WO2021129405A1 - Semiconductor light-emitting element - Google Patents

Semiconductor light-emitting element Download PDF

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Publication number
WO2021129405A1
WO2021129405A1 PCT/CN2020/135236 CN2020135236W WO2021129405A1 WO 2021129405 A1 WO2021129405 A1 WO 2021129405A1 CN 2020135236 W CN2020135236 W CN 2020135236W WO 2021129405 A1 WO2021129405 A1 WO 2021129405A1
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Prior art keywords
layer
emitting element
light
type semiconductor
metal
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PCT/CN2020/135236
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French (fr)
Chinese (zh)
Inventor
蔡均富
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天津三安光电有限公司
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Publication of WO2021129405A1 publication Critical patent/WO2021129405A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/10Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a light reflecting structure, e.g. semiconductor Bragg reflector
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/14Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a carrier transport control structure, e.g. highly-doped semiconductor layer or current-blocking structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/36Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
    • H01L33/38Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes with a particular shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/44Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the coatings, e.g. passivation layer or anti-reflective coating
    • H01L33/46Reflective coating, e.g. dielectric Bragg reflector

Definitions

  • the invention relates to a semiconductor light-emitting element, which belongs to the field of semiconductor optoelectronic devices and technology.
  • LED Light Emitting Diode
  • LEDs have the advantages of high luminous intensity, high efficiency, small size, long service life, etc., and is considered to be one of the most potential light sources at present.
  • LEDs have been widely used in daily life, such as lighting, signal display, backlights, car lights, and large-screen displays. At the same time, these applications also put forward higher requirements for the brightness and luminous efficiency of LEDs.
  • Existing light emitting diodes include horizontal type and vertical type.
  • the vertical type of light-emitting diode is obtained by transferring the semiconductor barrier crystal stack to other substrates such as silicon, silicon carbide or metal substrates, and removing the original epitaxially grown substrate. Compared with the horizontal type, it can effectively improve the epitaxy.
  • the growth substrate brings about the technical problems of light absorption, current crowding, or poor heat dissipation.
  • the transfer of the substrate generally uses a bonding process, and the bonding is mainly through metal-metal high-temperature and high-pressure bonding, that is, a metal bonding layer is formed between one side of the semiconductor barrier crystal stack and the substrate.
  • the other side of the semiconductor barrier crystal stack provides a light-emitting side, and the light-emitting side is equipped with a wire electrode to provide current injection or flow.
  • the substrate under the semiconductor barrier crystal stack provides current flow or flow, thereby forming a current that passes through the semiconductor vertically.
  • a light-emitting diode with a barrier crystal stack is equipped with a wire electrode to provide current injection or flow.
  • a metal reflective layer and a dielectric layer are usually designed to form an ODR reflective structure on one side of the metal bonding layer, and the light from the metal bonding layer is reflected to the light exit side to improve the light extraction efficiency. If the side of the first conductivity type semiconductor layer away from the active layer is the entire dielectric layer, electrical conduction cannot be formed.
  • a common method is to form an electrical connection with the first conductive semiconductor layer through the opening of the dielectric layer.
  • the common dielectric layer opening is designed as a circular opening. As shown in Figure 1(a), the dielectric layer has a high percentage of openings, and the contact area with the first conductivity type semiconductor layer is large.
  • the current is easy to conduct and expand, but at the same time ODR
  • the brightness of the LED will decrease; on the contrary, as shown in Figure 1(b), the ratio of openings in the dielectric layer is low, and the area in contact with the first conductivity type semiconductor layer is small, and current conduction and expansion are limited.
  • the voltage will increase, but the ODR mirror area will increase, and the reflection efficiency of the ODR reflection structure will increase, so that the luminous brightness of the LED will increase.
  • the metal reflective layer and the dielectric layer can form an ODR reflective structure.
  • ODR reflective structure There are also the above problems.
  • the opening ratio of the dielectric layer is high, the current is easy to conduct and expand, but at the same time the ODR mirror area is reduced, and the LED emits light. The brightness will decrease; on the contrary, when the opening ratio of the dielectric layer is low, the conduction and expansion of the current are limited, and the voltage increases, but the ODR mirror area increases, the reflection efficiency of the ODR reflection structure increases, and the light-emitting brightness of the LED also increases.
