WO2022092507A1 - Composition cosmétique ayant une couche d'huile située au fond de celle-ci - Google Patents

Composition cosmétique ayant une couche d'huile située au fond de celle-ci Download PDF

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Publication number
WO2022092507A1
WO2022092507A1 PCT/KR2021/010806 KR2021010806W WO2022092507A1 WO 2022092507 A1 WO2022092507 A1 WO 2022092507A1 KR 2021010806 W KR2021010806 W KR 2021010806W WO 2022092507 A1 WO2022092507 A1 WO 2022092507A1
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Prior art keywords
cosmetic composition
oil
weight
layer
oil layer
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PCT/KR2021/010806
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English (en)
Korean (ko)
Inventor
문지현
정동진
이화영
박명삼
Original Assignee
코스맥스 주식회사
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Publication of WO2022092507A1 publication Critical patent/WO2022092507A1/fr

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/03Liquid compositions with two or more distinct layers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365Hydroxycarboxylic acids; Ketocarboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/735Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole

Definitions

  • the present invention relates to a cosmetic composition in which an oil layer is located at a lower end than an aqueous layer by using an oil phase having a higher density than the aqueous phase.
  • Cosmetics are divided into many formulations according to how immiscible oils, water, and thickeners are mixed.
  • many cosmetic formulations such as light solubilization, emulsification, oil dispersion, oil drop and bilayer, etc. have been developed. According to these formulations, the content of the oil is changed, and thus the spreadability, feeling of use and efficacy are also changed.
  • cosmetic formulations that contain oil in the formulation, in particular, in the case of a two-layer or layer-separated formulation, the layer is separated by floating an oil layer on an aqueous layer that has no viscosity.
  • surfactant since surfactant is not included to mix the aqueous and oil layers without separating them, the effect of alleviating irritation when no surfactant is included is great, and the moisture of the aqueous phase and the nutrition of the oil can be felt at the same time. There is this.
  • the oil layer is located at the bottom of the water layer, it can attract the attention of consumers with its unique appearance, and it is expected that the oil with a higher density than the water layer is used, so that the user can feel a high nutritional feeling.
  • the present inventors implemented a cosmetic composition formulation in which the oil layer is located at the lower end than the water layer by using the oil phase having a higher density than the water phase, and it was confirmed that the nutritional feeling was significantly superior to that of the cosmetic composition in which the existing oil layer was located at the upper portion.
  • an object of the present invention is to provide a cosmetic composition in which the oil layer is located at the lower end.
  • the present invention relates to a cosmetic composition in which the oil layer is located at the lower end, and the present inventors have implemented a cosmetic composition formulation in which the oil layer is located at the lower end than the water layer by using an oil phase having a higher density than the water phase, so that the existing oil layer is located at the upper end. It was confirmed that the nutritional feeling was significantly better than that of the cosmetic composition located in
  • An example of the present invention is an oil phase comprising an oil; and an aqueous phase comprising a moisturizing agent; to a cosmetic composition comprising an oil layer located at the lower end.
  • the oil may be at least one selected from the group consisting of diphenyl dimethicone, dimethicone and camellia oil, but is not limited thereto.
  • the oil is 1.00 to 50.00% by weight, 1.00 to 45.00% by weight, 1.00 to 40.00% by weight, 1.00 to 35.00% by weight, 1.00 to 30.00% by weight, 1.00 to 25.00% by weight, 1.00 to 50.00% by weight based on the total cosmetic composition 20.00 wt%, 1.00-15.00 wt%, 1.00-10.00 wt%, 5.00-50.00 wt%, 5.00-45.00 wt%, 5.00-40.00 wt%, 5.00-35.00 wt%, 5.00-30.00 wt%, 5.00-25.00 wt% %, 5.00 to 20.00% by weight, 5.00 to 15.00% by weight, 5.00 to 10.00% by weight, for example, may be included in 9.90% by weight, but is not limited thereto.
  • the moisturizing agent may include at least one selected from the group consisting of beta-glucan, methylpropanediol, sodium PCA and sodium hyaluronate, but is not limited thereto.
