laminate with respect to the laser irradiation device is equal to the arrangement pitch of the irradiation ports. It can be longer than the pitch.
- the variation in the relative movement speed of the laminate with respect to the laser irradiation device and the variation in the irradiation time interval of the laser beam from the irradiation port occur during at least a part of the period. , may be performed in parallel.
- the decorative base layer may be irradiated with the laser light that has passed through the film material.
- the absorptivity of the laser light of the base decorative layer may be 3% or more.
- the absorptivity of the laser light of the film material may be lower than the absorptivity of the laser light of the base decorative layer.
- the base decorative layer includes a base design layer and a base light shielding layer,
- the base light-shielding layer is positioned between the film material and the base design layer,
- the laser light absorption rate of the base light shielding layer may be 3% or more.
- the base decorative layer includes a base design layer and a base light shielding layer,
- the base light-shielding layer is positioned between the film material and the base design layer,
- the absorptivity of the laser beam of the film material may be lower than the absorptivity of the laser beam of the base light-shielding layer.
- the base decorative layer includes a base design layer and a base light shielding layer,
- the base light-shielding layer is positioned between the film material and the base design layer,
- the base light shielding layer may be in contact with the film material.
- the numerical range of the parameter is any one upper limit candidate and any one lower limit value.
- “Parameter B is, for example, A1 or more, may be A2 or more, or may be A3 or more.
- Parameter B may be, for example, A4 or less, may be A5 or less, or A6 or less.
- the numerical range of the parameter B may be A1 or more and A4 or less, A1 or more and A5 or less, A1 or more and A6 or less, or A2 or more and A4 or less, It may be A2 or more and A5 or less, A2 or more and A6 or less, A3 or more and A4 or less, A3 or more and A5 or less, or A3 or more and A6 or less.
- drawings show common directions by arrows with common symbols.
- the tip side of the arrow is one side in each direction.
- an arrow pointing forward from the plane of the drawing along the direction perpendicular to the plane of the drawing is indicated by a dot in a circle, as shown in FIG. 2, for example.
- 1 to 17 are diagrams for explaining one embodiment.
- 1 and 2 are an exploded perspective view and a cross-sectional view schematically showing one specific example of a display device 1 with a decorative sheet.
- the display device 1 with a decorative sheet has a display device 10 and a decorative sheet 20 superimposed on the display device 10 .
- the display device 10 when the display device 10 is in the non-display state, the display device 10 is hidden by the decorative sheet, and the design is further expressed (see FIG. 1).
- the display device 10 is displaying an image, the image can be observed through the decorative sheet 20 (FIG. 4).
- the decorative sheet 20 according to the present embodiment is devised to suppress striped patterns that occur on the decorative sheet when the display device 10 is in the display state. More specifically, the decoration layer 30 of the decoration sheet 20 is provided with holes 22 for passing image light, and the arrangement of the holes 22 is devised.
- the display device 1 with a decorative sheet has a display device 10 and a decorative sheet 20.
- the display device 10 has a display surface 11 .
- the decorative sheet 20 covers the display surface 11. - ⁇
- the decorative sheet-equipped display device 1 can express a design with the decorative sheet 20 . According to this decorative sheet 20, the display device 10 can be installed while harmonizing with the surrounding environment.
- the display surface 11 has a rectangular shape in plan view.
- the rectangular display surface 11 extends in the first direction D1 and the second direction D2.
- the display device 10 and the decorative sheet 20 are laminated in a third direction D3 that is normal to the display surface 11 and perpendicular to both the first direction D1 and the second direction D2.
- the decorative sheet-equipped display device 1 shown in FIGS. 1 and 2 is shown in a flat plate shape.
- the decorative sheet-equipped display device 1 may be curved by curving each component of the decorative sheet-equipped display device 1 .
- the decorative sheet 20 may be curved.
- the decorative sheet 20 and at least the display surface 11 of the display device 10 may be curved.
- the display device 1 with a decorative sheet can be applied to various uses.
- the display device 1 with a decorative sheet can be applied to the interior of a moving body as a movable device. Examples of mobile objects include automobiles, ships, and airplanes.
- the display device 1 with a decorative sheet is applied to the center console of an automobile.
- the display device 1 with a decorative sheet can constitute a car navigation system, a stereo, a communication terminal, or the like.
- the decorative sheet-equipped display device 1 can also be applied to walls, doors, ceilings, partitions, and the like as the interior of a building.
- the display device 1 with a decorative sheet can also be applied to various devices such as furniture and home electric appliances.
- the display device 1 with a decorative sheet is applied to a desk.
- the display device 1 with a decorative sheet is applied to a refrigerator.
- the display device 10 employs a dot matrix system.
- the display device 10 has a plurality of pixels forming each dot.
- the display device 10 forms a desired image on the display surface 11 by controlling the light emission state of each pixel.
- Examples of the display device 10 include a liquid crystal display device, an electroluminescence display device also called an EL display device, and the like.
- the display device 10 has a surface light source device 12 and a display panel 15.
- the surface light source device 12 is a device that emits light in a planar manner.
- the surface light source device 12 has a light emitting surface 13 that emits light.
- the light emitting surface 13 has a rectangular shape in plan view.
- the light emitting surface 13 has edges extending along both the first direction D1 and the second direction D2.
- the surface light source device 12 is not particularly limited, and various types such as an edge light type or a direct type may be used.
- the display panel 15 and the surface light source device 12 are laminated in the third direction D3.
- the display panel 15 is, for example, a liquid crystal display panel.
- the display panel 15 may form an image by controlling transmission of planar light from the planar light source device 12 for each pixel.
- FIG. 5 shows an example of a pixel array in the display device 10.
- the illustrated display device 10 includes a first pixel 16A, a second pixel 16B and a third pixel 16C that emit different colors.
- the plurality of first pixels 16A are arranged in a first pixel arrangement direction DP1 and a second pixel arrangement direction DP2 that are non-parallel to each other.
- the first pixel array direction DP1 and the second pixel array direction DP2 are perpendicular.
- the plurality of first pixels 16A are arranged at a first pixel arrangement pitch PP1 in the first pixel arrangement direction DP1.
- the plurality of first pixels 16A are arranged at a second pixel arrangement pitch PP2 in the second pixel arrangement direction DP2.
- the plurality of second pixels 16B are arranged at a first pixel arrangement pitch PP1 in the first pixel arrangement direction DP1.
- the plurality of second pixels 16B are arranged at a second pixel arrangement pitch PP2 in the second pixel arrangement direction DP2.
- the plurality of third pixels 16C are arranged at a first pixel arrangement pitch PP1 in the first pixel arrangement direction DP1.
- the plurality of third pixels 16C are arranged at a second pixel arrangement pitch PP2 in the second pixel arrangement direction DP2.
- the first pixels 16A, the second pixels 16B and the third pixels 16C are arranged alternately in the first pixel arrangement direction DP1.
- a plurality of first pixels 16A are arranged continuously in the second pixel arrangement direction DP2.
- a plurality of second pixels 16B are arranged continuously in the second pixel arrangement direction DP2.
- a plurality of third pixels 16C are arranged continuously in the second pixel arrangement direction DP2.
- a unit pixel is formed by one first pixel 16A, one second pixel 16B, and one third pixel 16C arranged continuously in the first pixel arrangement direction DP1.
- FIG. 5 illustrates one unit pixel by surrounding it with a dotted line.
- the first pixel 16A emits red image light.
- the second pixels 16B emit green image light.
- the third pixel 16C emits blue image light.
- the first pixel array direction DP1 is parallel to the first direction D1.
- the second pixel array direction DP2 is parallel to the second direction D2.
- the arrangement of pixels in the display device 10 is not limited to the illustrated example, and various configurations may be employed.
- the pixel array pitch of the display device 10 to which the decorative sheet 20 is applied may be, for example, 40 ⁇ m or more and 500 ⁇ m or less. Within this range, in combination with the decorative sheet 20 according to the present embodiment, which employs the arrangement of holes described later, it is possible to effectively suppress the occurrence of striped patterns.
- the pixel array pitch of the display device 10 that can be used for a moving body shown in FIGS. 3A to 3C may be, for example, 40 ⁇ m or more and 200 ⁇ m or less.
- the arrangement pitch of pixels is the so-called arrangement pitches P P1 and P P2 of sub-pixels.
- the arrangement pitch of pixels is the arrangement pitch of pixels of the same color among a plurality of pixels included in the display device.
- the decorative sheet-equipped display device 1 may further have a panel member 18 .
- the illustrated display panel 15 is positioned between the display device 10 and the decorative sheet 20 in the third direction D3.
- the panel member 18 is provided with a transmissive region 18a.
- the transmissive region 18a may be an opening provided in the panel member 18, a transparent portion, or the like.
- the transmissive region 18 a is arranged to overlap the display surface 11 of the display device 10 . Image light from the display device 10 passes through the transmissive region 18 a toward the decorative sheet 20 .
- the panel member 18 can be configured as a panel material, a wall material, a casing, or the like at a place where the display device 10 is installed.
- the decorative sheet 20 may be attached to the panel member 18 .
- the display surface 11 is positioned over the entire transmissive area 18a of the panel member 18.
- FIG. The decorative sheet 20 covers at least the entire transmissive area 18 a of the panel member 18 .
- the illustrated decorative sheet 20 extends over the entire panel member 18 .
- the decorative sheet 20 is not limited to the illustrated example, and the decorative sheet 20 may cover the entire transmissive area 18a and may cover only a part of the panel member 18 other than the transmissive area 18a.
- the decorative sheet 20 may cover only the entire transmissive area 18a.
- the panel member 18 may be arranged on the opposite side of the display device 10 in the third direction D3 with respect to the decorative sheet 20 . That is, the decorative sheet 20 may be positioned between the panel member 18 and the display device 10 in the third direction D3. Furthermore, the panel member 18 may be omitted.
- Transparent as used herein means that the visible light transmittance is 50% or more, preferably 80% or more. Unless otherwise specified, the visible light transmittance is the light transmittance in the visible light range, and a spectrophotometer ("UV-3100PC" manufactured by Shimadzu Corporation, JIS K 0115 compliant product) was used. It is specified as the average value of the transmittance at each wavelength when measured at an incident angle of 0° every 1 nm within the measurement wavelength range of 380 nm to 780 nm.
- the decorative sheet 20 has a design, and imparts a design to the display device 1 with the decorative sheet. Also, the decorative sheet 20 is configured to allow image light from the display device 10 to pass therethrough.