  • the present invention adopts the annular opening design of the dielectric layer to ensure current conduction and injection, while taking into account the effect of mirror reflection, thereby improving the luminous brightness of the semiconductor light-emitting element and improving the luminous efficiency.
  • the present invention provides a semiconductor light emitting element, which includes: a semiconductor barrier crystal laminate, including a first conductivity type semiconductor layer, a second conductivity type semiconductor layer, and a semiconductor layer located between the first conductivity type semiconductor layer and the second conductivity type semiconductor layer; The active layer between the semiconductor layers; the dielectric layer is located on the side of the first conductivity type semiconductor layer away from the active layer, the dielectric layer has a plurality of through openings; the metal layer is located on the side of the dielectric layer away from the first One side of a conductive semiconductor layer, the metal layer is electrically connected to the first conductive semiconductor layer through a plurality of openings of the dielectric layer; characterized in that, the plurality of through openings of the dielectric layer are ring-shaped of.
  • the annular opening of the dielectric layer is circular, square, star-shaped, diamond-shaped or irregular in shape.
  • the width of the annular opening of the dielectric layer is 0-15um
  • the outer diameter of the annular opening is 3-30um
  • the area of the annular opening accounts for 10%-95% of the area of the entire dielectric layer.
  • the dielectric layer is at least one layer composed of at least one material of nitride, oxide or fluoride.
  • the metal layer at least includes a metal reflective layer.
  • the metal reflective layer may be formed of a metal or alloy containing at least one of Ag, Ni, Al, Rh, Pd, Ir, Ru, Mg, Zn, Pt, Au, and Hf.
  • the metal reflective layer and the dielectric layer form an ODR reflective structure to reflect the light emitted by the semiconductor barrier crystal stack to the light exit side.
  • the semiconductor barrier crystal stack radiates blue light, green light, red light or infrared light.
  • the semiconductor light emitting element further includes a second electrode located on the upper part of the second conductivity type semiconductor layer and electrically connected to the second conductivity type semiconductor layer.
  • the semiconductor light emitting element further includes a first electrode electrically connected to the metal layer.
  • the substrate is a conductive substrate, and the substrate is located between the opposite electrode and the metal layer.
  • the conductive substrate is silicon, silicon carbide, or metal substrate.
  • the metal substrate is preferably a copper, tungsten, or molybdenum substrate.
  • the metal layer forms an ohmic contact with the first conductivity type semiconductor layer through an ohmic contact layer.
  • the ohmic contact layer is a transparent conductive layer or a metal alloy.
  • the semiconductor light emitting element further includes a transparent substrate located on the second conductive type semiconductor layer.
  • the semiconductor light emitting element further includes a local defect area located on a part of the first conductivity type semiconductor layer and extending down to the second conductivity type semiconductor layer to form a mesa structure, and the mesa structure is exposed to emit light. Sidewall of the epitaxial structure.
  • the semiconductor element further includes a first electrode and a second electrode.
  • the first electrode is formed on the metal layer and is electrically connected to the first conductive semiconductor layer; the second electrode is formed In the local defect area, an electrical connection is formed with the second conductivity type semiconductor layer.
  • the semiconductor light emitting element provided by the present invention has the following beneficial effects:
  • the ODR reflective structure is formed by the dielectric layer and the metal reflective layer. Compared with the conventional metal reflective layer structure or the Bragg reflective structure, the reflectivity of the semiconductor light-emitting element can be improved, and the light output efficiency can be improved;
  • the dielectric layer compared with the hollow opening design, it can improve the light reflection effect while ensuring the current injection and conduction, thereby improving the luminous brightness of the semiconductor light-emitting element and improving the luminous efficiency.
  • FIG. 1 is a schematic diagram of the influence of the opening ratio of the dielectric layer on the current conduction and the reflection of the ODR structure in the prior art.
  • FIG. 2 is a schematic cross-sectional view of the semiconductor light-emitting device mentioned in Embodiment 1.
