WO2022033049A1 - 一种聚合物水泥基防水涂料及其制备方法 - Google Patents

一种聚合物水泥基防水涂料及其制备方法 Download PDF

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WO2022033049A1
WO2022033049A1 PCT/CN2021/085248 CN2021085248W WO2022033049A1 WO 2022033049 A1 WO2022033049 A1 WO 2022033049A1 CN 2021085248 W CN2021085248 W CN 2021085248W WO 2022033049 A1 WO2022033049 A1 WO 2022033049A1
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parts
waterproof coating
reducing agent
water reducing
polymer cement
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PCT/CN2021/085248
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English (en)
French (fr)
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谢玉华
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赣州市犇牛防水建材有限公司
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C09D1/06Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances cement
    • C09D1/08Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances cement with organic additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

Definitions

  • the invention relates to the field of waterproof coatings, in particular to a polymer cement-based waterproof coating and a preparation method thereof.
  • Polymer cement-based waterproof coating also known as JS composite waterproof coating.
  • the polymer cement-based waterproof coating is based on the loss of water from the organic polymer emulsion to form a cohesive and continuous elastic film layer.
  • the cement absorbs the water in the emulsion and hardens, and the flexible polymer and the cement hardened body penetrate each other and are firmly bonded. It forms a firm and elastic waterproof layer.
  • the flexible polymer is filled in the voids of the cement hardened body, making the cement hardened body more dense and elastic.
  • the coating film has a good elongation rate.
  • the cement hardened body is filled in the polymer phase. It has better outdoor durability and better adaptability to the base layer.
  • this waterproof coating is an environmentally friendly coating, which will not affect the environment. , so it has become more and more popular and has become a hot spot in the development of waterproof coatings in recent years.
  • the object of the present invention is to provide a polymer cement-based waterproof coating and a preparation method thereof.
  • the present invention provides a polymer cement-based waterproof coating, in parts by weight, its raw material components include: 60-70 parts of acrylate emulsion, 7-10 parts of dispersant, 8-10 parts of film-forming auxiliary 10 parts, 3-5 parts of leveling agent, 4-6 parts of drier, 0.05-0.2 parts of water reducer, 50-55 parts of cement, 40-60 parts of filling aid, 3-7 parts of water .
  • the solid content in the acrylate emulsion is 30-60%.
  • the water reducing agent is any one of polycarboxylate water reducer and polyether polycarboxylate water reducer.
  • the filling aid is a mixture of quartz sand powder, magnesium oxalate, and kaolin, and the mass ratio of quartz sand powder, magnesium oxalate, and kaolin in the mixture is 2:1-2:1-2.
  • the invention also provides a preparation method of the polymer cement-based waterproof coating, the specific steps comprising:
  • the polymer cement-based waterproof coating prepared by the invention has good mechanical properties, good tensile strength and bonding strength, good weather resistance and short drying time.
  • the raw material is cheap, the preparation process is simple, the requirement for production equipment is low, and the waterproof performance is good.
  • the mechanical properties of the waterproof coating are improved by utilizing the synergistic effect of quartz sand powder, magnesium oxalate and kaolin.
  • a polymer cement-based waterproof coating in parts by weight, its raw material components include: 65 parts of acrylate emulsion, 8 parts of dispersant, 9 parts of film-forming auxiliary, 4 parts of leveling agent, 5 parts of drier, 0.15 parts of water reducing agent, 50 parts of cement, 5 parts of filling aids, and 5 parts of water.
  • the solid content in the acrylate emulsion is 30-60%.
  • the water reducing agent is any one of polycarboxylate water reducer and polyether polycarboxylate water reducer.
  • the filling aid is a mixture of quartz sand powder, magnesium oxalate, and kaolin, and the mass ratio of quartz sand powder, magnesium oxalate, and kaolin in the mixture is 2:1:1.
  • a preparation method of polymer cement-based waterproof coating, the concrete steps include:
  • a polymer cement-based waterproof coating in parts by weight, its raw material components include: 60 parts of acrylate emulsion, 7 parts of dispersant, 8 parts of film-forming auxiliary, 3 parts of leveling agent, 4 parts of drier, 0.05 parts of water reducing agent, 50 parts of cement, 40 parts of filling aids, and 3 parts of water.
  • the filling aid is a mixture of quartz sand powder, magnesium oxalate, and kaolin, and the mass ratio of quartz sand powder, magnesium oxalate, and kaolin in the mixture is 2:2:1.
  • a polymer cement-based waterproof coating in parts by weight, its raw material components include: 70 parts of acrylate emulsion, 10 parts of dispersant, 10 parts of film-forming auxiliary, 5 parts of leveling agent, 6 parts of drier, 0.2 parts of water reducing agent, 55 parts of cement, 60 parts of filling aids, and 7 parts of water.
  • the filling aid is a mixture of quartz sand powder, magnesium oxalate, and kaolin, and the mass ratio of quartz sand powder, magnesium oxalate, and kaolin in the mixture is 2:1:2.
  • the filling aid is a mixture of quartz sand powder and magnesium oxalate, and the mass ratio of quartz sand powder and magnesium oxalate in the mixture is 2:1.
  • the filling aid is a mixture of quartz sand powder and kaolin, and the mass ratio of quartz sand powder and kaolin in the mixture is 2:1.
  • the filling aid is a mixture of magnesium oxalate and kaolin, and the mass ratio of magnesium oxalate and kaolin in the mixture is 1:1.
  • the filling aid is a mixture of quartz sand powder, magnesium oxalate, and kaolin, and the mass ratio of quartz sand powder, magnesium oxalate, and kaolin in the mixture is 2:3:3.
  • the filling aid is a mixture of quartz sand powder, magnesium oxalate, and kaolin, and the mass ratio of quartz sand powder, magnesium oxalate, and kaolin in the mixture is 1:2:2.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Paints Or Removers (AREA)

