WO2021132778A1 - 향상된 내구성을 갖는 에어백 원단 및 그 제조방법 - Google Patents
향상된 내구성을 갖는 에어백 원단 및 그 제조방법 Download PDFInfo
- Publication number
- WO2021132778A1 WO2021132778A1 PCT/KR2019/018637 KR2019018637W WO2021132778A1 WO 2021132778 A1 WO2021132778 A1 WO 2021132778A1 KR 2019018637 W KR2019018637 W KR 2019018637W WO 2021132778 A1 WO2021132778 A1 WO 2021132778A1
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- WO
- WIPO (PCT)
- Prior art keywords
- airbag fabric
- thickener
- coating layer
- airbag
- coating solution
- Prior art date
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- 239000004744 fabric Substances 0.000 title claims abstract description 79
- 238000000034 method Methods 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 238000000576 coating method Methods 0.000 claims abstract description 66
- 239000011248 coating agent Substances 0.000 claims abstract description 60
- 239000011247 coating layer Substances 0.000 claims abstract description 55
- 239000002562 thickening agent Substances 0.000 claims abstract description 50
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 44
- 239000000758 substrate Substances 0.000 claims abstract description 39
- 239000004814 polyurethane Substances 0.000 claims abstract description 24
- 229920002635 polyurethane Polymers 0.000 claims abstract description 23
- 238000001035 drying Methods 0.000 claims abstract description 10
- 239000004753 textile Substances 0.000 claims abstract description 10
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 9
- 239000000835 fiber Substances 0.000 claims description 73
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 24
- SDXAWLJRERMRKF-UHFFFAOYSA-N 3,5-dimethyl-1h-pyrazole Chemical group CC=1C=C(C)NN=1 SDXAWLJRERMRKF-UHFFFAOYSA-N 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 22
- WHIVNJATOVLWBW-UHFFFAOYSA-N n-butan-2-ylidenehydroxylamine Chemical compound CCC(C)=NO WHIVNJATOVLWBW-UHFFFAOYSA-N 0.000 claims description 21
- 230000000903 blocking effect Effects 0.000 claims description 20
- 230000035515 penetration Effects 0.000 claims description 15
- 229920001228 polyisocyanate Polymers 0.000 claims description 9
- 239000005056 polyisocyanate Substances 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 claims description 7
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 7
- 239000010410 layer Substances 0.000 claims description 7
- 230000032683 aging Effects 0.000 claims description 6
- 239000004760 aramid Substances 0.000 claims description 6
- 229920003235 aromatic polyamide Polymers 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 6
- 239000004953 Aliphatic polyamide Substances 0.000 claims description 4
- 229920003231 aliphatic polyamide Polymers 0.000 claims description 4
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 229920005862 polyol Polymers 0.000 description 12
- 150000003077 polyols Chemical class 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 6
- 239000003063 flame retardant Substances 0.000 description 6
- 239000011527 polyurethane coating Substances 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 229920001084 poly(chloroprene) Polymers 0.000 description 5
- 238000009941 weaving Methods 0.000 description 5
- -1 acrylic ester Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 239000002981 blocking agent Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000012748 slip agent Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 238000010345 tape casting Methods 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000001718 carbodiimides Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
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- 229920000570 polyether Polymers 0.000 description 2
- 238000009958 sewing Methods 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000013585 weight reducing agent Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
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- 230000000149 penetrating effect Effects 0.000 description 1
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- 238000009991 scouring Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R21/00—Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
- B60R21/02—Occupant safety arrangements or fittings, e.g. crash pads
- B60R21/16—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags
- B60R21/23—Inflatable members
- B60R21/235—Inflatable members characterised by their material
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R21/00—Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
- B60R21/02—Occupant safety arrangements or fittings, e.g. crash pads
- B60R21/16—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags
- B60R21/23—Inflatable members
- B60R21/235—Inflatable members characterised by their material
- B60R2021/23504—Inflatable members characterised by their material characterised by material
- B60R2021/23509—Fabric
- B60R2021/23514—Fabric coated fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R21/00—Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
- B60R21/02—Occupant safety arrangements or fittings, e.g. crash pads
- B60R21/16—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags
- B60R21/23—Inflatable members
- B60R21/235—Inflatable members characterised by their material
- B60R2021/23504—Inflatable members characterised by their material characterised by material
- B60R2021/23519—Resin
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06N2203/068—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2205/00—Condition, form or state of the materials
- D06N2205/20—Cured materials, e.g. vulcanised, cross-linked
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/26—Vehicles, transportation
- D06N2211/268—Airbags
Definitions
- the present invention relates to an airbag fabric and a method for manufacturing the same, and more particularly, to an airbag fabric having excellent airtightness and improved durability at the same time, and a method for manufacturing such an airbag fabric with high productivity.
