WO2021145314A1 - 樹脂製容器の製造方法、製造装置および金型ユニット - Google Patents

樹脂製容器の製造方法、製造装置および金型ユニット Download PDF

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Publication number
WO2021145314A1
WO2021145314A1 PCT/JP2021/000722 JP2021000722W WO2021145314A1 WO 2021145314 A1 WO2021145314 A1 WO 2021145314A1 JP 2021000722 W JP2021000722 W JP 2021000722W WO 2021145314 A1 WO2021145314 A1 WO 2021145314A1
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WO
WIPO (PCT)
Prior art keywords
layer
mold
injection molding
unit
preform
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2021/000722
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English (en)
French (fr)
Japanese (ja)
Inventor
俊輝 大池
土屋 要一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissei ASB Machine Co Ltd
Original Assignee
Nissei ASB Machine Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissei ASB Machine Co Ltd filed Critical Nissei ASB Machine Co Ltd
Priority to KR1020227026997A priority Critical patent/KR20220124755A/ko
Priority to US17/792,257 priority patent/US12544955B2/en
Priority to JP2021571189A priority patent/JP7480186B2/ja
Priority to EP21741234.5A priority patent/EP4091793B1/en
Priority to CN202180009209.2A priority patent/CN114945454B/zh
Publication of WO2021145314A1 publication Critical patent/WO2021145314A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/02Combined blow-moulding and manufacture of the preform or the parison
    • B29C49/06Injection blow-moulding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/02Combined blow-moulding and manufacture of the preform or the parison
    • B29C49/06Injection blow-moulding
    • B29C49/061Injection blow-moulding with parison holding means displaceable between injection and blow stations
    • B29C49/062Injection blow-moulding with parison holding means displaceable between injection and blow stations following an arcuate path, e.g. rotary or oscillating-type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B11/00Making preforms
    • B29B11/06Making preforms by moulding the material
    • B29B11/08Injection moulding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/16Making multilayered or multicoloured articles
    • B29C45/1615The materials being injected at different moulding stations
    • B29C45/1625Injecting parison-like articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/16Making multilayered or multicoloured articles
    • B29C45/1684Injecting parison-like articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/071Preforms or parisons characterised by their configuration, e.g. geometry, dimensions or physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/22Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor using multilayered preforms or parisons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/02Combined blow-moulding and manufacture of the preform or the parison
    • B29C2049/023Combined blow-moulding and manufacture of the preform or the parison using inherent heat of the preform, i.e. 1 step blow moulding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/22Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor using multilayered preforms or parisons
    • B29C2049/222Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor using multilayered preforms or parisons only parts of the preforms or parisons are layered
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/07Preforms or parisons characterised by their configuration
    • B29C2949/0715Preforms or parisons characterised by their configuration the preform having one end closed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/07Preforms or parisons characterised by their configuration
    • B29C2949/074Preforms or parisons characterised by their configuration having ribs or protrusions
    • B29C2949/0741Preforms or parisons characterised by their configuration having ribs or protrusions longitudinal, e.g. from top to bottom
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/07Preforms or parisons characterised by their configuration
    • B29C2949/076Preforms or parisons characterised by their configuration characterised by the shape
    • B29C2949/0768Preforms or parisons characterised by their configuration characterised by the shape characterised by the shape of specific parts of preform
    • B29C2949/0769Preforms or parisons characterised by their configuration characterised by the shape characterised by the shape of specific parts of preform characterised by the lip, i.e. very top of preform neck
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/07Preforms or parisons characterised by their configuration
    • B29C2949/076Preforms or parisons characterised by their configuration characterised by the shape
    • B29C2949/0768Preforms or parisons characterised by their configuration characterised by the shape characterised by the shape of specific parts of preform
    • B29C2949/077Preforms or parisons characterised by their configuration characterised by the shape characterised by the shape of specific parts of preform characterised by the neck
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/07Preforms or parisons characterised by their configuration
    • B29C2949/076Preforms or parisons characterised by their configuration characterised by the shape
    • B29C2949/0768Preforms or parisons characterised by their configuration characterised by the shape characterised by the shape of specific parts of preform
    • B29C2949/078Preforms or parisons characterised by their configuration characterised by the shape characterised by the shape of specific parts of preform characterised by the bottom
    • B29C2949/0781Preforms or parisons characterised by their configuration characterised by the shape characterised by the shape of specific parts of preform characterised by the bottom characterised by the sprue, i.e. injection mark
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/20Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer
    • B29C2949/22Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer at neck portion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/30Preforms or parisons made of several components
    • B29C2949/3006Preforms or parisons made of several components having tangentially different components within one layer, e.g. longitudinal stripes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/30Preforms or parisons made of several components
    • B29C2949/3032Preforms or parisons made of several components having components being injected
    • B29C2949/3034Preforms or parisons made of several components having components being injected having two or more components being injected
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/30Preforms or parisons made of several components
    • B29C2949/3086Interaction between two or more components, e.g. type of or lack of bonding
    • B29C2949/3088Bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/16Making multilayered or multicoloured articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/002Coloured
    • B29K2995/0021Multi-coloured
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/712Containers; Packaging elements or accessories, Packages
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/712Containers; Packaging elements or accessories, Packages
    • B29L2031/7158Bottles
    • B29L2031/716Bottles of the wide mouth type, i.e. the diameters of the bottle opening and its body are substantially identical