- the decorative sheet 20 has a decorative layer 30 that displays the design expressed by the decorative sheet 20. - ⁇ That is, the decorative layer 30 is decorated. Holes 22 are provided in the decorative layer 30 so that image light can pass through.
- the decorative sheet 20 covers at least the entire display surface 11 so that the display surface 11 is not directly observed from the outside.
- the decorative sheet 20 is located closest to the viewer side of the display device 1 with the decorative sheet in the third direction D3.
- the decorative sheet 20 is a plate-like member extending in the same direction as the display surface 11 of the display device 10 as a whole.
- the thickness of the decorative sheet 20 may be, for example, 20 ⁇ m or more and 550 ⁇ m or less.
- the illustrated decorative sheet 20 has a rectangular shape in plan view. Planar view means observation from the third direction D3.
- the decorative sheet 20 includes a first edge 20a and a second edge 20b extending parallel to each other as long sides.
- the decorative sheet 20 further includes a third edge 20c and a fourth edge 20d extending parallel to each other as short sides. As shown in FIG. 1, the first edge 20a and the second edge 20b extend linearly in the first direction D1.
- the third edge 20c and the fourth edge 20d linearly extend in a second direction D2 perpendicular to the first direction D1.
- FIG. 6A A specific example of the decorative sheet 20 is shown in FIG. 6A.
- This decorative sheet 20 further has a base material 25 that supports the decorative layer 30 .
- the base material 25 is sheet-like.
- the base material 25 is laminated on the decorative layer 30 in the third direction D3.
- the base material 25 is positioned between the decorative layer 30 and the display device 10 in the third direction D3.
- Substrate 25 may be transparent. Image light passes through the substrate 25 .
- a resin film can be used as the base material 25 .
- Examples of materials for the base material 25 include polymethyl methacrylate, polyethylene terephthalate, polyethylene naphthalate, polycarbonate, polystyrene, cyclic polyolefin, and ABS (acrylonitrile-butadiene-styrene copolymer).
- the thickness of the base material 25 is, for example, 10 ⁇ m or more and 500 ⁇ m or less in consideration of visible light transmittance, appropriate supportability of the decorative layer 30, and the like.
- the decorative layer 30 will be explained.
- the decorative layer 30 is provided with a design.
- the decorative layer 30 displays a design.
- the decorative layer 30 may have a design layer 32 and a light shielding layer 34 laminated in the third direction D3.
- the light shielding layer 34 is closer to the display device 10 in the third direction D3 than the design layer 32 is.
- the light shielding layer 34 is positioned between the design layer 32 and the display device 10 in the third direction D3.
- hole 22 penetrates both design layer 32 and light shielding layer 34 .
- the design layer 32 has a design displayed by the decorative sheet 20 formed thereon.
- the design layer 32 may be provided with designs such as graphics, patterns, designs, colors, pictures, photographs, characters, marks, pictograms, characters, numbers, and the like.
- the design layer 32 can also perform design expression to display the background.
- the design layer 32 displays a wood grain pattern, a marble pattern, a metallic texture, and a geometric pattern as designs that can harmonize the decorative sheet with the surrounding environment where the display device 1 with the decorative sheet is provided.
- You may
- the design layer 32 may be formed by printing.
- the design layer 32 may be a printed layer formed on the light shielding layer 34 by printing.
- the design layer 32 may also be formed by transfer.
- the design layer 32 may be a transfer layer transferred onto the light shielding layer 34 .
- the design layer 32 may have a thickness of, for example, 1 ⁇ m or more and 20 ⁇ m or less.
- the light shielding layer 34 is a dark layer.
- the light shielding layer 34 can display a design as a dark colored layer.
- the light shielding layer 34 is a layer having a visible light transmittance lower than that of the design layer 32 .
- the visible light transmittance of the light shielding layer 34 is lower than the visible light transmittance of the design layer 32 .
- the light shielding layer 34 may have a light shielding property. The light shielding property may be controlled by the thickness of the light shielding layer 34 .
- the light shielding layer 34 covers the design layer 32 from the display device 10 .
- the light shielding layer 34 prevents image light from the display device 10 from entering the design layer 32 .
- the light shielding layer 34 can prevent image light from transmitting through the design layer 32 when displaying an image.
- the light shielding layer 34 has, for example, a binder resin and light absorbing particles dispersed in the binder resin. Examples of light-absorbing particles include black pigments such as carbon black and titanium black. Since the light shielding layer 34 has a sufficient thickness, the design formed by the design layer 32 can be displayed darkly and clearly.
- the thickness of the light shielding layer 34 may be 1 ⁇ m or more and 20 ⁇ m or less.
- the decorative sheet 20 may further have a foundation layer between the decorative layer 30 and the light shielding layer 34.
- the underlayer can be configured as layers of different colors. That is, by providing the base layer, the color of the design layer 32 can be selected without being restricted by the light shielding layer 34 .
- the underlayer may be a white layer. Since the white base layer has scattering reflectivity, the design can be clearly displayed by the design layer 32 .
- the decorative layer 30 is provided with the holes 22 that allow transmission of image light.
- the decorative layer 30 includes a decorative portion 30A forming a design and a transparent portion 30B as a non-forming portion of the decorative portion 30A.
- the decorative portion 30A is formed by a region of the decorative layer 30 where the hole 22 is not provided.
- the transmissive portion 30B is formed by a region of the decorative layer 30 in which the holes 22 are provided. That is, the decorative portion 30A is a portion where the design layer 32 is formed.
- the transparent portion 30B is a portion of the decorative layer 30 in which the decorative portion 30A is not formed.
- the transparent portion 30B is a portion of the decorative layer 30 in which the design layer 32 is not formed.
- the transmitting portion 30B is a portion of the decorative sheet 20 through which the image light from the display device 10 is transmitted. Therefore, the transmissive portion 30B has high visible light transmittance.
- the holes 22 that allow image light to pass through may be through holes formed in the decorative layer 30 .
- the decorative layer 30 includes a design layer 32 and a light shielding layer 34.
- FIG. The hole 22 penetrates both the design layer 32 and the light shielding layer 34 .
- the holes 22 that allow image light to pass through may not be through holes penetrating the entire thickness of the decorative layer 30 .
- the hole 22 forming the transmissive portion 30B opens on the side opposite to the display device 10.
- the transmissive portion 30B shown in FIG. 6A is a void.
- the decorative sheet 20 further has a cover layer 36 that covers the decorative layer 30 from the side opposite to the base material 25 in the third direction D3.
- the cover layer 36 is transparent and transmits image light.
- the illustrated cover layer 36 covers the decorative layer 30 and also fills the holes 22 .
- the cover layer 36 within the hole 22 forms the transmissive portion 30B.
- the cover layer 36 can protect the decorative portion 30A and prevent foreign matter such as dust from entering the hole 22. As shown in FIG.
- the cover layer 36 is preferably made of a material having a small refractive index difference with the base material 25 . Refraction at the interface between the cover layer 36 and the base material 25 can be suppressed by reducing the refractive index difference between the cover layer 36 and the base material 25 . Thereby, the distortion of the image displayed by the display device 10 can be suppressed.
- a resin material having a refractive index of 1.33 to 1.77 can be used for cover layer 36 .
- an acrylic resin with a refractive index of 1.53 to 1.57 can be used for substrate 25 .
- Examples of materials for the cover layer 36 include polymethyl methacrylate resin, fluororesin, silicone resin, polypropylene, urethane resin, polyethylene, nylon, polyvinyl chloride, epoxy, polycarbonate, and polystyrene.
- the decorative layer 30 may be positioned between the base material 25 and the display device 10 in the third direction D3.
- the design layer 32 and the light shielding layer 34 are formed on the substrate 25 in this order.
- the decorative sheet 20 shown in FIG. 6C further has a cover layer 36 that covers the decorative layer 30 from the side close to the display device 10 .
- the cover layer 36 can be omitted from the decorative sheet 20 shown in FIG. 6C.
- FIG. 7 is a partial plan view showing the decorative sheet 20.
- the decorative sheet 20 in plan view can be divided into a decorative portion 30A and a transparent portion 30B.
- the position, shape and area of hole 22 respectively determine the position, shape and area of transmissive portion 30B.
- the shape of the hole 22 in plan view is not particularly limited.
- a shape including a curved contour such as a circular shape or an elliptical shape, a polygonal shape such as a triangular shape, a quadrangular shape, a pentagonal shape, a hexagonal shape, an octagonal shape, or a polygonal shape.
- planar shape of the hole is preferably circular.
- plan view shape of the hole 22 is a circle.
- the ratio of the area occupied by the holes 22 to the area of the decorative layer 30 in plan view is defined as the aperture ratio of the decorative layer 30 .
- the contour of the hole 22 in plan view is specified as the contour of the portion that allows the transmission of visible light and contributes to image observation.
- the contour of the hole 22 formed as a through hole is the contour of the portion penetrating the decorative layer 30 when projected in the third direction D3.
- the area of each hole 22 formed as a through hole is the area of the portion penetrating the decorative layer 30 when projected in the third direction D3. That is, it is a region that penetrates the decoration layer 30 over the entire thickness in the third direction D3, and the light traveling in the third direction D3 passes through the decoration layer 30 without entering the decoration portion 30A.
- the area of the obtained area be the area of each hole 22 .
- the area of each hole 22 defined in this way is a region that enables observation of the display device in observation from the third direction D3.
- the aperture ratio is specified using a digital microscope VHX-6000 manufactured by Keyence Corporation. Specifically, an image is taken in a transmission mode while light is irradiated from the back side, and a hole through which the light passes is specified as a hole. In the case of a circle or a shape close to a circle in which the holes are arranged with a certain period, the aperture ratio can be obtained using the average diameter of the circle and the period of the holes.
- the lower limit of the aperture ratio of the decorative layer 30 is preferably determined so that the image can be observed sufficiently clearly while the display device 10 is displaying the image.
- the aperture ratio of the decorative layer 30 is preferably 5% or more, more preferably 10% or more, and even more preferably 15% or more.
- the upper limit of the aperture ratio of the decorative layer 30 is preferably determined so that the design of the decorative layer 30 can be observed sufficiently clearly when the display device 10 does not display an image.
- the aperture ratio of the decorative layer 30 is preferably 50% or less, more preferably 45% or less, and still more preferably 40% or less.
- the lower limit of the total light transmittance of the decorative sheet is preferably determined so that the image can be observed sufficiently clearly while the display device 10 is displaying the image.