  • the moisturizing agent is glycerin, xanthan gum, ethanol, 1,2-butylene glycol, propanediol, dipropylene glycol, propylene glycol, diglycerin, betaine, trehalose, sodium hyaluronate and glycerin. It may be to further include one or more selected from the group consisting of Res-26, but is not limited thereto.
  • the humectant is 0.01 to 50.00% by weight, 0.01 to 45.00% by weight, 0.01 to 40.00% by weight, 0.01 to 35.00% by weight, 0.01 to 30.00% by weight, 0.01 to 25.00% by weight, 0.01 to 25.00% by weight, based on the total cosmetic composition 20.00% by weight, 0.01 to 15.00% by weight, 0.01 to 10.00% by weight, 3.00 to 50.00% by weight, 3.00 to 45.00% by weight, 3.00 to 40.00% by weight, 3.00 to 35.00% by weight, 3.00 to 30.00% by weight, 3.00 to 25.00% by weight %, 3.00 to 20.00 wt%, 3.00 to 15.00 wt%, 3.00 to 10.00 wt%, for example, 5.15 wt% may be included.
  • the cosmetic composition contains 10.00% by weight of oil based on the total cosmetic composition
  • the oil content is lighter than that of the aqueous phase, and thus a phenomenon of floating upward may occur.
  • the cosmetic composition may further include one or more selected from the group consisting of sodium citrate, citric acid, potassium hydroxide, sodium hydroxide and tromethamine as a pH adjuster, but limited thereto it is not going to be
  • the pH adjusting agent may be included in 0.01 to 5.00% by weight, 0.01 to 3.00% by weight, 0.01 to 1.00% by weight, 0.01 to 0.50% by weight, for example, 0.06% by weight based on the total cosmetic composition.
  • the cosmetic composition is a preservative, at least one selected from the group consisting of pentylene glycol, 1,2-hexanediol, ethylhexyl glycerin, glyceryl caprylate, hydroxyacetophenone, and caprylyl glycol. may be included.
  • the preservative is 0.10 to 15.00% by weight, 0.10 to 13.00% by weight, 0.10 to 11.00% by weight, 0.10 to 9.00% by weight, 0.10 to 7.00% by weight, 0.10 to 5.00% by weight, 1.00 to 15.00% by weight, 1.00 to 13.00% by weight, 1.00 to 11.00% by weight, 1.00 to 9.00% by weight, 1.00 to 7.00% by weight, 1.00 to 5.00% by weight, 1.50 to 15.00% by weight, 1.50 to 13.00% by weight, 1.50 to 11.00% by weight %, 1.50 to 9.00 wt%, 1.50 to 7.00 wt%, 1.50 to 5.00 wt%, for example, 4.00 wt% may be included.
  • the present invention relates to a cosmetic composition in which an oil layer is located at the lower end, and by using an oil phase having a higher density than the aqueous phase, a cosmetic composition formulation in which the oil layer is located at the lower end than the water layer is implemented, and the existing oil layer is located at the upper end It has the effect of feeling more nutritious than the cosmetic composition.
  • 2A is a graph showing the results of comparative evaluation of skin moisture (A.U) using a moisture meter after application of Example 4 according to an experimental example of the present invention.
  • 2B is a graph showing the results of comparative evaluation of the skin moisture level (%) using a moisture meter after application of Example 4 according to an experimental example of the present invention.
  • Figure 3a is a graph showing the results of comparative evaluation of the improvement in gloss (A.U) through a skin gloss meter after application of Example 4 according to an experimental example of the present invention.
  • Figure 3b is a graph showing the results of comparative evaluation of the improvement in gloss (%) through a skin gloss meter after application of Example 4 according to an experimental example of the present invention.
  • Example 4 is a photograph showing the improvement of gloss before and after application of Example 4.
  • oil phase containing oil; and an aqueous phase comprising a moisturizing agent; to a cosmetic composition comprising an oil layer located at the lower end.
  • a mixture was prepared by uniformly mixing at 30 rpm for 10 minutes at room temperature using a Disper. Then, the mixture was separately discharged through a filter screen at the same temperature.
  • each raw material was measured in a beaker according to each component and content of the oil phase described in Table 1, and then uniformly mixed at 30 rpm for 5 minutes at room temperature using a Disper to prepare an oil phase. Thereafter, the oil phase was dropped on the aqueous phase from which the mixture was separately discharged through a filtration network to prepare a cosmetic composition as shown in FIG. 1 .
  • Example 1 to 4 the oil layer was located at the lower end.
  • the separation of the interface between the aqueous layer and the oil layer was not good, but in Example 4, it was confirmed that the separation of the interface became clear.