Abstract

本发明提供一种聚合物水泥基防水涂料,属于防水涂料领域。按重量份计,其原料组分包括:丙烯酸酯乳液60‑70份、分散剂7‑10份、成膜助剂8‑1 0份、流平剂3 ‑5份、催干剂4 ‑6份、减水剂0.05‑0.2份、水泥50‑55份、填充助剂40‑60份、水3‑7份。其中,所述丙烯酸酯乳液中固含量为30‑60%。其中,所述减水剂为聚羧酸系减水剂、聚醚聚羧酸系减水剂中的任意一种。其中,填充助剂为石英砂粉、草酸镁、高岭土的混合物,所述混合物中石英砂粉、草酸镁、高岭土的质量比为2:1‑2:1‑2。本发明还提供了一种上述防水涂料的制备方法。本发明提供的制备方法简单易操作,防水涂料的原料价格低廉,机械性能、防水性能和耐候性好。

Description

一种聚合物水泥基防水涂料及其制备方法 技术领域
本发明涉及防水涂料领域 ,具体是涉及一种聚合物水泥基防水涂料及其制备方法。
背景技术
聚合物水泥基防水涂料,又称JS复合防水涂料。聚合物水泥基防水涂料基于有机聚合物乳液失水,而形成具有黏结性、连续性的弹性膜层,水泥吸收乳液中的水而硬化,柔性聚合物与水泥硬化体相互贯穿而牢固地粘结成一个坚固有弹性的防水层,柔性聚合物填充在水泥硬化体的空隙中,使水泥硬化体更加致密而富有弹性,涂膜具有较好的延伸率,水泥硬化体填充在聚合物相中,使其具有更好的户外耐久性和更好的基层适应性。因此,既有刚性,又有一定的韧性,并且具有更好的粘结性,涂层可以做的很薄,再加上这种防水涂料是一种环境友好型涂料,对环境不会造成影响,所以愈发收到人们青睐,成为近几年来防水涂料发展的热点。
技术问题
本发明的目的是提供一种聚合物水泥基防水涂料及其制备方法。
技术解决方案
为了实现上述目的,本发明提供的一种聚合物水泥基防水涂料,按重量份计,其原料组分包括:丙烯酸酯乳液60-70份、分散剂7-10份、成膜助剂8-10份、流平剂3-5份、催干剂4-6份、减水剂0 .05-0 .2份、水泥50-55份、填充助剂40-60份、水3-7份。
其中,所述丙烯酸酯乳液中固含量为30-60%。
其中,所述减水剂为聚羧酸系减水剂、聚醚聚羧酸系减水剂中的任意一种。
其中,填充助剂为石英砂粉、草酸镁、高岭土的混合物,所述混合物中石英砂粉、草酸镁、高岭土的质量比为2:1-2:1-2。
需要声明的是,其余原料均为市售常用材料。
本发明还提供了一种聚合物水泥基防水涂料的制备方法,具体步骤包括:
按重量份将丙烯酸酯乳液、分散剂、成膜助剂、流平剂、催干剂和减水剂倒入搅拌釜中搅拌,搅拌时间为6-7分钟,再加入水泥、填充助剂和水继续搅拌至均匀,即得成品。
有益效果
本发明制备的聚合物水泥基防水涂料机械性能好,具有较好的抗拉伸强度和粘结强度,耐候性能好,干结时间短。其原料价格低廉,制备工艺简单,对生产设备要求低,防水性能好。本发明中,利用石英砂粉、草酸镁、高岭土的协同作用,提升了防水涂料的机械性能。
本发明的实施方式
为了更清楚、完整的描述本发明的技术方案,以下通过具体实施例进一步详细说明本发明,应当理解,此处所描述的具体实施例仅用于解释本发明,并不用于限定本发明,可以在本发明权利限定的范围内进行各种改变。
实施例1
一种聚合物水泥基防水涂料,按重量份计,其原料组分包括:丙烯酸酯乳液65份、分散剂8份、成膜助剂9份、流平剂4份、催干剂5份、减水剂0.15份、水泥50份、填充助剂5份、水5份。