  • FIG. 2 is a schematic cross-sectional view of the semiconductor light-emitting device mentioned in Embodiment 1.
  • FIG. 3 is a schematic diagram of the circular opening of the dielectric layer of the semiconductor light-emitting element mentioned in Embodiment 1.
  • FIG. 3 is a schematic diagram of the circular opening of the dielectric layer of the semiconductor light-emitting element mentioned in Embodiment 1.
  • FIG. 4 is a schematic diagram of the photoelectric characteristic interaction of the semiconductor light-emitting element mentioned in the first embodiment with and without the annular opening when the current is injected and turned on.
  • FIG. 5 is a schematic diagram showing that the annular opening of the dielectric layer of the semiconductor light-emitting element mentioned in Example 2 is square.
  • Example 6 is a schematic diagram of the annular opening of the dielectric layer of the semiconductor light-emitting element mentioned in Example 3 being a rhombus.
  • FIG. 7 is a schematic cross-sectional view of the semiconductor light-emitting device mentioned in Embodiment 4 having a flip-chip structure.
  • FIG. 8 is a schematic diagram of the structure of the semiconductor light-emitting element package mentioned in Embodiment 5.
  • FIG. 8 is a schematic diagram of the structure of the semiconductor light-emitting element package mentioned in Embodiment 5.
  • 101/201 substrate; 102: metal bonding layer; 202: metal protective layer; 103/203: metal reflective layer; 104/204: ohmic contact layer; 105/205: dielectric layer; 106/206: section A conductive semiconductor layer; 107/207: the active layer; 108/208: the second conductive semiconductor layer; 109/209: the second electrode; 110/210: the first electrode; 1051/2051: the annular opening of the dielectric layer; D1: the width of the annular opening; D2: the outer diameter of the annular opening; 2211: local defect area; 2111: the first through hole structure of the insulating protection layer; 2112: the second through hole structure of the insulating protection layer; 10: semiconductor light emitting element 30: mounting substrate; 301: first package electrode; 302: second package electrode; 303: first bonding part; 304: second bonding part; 305: sealing resin.
  • diagrams provided in this embodiment only illustrate the basic idea of the present invention in a schematic manner, so the diagrams only show the components related to the present invention instead of the number, shape, and shape of the components in actual implementation.
  • the type, quantity, and proportion of each component can be changed at will during actual implementation, and the component layout type may also be more complicated.
  • the present invention provides the following semiconductor light emitting element, as shown in the schematic cross-sectional view of FIG. 2, which includes the following stacked layers: 101: substrate; 102: metal bonding layer; 103: metal reflective layer; 104: ohmic contact layer; 105: Dielectric layer; 106: first conductivity type semiconductor layer; 107: active layer; 108: second conductivity type semiconductor layer; 109: second electrode; 110: first electrode; 1051: annular opening of the dielectric layer.
  • the substrate 101 is a conductive substrate, and the conductive substrate may be a silicon, silicon carbide, or a metal substrate.
  • the metal substrate is preferably a copper, tungsten or molybdenum substrate.
  • the substrate 101 may have a thickness of about 50 ⁇ m to about 300 ⁇ m.
  • the metal layer may be divided into a single layer or at least two layers according to functions, and more preferably at least two functional layers, of which at least one layer may be defined as the metal bonding layer 102 according to functions.
  • the metal bonding layer 102 is a bonding metal material used when adhering one side of the semiconductor barrier crystal stack to the substrate 101, such as gold, tin, titanium, nickel, platinum and other metals.
  • the bonding metal layer itself may be Multi-layer material combination.
  • the metal layer may also include a metal reflective layer 103 on the upper side of the metal bonding layer 102 and closer to the semiconductor barrier crystal stack.
  • the metal reflective layer 103 may be composed of Ag, Ni, Al, Rh, Pd, Ir, Ru, Mg.
  • the metal reflective layer 103 can reflect the light radiated from the semiconductor barrier crystal stack toward the side of the substrate 101 back to the semiconductor barrier crystal stack and radiate out from the light exit side.
  • the dielectric layer 105 is located on a side of the first conductivity type semiconductor layer 106 away from the active layer 107, and the dielectric layer 105 has a plurality of through openings.