Definitions

  • a hot parison type blow molding method As one of the methods for manufacturing resin containers, a hot parison type blow molding method has been conventionally known.
  • the resin container is blow molded by utilizing the heat held during the injection molding of the preform. Therefore, it is advantageous in that it is possible to manufacture a resin container which is more diverse and has an excellent aesthetic appearance as compared with the cold parison type.
  • Patent Document 1 it is actually very difficult to precisely control the width, position, and shape of the intermediate layer by simultaneously injecting a plurality of types of resins, and the configuration of the injection molding apparatus. Is also complicated and expensive. Therefore, the technique of Patent Document 1 is not necessarily suitable for the application of stably forming a vertical stripe color pattern on a container after blow molding by internal coloring.
  • a plurality of grooves 11a extending in the axial direction are formed on the outer peripheral side of the first layer 11, respectively.
  • the grooves 11a of the first layer 11 are arranged at equal intervals in the circumferential direction, so that the cross section of the first layer 11 shown in FIG. 1B has an external gear shape.
  • a second layer 12 is formed in each groove 11a on the outer peripheral side of the first layer 11 so as to fill the space of the groove 11a.
  • the body 22 of these containers 20 is formed so that color patterns extending along the axial direction are striped in the circumferential direction.
  • the blow molding apparatus 30 includes a first injection molding unit 31, a second injection molding unit 32, a temperature adjusting unit 33, a blow molding unit 34, a take-out unit 35, and a transport mechanism 36.
  • the first injection molding unit 31, the second injection molding unit 32, the temperature adjusting unit 33, the blow molding unit 34, and the take-out unit 35 are arranged at positions rotated by a predetermined angle (for example, 72 degrees) about the transport mechanism 36. There is.
  • the second injection molding unit 32a accommodates the first layer 11 of the preform 10 injection molded by the first injection molding unit 31a.
  • FIG. 4B when the second injection molding portion 32a is closed, a mold space is formed between the inner surface of the cavity mold 50 and the inner surface of the cavity mold 50 from the body portion to the bottom portion on the outer peripheral side of the first layer 11. Will be done.
  • the core mold 51 shown in FIG. 4B is inserted into the inner layer (first layer 11) of the preform 10 and holds the inner layer from the inside.
  • the cavity type 50 faces the outer peripheral side of the first layer 11, and the cavity type 50 holds the shape of the first layer 11 from the outer peripheral side. Therefore, even if the second resin material comes into contact with the first layer 11, the thermal deformation of the first layer 11 can be suppressed.
  • the preform 10 of the second example is molded as described above, the second layer 12 can be formed on the inner peripheral side of the first layer 11.
  • the first layer 11 in the second injection molding process has the heat retained during injection molding and is in a state of being relatively easily deformed. Therefore, when the second resin material is injected into the mold space, the air existing in the mold space is extruded upward while slightly elastically deforming the first layer 11 and exhausted. Therefore, since air pools are unlikely to occur during the molding of the second layer 12, molding defects of the preform 10 are suppressed.
  • Step S105 Container removal step
  • the blow cavity mold is opened.
  • the container 20 can be moved from the blow molding unit 34.
  • the transfer plate of the transfer mechanism 36 rotates by a predetermined angle, and the container 20 is transferred to the take-out unit 35.
  • the neck portion 21 of the container 20 is released from the neck mold 36a, and the container 20 is taken out to the outside of the blow molding apparatus 30.
  • the body of the container 20 corresponding to the ridge 11c or the groove 11b is the remaining amount of the contents. It is also a part where you can check.
  • the transfer mechanism 36 of the blow molding apparatus 30a includes a transfer plate 36b that rotates about an axis in the direction perpendicular to the paper surface of FIG.
  • the transfer plate 36b is a neck-shaped preform 10 (or container 20) whose neck is held, and is a first injection molding unit 31, a temperature adjusting unit 39, a second injection molding unit 32, a temperature adjusting unit 33, and a blow molding unit. 34 and the take-out section 35 are conveyed in this order.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Geometry (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Moulding By Coating Moulds (AREA)
  • Auxiliary Devices For And Details Of Packaging Control (AREA)
PCT/JP2021/000722 2020-01-14 2021-01-12 樹脂製容器の製造方法、製造装置および金型ユニット Ceased WO2021145314A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
KR1020227026997A KR20220124755A (ko) 2020-01-14 2021-01-12 수지제 용기의 제조 방법, 제조 장치 및 금형 유닛
US17/792,257 US12544955B2 (en) 2020-01-14 2021-01-12 Resin-made container manufacturing method, manufacturing device, and metal mold unit
JP2021571189A JP7480186B2 (ja) 2020-01-14 2021-01-12 樹脂製容器の製造方法、製造装置および金型ユニット
EP21741234.5A EP4091793B1 (en) 2020-01-14 2021-01-12 Resin-made container manufacturing method, manufacturing device, and metal mold unit
CN202180009209.2A CN114945454B (zh) 2020-01-14 2021-01-12 树脂制容器的制造方法、制造装置以及模具组件

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2020003915 2020-01-14
JP2020-003915 2020-01-14

Publications (1)

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WO2021145314A1 true WO2021145314A1 (ja) 2021-07-22

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PCT/JP2021/000722 Ceased WO2021145314A1 (ja) 2020-01-14 2021-01-12 樹脂製容器の製造方法、製造装置および金型ユニット

Country Status (6)

Country Link
US (1) US12544955B2 (https=)
EP (1) EP4091793B1 (https=)
JP (1) JP7480186B2 (https=)
KR (1) KR20220124755A (https=)
CN (1) CN114945454B (https=)
WO (1) WO2021145314A1 (https=)

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US12544955B2 (en) 2026-02-10
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