- the airbag When the impact sensor senses an impact applied to the vehicle during a collision or overturn of a vehicle traveling at a speed higher than a predetermined speed, the airbag is inflated and deployed to protect the driver and passengers of the vehicle from accidents.
- the airbag fabric further includes a coating layer for increasing air tightness of the fabric in addition to the textile substrate.
- an air-part airbag is manufactured by a cut and sewing method of a fiber base woven in a plain weave or a basket weave, or a joint formed by the cutting and sewing method. It is manufactured by a joint-sealing method that treats (seam) with a sealant, or uses a One Piece Woven (OPW) type of fiber base that forms an expanded portion of a double-layer structure in the weaving process is manufactured by
- the coating layer formed on the fiber substrate is to provide airtightness required for the airbag.
- the side curtain airbag has to be maintained in an inflated form for a relatively long time (for example, 6 seconds) to protect the occupants in the event of a roll-over, so it is relatively relatively compared to other types of airbags. It should have a higher degree of confidentiality.
- Neoprene rubber was initially used as the main material of the coating layer.
- an excessively large amount of neoprene rubber was required to be coated. Therefore, forming the coating layer with neoprene rubber is not preferable in terms of production cost and packability of the airbag.
- the coating layer is formed of neoprene rubber, the airbag becomes too heavy, resulting in deterioration of vehicle fuel efficiency.
- silicone resins or polyurethane resins have recently replaced neoprene rubber.
- silicone resins or polyurethane resins have recently replaced neoprene rubber.
- restrictions are applied to the use of volatile organic solvents due to environmental problems and cost problems, interest in aqueous polyurethane dispersion coating layers is increasing.
- water-dispersible polyurethane can provide an airbag with excellent internal pressure retention characteristics even with a relatively small coating amount compared to silicone resins.
- the water-dispersible polyurethane coating layer has a relatively low adhesive strength with the fiber substrate, and thus there is a risk that the coating layer may be peeled off from the fiber substrate when stored in a vehicle for a long time. Such peeling of the coating layer makes it impossible for the side curtain airbag to be maintained in an inflated form in the event of a vehicle rollover accident.
- the airbag manufacturer is burdened with completing the coating process within about two to three hours after adding the crosslinking agent to the coating solution. That is, if the coating process is delayed even a little, there is a risk of wastage of materials and reduced productivity.
- the coating layer is formed with a water-dispersible polyurethane coating solution to which a crosslinking agent is added, the durability of the airbag is not improved as much as expected.
- the present invention relates to an airbag fabric and a method for manufacturing the same that can satisfy the requirements of the related technical field as described above.
- One aspect of the invention is to provide an airbag fabric having excellent airtightness and improved durability at the same time.
- Another aspect of the present invention is to provide a method for manufacturing an airbag fabric having excellent airtightness and improved durability without wasting materials with high productivity.
- a fiber substrate textile substrate
- a coating layer on at least one surface of the fiber substrate
- the coating layer includes a polyurethane resin, a crosslinking agent, and a hydrophilic thickener, and the crosslinking agent is a compound having a blocked active group, an airbag fabric is provided.
- the penetration rate of the coating layer into the fiber substrate as defined by Equation 1 below may be 10 to 50%.
- D is the maximum depth through which the coating layer penetrates into the fiber base
- T is the thickness of the fiber base
- the fiber base may be a fabric including warps and wefts, and after aging for 408 hours under a temperature of 70 ⁇ 2° C. and a relative humidity of 95 ⁇ 2%, the airbag fabric measured according to ISO 5981 Scrub resistance can be over 1,000 strokes in both warp and weft directions.
- the hydrophilic thickener may be a non-associative thickener.
- the hydrophilic thickener may be a non-Newtonian pseudoplastic acrylic thickener.
- the fiber base may be a One Piece Woven (OPW) type fabric including a plurality of warps and wefts, and each of the warps and the wefts may have a fineness of 210 to 1500 denier, and , the density of the warp yarns and the density of the weft yarns may be from 40 th/inch to 80 th/inch based on one layer of the chamber area of the fabric, wherein each of the warps and the weft yarns is an aliphatic polyamide , aromatic polyamides, polyesters, and polyolefins.