  • the plurality of through openings of the dielectric layer 105 are ring-shaped, and the openings may be uniformly or non-uniformly distributed on one side of the semiconductor barrier crystal stack.
  • the circled part is the annular opening 1051 of the dielectric layer 105.
  • the width of the annular opening 1051 of the dielectric layer is D1, and its range is 0 ⁇ 15um; the outer diameter of the annular opening is D2, and its range is 3 ⁇ 30um, and the area of the annular opening accounts for 10% ⁇ 95 of the area of the entire dielectric layer. %.
  • the dielectric layer 105 may be formed of an insulating material having a conductivity smaller than that of the metal reflective layer 103 or the ohmic contact layer 104, a material having low conductivity, or a material that is Schottky contacting the first conductivity type semiconductor layer 106.
  • the dielectric layer 105 may be composed of at least one of fluoride, nitride, or oxide, such as ZnO, SiO 2 , SiO x , SiO x N y , Si 3 N 4 , Al 2 O 3 , TiO x , At least one of MgF or GaF is formed.
  • the dielectric layer 105 is formed by a combination of at least one layer of composition or multiple layers of dielectric layer materials with different refractive indexes.
  • the dielectric layer 105 is more preferably a light-transmitting dielectric layer, and at least 50% of light can pass through the dielectric layer. More preferably, the refractive index of the dielectric layer 105 is lower than the refractive index of the semiconductor barrier crystal stack.
  • the pattern of the annular opening is preferably circular. As shown in FIG. 3, D1 is the width of the annular opening, and its range is preferably 0 ⁇ 15 ⁇ m, and D2 is the width of the outer diameter of the annular opening, and its range is preferably 3 ⁇ 30 ⁇ m.
  • An ohmic contact layer 104 may be included between the metal reflective layer 103 and the dielectric layer 105.
  • the ohmic contact layer 104 forms a plurality of regions to ohmically contact the first conductive type semiconductor layer 106 by filling at least the plurality of annular openings of the dielectric layer 105 to transfer current from
  • the metal layer including the metal reflective layer 103 and the bonding layer 102 is uniformly transferred to the semiconductor barrier crystal stack, so the ohmic contact layer 104 does not contact the side of the first conductive type semiconductor layer 106 in the form of an entire surface.
  • the ohmic contact layer 104 may be formed of a transparent conductive layer such as at least one of ITO, IZO, IZTO, IAZO, IGZO, IGTO, AZO, and ATO.
  • the ohmic contact layer 104 may alternatively use a light-transmitting conductive layer and metal.
  • the metal is preferably an alloy material, such as gold zinc, gold germanium, gold germanium nickel, or gold beryllium.
  • the ohmic contact layer 104 may have a single-layer or multi-layer structure.
  • the metal reflective layer 103 and the dielectric layer 105 form an ODR reflective structure, which returns the light radiated from the semiconductor barrier crystal stack toward the substrate 101 to the semiconductor barrier crystal stack and radiates out from the light exit side to improve light extraction efficiency.
  • the dielectric layer 105 of the present invention has a plurality of through annular openings.
  • the ohmic contact layer 104 is electrically connected to the first conductivity type semiconductor layer through the annular openings to ensure current injection and conduction.
  • the dielectric layer of the inner ring and the outer ring compared with the hollow design of the dielectric layer, it can be found that after the opening position of the dielectric layer adopts the annular opening design of the inner ring and the outer ring, the strongest current injection has the strongest luminous intensity, and the dielectric layer of the inner ring and the outer ring
  • the reflection effect of (ODR) can be enhanced internally and externally. It can be seen that there is a better ODR reflection effect, and the interaction between electrical and optical characteristics is enhanced.
  • the LED After adopting the annular opening design of the dielectric layer, the LED can maintain the same working voltage, increase the luminous brightness, and improve the overall luminous efficiency.
  • the semiconductor barrier crystal stack is a semiconductor barrier crystal stack obtained by MOCVD or other growth methods.
  • the semiconductor barrier crystal stack is a semiconductor material that can provide conventional radiation such as ultraviolet, blue, green, yellow, red, and infrared light.