其中,所述丙烯酸酯乳液中固含量为30-60%。
其中,所述减水剂为聚羧酸系减水剂、聚醚聚羧酸系减水剂中的任意一种。
其中,填充助剂为石英砂粉、草酸镁、高岭土的混合物,所述混合物中石英砂粉、草酸镁、高岭土的质量比为2:1:1。
一种聚合物水泥基防水涂料的制备方法,具体步骤包括:
按重量份将丙烯酸酯乳液、分散剂、成膜助剂、流平剂、催干剂和减水剂倒入搅拌釜中搅拌,搅拌时间为6-7分钟,再加入水泥、填充助剂和水继续搅拌至均匀,即得成品。
实施例2
一种聚合物水泥基防水涂料,按重量份计,其原料组分包括:丙烯酸酯乳液60份、分散剂7份、成膜助剂8份、流平剂3份、催干剂4份、减水剂0.05份、水泥50份、填充助剂40份、水3份。
其中,填充助剂为石英砂粉、草酸镁、高岭土的混合物,所述混合物中石英砂粉、草酸镁、高岭土的质量比为2:2:1。
其余同实施例1。
实施例3
一种聚合物水泥基防水涂料,按重量份计,其原料组分包括:丙烯酸酯乳液70份、分散剂10份、成膜助剂10份、流平剂5份、催干剂6份、减水剂0.2份、水泥55份、填充助剂60份、水7份。
其中,填充助剂为石英砂粉、草酸镁、高岭土的混合物,所述混合物中石英砂粉、草酸镁、高岭土的质量比为2:1:2。
其余同实施例1。
对比例1
其中,填充助剂为石英砂粉、草酸镁的混合物,所述混合物中石英砂粉、草酸镁的质量比为2:1。
其余同实施例1。
对比例2
其中,填充助剂为石英砂粉、高岭土的混合物,所述混合物中石英砂粉、高岭土的质量比为2:1。
其余同实施例1。
对比例3
其中,填充助剂为草酸镁、高岭土的混合物,所述混合物中草酸镁、高岭土的质量比为1:1。
其余同实施例1。
对比例4
其中,填充助剂为石英砂粉、草酸镁、高岭土的混合物,所述混合物中石英砂粉、草酸镁、高岭土的质量比为2:3:3。
其余同实施例1。
对比例5
其中,填充助剂为石英砂粉、草酸镁、高岭土的混合物,所述混合物中石英砂粉、草酸镁、高岭土的质量比为1:2:2。
其余同实施例1。
根据GB/T 23445-2009对上述实施例和对比例制备的聚合物基防水涂料进行性能测试,结果如表1所示。
表1
Figure 352958dest_path_image001
由表1可知,实施例1-3制备的聚合物水泥基防水涂料机械性能好,具有较好的抗拉伸强度和粘结强度,耐候性能好,干结时间短,防水性能好。由对比例1-3与实施例1对比可知,石英砂粉、草酸镁、高岭土中的任意两种的组合相较于三种的混合,制备的防水涂料机械性能较差,并且防水性能、耐候性差。对比例4与实施例1对比可知,当石英砂粉、草酸镁、高岭土的质量比为2:3:3时,防水涂料的抗拉伸强度相差不大,粘结强度和延伸性能有所下降,但防水性能较差。对比例5与实施例1对比可知,当石英砂粉、草酸镁、高岭土的质量比为1:2:2时,防水涂料的抗拉伸强度相差不大,粘结强度和延伸性能有所下降,其耐候性有较大下降。
最后需要强调的是,以上所述仅为本发明的优选实施例,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种变化和更改,凡在本发明的精神和原则之内,所做的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。