- OHPW One Piece Woven
- the blocked active group may include a blocking component that dissociates from the active group at 100° C. or higher.
- the active group may be an isocyanate group or a carbodiimide group.
- the blocking component may be 3,5-dimethyl pyrazole (DMP), caprolactam ( ⁇ -caprolactame), or methylethylketoxime.
- the crosslinking agent is 3,5-dimethyl pyrazole (DMP), caprolactam ( ⁇ -caprolactame) and at least one blocking component selected from the group consisting of methylethylketoxime (methylethylketoxime) is combined It may be a polyisocyanate compound or a polycarbodiimide compound.
- the step of preparing a fiber substrate; and forming a coating layer on at least one surface of the fiber base includes preparing a coating solution by adding a crosslinking agent and a hydrophilic thickener to the water-dispersed polyurethane; applying the coating solution on at least one surface of the fiber substrate; drying the fiber substrate to which the coating solution is applied; and heat-treating the dried fiber base, wherein the crosslinking agent is a compound having a blocked active group.
- the blocked active group may include a blocking component that dissociates from the active group at 100° C. or higher.
- the active group may be an isocyanate group or a carbodiimide group.
- the blocking component may be 3,5-dimethyl pyrazole (DMP), caprolactam ( ⁇ -caprolactame), or methylethylketoxime.
- the crosslinking agent is 3,5-dimethyl pyrazole (DMP), caprolactam ( ⁇ -caprolactame) and at least one blocking component selected from the group consisting of methylethylketoxime (methylethylketoxime) is combined It may be a polyisocyanate compound or a polycarbodiimide compound.
- the thickener may be a non-associative thickener.
- the thickener may be a non-Newtonian pseudoplastic acrylic thickener.
- the thickener may have a viscosity of 25,000 to 60,000 cps, and the coating solution may have a viscosity of 6,000 to 30,000 cps.
- the amount of the coating solution applied on at least one surface of the fiber base may be 15 to 50 gsm.
- the drying step may be performed by raising the temperature in a range between 80°C and 150°C, and the heat treatment step may be performed at a temperature exceeding 150°C.
- FIG. 1 is a cross-sectional view of an airbag fabric according to an embodiment of the present invention.
- the airbag fabric 100 includes a fiber base 110 and a coating layer 120 .
- the fabric 100 of the invention is for a side curtain airbag
- the fiber base 110 is a one-piece weaving (OPW) type including warps 111 and weft yarns 112 .
- OPW one-piece weaving
- the fineness of the warp and weft yarns 111 and 112 should be 210 denier or more in order to maintain excellent mechanical properties (eg, strength) in terms of absorption performance capable of absorbing deployment energy of high temperature-high pressure when the airbag is deployed.
- the fineness of the warp and weft yarns 111 and 112 is preferably 1500 denier or less.
- each of the warp weft yarns 111 and 112 is preferably a multifilament including 72 or more filaments 111a and 112a.
- Each of the warp yarns 111 and the weft yarns 112 is an aliphatic polyamide (eg, nylon 6 or nylon 66), an aromatic polyamide (eg, aramid), a polyester (eg, PET), and polyolefin (eg, PE or PP).
- aliphatic polyamide eg, nylon 6 or nylon 66
- aromatic polyamide eg, aramid
- polyester eg, PET
- polyolefin eg, PE or PP
- the coating layer 120 on at least one surface of the fiber base 110 may include a polyurethane resin, a crosslinking agent, and a hydrophilic thickener.
- the polyurethane resin of the present invention formed by bonding a polyol and an isocyanate to a urethane bond may include at least one of a polycarbonate-based polyol, a polyether-based polyol, a polyester-based polyol, and a silicone-based polyol as a polyol component.
- the polyurethane resin may be a water dispersible (water dispersible) polyurethane resin.
- the thickener improves the uniformity of the coating and the efficiency of the coating process by imparting a viscosity above a certain level to the coating solution used for forming the coating layer 120 .
- the thickener is a hydrophilic thickener. Since the hydrophilic thickener is contained as an additive in the coating solution containing water-dispersed polyurethane as a main component, when water, the medium of the coating solution, penetrates into the fiber base 110 by the wetting effect, the polyurethane particles are formed in the fiber base 110 ) can penetrate better and more uniformly into the interior.
- the hydrophilic thickener may be a non-associative thickener that swells water, which is the medium of the coating solution, and more preferably a low shear type, in which viscosity deformation occurs when a shear force is applied. It may be a nonnewtonian pseudoplastic acrylic thickener.