  • Comparative Examples 1 to 3 it was confirmed that the oil layer was located at the upper end.
  • the separation rates of the aqueous layer and the oil layer of the cosmetic compositions of Examples and Comparative Examples were measured. Specifically, each composition was placed at room temperature, and the time for the layers to separate was measured.
  • Example 1 showed a layer separation pattern at 210 seconds, Example 2 at 300 seconds, Example 3 at 1200 seconds, and Example 4 at 2700 seconds.
  • Comparative Example 1 was 90 seconds
  • Comparative Example 2 was 30 seconds
  • Comparative Example 3 was 30 seconds, indicating a faster layer separation than the Example.
  • the density of diphenyl dimethicone used in Examples is higher than triethylhexanoin, cetylethyl hexanoate or dicaprylyl carbonate used in Comparative Examples, and diphenyl dimethicone is greater than the density of water 1 g/ml. Therefore, it was confirmed that the oil layer may be located below the aqueous layer in Examples 1 to 4 due to the density difference.
  • Example 1 contained only glycerin as a moisturizing agent and lacked a moisturizing feeling, so the separation rate was fast.
  • Example 3 xanthan gum was included as a moisturizer to increase the viscosity, and the layer separation rate was slower than in Examples 1 and 2.
  • Example 4 which contains all of sodium PCA, sodium hyaluronate, beta-glucan and methylpropanediol in the aqueous phase, layer separation was the slowest.
  • Example 4 and Comparative Example 1 After applying an appropriate amount of Example 4 and Comparative Example 1 to the face of 10 professional female panelists aged 26 to 40 and using them, the applicability, nutrition, adhesion, and overall satisfaction felt when applied according to the following evaluation criteria were evaluated. The feeling of use was evaluated and the results are shown in Table 2.
  • Applicability among the criteria includes application without stickiness and dripping with the property of being applied to the skin and spreading smoothly on the skin.
  • Adhesion refers to the feeling that the composition is applied thinly to the skin surface and adheres to the skin when applied to the skin.
  • Nutrition refers to the feeling of giving nutrition and moisture to the skin when applied to the skin.
  • Example 4 Comparative Example 1 spreadability 4.2 3.3 nutrition 4.3 3 moisturizing 4.7 3.2 overall satisfaction 4.5 3.1
  • Example 4 As shown in Table 2 above, as a result of comparison of Example 4 and Comparative Example 1, Example 4 was found to be superior to Comparative Example 1 in spreadability, nutritional feeling, adhesion, and overall satisfaction. This is because diphenyldimethicone is denser than triethylhexanoin and has a sense of nutrition.
  • Moisture power test was performed using a moisture meter (Epsilon, BiOX, UK). Specifically, 10 minutes before the test, the test site (inner arm, 2 cm X 2 cm) was washed with lukewarm water. After waiting in a constant temperature and humidity room (22° C., humidity 40 to 60%) for 10 minutes, the moisture content of the skin was measured when the test site was not applied. Then, 8 mL of the sample of Example 4 was spread evenly on the test site for absorption, and the skin moisture level was measured 3 times each 2 hours, 4 hours and 8 hours after application. As for the result analysis method, the change rate of the skin moisture level was calculated using the average of the three measurements, and then compared with the value before use, and the results are shown in Table 3, FIGS. 2A and 2B.
  • Example 4 As can be seen in Table 3 and FIGS. 2a and 2b, in the case of Example 4, it was confirmed that the skin moisture content increased by about 79.1% from immediately after application to after application compared to that of no application. Through this, it was confirmed that the moisturizing power of the product was superior to that of the non-applied product, which increased by about 14.5%.
  • the gloss improvement effect was performed using a skin gloss meter (Skin Gloss meter, Delfin, Finland). Specifically, the gloss of the test site (facial part) was measured before application of the sample, and the gloss of the same site after using Example 4 was measured.
  • the present invention relates to a cosmetic composition in which the oil layer is located at the lower end than the water layer by using the oil phase having a higher density than the aqueous phase.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
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  • Veterinary Medicine (AREA)
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Abstract