- the total light transmittance of the decorative sheet is preferably 3% or more, more preferably 5% or more, and even more preferably 10% or more.
- the upper limit of the total light transmittance of the decorative sheet is preferably determined so that the design of the decorative layer 30 can be observed sufficiently clearly when the display device 10 does not display an image.
- the total light transmittance of the decorative sheet is preferably 40% or less, more preferably 35% or less, still more preferably 30% or less.
- the total light transmittance of the decorative sheet can be set within a preferable range by appropriately setting the diameter and pitch of the holes, the transmittance of the substrate 25, and the like.
- the total light transmittance of the decorative sheet is a value measured using a haze meter HM-150N (Murakami Color Research Laboratory) in accordance with JIS K 7136:2000.
- the holes 22 are arranged in a plurality of arrangement directions.
- the average value of the arrangement pitch P A1 of the holes 22 arranged in the first arrangement direction DA1 is A A1 ( ⁇ m)
- the standard deviation of the arrangement pitch P A1 of the holes 22 arranged in the first arrangement direction DA1 is ⁇ A1 ( ⁇ m).
- the average value of the arrangement pitch P A2 of the holes 22 arranged in the second arrangement direction DA2 is A A2 ( ⁇ m)
- the standard deviation of the arrangement pitch P A2 of the holes 22 arranged in the second arrangement direction DA2 is ⁇ A2 ( ⁇ m).
- the first arrangement direction DA1 is the direction in which the average value of the arrangement pitches in that direction among the plurality of arrangement directions of the holes 22 is the smallest.
- the second arrangement direction DA2 is the direction in which the average value of the arrangement pitches in this direction among the plurality of arrangement directions of the holes 22 is the second smallest.
- the following conditions (A) to (F) are satisfied. 40 ⁇ A A1 ⁇ 400 (A) 40 ⁇ A A2 ⁇ 400 (B) 3 ⁇ A1 ⁇ 20 (C) 3 ⁇ A2 ⁇ 20 (D) 0.0060 ⁇ A1 /A A1 (E) 0.0060 ⁇ A2 /A A2 (F)
- the arrangement pitch P A1 of the plurality of holes 22 arranged in the first arrangement direction DA1 is hereinafter referred to as “first arrangement pitch P A1 ".
- the average value A A1 of the first arrangement pitch P A1 is called “first pitch average value A A1 "
- the standard deviation ⁇ A1 of the first arrangement pitch P A1 is called “first pitch standard deviation ⁇ A1 ".
- the arrangement pitch P A2 of the plurality of holes 22 arranged in the second arrangement direction DA2 is called “second arrangement pitch P A2 ".
- the average value A A2 of the second arrangement pitch P A2 is called “second pitch average value A A2 "
- the standard deviation ⁇ A2 of the second arrangement pitch P A2 is called “second pitch standard deviation ⁇ A2 ".
- Conditions ( A ) and (B) define the upper and lower limits of the first pitch average value AA1 and the second pitch average value AA2 , respectively.
- the lower limits of the first pitch average value AA1 and the second pitch average value AA2 are such that the design of the decorative layer 30 can be observed sufficiently clearly when the display device 10 does not display an image, and the display device 10 is It is determined so that the image can be observed clearly enough while the image is being displayed.
- the upper limits of the first pitch average value AA1 and the second pitch average value AA2 are determined so that the image can be observed sufficiently clearly while the display device 10 is displaying the image.
- the second pitch average value AA2 is preferably twice or less than the first pitch average value AA1 , and more preferably 1.5 times or less.
- the upper limits of the first pitch average value AA1 and the second pitch average value AA2 are more preferably 300 ⁇ m or less, and still more preferably 200 ⁇ m or less.
- the first pitch average value AA1 is preferably smaller than the pixel pitch of the display device 10 along the first arrangement direction DA1 .
- the first pitch average value A A1 is preferably within a range of 60% or more and 90% or less of the pixel pitch of the display device 10 along the first arrangement direction DA1.
- the second pitch average value AA2 is preferably smaller than the pixel pitch of the display device 10 along the second arrangement direction DA2 .
- the second pitch average value AA2 is preferably within a range of 60% or more and 90% or less of the pixel pitch of the display device 10 along the second arrangement direction DA2 .
- Conditions (C) and (D) define the upper limits of the first pitch standard deviation ⁇ A1 and the second pitch standard deviation ⁇ A2 , respectively.
- the upper limits of the first pitch standard deviation ⁇ A1 and the second pitch standard deviation ⁇ A2 are determined so as to sufficiently suppress unevenness in the design displayed while the display device 10 is not displaying an image.
- the upper limit of the triple values of the first pitch standard deviation ⁇ A1 and the second pitch standard deviation ⁇ A2 (3 ⁇ A1 , 3 ⁇ A2 ) is more preferably 10 ⁇ m or less, more preferably 7 ⁇ m or less. Yes, and more preferably 5 ⁇ m or less.
- the lower limits of the first pitch standard deviation ⁇ A1 and the second pitch standard deviation ⁇ A2 can be determined so as to sufficiently suppress the occurrence of striped patterns while the display device 10 is displaying an image.
- the three times lower limit values (3 ⁇ A1 , 3 ⁇ A2 ) of the first pitch standard deviation ⁇ A1 and the second pitch standard deviation ⁇ A2 are preferably 1.0 ⁇ m or more, more preferably 2.0 ⁇ m. It is 0 ⁇ m or more, more preferably 3.0 ⁇ m or more.
- the ratio of the first pitch standard deviation ⁇ A1 to the first pitch average value A A1 and the ratio of the second pitch standard deviation ⁇ A2 to the second pitch average value A A2 It defines the lower limit of the value.
- the lower limit values of the ratio value “ ⁇ A1 /A A1 ” defined under condition (E) and the ratio value “ ⁇ A2 /A A2 ” defined under condition (F) are such that the display device 10 can display an image.
- the upper limit values of these ratio values “ ⁇ A1 /A A1 ” and “ ⁇ A2 /A A2 ” sufficiently suppress unevenness in the design displayed while the display device 10 is not displaying an image. can be determined as possible.
- the upper limit of the ratio value “ ⁇ A1 /A A1 ” and the ratio value “ ⁇ A2 /A A2 ” is preferably 0.070 or less, more preferably 0.040 or less, and still more preferably 0.020 or less.
- the arrangement direction of the holes 22 is specified by observing the decorative sheet 20 in a range including about 30 to 500 holes 22 with a microscope, for example, magnified 100 times to 1000 times. be.
- the holes 22 are arranged along each of the first arranging direction DA1, the second arranging direction DA2 and the third arranging direction DA3.
- the first arranging direction DA1, the second arranging direction DA2 and the third arranging direction DA3 are inclined to each other by about 60°.
- the holes 22 can specify the arrangement direction in which is arranged.
- the array direction may be specified as follows. First, in the magnified observation of the decorative sheet 20, one first reference hole positioned approximately in the center of the observation range is set, and the second reference hole observed to be closest to the first reference hole and the second reference hole are set. The direction connecting one reference hole is defined as the arrangement direction. In the enlarged observation of the decorative sheet, the direction connecting the first reference hole with one or more holes other than the second reference hole located around the first reference hole is also the arrangement direction. At this time, as one or more holes, using the first reference hole as a reference, 2 to 4 holes next to the second reference hole and holes in the same arrangement direction are selected, and the direction in which the pitch is the smallest is selected. can be the alignment direction.
- the arrangement pitch of the holes 22 arranged along a specific arrangement direction means the distance between the centers of two holes 22 arranged adjacent to each other in the specific arrangement direction.
- the center of the hole 22 is the center of gravity of the shape of the hole 22 in plan view.
- the distance between the centers of the circles is the arrangement pitch.
- the center of the circle formed by the hole 22 is specified as follows. First, three points that are located on the outer contour of the hole 22 and are determined to be separated from each other by about 120° at the central angle are identified. The three points may be specified manually by the measurer, or may be automatically specified by the measuring device. A circle passing through the identified three points is then determined, for example by image processing. Treat the center for the determined circle as the center of hole 22 . A digital microscope VHX-6000 manufactured by Keyence Corporation is used to identify such a circle.
- the shape of each hole 22 as a through hole is decorated in the projection in the third direction D3 in the same manner as in the specification of the aperture ratio described above. Identified as a portion penetrating layer 30 .
- the area of the circular hole 22 is specified after specifying the center and diameter of the circle as described herein.
- the average value of the arrangement pitch of the holes 22 and the standard deviation of the arrangement pitch of the holes 22 were specified based on a finite number of measured values of the arrangement pitch of two adjacent holes 22 in a specific arbitrarily selected arrangement direction. value. Specifically, based on the array pitch measurements at 30 locations for the holes 22 arrayed in a specific array direction, the array pitch average values A A1 and A A2 and the array pitch standard deviations ⁇ A1 and ⁇ A2 are identified. When determining whether conditions (G) and (H), which will be described later, are satisfied, the number of measurement points is 30 as in the case of determining whether conditions (A) to (F) are satisfied.
- the first arrangement direction DA1 with the shortest average arrangement pitch and the second arrangement pitch with the second shortest average arrangement pitch are specified.
- Two alignment directions DA2 are specified.
- FIG. 7 shows a first array direction DA1 with the shortest average array pitch, a second array direction DA2 with the second shortest average array pitch, and a third array with the third shortest average array pitch.
- a direction DA3 is indicated.
- the angle between the first arrangement direction DA1 and the second arrangement direction DA2 is 45° or more, and tends to be 60° or more. From the viewpoint of preventing uneven distribution of holes in a plane, the angle between the first arrangement direction DA1 and the second arrangement direction DA2 is preferably 60° or more and 90° or less.
- the first to third arrangement directions DA1, DA2, DA3 are all inclined with respect to the first direction D1 and the second direction D2.
- the first pixel array direction DP1, which is the pixel array direction of the display device 10 is parallel to the first direction D1 (see FIG. 5).
- the second pixel array direction DP2, which is the pixel array direction of the display device 10 is parallel to the second direction D2. That is, in the example shown in FIG. 7, the first to third array directions DA1, DA2, DA3 regarding the holes 22 are inclined with respect to the pixel array directions DP1, DP2 regarding the pixels.
- a film material 25A that will form the base material 25 is prepared.
- the film material 25A the transparent resin film material used for the substrate 25 described above can be used.
- a base decorative layer 30C for forming the decorative layer 30 is formed on the film material 25A.