- the thickener may be a hydrophilic non-associated thickener including a (meth)acryl functional group, and the thickener may be a liquid containing about 5 to 20% by weight of solid content.
- the penetration rate of the coating layer 120 into the fiber base 110 may be 10 to 50%, preferably 25 to 40%.
- the penetration rate may be defined by Equation 1 below.
- D is the maximum depth at which the coating layer 120 penetrates into the fiber base 110
- T is the thickness of the fiber base 110 . D and T may be measured through an SEM photograph of the cross section of the airbag fabric 100 .
- the airbag fabric 100 may have excellent flexibility, but the adhesive force between the fiber base 110 and the coating layer 120 is low, so that when stored in a car for a long time, they will be separated from each other. There is a risk. Such peeling of the coating layer makes it impossible for the side curtain airbag to be maintained in an inflated form in the event of a vehicle rollover accident.
- the penetration rate of the coating layer 120 is 10% or more
- aging is performed for 408 hours at a temperature of 70 ⁇ 2° C. and a relative humidity of 95 ⁇ 2%, and then the measured according to the ISO 5981 standard.
- the scrub resistance of the airbag fabric 100 is 1,000 strokes or more in both the warp direction and the weft direction, which means that the coating layer 120 is peeled off from the fiber base 110 only after 1,000 strokes or more.
- Such improvement in scrub resistance of the airbag fabric 100 is due to the anchoring effect of the coating layer 120 formed by penetrating deeply into the fiber base 110 .
- the penetration rate of the coating layer 120 exceeds 50%, the stiffness of the airbag fabric 100 is sharply increased (that is, the flexibility is rapidly reduced), and the foldability, tear strength, and airbag accommodation properties are deteriorated. .
- the coating layer 120 of the present invention is a wetting agent (for example, an acrylic ester-based wetting agent) that further facilitates uniform penetration of the polyurethane particles into the fiber base 110, and the flame retardant of the airbag fabric 100 It may further include a flame retardant (eg, a non-halogen phosphorus flame retardant), an anti-blocking agent for improving the surface properties of the airbag fabric 100, and/or a slip agent for improving the have.
- a wetting agent for example, an acrylic ester-based wetting agent
- a flame retardant eg, a non-halogen phosphorus flame retardant
- an anti-blocking agent for improving the surface properties of the airbag fabric 100
- a slip agent for improving the have.
- the crosslinking agent may be a compound having a blocked active group.
- the blocked active group may include a blocking component that dissociates from the active group at 100° C. or higher.
- the active group may be an isocyanate group or a carbodiimide group.
- the blocking component may be 3,5-dimethyl pyrazole (DMP), caprolactam ( ⁇ -caprolactame), or methylethylketoxime.
- the crosslinking agent is 3,5-dimethyl pyrazole (DMP), caprolactam ( ⁇ -caprolactame) and at least one blocking component selected from the group consisting of methylethylketoxime (methylethylketoxime) is combined It may be a polyisocyanate compound or a polycarbodiimide compound.
- the polyisocyanate compound is a compound having two or more NCO functional groups, and aliphatic, cycloaliphatic, aromatic, araliphatic polyisocyanate or a mixture thereof may be used.
- the polycarbodiimide compound a compound having a carbodiimide equivalent weight of 200 to 600 may be used.
- the carbodiimide equivalent may mean the weight of the polycarbodiimide-based crosslinking agent with respect to the number of moles of carbodiimide groups of the polycarbodiimide-based crosslinking agent.
- the polycarbodiimide-based crosslinking agent has an advantage in that it has a long pot lift and excellent crosslinking efficiency.
- Such polycarbodiimide-based crosslinking agents include Nisshinbo Chemical Inc. Carbodilite V-02, SV-02, V-02-L2, V-04, E-01, E-02, E-03A or E-05 provided by the company can be used.
- the method of the invention includes the steps of preparing the fiber base 110 and forming the coating layer 120 on at least one surface of the fiber base 110 .
- the fiber base 110 may be a one-piece weaving (OPW) type fabric including warps 111 and weft yarns 112 , the density of the warps 111 and the weft yarns 112 .
- the density of each may be 40 to 80 th/inch based on one layer of the chamber area of the fabric.
- Each of the warp weft yarns 111 and 112 includes 72 or more filaments 111a and 112a and may be a multifilament having a total fineness of 210 to 1500 denier, and an aliphatic polyamide (eg, nylon 6 or nylon). 66), aromatic polyamides (eg aramid), polyesters (eg PET), and polyolefins (eg PE or PP).