Claims (6)

  1. 一种聚合物水泥基防水涂料,其特征在于,按重量份计,其原料组分包括:丙烯酸酯 乳液60-70份、分散剂7-10份、成膜助剂8-10份、流平剂3-5份、催干剂4-6份、减水剂0 .05- 0 .2份、水泥50-55份、填充助剂40-60份、水3-7份。
  2. 根据权利要求1所述的一种聚合物水泥基防水涂料,其特征在于:所述丙烯酸酯乳液 中固含量为30-60%。
  3. 根据权利要求1所述的一种聚合物水泥基防水涂料,其特征在于:所述减水剂为聚羧 酸系减水剂、聚醚聚羧酸系减水剂中的任意一种。
  4. 根据权利要求1所述的一种聚合物水泥基防水涂料,其特征在于:所述填充助剂为石 英砂粉、草酸镁、高岭土的混合物。
  5. 根据权利要求4所述的一种聚合物水泥基防水涂料,其特征在于:所述混合物中石英 砂粉、草酸镁、高岭土的质量比为2:1-2:1-2。
  6. 根据权利要求1至5任一项所述的一种聚合物水泥基防水涂料的制备方法,其特征在 于:具体步骤包括:
        按重量份将丙烯酸酯乳液、分散剂、成膜助剂、流平剂、催干剂和减水剂倒入搅拌釜中 搅拌,搅拌时间为6-7分钟,再加入水泥、填充助剂和水继续搅拌至均匀,即得成品。
PCT/CN2021/085248 2020-08-14 2021-04-02 一种聚合物水泥基防水涂料及其制备方法 WO2022033049A1 (zh)

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CN115521677A (zh) * 2022-05-26 2022-12-27 苏州百联节能科技股份有限公司 耐老化稳定型环保防水涂料
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CN115975462A (zh) * 2022-12-26 2023-04-18 广州全系新材料股份有限公司 一种建筑面复合纳米内成膜防水层及制备方法

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CN112011234A (zh) * 2020-08-14 2020-12-01 赣州市犇牛防水建材有限公司 一种聚合物水泥基防水涂料及其制备方法
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