- the decorative layer 30 includes the design layer 32 and the light shielding layer 34 .
- the decorative base layer 30C consists of a base design layer 32A used to form the design layer 32 and a base light shielding layer 34A used to form the light shielding layer 34. and may include
- the film material 25A is coated with ink that will form the light shielding layer 34 .
- the ink on the film material 25A is dried and solidified.
- the base light shielding layer 34A is formed on the film material 25A. Unlike the light shielding layer 34, the obtained base light shielding layer 34A does not have the holes 22 formed therein.
- a coating device such as a printer is used to form the base light shielding layer 34A.
- the base design layer 32A is formed on the base light shielding layer 34A by printing, transfer, or the like. Unlike the design layer 32, the base design layer 32A is formed as a layer in which the holes 22 are not formed.
- a laminate 31 is obtained in which the base light shielding layer 34A and the base design layer 32A are laminated in this order on the film material 25A.
- a coating device such as a printing machine or a transfer device is used to form the base design layer 32A.
- the illustrated base decorative layer 30C includes a base design layer 32A and a base light shielding layer 34A.
- the holes 22 may be formed in the base design layer 32A and the base light shielding layer 34A.
- the holes 22 are formed by irradiating laser light onto the positions where the holes 22 of the laminate 31 are to be formed, and removing the base design layer 32A and the base light shielding layer 34A in the irradiated regions. can be formed.
- the surface of the laminate 31 adjacent to the film material 25A may be irradiated with laser light.
- the base decorative layer 30C is irradiated with the laser light that has passed through the film material 25A.
- the laser light passes through the film material 25A and is efficiently absorbed by the base light shielding layer 34A.
- the base light shielding layer 34A melts and evaporates together with the adjacent base design layer 32A.
- a hole 22 is formed by irradiation with laser light.
- the design layer 32 is obtained from the base design layer 32A in which the holes 22 are formed.
- the light shielding layer 34 is obtained from the base light shielding layer 34A in which the holes 22 are formed.
- the laser light absorptivity of the film material 25A and the substrate 25 obtained from the film material 25A may be lower than the laser light absorptivity of the base decorative layer 30C and the decorative layer 30 obtained from the base decorative layer 30C. .
- the laser light absorptivity of the film material 25A and the substrate 25 obtained from the film material 25A is smaller than the laser light absorptance of the base light shielding layer 34A and the light shielding layer 34 obtained from the base light shielding layer 34A.
- the base decorative layer 30C and the decorative layer 30 obtained from the base decorative layer 30C may have an absorptivity of laser light of 3% or more, 5% or more, or 10% or more.
- the laser light absorption rate of the base light shielding layer 34A and the light shielding layer 34 obtained from the base light shielding layer 34A may be 3% or more, 5% or more, or 10% or more. According to these examples, the hole 22 can be formed efficiently and stably by irradiating the base decorative layer 30C with the laser beam that has passed through the film material 25A.
- the decorative layer 30 has a design layer 32 and a light shielding layer 34 .
- the light shielding layer 34 is positioned between the design layer 32 and the substrate 25 .
- the light shielding layer 34 is in contact with the substrate 25 .
- the base decorative layer 30C has a base design layer 32A and a base light shielding layer 34A.
- the base light shielding layer 34A is positioned between the base design layer 32A and the film material 25A.
- the base light shielding layer 34A is in contact with the film material 25A.
- the hole 22 can be efficiently and stably formed in the decorative base layer 30C by the laser beam transmitted through the film material 25A.
- the decorative layer 30 obtained from the base decorative layer 30C by irradiating the laser beam transmitted through the film material 25A is arranged in the arrangement direction of the holes 22 (for example, the first arrangement direction DA1 or the first arrangement direction DA1).
- the width along the second arrangement direction DA2) can be narrower at the base end portion 22A closer to the base material 25 along the third direction D3 than at the tip end portion 22B farther from the base material 25 along the third direction D3.
- the width of the holes 22 in the light shielding layer 34 may be narrower than the width of the holes 22 in the design layer 32 .
- the width along the arrangement direction (for example, the first arrangement direction DA1 or the second arrangement direction DA2) of the holes 22 is changed from the tip portion 22B away from the base material 25 along the third direction D3 to the width along the third direction D3. It may be gradually narrowed toward the base end portion 22A closer to the base material 25. As shown in FIG. According to such an example, external light entering the hole 22 is easily absorbed by the decorative layer 30 , for example, the light shielding layer 34 . As a result, images and designs can be displayed with high contrast.
- the sheet article 50 shown in FIG. 10 is a sheet-like member elongated in the longitudinal direction LD.
- the sheet article 50 is wound around a winding axis RA non-parallel to the longitudinal direction LD and can be handled as a wound body 50R.
- the winding axis RA is perpendicular to the longitudinal direction LD.
- the decorative sheet 20 is obtained by unwinding the sheet article 50 from the winding body 50R and cutting the unwound sheet article 50. - ⁇ That is, the sheet article 50 is obtained by cutting the decorative sheet 20 seamlessly connected to other parts from the sheet article 50 to obtain the individual decorative sheets 20 .
- each decorative sheet 20 may be cut out from the sheet article 50 so that the decorative sheet 20 does not include the widthwise edge 51 .
- the first edge 20a and the second edge 20b which are the longer sides of the decorative sheet 20, are parallel to the longitudinal direction LD of the sheet article 50.
- a high yield can be expected from the method of cutting out the decorative sheet 20 from the sheet article 50 shown in FIG.
- a laser irradiation device 100 shown in FIG. 11 when collecting a plurality of decorative sheets 20 from a sheet article 50, a laser irradiation device 100 shown in FIG. 11 can be used.
- a laser irradiation device 100 shown in FIG. 11 has a plurality of irradiation ports 100a.
- a plurality of irradiation ports 100a are arranged in the arrangement direction DX. In the illustrated example, the intervals between the plurality of irradiation ports 100a along the arrangement direction DX are constant.
- the laser irradiation device 100 of FIG. 11 can simultaneously form a plurality of holes 22 in the facing laminate 31 .
- a hole 22 can be formed in the laminate 31 by moving the laminate 31 relative to the laser irradiation device 100 and intermittently irradiating the laser beam from the irradiation port 100a of the laser irradiation device 100 .
- laser light does not have to be emitted simultaneously from the plurality of irradiation ports 100a.
- the irradiation timings of the laser beams from the plurality of irradiation ports 100a may differ.
- Laser light may be sequentially irradiated from each of the plurality of irradiation ports 100a with different timings.
- the irradiation openings 100a that emit laser light may change in order along the arrangement direction DX. That is, the irradiation port 100a that emits the laser light sequentially changes from the irradiation port 100a positioned on the first side in the arrangement direction DX to the irradiation port 100a positioned on the second side opposite to the first side. good too.
- the laser light emission period may be the same, partially the same, or completely different.
- the arrangement direction DX of the irradiation ports 100a may be inclined with respect to both the width direction WD and the longitudinal direction LD of the laminate 31 forming the sheet article 50.
- the laminate 31 may be moved relative to the laser irradiation device 100 not only in the longitudinal direction LD of the laminate 31 but also in the width direction WD.
- DA3 As shown in FIG. , DA3. That is, in the decorative sheet 20 included in the sheet article 50 , the first arrangement direction DA1 of the holes 22 can be inclined with respect to the longitudinal direction LD of the sheet article 50 .
- the second arrangement direction DA2 of the holes 22 may also be inclined with respect to the longitudinal direction LD of the sheet article 50.
- the first arrangement direction DA1 and the second arrangement direction DA2 can be non-perpendicular to the longitudinal direction LD and non-parallel to the longitudinal direction LD.
- the first arrangement direction DA1 of the holes 22 can be inclined with respect to the winding axis RA of the wound body 50R.
- the second arrangement direction DA2 of the holes 22 can also be inclined with respect to the winding axis RA of the wound body 50R.
- ink that will form the cover layer 36 is applied onto the produced decorative layer 30 .
- the cover layer 36 can be produced on the decoration layer 30 by drying and solidifying the ink applied on the decoration layer 30 .
- the decorative sheet 20 and the sheet article 50 satisfy the conditions (A) to (F) described above. Moreover, the decorative sheet 20 and the sheet article 50 may further satisfy conditions (G) and conditions (H) described later.
- conventional decorative sheets and sheet articles do not satisfy all of the conditions (A) to (F).
- the conventional decorative sheet 20 and sheet article 50 in which the holes are evenly arranged have little variation in the arrangement of the holes and do not satisfy the conditions (E) and (F).
- conventional decorative sheets and sheet articles with irregularly arranged holes do not satisfy the conditions (C) and (D). In the decorative sheet and sheet article in which the holes are arranged irregularly, the dispersion of the hole arrangement becomes too large for the conditions (C) and (D).
- the present inventors used the decorative sheet manufacturing apparatus 80 and the laser irradiation apparatus 100 shown in FIGS. It was confirmed that the sheet 20 and the sheet article 50 could be produced stably.
- the holes 22 are sequentially formed in the laminate 31 by moving the laminate 31 relative to the laser irradiation device 100 .
- the laminate 31 is placed relative to the laser irradiation device 100 in a direction non-parallel to the arrangement direction DX of the irradiation ports 100a, that is, in a direction inclined with respect to the arrangement direction DX or in a direction DM orthogonal to the arrangement direction DX. It is moved, and laser light is intermittently emitted from the irradiation port 100a.
- at least one of the relative movement speed of the laminate 31 with respect to the laser irradiation device 100 and the time interval for emitting laser light from the irradiation port 100a is varied.
- the change in the irradiation time interval of the laser light from the irradiation port 100a means the time interval from the start timing of the irradiation of the laser light from the irradiation port 100a to the next timing of the irradiation start of the laser light, and the irradiation port 100a. It means that at least one of the time intervals from the timing of stopping the irradiation of the laser light from the first to the timing of starting the irradiation of the next laser light fluctuates.
- the variation in the relative movement speed and the variation in the irradiation time interval may be implemented in parallel, may be implemented in parallel only during a part of the period, or may be implemented in a completely separate period.
- the regularity of the arrangement of the holes 22 can be weakened by simultaneously changing the relative movement speed and the irradiation time interval. This makes it easier to manufacture the decorative sheet 20 and the sheet article 50 that satisfy the conditions (A) to (F), as well as the conditions (G) and (H).