- aliphatic polyamide eg, nylon 6 or nylon
- 66 aromatic polyamides
- polyesters eg PET
- polyolefins eg PE or PP
- the yarn is given an emulsion or a size before weaving. Therefore, before forming the coating layer 120 on at least one surface of the fiber base 110, in order to remove the oil or size agent from the fiber base 110, the step of refining the fiber base 110 and washing the refined fiber base with water may be further performed.
- a coating solution is first prepared.
- the coating solution may be prepared by adding a crosslinking agent for strengthening the adhesion between the fiber base 110 and the coating layer 120 and a thickener for controlling the viscosity of the coating solution to the water-dispersed polyurethane.
- the water-dispersible polyurethane resin of the present invention formed by bonding a polyol and an isocyanate to a urethane bond may include one or more of a polycarbonate-based polyol, a polyether-based polyol, a polyester-based polyol, and a silicone-based polyol as a polyol component.
- the airbag manufacturer is burdened with completing the coating process within about two to three hours after adding the crosslinking agent. That is, if the coating process is delayed even a little, there is a risk of wastage of materials and reduced productivity.
- the crosslinking agent has a blocked active group. Since the active groups of the cross-linking agent are blocked with components that dissociate at high temperatures (e.g., 100° C. or higher), a significant amount of time [i.e., significant pot life] after the addition of the cross-linking agent to the water-dispersed polyurethane begins curing at room temperature lifetime)]. Therefore, according to the present invention, after adding the crosslinking agent to the water-dispersed polyurethane, a significant spare time (eg, about 48 hours or more) can be secured before the coating solution is actually applied on the fiber base 110 .
- a significant spare time eg, about 48 hours or more
- the active group may be an isocyanate group or a carbodiimide group.
- the blocking component can only be dissociated from the active group at 100 ° C. or higher, and can be completely vaporized at a temperature exceeding 150 ° C. (that is, completely removed during the heat treatment process for curing the coating solution) may be any compound, for example, 3,5-dimethyl pyrazole (DMP), caprolactam ( ⁇ -caprolactame), or methylethylketoxime (methylethylketoxime) can be any compound, for example, 3,5-dimethyl pyrazole (DMP), caprolactam ( ⁇ -caprolactame), or methylethylketoxime (methylethylketoxime) can be any compound, for example, 3,5-dimethyl pyrazole (DMP), caprolactam ( ⁇ -caprolactame), or methylethylketoxime (methylethylketoxime) can be any compound, for example, 3,5-dimethyl pyrazole (DMP), caprolactam ( ⁇ -caprolactame), or
- the crosslinking agent is at least one selected from the group consisting of 3,5-dimethyl pyrazole (DMP), caprolactam ( ⁇ -caprolactame) and methylethylketoxime (methylethylketoxime) blocking
- DMP 3,5-dimethyl pyrazole
- caprolactam ⁇ -caprolactame
- methylethylketoxime methylethylketoxime blocking
- the component may be a bound polyisocyanate compound or a polycarbodiimide compound.
- the coating solution may include 1 to 5 parts by weight of the crosslinking agent based on 100 parts by weight of the aqueous dispersion polyurethane.
- the thickener of the present invention added to the water-dispersed polyurethane is a hydrophilic thickener, and when water, which is the medium of the coating solution, penetrates into the fiber base 110 by the wetting effect, the polyurethane particles are formed in the fiber base 110 ) to allow better and more uniform penetration into the interior.
- the hydrophilic thickener may be a non-associative thickener that swells water, which is the medium of the coating solution, and is more preferably a low shear type and has a viscosity when a shear force is applied by the coating knife head. It may be a non-Newtonian pseudoplastic acrylic thickener that deforms.
- the thickener may be a hydrophilic non-associated thickener including a (meth)acryl functional group, and the thickener may be a liquid containing about 5 to 20% by weight of solid content.
- the hydrophilic additive may have a viscosity of 25,000 to 60,000 cps, and may be added to the water-dispersed polyurethane in an amount capable of making the viscosity of the coating solution to 6,000 to 30,000 cps.
- the viscosity of the coating solution exceeds 30,000 cps, it is difficult to adjust the coating solution application amount to 50 gsm or less (the reason for adjusting the coating solution application amount to 50 gsm or less will be described later), an excess of thickener is required, and homogeneity due to high viscosity ( homogeneity) is lowered, and it is difficult for the coating solution to penetrate into the fiber substrate 110 .