La présente invention concerne une composition cosmétique ayant une couche d'huile située au fond de celle-ci, et met en œuvre une formulation de composition cosmétique dans laquelle une couche d'huile est située au-dessous d'une couche de phase aqueuse par utilisation d'une partie de phase huileuse ayant une densité supérieure à celle d'une partie de phase aqueuse. Ainsi, la présente invention a pour effet de fournir une sensation nourrissante considérablement supérieure à celle d'une composition cosmétique classique dans laquelle une couche d'huile est située au sommet de celle-ci.
PCT/KR2021/010806 2020-10-26 2021-08-13 Composition cosmétique ayant une couche d'huile située au fond de celle-ci WO2022092507A1 (fr)

Applications Claiming Priority (2)

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KR10-2020-0139475 2020-10-26
KR1020200139475 2020-10-26

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WO2022092507A1 true WO2022092507A1 (fr) 2022-05-05

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005089459A (ja) * 2003-09-12 2005-04-07 L'oreal Sa 2相組成物およびその化粧料としての使用
KR20110084053A (ko) * 2010-01-15 2011-07-21 한국콜마 주식회사 보습효과를 가지는 이층상 클렌져 화장료 조성물 및 그 제조방법
KR20130011800A (ko) * 2011-07-22 2013-01-30 코웨이 주식회사 피부 유사 지질을 포함하는 수중유형 유화 조성물 및 이를 포함하는 화장료 조성물
KR101262103B1 (ko) * 2012-06-11 2013-05-14 김주덕 응집된 펄 파우더 덩어리가 눈처럼 떨어지는 2층상 화장료 조성물 및 그 제조방법
KR101507890B1 (ko) * 2013-03-27 2015-04-07 한국콜마주식회사 투명 성상을 가지는 수중유형 실리콘 유화 보습 화장료 조성물, 그의 제조방법 및 그를 함유한 보습화장품

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101899024B1 (ko) * 2016-12-16 2018-11-05 주식회사 코리아나화장품 녹는 질감의 자외선 차단용 화장료 조성물

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005089459A (ja) * 2003-09-12 2005-04-07 L'oreal Sa 2相組成物およびその化粧料としての使用
KR20110084053A (ko) * 2010-01-15 2011-07-21 한국콜마 주식회사 보습효과를 가지는 이층상 클렌져 화장료 조성물 및 그 제조방법
KR20130011800A (ko) * 2011-07-22 2013-01-30 코웨이 주식회사 피부 유사 지질을 포함하는 수중유형 유화 조성물 및 이를 포함하는 화장료 조성물
KR101262103B1 (ko) * 2012-06-11 2013-05-14 김주덕 응집된 펄 파우더 덩어리가 눈처럼 떨어지는 2층상 화장료 조성물 및 그 제조방법
KR101507890B1 (ko) * 2013-03-27 2015-04-07 한국콜마주식회사 투명 성상을 가지는 수중유형 실리콘 유화 보습 화장료 조성물, 그의 제조방법 및 그를 함유한 보습화장품

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