- the laminate 31 may be moved relative to the laser irradiation device 100 in a direction inclined in the arrangement direction DX of the irradiation ports 100a to intermittently emit laser light from the irradiation ports 100a.
- the regularity of the arrangement of the holes 22 can be weakened. This makes it easier to manufacture the decorative sheet 20 and the sheet article 50 that satisfy the conditions (A) to (F), as well as the conditions (G) and (H).
- the arrangement pitch of the holes 22 in the direction parallel to the relative movement direction DM of the laminate 31 with respect to the laser irradiation device 100 may be different from the arrangement pitch of the irradiation ports 100a. Also in this example, at least one of the first arrangement direction DA1 and the second arrangement direction DA2 is likely to be non-parallel to both the arrangement direction DX of the irradiation port 100a and the relative movement direction DM of the laminate 31 with respect to the laser irradiation device 100.
- the arrangement pitch of the holes 22 in the direction parallel to the relative movement direction DM of the laminate 31 with respect to the laser irradiation device 100 may be larger than the arrangement pitch of the irradiation ports 100a.
- both the first arrangement direction DA1 and the second arrangement direction DA2 are likely to incline with the relative movement direction DM of the laminate 31 with respect to the laser irradiation device 100 .
- the direction DA1 and the second arrangement direction DA2 can be easily inclined with respect to the pixel arrangement directions DP1 and DP2. Therefore, the obtained decorative sheet 20 can sufficiently suppress the generation of striped patterns when combined with a general display device 10 .
- a decorative sheet manufacturing apparatus that forms holes by laser irradiation has, for example, a conveying section that conveys a laminate including a film material and a base decorative layer on which a design is formed, and a plurality of irradiation ports.
- a laser irradiation device that intermittently irradiates the laminate transported by the unit with laser light from a plurality of irradiation ports to form holes in the base decorative layer, and a control unit that controls the transport unit and the laser irradiation device.
- the plurality of irradiation ports are arranged in a direction non-parallel to the direction of relative movement of the laminate conveyed by the conveying unit with respect to the laser irradiation device, and the control unit controls the relative movement speed of the laminate with respect to the laser irradiation device and
- a decorative sheet manufacturing apparatus that varies at least one of the irradiation time intervals of the laser light from the irradiation port can be exemplified.
- the laser irradiation device may be arranged so that the base decorative layer is irradiated with the laser light that has passed through the film material.
- FIG. 13 shows an example of a manufacturing device 80 for decorative sheets.
- the manufacturing apparatus 80 includes a transport section 85 , a laser irradiation device 100 and a control section 90 .
- the decorative sheet manufacturing apparatus 80 may include a coating device and a transfer device for forming the decorative base layer 30 ⁇ /b>C of the laminate 31 .
- the transport unit 85 transports the laminate 31 including the film material 25A and the base decorative layer 30C.
- the conveying unit 85 may include a driving roller 86 that winds the layered product 31 and a driven roller 87 that feeds out the layered product.
- the transport unit 85 transports the laminate 31 in a direction DM non-parallel to the arrangement direction DX of the plurality of irradiation ports 100a of the laser irradiation device 100, for example, a direction inclined to the arrangement direction DX or a direction DM orthogonal to the arrangement direction DX. You may
- the control unit 90 may be electrically connected to the transport unit 85 and the laser irradiation device 100.
- the control unit 90 may control the transport unit 85 and the laser irradiation device 100 .
- the transportation unit 85 may change the relative movement speed of the laminate 31 with respect to the laser irradiation device 100 under the control of the control unit 90 .
- the laser irradiation device 100 may change the irradiation time interval of the laser light under the control of the control unit 90 .
- the control unit 90 may be a computer having a processing unit such as a CPU (processor) and a storage unit such as a RAM.
- the storage unit may record a computer program defining the processing procedure of the manufacturing apparatus 80 .
- the processing unit may implement the variation in the relative movement speed of the laminate and the variation in the laser light irradiation time interval described above.
- the decorative sheet 20 covering the display surface 11 is observed as shown in FIG.
- the decorative sheet 20 can conceal the display device, which is normally observed black in the non-display state.
- the design layer 32 of the decorative layer 30 is directly observed.
- the design layer 32 of the decorative layer 30 can be observed through the transparent cover layer 36 .
- the design layer 32 of the decorative layer 30 is observed through the transparent substrate 25.
- the design layer 32 forms an excellent design with rich expressive power such as printing.
- the design expression of the decorative sheet 20 using the decorative layer 30 allows the display device 10 to be installed while ensuring harmony and uniformity with the surrounding environment. Recently, the application range of the display device 10 is rapidly expanding. By using the decorative sheet 20, the display device 10 can be applied to interiors of automobiles, interiors of buildings, furniture, home electric appliances, etc., where design is important.
- image light is emitted from the display surface 11 .
- Image light emitted from the display surface 11 passes through the base material 25 of the decorative sheet 20 and travels toward the decorative layer 30 .
- the image light incident on the transmission portion 30B of the decorative layer 30 passes through the decorative layer 30 and is emitted from the decorative sheet 20 toward the viewer.
- the image light transmitted through the decorative sheet 20 forms an image displayed on the display surface 11 as shown in FIG. In the example shown in FIG. 4, the letter "D" of the alphabet is displayed.
- the image light directed to the decorative portion 30A of the decorative layer 30 is absorbed by the light shielding layer 34 closer to the display device 10 than the design layer 32 is. That is, the image light from the display surface 11 does not pass through the decoration portion 30A. Therefore, the image light does not illuminate the design layer 32 from the back side. Accordingly, it is possible to prevent the image displayed on the display surface 11 from being mixed with the design formed on the decorative portion 30 ⁇ /b>A of the decorative sheet 20 .
- the design of the design layer 32 can be suppressed from being conspicuous. Accordingly, when the display device 10 is in the display state, the image displayed on the display surface 11 can be clearly observed.
- Striped patterns were sometimes observed on the decorative sheet 20 while the display device 10 was displaying an image.
- This striped pattern has no relevance to the design displayed by the decorative sheet, nor does it have relevance to the image displayed by the display device.
- the striped pattern spreads over a relatively large area of several centimeters to ten and several centimeters.
- a stripe pattern includes a plurality of stripes arranged at a pitch that is observable to the unaided human eye. Each muscle extends linearly in a direction intersecting the array direction.
- the striped pattern changed according to the combination of the decorative sheet and the display device.
- the holes 22 are arranged in a plurality of arrangement directions.
- a A1 in the conditions (A), (C) and (E) is the arrangement pitch P of the holes 22 arranged in the first arrangement direction DA1 in which the arrangement pitch of the holes 22 among the plurality of arrangement directions is the smallest. It is the average value ( ⁇ m) of A1 .
- ⁇ A1 is the standard deviation ⁇ P1 ( ⁇ m) of the arrangement pitch P A1 of the holes 22 arranged in the first arrangement direction DA1.
- a A2 in the conditions (B), (D) and (F) is the arrangement of the holes 22 arranged in the second arrangement direction DA2 in which the arrangement pitch of the holes 22 among the plurality of arrangement directions is the second smallest. It is the average value ( ⁇ m) of the pitch PA2 .
- ⁇ A2 is the standard deviation ( ⁇ m) of the arrangement pitch P A2 of the holes 22 arranged in the second arrangement direction DA2.
- the decoration The sheet 20 effectively functions to suppress the striped pattern. That is, when the display device 10 is in the display state, the decorative sheet 20 transmits image light to such an extent that the image can be observed. An observer can observe the image displayed on the display surface 11 through the decorative sheet 20 . The decorative sheet 20 hides the display surface 11 when the display device 10 is in the non-display state. An observer can observe the design expressed by the decorative layer 30 .
- the arrangement pitches P A1 and P A2 of the holes 22 and a general display device A striped pattern can occur in combination with an arrangement pitch of 10 pixels, for example, an arrangement pitch of 40 ⁇ m or more and 500 ⁇ m or less.
- the pixel array pitch of the display device 10 that can be used for mobile objects for example, 40 ⁇ m or more and 200 ⁇ m or less
- a striped pattern can occur in a combination of the arrangement pitch of 120 ⁇ m or more and 300 ⁇ m or less and the arrangement pitches P A1 and P A2 of the holes 22 .
- the provisions of conditions (E) and (F) weaken the regularity of the arrangement of the holes 22 .
- the regularity of the arrangement of the holes 22 is broken beyond the error due to the general manufacturing method when forming the holes at a constant pitch.
- the values of " ⁇ A1 /A A1 " and " ⁇ A2 /A A2 " are both 0.0060 or more, the regularity of the arrangement of the holes 22 and It is possible to sufficiently suppress the occurrence of striped patterns due to the regularity of the arrangement of images.
- the values of " ⁇ A1 /A A1 " and “ ⁇ A2 /A A2 " defined in conditions (E) and (F) are both more preferably 0.0080 or more, more preferably 0.020 or more. is more preferable.
- making the arrangement directions DA1 and DA2 of the holes 22 inclined with respect to the arrangement directions DP1 and DP2 of the pixels is effective in suppressing the striped pattern.
- the arrangement directions DA1 and DA2 of the holes 22 are aligned with the arrangement directions DP1 and DP2 of the pixels.
- the arrangement directions DA1 and DA2 of the holes 22 correspond to the pixel arrangement directions DP1 and DA2. Even when it was parallel to DP2, the striped pattern could be sufficiently suppressed.
- the aperture ratio of the decorative sheet 20 is set very small. It can be said that the occurrence of moiré itself caused by the decorative sheet 20 having a low aperture ratio is unexpected. Furthermore, as a method of coping with moire, the ratio of the standard deviations ⁇ A1 and ⁇ A2 to the average pitches A A1 and A A2 is adjusted instead of the standard deviations ⁇ A1 and ⁇ A2 . It can be said that the discovery of such problems and the proposal of means for solving them are remarkable, exceeding the scope expected from the current technical level.
- Conditions (E) and (F) weaken the regularity of the arrangement of the holes 22 . If the arrangement of the holes 22 becomes irregular, the design displayed by the decorative layer 30 of the decorative sheet 20 becomes uneven. Conditions (C) and (D) limit the extent to which the regularity of the arrangement of the holes 22 is weakened. As defined by the conditions (C) and (D), when the values of "3 ⁇ A1 " and “3 ⁇ A2 " are both 20 or less, the occurrence of design unevenness can be suppressed.
- the arrangement of the holes 22 in a plurality of arrangement directions means that the holes 22 are arranged two-dimensionally.
- the holes 22 are arranged in three or more directions.