- the viscosity of the coating solution is less than 6,000 cps, it is difficult to apply a sufficient coating solution, it is difficult to express desired mechanical properties in the coating layer 120, and the coating solution penetrates too deeply into the fiber substrate 110 due to the capillary phenomenon. The foldability and storage property of the airbag may be deteriorated.
- the viscosity can be measured with a rotary viscometer, for example, with a Brookfield DV2T, spindle LV-3 (63) or LV-4 (64), at a speed of 10 rpm.
- a wetting agent for example, an acrylic ester-based wetting agent
- a flame retardant for improving the flame retardancy of the airbag fabric 100 for example, , a halogen-free phosphorus-based flame retardant
- an anti-blocking agent for improving the surface properties of the airbag fabric 100 for example, a slip agent
- the coating solution contains 30 to 60% by weight of solids, and 1 to 5 parts by weight of a crosslinking agent, 3 to 10 parts by weight of a thickener, 5 to 20 parts by weight of a flame retardant, and 0.1 to 5 parts by weight of 100 parts by weight of water-dispersed polyurethane It can be prepared by adding 2 parts by weight of other additives (silicone-based anti-blocking agent and/or slip agent).
- the coating solution is applied on at least one surface of the fiber base 110 .
- the coating solution may be uniformly coated on the fiber base 110 by a knife coating method or a roll coating method.
- a knife coating method may be preferable in that it is easy to control the amount of application and uniform coating is possible.
- the amount of the coating solution applied on at least one surface of the fiber base may be 15 to 50 gsm.
- the application amount is less than 15 gsm, the pressure retention of the airbag is lowered, and when the application amount exceeds 50 gsm, the stiffness of the airbag fabric 100 is sharply increased (that is, the flexibility is sharply reduced), so that the foldability and the airbag The storage performance deteriorates and the weight reduction of the airbag cannot be realized.
- the fiber base 110 to which the coating solution is applied is dried.
- the fiber substrate 110 may be dried in a tenter oven.
- the drying process may be performed by raising the temperature in a range between 80°C and 150°C.
- the dried fiber base is heat-treated.
- the heat treatment step may be performed at a temperature exceeding 150 °C, for example, 155 to 200 °C for 120 to 350 seconds.
- the blocking component dissociated from the active group is vaporized and completely removed during the heat treatment process.
- a cooling process for lowering the temperature of the airbag fabric 100 may be further performed using, for example, a cooling cylinder (not shown), and the cooled fabric 100 is wound around a winder (not shown).
- An OPW fiber base (warp density: 57th/inch, weft density: 49th/inch) was prepared using polyethylene terephthalate (PET) yarn.
- PET polyethylene terephthalate
- the OPW fiber substrate was dried after sequentially passing through a scouring tank and a water washing tank.
- a crosslinking agent IMPRAFIX® 2794 (Covestro) [a polyisocyanate blocked with DMP (3,5-dimethyl pyrazole)] and 5 parts by weight of a hydrophilic non-associative acrylic thickener Borchi® Gel A-LA in 100 parts by weight of an aqueous dispersion polyurethane (Borchers) was added to obtain a coating solution having a viscosity of 15,000 cps.
- the coating solution was uniformly applied in an amount of 30 gsm on the fiber substrate using a knife coating method.
- the drying process was performed by raising the temperature in a range between 80°C and 150°C. After that, the top coating was separately treated to continuously impart slip properties and blocking resistance to the coating surface, and the top coating applied at this time was a silicone-based top coating composition containing talc, which was transferred to the surface of the base coating layer using a gravure roller, Drying is carried out at a temperature of about 150 degrees. After that, the airbag fabric was completed by additionally performing a heat treatment process at 180°C.
- An airbag fabric was obtained in the same manner as in Example 1, except that the coating solution did not contain the crosslinking agent.
- a fiber substrate and a coating solution were prepared in the same manner as in Example 1, except that a crosslinking agent DESMODUR® N3900 (Covestro) in which the isocyanate group was not blocked was used. Then, this coating solution was tried to be applied on the fiber substrate in the same manner as in Example 1 (that is, after 24 hours had elapsed since the addition of the crosslinking agent to the water-dispersed polyurethane, the coating solution was attempted to be applied on the fiber substrate), but the coating solution It was impossible to apply because the curing of the resin had already progressed considerably.
- a crosslinking agent DESMODUR® N3900 Covestro
- An airbag fabric was obtained in the same manner as in Example 1, except that the hydrophobic PU thickener Borchi® Gel L75N (Borchers) was used instead of the hydrophilic non-associative acrylic thickener.