- the holes 22 are also arranged in a direction parallel to the axis ALX and the axis LAY.
- whether a striped pattern or design unevenness occurs is strongly influenced by the arrangement in the direction in which the arrangement pitch is short. Therefore, in the present embodiment, by adjusting the arrangement of the holes 22 in the first arrangement direction DA1 and the second arrangement direction DA2, it is possible to sufficiently suppress striped patterns and design unevenness.
- condition (G) is preferably satisfied.
- Condition (G) relates to the first pitch average value A A1 , the second pitch average value A A2 , the first pitch standard deviation ⁇ A1 and the second pitch standard deviation ⁇ A2 .
- the adjustment of the angle of inclination of the hole array direction with respect to the pixel array direction is effective in suppressing the generation of the striped pattern.
- the angular range of the orientation of the decorative sheet 20 with respect to the display device 10 that can suppress the occurrence of stripes that is, the range of the inclination angle of the hole arrangement direction with respect to the pixel arrangement direction is widened.
- " was 0.00070 or less, this effect was more remarkable.
- the opening area of the holes 22 can be appropriately set within a range that satisfies the above-described opening ratio conditions and the above-described conditions regarding the arrangement pitch of the holes 22 .
- the average value A D ( ⁇ m) of the diameter of the holes 22 and the standard deviation ⁇ D ( ⁇ m) of the diameter of the holes 22 satisfy the following condition (H).
- Condition (H) defines the upper limit of the ratio of the hole diameter standard deviation ⁇ D1 to the hole diameter mean value AD .
- the upper limit of the condition (H) is determined so as to suppress variations in transmittance in the surface of the decorative sheet 20 and sufficiently suppress unevenness in brightness of the image displayed by the display device 10 .
- the upper limit of the value of the ratio “ ⁇ D /A D ” is more preferably 0.050 ⁇ m or less, still more preferably 0.030 or less.
- the circle forming the hole 22 is specified in the same manner as the method for specifying the center of the circular hole 22 described above, and the diameter of the specified circle is used. That is, identification of the circle and identification of the diameter of the circle are performed using a digital microscope VHX-6000 manufactured by Keyence Corporation.
- the decorative sheet 20 includes the decorative layer 30 .
- the decoration layer 30 is provided with a plurality of holes 22 arranged in the arrangement direction.
- the average value A A1 ( ⁇ m) and the standard deviation ⁇ A1 ( ⁇ m) of the arrangement pitch P A1 of the holes 22 arranged in the first arrangement direction DA1 and the second arrangement direction The average value A A2 ( ⁇ m) and the standard deviation ⁇ A2 ( ⁇ m) of the arrangement pitch P A2 of the holes 22 arranged in DA2 satisfy the condition (G). According to this specific example, it is possible to widen the range of angles in which the occurrence of striped patterns in the orientation of the decorative sheet 20 with respect to the display device 10 can be suppressed.
- the average value A D ( ⁇ m) of the diameter of the holes 22 and the standard deviation ⁇ D ( ⁇ m) of the diameter of the holes 22 satisfy the condition (H) described above. According to this specific example, in-plane variations in the brightness of the image displayed on the decorative sheet 20 can be suppressed.
- the decorative layer 30 includes the design layer 32 and the light shielding layer 34 .
- the decorative layer 30 may include only one of the design layer 32 and the light shielding layer 34 .
- the decorative layer 30 may include other layers in addition to the design layer 32 and the light shielding layer 34 .
- the holes 22 were through holes penetrating the decorative layer 30.
- the holes 22 extend over the entire length in the thickness direction of the decorative layer 30, which is the third direction D3 in the illustrated example. That is, the hole 22 was a hole penetrating the decorative layer 30 .
- the holes 22 may extend partially in the thickness direction of the decorative layer 30, which is the third direction D3 in the illustrated example. That is, the hole 22 may be a bottomed hole.
- the hole 22 is a portion that allows transmission of image light. Image light transmitted through the hole 22 enables image observation.
- the length of the hole 22 along the thickness direction is sufficient as long as the image can be observed.
- the length of the holes 22 along the thickness direction and the ratio of the length of the holes 22 along the thickness direction to the total thickness of the decorative layer 30 are adjusted according to the visible light transmittance of the design layer 32. good too.
- the decorative layer 30 includes a design layer 32 and a light shielding layer .
- the hole 22 may extend only partially in the thickness direction of at least one of the design layer 32 and the light shielding layer 34 .
- hole 22 penetrates the entire thickness of design layer 32 and extends over only a portion of the thickness of light shielding layer 34 .
- holes 22 are not provided in design layer 32 .
- a design layer 32 with sufficient visible light transmittance may be used.
- the visible light transmittance of the design layer 32 may be 5% or more, 10% or more, 15% or more, or 20% or more.
- hole 22 penetrates light blocking layer 34 .
- the holes 22 extend only partially through the thickness of the light shielding layer 34 .
- the design layer 32 and the light shielding layer 34 may be separated in the normal direction D3 of the decorative layer 30.
- the holes 22 may extend through only a portion of the thickness of the design layer 32 .
- the holes 22 may extend through only a portion of the thickness of the light shielding layer 34 .
- holes 22 are formed in both design layer 32 and light shielding layer 34 .
- the holes 22 are not formed in the design layer 32, but are formed only in the light shielding layer 34.
- FIG. 15C and 15D holes 22 extend only part of the thickness of light shielding layer 34 .
- the film material 25A of the laminate 31 is arranged in the lamination direction of the laminate 31, which is the third direction D3 in the illustrated example, the base decorative layer 30C of the laminate 31 and the laser beam. It was located between the irradiation ports 100 a of the irradiation device 100 .
- the film material 25A was closer to the irradiation port 100a of the laser irradiation device 100 than the base decorative layer 30C.
- the base decorative layer 30C is irradiated with laser light that has passed through the film material 25A.
- the arrangement of the laser irradiation device 100 is not limited to the examples shown in FIGS. 9 and 11 . As shown in FIG.
- the base decorative layer 30C of the laminate 31 is irradiated with the film material 25A of the laminate 31 and the laser irradiation device 100 in the lamination direction of the laminate 31, which is the third direction D3 in the illustrated example. It may be located between the mouths 100a.
- the base decorative layer 30C may be closer to the irradiation port 100a of the laser irradiation device 100 than the film material 25A.
- the laser light from the laser irradiation device 100 may be irradiated onto the decorative base layer 30C without entering the film material 25A.
- the decorative sheet 20 included the base material 25 and the decorative layer 30 .
- the decorative sheet 20 may include one or more of wood, natural fiber, natural leather, natural stone, synthetic fiber, synthetic leather, and artificial stone as a decorative layer 30 .
- the decorative layer 30 may include one or more of wood, natural fiber, natural leather, natural stone, synthetic fiber, synthetic leather, and artificial stone.
- the decorative layer 30 of the decorative sheet 20 includes a thin plate made of any one of wood, natural fiber, natural leather, natural stone, synthetic fiber, synthetic leather, and artificial stone. I'm in.
- the decoration layer 30 is provided with holes 22, and can exhibit the above-described effects. This decorative sheet 20 functions as a decorative material.
- the display device 10 has a plurality of pixels 16A, 16B, and 16C for displaying different colors, but it is not limited to this example. Display device 10 may only have pixels that display a single color. Also, the pixel arrangement shown in FIG. 5 is merely an example, and various pixel arrangements can be used.
- the decorative sheets according to Examples 1-7 and the decorative sheets according to Comparative Examples 1-4 were manufactured as follows.
- a metallic decorative sheet was produced by patterning the chromium layer by a laser drawing method.
- a transparent quartz glass with a thickness of 2.3 mm was used as a substrate for supporting the chromium layer.
- the thickness of the chromium layer was 105 nm.
- Holes holes passing through the decorative layer
- the arrangement of the holes was a so-called honeycomb arrangement. That is, the holes were formed in three arranging directions inclined at 60° with respect to each other with a constant arranging pitch that was mutually identical in each direction.
- a decorative sheet according to Comparative Example 1 was produced using the same production method and conditions as those for the photomask.
- ⁇ Comparative Example 2> A decorative sheet having a black decorative layer was produced by patterning the positive black resist film by dry etching using a photolithographic technique. For the pattern exposure of the positive black resist film, the decorative sheet produced in Comparative Example 1 was used as a mask after the evaluation described later was completed. A transparent acrylic film having a thickness of 75 ⁇ m was used as a substrate for supporting the resist film. The thickness of the resist film was set to 5 ⁇ m.
- Decorative sheets according to Examples 1 to 7 and Comparative Examples 3 and 4 described with reference to FIGS. 8 to 11 were produced. Specifically, by moving the laminate relative to the laser irradiation device, the laminate was sequentially irradiated with laser light to form holes, thereby producing a decorative sheet. The direction of relative movement of the laminate with respect to the laser irradiation device was inclined with respect to the arrangement direction of the irradiation ports of the laser irradiation device. That is, the direction of relative movement forms an angle of more than 0° and less than 90° with respect to the direction of arrangement of the irradiation apertures.
- the direction of relative movement made an angle of approximately 60° with respect to the arrangement direction of the irradiation apertures.
- At least one of the speed of relative movement of the laminate with respect to the laser irradiation device and the irradiation time interval of laser light from the laser irradiation device was varied.
- the degree of variation among the decorative sheets according to Examples 1 to 7 and Comparative Examples 3 and 4 the variation of the holes in each decorative sheet was changed.
- a transparent acrylic film with a thickness of 75 ⁇ m was used as a base material for supporting the decorative layer 30 .
- the decorative layer had the same configuration as shown in FIG. 6A.
- the decorative layer had a light shielding layer and a design layer in this order on the substrate 25 .
- the total thickness of the light shielding layer and the design layer was set to 5 ⁇ m.
- the decorative sheets according to Reference Examples 1 to 4 were also evaluated.
- Reference Examples 1-4 were prepared in the same manner as Examples 1-7 and Comparative Examples 3 and 4.
- At the time of producing the decorative sheets according to Reference Examples 1 to 4 at least one of the relative movement speed of the laminate with respect to the laser irradiation device and the irradiation time interval of the laser light from the laser irradiation device was changed.
- the degree of variation among the decorative sheets according to Reference Examples 1 to 4, Examples 1 to 7, and Comparative Examples 3 and 4 the variation of the holes in each decorative sheet was changed.