- the fabric sample was cut in a direction parallel to the weft yarn. Then, after taking an SEM picture of the cross-section, the maximum depth (D) that the coating layer penetrated into the fiber substrate and the thickness (T) of the fiber substrate were measured, respectively, and using the measured values, according to Equation 1 below The coating layer penetration rate of each fabric was calculated.
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Abstract
Description
Claims (20)
- 섬유 기재(textile substrate); 및상기 섬유 기재의 적어도 일 면 상의 코팅층(coating layer);을 포함하며,상기 코팅층은 폴리우레탄 수지, 가교제, 및 친수성 증점제(hydrophilic thickener)를 포함하고,상기 가교제는 블로킹된 활성기(blocked active group)를 갖는 화합물인에어백 원단.
- 제1항에 있어서,상기 섬유 기재는 경사들 및 위사들을 포함하는 직물이고,70±2 ℃의 온도 및 95±2 %의 상대습도 하에 408 시간 동안 에이징을 수행한 후 ISO 5981 규격에 따라 측정된 상기 에어백 원단의 내스크럽성은 경사방향 및 위사방향 모두에서 1,000 strokes 이상인,에어백 원단.
- 제1항에 있어서,상기 친수성 증점제는 비회합성(non-associative) 증점제인,에어백 원단.
- 제4항에 있어서,상기 친수성 증점제는 비뉴턴형(non-newtonian)의 의가소성(pseudoplastic) 아크릴계 증점제인,에어백 원단.
- 제1항에 있어서,상기 블로킹된 활성기는 100 ℃ 이상에서 활성기로부터 해리되는 블로킹 성분을 포함하는, 에어백 원단.
- 제1항에 있어서,상기 활성기는 이소시아네이트기(isocyanate group) 또는 카르보디이미드기(carbodiimide group)인, 에어백 원단.
- 제1항 또는 제6항에 있어서,상기 블로킹 성분은 3,5-디메틸 피라졸(3,5-dimethyl pyrazole)(DMP), 카프로락탐(ε-caprolactame), 또는 메틸에틸케톡심(methylethylketoxime)인, 에어백 원단.
- 제1항에 있어서,상기 가교제는 3,5-디메틸 피라졸(3,5-dimethyl pyrazole)(DMP), 카프로락탐(ε-caprolactame) 및 메틸에틸케톡심(methylethylketoxime)으로 이루어진 군에서 선택된 1종 이상의 블로킹 성분이 결합된 폴리이소시아네이트 화합물 또는 폴리카르보디이미드 화합물인, 에어백 원단.
- 제1항에 있어서,상기 섬유 기재는 복수의 경사들 및 위사들을 포함하는 원-피스 제직(One Piece Woven: OPW) 타입의 직물이고,상기 경사들 및 상기 위사들 각각은 210 내지 1500 데니어의 섬도를 갖고,상기 경사들의 밀도 및 상기 위사들의 밀도는 상기 직물의 챔버 영역의 한 층(one layer) 기준으로 40 th/inch 내지 80 th/inch이며,상기 경사들 및 상기 위사들 각각은 지방족 폴리아미드, 방향족 폴리아미드, 폴리에스테르, 및 폴리올레핀 중 적어도 하나를 포함하는,에어백 원단.
- 섬유 기재를 준비하는 단계; 및상기 섬유 기재의 적어도 일 면 상에 코팅층을 형성하는 단계;를 포함하며,상기 코팅층 형성 단계는,수분산 폴리우레탄에 가교제 및 친수성 증점제를 첨가함으로써 코팅액을 준비하는 단계;상기 코팅액을 상기 섬유 기재의 적어도 일 면 상에 가하는 단계;상기 코팅액이 도포된 상기 섬유 기재를 건조시키는 단계; 및상기 건조된 섬유 기재를 열처리하는 단계를 포함하고,상기 가교제는 블로킹된 활성기(blocked active group)를 갖는 화합물인,에어백 원단 제조방법.
- 제11항에 있어서,상기 블로킹된 활성기는 100 ℃ 이상에서 활성기로부터 해리되는 블로킹 성분을 포함하는,에어백 원단 제조방법.
- 제11항에 있어서,상기 활성기는 이소시아네이트기(isocyanate group) 또는 카르보디이미드기(carbodiimide group)인,에어백 원단 제조방법.