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Abstract
Description
意匠を表示する加飾層を備え、
前記加飾層に複数の方向に配列された穴が設けられ、
前記複数の方向のうちの前記穴の配列ピッチの平均値が最も小さくなる第1配列方向に配列された前記穴の配列ピッチの平均値AA1は、40μm以上400μm以下であり、
前記第1配列方向に配列された前記穴の前記配列ピッチの標準偏差σA1の三倍は、20μm以下であり、
前記標準偏差σA1(μm)の前記平均値AA1(μm)に対する比は、0.0060以上であり、
前記複数の方向のうちの前記穴の配列ピッチの平均値が二番目に小さくなる第2配列方向に配列された前記穴の配列ピッチの平均値AA2は、40μm以上400μm以下であり、
前記第2配列方向に配列された前記穴の前記配列ピッチの標準偏差σA2の三倍は、20μm以下であり、
前記標準偏差σA2(μm)の前記平均値AA2(μm)に対する比は、0.0060以上である。
意匠を表示する加飾層を備え、
前記加飾層に複数の方向に配列された穴が設けられ、
前記複数の方向のうちの前記穴の配列ピッチの平均値が最も小さくなる第1配列方向に配列された前記穴の配列ピッチの平均値AA1は、40μm以上400μm以下であり、
前記第1配列方向に配列された前記穴の前記配列ピッチの標準偏差σA1の三倍は、20μm以下であり、
前記標準偏差σA1(μm)の前記平均値AA1(μm)に対する比は、0.0060以上であり、
前記複数の方向のうちの前記穴の配列ピッチの平均値が二番目に小さくなる第2配列方向に配列された前記穴の配列ピッチの平均値AA2は、40μm以上400μm以下であり、
前記第2配列方向に配列された前記穴の前記配列ピッチの標準偏差σA2の三倍は、20μm以下であり、
前記標準偏差σA2(μm)の前記平均値AA2(μm)に対する比は、0.0060以上である。
つまり、一実施の形態による加飾シートでは次の条件が満たされる。
40μm≦AA1≦400μm
40μm≦AA2≦400μm
3×σA1≦20μm
3×σA2≦20μm
0.0060≦σA1/AA1
0.0060≦σA2/AA2
σD/AD≦0.080
|σA1/AA1-σA2/AA2|≦0.0010
前記加飾層と積層された基材を更に備え、
前記遮光層は、前記基材及び前記意匠層の間に位置し、
前記穴の前記基材に接近した基端における幅は、前記穴の前記基材から離れた先端における幅より狭くてもよい。
表示装置と、
前記表示装置と重ねて配置された上述の本開示によるいずかの加飾シートと、を備える。
前記加飾シートの前記第1配列方向は、前記シート物品の長手方向に対して傾斜してもよく、
前記加飾シートの前記第2配列方向は、前記シート物品の長手方向に対して傾斜してもよい。
巻取軸線を中心として巻かれており、
前記加飾シートの前記第1配列方向は、前記巻取軸線に対して傾斜してもよく、
前記加飾シートの前記第2配列方向は、前記巻取軸線に対して傾斜してもよい。
意匠が形成されたベース加飾層を含む積層体を作製する工程と、
複数の照射口を有したレーザー照射装置に対して前記積層体を相対移動させながら、前記複数の照射口から前記積層体にレーザー光を間欠的に照射し、前記ベース加飾層に穴を形成する工程と、を備え、
前記穴を形成する工程において、前記複数の照射口の配列方向に対して非平行な方向に前記積層体を前記レーザー照射装置に対して相対移動させ、前記積層体の前記レーザー照射装置に対する相対移動速度および前記照射口からの前記レーザー光の照射時間間隔の少なくとも一方を変動させる。
製造された加飾シートにおける前記穴は複数の方向に配列され、
前記複数の方向のうちの前記穴の配列ピッチの平均値が最も小さくなる第1配列方向は、前記傾斜した方向と非平行でもよい。
ベース加飾層は、ベース意匠層及びベース遮光層を含み、
前記ベース遮光層は、前記フィルム材及び前記ベース意匠層の間に位置し、
前記ベース遮光層の前記レーザー光の吸収率は3%以上でもよい。
ベース加飾層は、ベース意匠層及びベース遮光層を含み、
前記ベース遮光層は、前記フィルム材及び前記ベース意匠層の間に位置し、
前記フィルム材の前記レーザー光の吸収率は、前記ベース遮光層の前記レーザー光の吸収率より低くてもよい。
ベース加飾層は、ベース意匠層及びベース遮光層を含み、
前記ベース遮光層は、前記フィルム材及び前記ベース意匠層の間に位置し、
前記ベース遮光層は、前記フィルム材に接触していてもよい。
40≦AA1≦400 ・・・(A)
40≦AA2≦400 ・・・(B)
3×σA1≦20 ・・・(C)
3×σA2≦20 ・・・(D)
0.0060≦σA1/AA1 ・・・(E)
0.0060≦σA2/AA2 ・・・(F)
40≦AA1≦400 ・・・(A)
40≦AA2≦400 ・・・(B)
3×σA1≦20 ・・・(C)
3×σA2≦20 ・・・(D)
0.0060≦σA1/AA1 ・・・(E)
0.0060≦σA2/AA2 ・・・(F)
|σA1/AA1-σA2/AA2|≦0.0010 ・・・(G)
条件Gを満たす場合、穴の配列方向の画素の配列方向に対する傾斜角度の調整が、縞模様の発生抑制により有効となる。また、上限(G)を満たす場合、縞模様の発生を抑制し得る表示装置10に対する加飾シート20の向きの角度範囲、すなわち、穴の配列方向の画素の配列方向に対する傾斜角度の範囲を広くできる。「|σA1/AA1-σA2/AA2|」の値が0.00070以下の場合、この効果をより顕著にできた。
σD/AD≦0.080・・・条件(H)
条件(H)では、穴直径の標準偏差σD1の穴直径の平均値ADに対する比の値の上限値を規定している。条件(H)の上限は、加飾シート20面内における透過率のばらつきを抑制して表示装置10によって表示される画像の明るさのムラを十分に抑制し得るよう決定される。すなわち、条件(H)では、穴22の面積のばらつきの大きさに制限を設けることによって、画像の明るさのムラを抑制する。比の値「σD/AD」の上限値は、より好ましくは0.050μm以下であり、更に好ましくは0.030以下である。穴直径の標準偏差σD1は小さい程、画像の明るさムラが生じにくくなり好ましい。したがって、比の値「σD/AD」の下限値は0以上となる。なお、穴22の直径は、上述した円形状の穴22の中心を特定する方法と同様にして当該穴22をなす円を特定し、特定された円の直径の値とする。すなわち、円の特定および円の直径の特定は、株式会社キーエンス社製のデジタルマイクロスコープVHX-6000を用いて行う。
40≦AA1≦400 ・・・(A)
40≦AA2≦400 ・・・(B)
3×σA1≦20 ・・・(C)
3×σA2≦20 ・・・(D)
0.0060≦σA1/AA1 ・・・(E)
0.0060≦σA2/AA2 ・・・(F)
|σA1/AA1-σA2/AA2|≦0.0010 ・・・(G)
σD/AD≦0.080 ・・・条件(H)
レーザー描画法によってクロム層をパターニングして、金属調の加飾シートを作製した。クロム層を支持する基材として、厚みが2.3mmの透明な石英ガラスを用いた。クロム層の厚みは105nmとした。石英ガラス上のクロム層に、レーザー描画法により穴(加飾層を貫通する孔)を形成した。穴の配列は、所謂ハニカム配列とした。すなわち、互いに対して60°傾斜した三つの配列方向に、各方向で互いに同一となる一定の配列ピッチで、穴を形成した。比較例1に係る加飾シートは、フォトマスクと同様の製造方法及び条件を採用して作製した。
フォトリソグラフィー技術を用いたドライエッチングにて、ポジ型ブラックレジスト膜をパターニングすることにより、黒色の加飾層を有する加飾シートを作製した。ポジ型ブラックレジスト膜のパターン露光には、比較例1で作製した加飾シートを後述する評価が終了した後にマスクとして用いた。レジスト膜を支持する基材として、厚みが75μmの透明なアクリルフィルムを用いた。レジスト膜の厚みは5μmとした。
図8~図11を参照して説明した、実施例1~7、比較例3及び4に係る加飾シートを作製した。具体的には、レーザー照射装置に対して積層体を相対移動させることによって、積層体にレーザー光を順次照射して穴を形成していき、加飾シートを作製した。積層体のレーザー照射装置に対する相対移動方向は、レーザー照射装置の照射口の配列方向に対して傾斜していた。すなわち、相対移動方向は、照射口の配列方向に対して0°より大きく90°未満の角度をなしていた。より具体的には、相対移動方向は、照射口の配列方向に対して約60°の角度をなしていた。積層体のレーザー照射装置に対する相対移動速度およびレーザー照射装置からのレーザー光の照射時間間隔の少なくとも一方を変動させた。変動の程度を、実施例1~7、比較例3及び4に係る加飾シートの間で変更することによって、各加飾シートにおける穴のバラツキ具合を変化させた。
実施例1~7及び比較例1~4に係る加飾シートのそれぞれについて、穴の配列ピッチが最も小さくなる第1配列方向DA1に配列された穴の配列ピッチPA1の平均値AA1(μm)及び標準偏差σA1(μm)を計測した。これらの測定結果を表1に示す。また表1には、上述した条件(C)及び(E)で規定された「3×σA1」(μm)の値と、「σA1/AA1」の値も記載している。
全面で白を表示している表示装置の表示面上に各例に係る加飾シートを配置し、縞模様が発生するかを観察した。表示装置は、市販されている横1280画素、縦720画素の8インチの液晶ディスプレイ(縦177mm、横99mm、画素のピッチは縦、横とも138μm)を使用した。実施例1~7及び比較例1~4で共通する表示装置を用いた。穴の配列方向と画素の配列方向を平行にして、縞模様の有無を評価した。評価結果を表3の「評価1」欄に記載した。実製品として許容できない程度に縞模様が観察された場合に「×」を記入している。視認距離20cmで注意深く観察しても、縞模様が全く観察されなかった場合に「AA」を記入している。縞模様が薄く観察されたが実製品としての使用時を想定し、50cmの距離をおいて観察した際には、許容される程度であった場合に「A」を記入している。
穴の配列方向を画素の配列方向に対して調節して、縞模様が最も観察されない向きに加飾シートを表示装置に対して位置決めした。その他は、評価1と同様にして、縞模様の有無を評価した。評価結果を表3の「評価2」欄に記載した。実製品として許容できない程度に縞模様が観察された場合に「×」を記入している。視認距離20cmで注意深く観察しても、縞模様が全く観察されなかった場合に「AA」を記入している。縞模様が薄く観察されたが実製品としての使用時を想定し、50cmの距離をおいて観察した際には許容される程度であった場合に「A」を記入している。
表示装置を非表示とした状態で、加飾シートの加飾層を種々の方向から観察して、加飾層の色調や質感等に関するムラの有無を評価した。評価結果を表3の「評価3」の欄に記載した。実製品として許容できない程度のムラが確認された場合に「×」を記入している。視認距離20cmで注意深く観察しても、ムラが全く確認されなかった場合に「AA」を記入している。ムラが薄く観察されたが実製品としての使用時を想定し、50cmの距離をおいて観察した際には許容される程度であった場合に「A」を記入している。
評価1で用いた表示装置の表示面上に各例に係る加飾シートを配置し、明るさのムラを評価した。表示装置は全面白表示とした。評価結果を表4の「評価4」の欄に記載した。実製品として許容できない程度の明るさのムラが確認された場合に「×」を記入している。注意深く観察しても、明るさのムラが全く確認されなかった場合に「AA」を記入している。明るさのムラが薄く観察されたが実製品として許容される程度であった場合に「A」を記入している。
評価1で用いた表示装置の表示面上に各例に係る加飾シートを配置し、表示装置によって表示される画像を種々の方向から観察して、表示画像の明瞭さを評価した。表示装置は表示状態として、種々の表示画像で明瞭さを確認した。評価結果を表5の「評価5」の欄に記載した。実製品として許容できない程度に表示装置による表示画像が暗く観察された場合に「×」を記入している。非常に明瞭に表示画像を観察できた場合に「AA」を記入している。実製品として許容される程度に表示画像を明瞭に観察できた場合に「A」を記入している。液晶ディスプレイである表示装置のバックライトを調整することによって、実製品として許容される程度に表示画像を明瞭に観察できた場合に「△」を記入している。
表示装置を非表示とした状態で、加飾シートの加飾層を種々の方向から観察して、加飾層の意匠の鮮明さを評価した。評価結果を表5の「評価6」の欄に記載した。
50cmの観察距離から観察して実製品として許容できない程度に意匠が不鮮明であった場合に「×」を記入している。20cmの観察距離から注意深く観察しても意匠が鮮明であった場合に「AA」を記入している。50cmの観察距離から観察して実製品として許容される程度に意匠が鮮明であった場合に「A」を記入している。50cmの観察距離から観察して一部分に意匠が不鮮明であった場合に「A」を記入している。
Claims (20)
- 意匠を表示する加飾層を備え、
前記加飾層に複数の方向に配列された穴が設けられ、
前記複数の方向のうちの前記穴の配列ピッチの平均値が最も小さくなる第1配列方向に配列された前記穴の配列ピッチの平均値AA1は、40μm以上400μm以下であり、
前記第1配列方向に配列された前記穴の前記配列ピッチの標準偏差σA1の三倍は、20μm以下であり、
前記標準偏差σA1(μm)の前記平均値AA1(μm)に対する比は、0.0060以上であり、
前記複数の方向のうちの前記穴の配列ピッチの平均値が二番目に小さくなる第2配列方向に配列された前記穴の配列ピッチの平均値AA2は、40μm以上400μm以下であり、
前記第2配列方向に配列された前記穴の前記配列ピッチの標準偏差σA2の三倍は、20μm以下であり、
前記標準偏差σA2(μm)の前記平均値AA2(μm)に対する比は、0.0060以上である、加飾シート。 - 前記加飾層に設けられた前記穴の直径の平均値AD(μm)に対する前記穴の前記直径の標準偏差σD(μm)の比は、0.080以下である、請求項1に記載の加飾シート。
- 前記第1配列方向に配列された前記穴の配列ピッチの前記平均値AA1(μm)及び前記標準偏差σA1(μm)と、前記第2配列方向に配列された前記穴の配列ピッチの前記平均値AA2(μm)及び前記標準偏差σA2(μm)とが、次の条件を満たす、請求項1又は2に記載の加飾シート。
|σA1/AA1-σA2/AA2|≦0.0010 - 前記加飾層は、意匠を表示する意匠層と、前記意匠層と積層された遮光層と、を含む、請求項1~3のいずれか一項に記載の加飾シート。
- 前記加飾層と積層された基材を更に備え、
前記遮光層は、前記基材及び前記意匠層の間に位置し、
前記穴の前記基材に接近した基端における幅は、前記穴の前記基材から離れた先端における幅より狭い、請求項4に記載の加飾シート。 - 前記加飾層に設けられた前記穴の直径の平均値ADは20μm以上200μm以下である、請求項1~5のいずれか一項に記載の加飾シート。
- 前記加飾層の開口率は5%以上50%以下である、請求項1~6のいずれか一項に記載の加飾シート。
- 全光線透過率は3%以上40%以下である、請求項1~7のいずれか一項に記載の加飾シート。
- 前記加飾層は、木材、天然繊維、天然皮革、天然石材、合成繊維、合成皮革、及び人工石から選択される一以上を含む、請求項1~8のいずれか一項に記載の加飾シート。
- 表示装置と、
前記表示装置と重ねて配置された請求項1~9のいずれか一項に記載の加飾シートと、を備える、加飾シート付き表示装置。 - 前記表示装置に含まれる同一色を表示する画素の配列ピッチは、40μm以上500μm以下である、請求項10に記載の加飾シート付き表示装置。
- 複数の請求項1~9のいずれか一項に記載の加飾シートを備える、シート物品。
- 前記加飾シートの前記第1配列方向は、前記シート物品の長手方向に対して傾斜し、
前記加飾シートの前記第2配列方向は、前記シート物品の長手方向に対して傾斜している、請求項12に記載のシート物品。 - 前記シート物品は巻取軸線を中心として巻かれており、
前記加飾シートの前記第1配列方向は、前記巻取軸線に対して傾斜し、
前記加飾シートの前記第2配列方向は、前記巻取軸線に対して傾斜している、請求項12又は13に記載のシート物品。 - 意匠が形成されたベース加飾層を含む積層体を作製する工程と、
複数の照射口を有したレーザー照射装置に対して前記積層体を相対移動させながら、前記複数の照射口から前記積層体にレーザー光を間欠的に照射し、前記ベース加飾層に穴を形成する工程と、を備え、
前記穴を形成する工程において、前記複数の照射口の配列方向に対して非平行な方向に前記積層体を前記レーザー照射装置に対して相対移動させ、前記積層体の前記レーザー照射装置に対する相対移動速度および前記照射口からの前記レーザー光の照射時間間隔の少なくとも一方を変動させる、加飾シートの製造方法。 - 前記穴を形成する工程において、前記複数の照射口の配列方向に対して傾斜した方向に前記積層体を前記レーザー照射装置に対して相対移動させる、請求項15に記載の加飾シートの製造方法。
- 製造された加飾シートにおいて、前記穴は複数の方向に配列され、
前記複数の方向のうちの前記穴の配列ピッチの平均値が最も小さくなる第1配列方向は、前記傾斜した方向と非平行である、請求項16に記載の加飾シートの製造方法。 - 前記複数の方向のうちの前記穴の配列ピッチの平均値が二番目に小さくなる第2配列方向は、前記傾斜した方向と非平行である、請求項17に記載の加飾シートの製造方法。
- 製造された加飾シートにおける前記積層体の前記レーザー照射装置に対する相対移動方向と平行な方向への前記穴の配列ピッチは、前記照射口の配列ピッチより長い、請求項18に記載の加飾シートの製造方法。
- 前記積層体の前記レーザー照射装置に対する相対移動速度の変動および前記照射口からの前記レーザー光の照射時間間隔の変動が、少なくとも一部の期間に、並行して生じる、請求項15~18のいずれか一項に記載の加飾シートの製造方法。
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001331132A (ja) | 2000-05-23 | 2001-11-30 | Yazaki Corp | 表示装置 |
US20060044228A1 (en) * | 2004-09-02 | 2006-03-02 | 3M Innovative Properties Company | Substrates with multiple images and methods of use |
JP2012163951A (ja) * | 2011-01-18 | 2012-08-30 | Fujifilm Corp | 導電性フイルムを備える表示装置及び導電性フイルム |
JP2018173561A (ja) * | 2017-03-31 | 2018-11-08 | 大日本印刷株式会社 | 加飾シート並びに該加飾シートを使用した加飾成形品及び背面投射型表示装置 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011162013A1 (ja) * | 2010-06-23 | 2011-12-29 | シャープ株式会社 | 表示装置、およびその製造方法 |
-
2022
- 2022-03-09 WO PCT/JP2022/010421 patent/WO2022191257A1/ja active Application Filing
- 2022-03-09 KR KR1020237034288A patent/KR20230155537A/ko unknown
- 2022-03-09 EP EP22767211.0A patent/EP4306349A1/en active Pending
- 2022-03-09 US US18/281,100 patent/US20240294034A1/en active Pending
- 2022-03-09 JP JP2022555176A patent/JP7173427B1/ja active Active
- 2022-03-09 CN CN202280019887.1A patent/CN117063222A/zh active Pending
- 2022-11-01 JP JP2022175722A patent/JP2023022012A/ja active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001331132A (ja) | 2000-05-23 | 2001-11-30 | Yazaki Corp | 表示装置 |
US20060044228A1 (en) * | 2004-09-02 | 2006-03-02 | 3M Innovative Properties Company | Substrates with multiple images and methods of use |
JP2012163951A (ja) * | 2011-01-18 | 2012-08-30 | Fujifilm Corp | 導電性フイルムを備える表示装置及び導電性フイルム |
JP2018173561A (ja) * | 2017-03-31 | 2018-11-08 | 大日本印刷株式会社 | 加飾シート並びに該加飾シートを使用した加飾成形品及び背面投射型表示装置 |
Also Published As
Publication number | Publication date |
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JP7173427B1 (ja) | 2022-11-16 |
KR20230155537A (ko) | 2023-11-10 |
EP4306349A1 (en) | 2024-01-17 |
JP2023022012A (ja) | 2023-02-14 |
JPWO2022191257A1 (ja) | 2022-09-15 |
US20240294034A1 (en) | 2024-09-05 |
CN117063222A (zh) | 2023-11-14 |
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