- 제11항 또는 제12항에 있어서,상기 블로킹 성분은 3,5-디메틸 피라졸(3,5-dimethyl pyrazole)(DMP), 카프로락탐(ε-caprolactame), 또는 메틸에틸케톡심(methylethylketoxime)인,에어백 원단 제조방법.
- 제1항에 있어서,상기 가교제는 3,5-디메틸 피라졸(3,5-dimethyl pyrazole)(DMP), 카프로락탐(ε-caprolactame) 및 메틸에틸케톡심(methylethylketoxime)으로 이루어진 군에서 선택된 1종 이상의 블로킹 성분이 결합된 폴리이소시아네이트 화합물 또는 폴리카르보디이미드 화합물인, 에어백 원단.
- 제11항에 있어서,상기 증점제는 비회합성 증점제인, 에어백 원단 제조방법.
- 제11항에 있어서,상기 증점제는 비뉴턴형의 의가소성 아크릴계 증점제인, 에어백 원단 제조방법.
- 제11항에 있어서,상기 증점제는 25,000 내지 60,000 cps의 점도를 갖고,상기 코팅액은 6,000 내지 30,000 cps의 점도를 갖는,에어백 원단 제조방법.
- 제11항에 있어서,상기 섬유 기재의 적어도 일 면 상에 가해지는 상기 코팅액의 양은 15 내지 50 gsm인,에어백 원단 제조방법.
- 제11항에 있어서,상기 건조 단계는 80 ℃와 150 ℃ 사이의 범위에서 승온시킴으로써 수행되고,상기 열처리 단계는 150 ℃를 초과하는 온도에서 수행되는,에어백 원단 제조방법.
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JP2022529098A JP7373071B2 (ja) | 2019-12-27 | 2019-12-27 | 向上した耐久性を有するエアバッグ布およびその製造方法 |
US17/767,879 US20230322179A1 (en) | 2019-12-27 | 2019-12-27 | Airbag fabric of improved durability and method for manufacturing the same |
CA3158397A CA3158397A1 (en) | 2019-12-27 | 2019-12-27 | Airbag fabric of improved durability and method for manufacturing the same |
PCT/KR2019/018637 WO2021132778A1 (ko) | 2019-12-27 | 2019-12-27 | 향상된 내구성을 갖는 에어백 원단 및 그 제조방법 |
MX2022007984A MX2022007984A (es) | 2019-12-27 | 2019-12-27 | Tela de bolsa de aire que tiene durabilidad mejorada y metodo para fabricar la misma. |
EP19957237.1A EP4074888A4 (en) | 2019-12-27 | 2019-12-27 | AIRBAG FABRIC HAVING IMPROVED DURABILITY AND METHOD FOR PRODUCING THE SAME |
CN201980102579.3A CN114746604A (zh) | 2019-12-27 | 2019-12-27 | 改善了耐久性的安全气囊用织物及其制备方法 |
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JP6892200B2 (ja) * | 2017-06-28 | 2021-06-23 | 旭化成ワッカーシリコーン株式会社 | ブロックポリイソシアネート組成物を含有するシリコーンゴム組成物、コーティング物の製造方法およびコーティング物。 |
JP6877837B2 (ja) * | 2017-06-28 | 2021-05-26 | 旭化成ワッカーシリコーン株式会社 | ブロックポリイソシアネート組成物を含有するシリコーンゴム組成物、コーティング物の製造方法およびコーティング物 |
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2019
- 2019-12-27 JP JP2022529098A patent/JP7373071B2/ja active Active
- 2019-12-27 CN CN201980102579.3A patent/CN114746604A/zh active Pending
- 2019-12-27 MX MX2022007984A patent/MX2022007984A/es unknown
- 2019-12-27 US US17/767,879 patent/US20230322179A1/en active Pending
- 2019-12-27 WO PCT/KR2019/018637 patent/WO2021132778A1/ko unknown
- 2019-12-27 EP EP19957237.1A patent/EP4074888A4/en active Pending
- 2019-12-27 CA CA3158397A patent/CA3158397A1/en active Pending
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Also Published As
Publication number | Publication date |
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US20230322179A1 (en) | 2023-10-12 |
EP4074888A1 (en) | 2022-10-19 |
MX2022007984A (es) | 2022-07-11 |
JP2023503078A (ja) | 2023-01-26 |
CN114746604A (zh) | 2022-07-12 |
CA3158397A1 (en) | 2021-07-01 |
EP4074888A4 (en) | 2023-09-20 |
JP7373071B2 (ja) | 2023-11-01 |
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