  • the specific material can be 200 ⁇ 950nm, such as common nitride, specific such as gallium nitride-based semiconductor barrier crystal stack, gallium nitride-based barrier crystal stack is usually doped with aluminum, indium and other elements, mainly to provide Radiation in the 200 ⁇ 550nm band; or the common aluminum gallium indium phosphorus-based or aluminum gallium arsenic-based semiconductor barrier crystal stack, which mainly provides radiation in the 550 ⁇ 950nm band.
  • the semiconductor barrier layer stack mainly includes a first conductivity type semiconductor layer 106, a second conductivity type semiconductor layer 108, and an active layer 107 between the first conductivity type semiconductor layer 106 and the second conductivity type semiconductor layer 108.
  • the first conductive type semiconductor layer 106 and the second conductive type semiconductor layer 108 may be respectively n-type doped or p-type doped to realize a material layer that at least provides electrons or holes, respectively.
  • the n-type semiconductor layer may be doped with n-type dopants such as Si, Ge, or Sn
  • the p-type semiconductor layer may be doped with p-type dopants such as Mg, Zn, Ca, Sr, or Ba.
  • the first conductive semiconductor layer 106, the active layer 107, and the second conductive semiconductor layer 108 may specifically be aluminum gallium indium nitride, gallium nitride, aluminum gallium nitride, aluminum indium phosphorus, aluminum gallium indium phosphorus, or gallium arsenide or aluminum gallium. Made of arsenic and other materials.
  • the first conductive type semiconductor layer 106 or the second conductive type semiconductor layer 108 includes a covering layer that provides electrons or holes, and may include other layer materials such as a current spreading layer, a window layer, or an ohmic contact layer, etc., depending on the doping concentration or The content of the components is different, and it is set to different multi-layers.
  • the active layer 107 is a region where electrons and holes are recombined to provide light radiation. Different materials can be selected according to different emission wavelengths.
  • the active layer 107 may be a periodic structure of single quantum well or multiple quantum wells. By adjusting the composition ratio of the semiconductor materials in the active layer 107, light of different wavelengths is expected to be radiated.
  • the second electrode 109 is arranged on the light emitting side of the semiconductor barrier crystal stack, and forms an electrical connection with the second conductivity type semiconductor layer.
  • the second electrode 109 mainly includes a pad portion, and the pad portion is mainly used for external wiring during packaging.
  • the pads of the second electrode can be designed in different shapes according to actual wire bonding requirements, such as cylindrical or square or other polygonal shapes.
  • the second electrode may further include an extension part extending from the pad, the extension part may be formed in a predetermined pattern shape, and the extension part may have various shapes, such as a strip shape.
  • the semiconductor light emitting element further includes a first electrode 110, and the first electrode 110 is electrically connected to the first conductive semiconductor layer through the metal layer.
  • the first electrode 110 described in this embodiment is formed on the back side of the substrate 101 in the form of a whole surface.
  • the substrate of this embodiment is a conductive support substrate, and the second electrode 109 and the first electrode 110 are formed on both sides of the support substrate 101 Side, in order to realize that the current flows vertically through the semiconductor barrier crystal stack to provide a uniform current density.
  • the second electrode 109 and the first electrode 110 are preferably made of metal materials. At least the pad portion and the extension portion of the second electrode 109 may also include a metal material for forming a good ohmic contact with the semiconductor light emitting sequence.
  • the present invention also prepared a sample of a comparative example.
  • the opening of the dielectric layer in the comparative example was a conventional circular opening.
  • the semiconductor light-emitting element was fabricated under the same conditions as in Example 1, and the comparative example and the dielectric in Example 1 The area of the layer openings accounts for the same proportion.
  • a current was passed between the first electrode and the second electrode, and infrared light with a peak emission wavelength of 944 nm was emitted.
  • the forward voltage Vf 1 was 2.98V.
  • the luminous output power (P 0 ) when the forward current is set to 350 mA is 350 mW.
  • the semiconductor light-emitting element in Example 1 was tested, and when the forward current was 350 mA, its luminous output power (P 0 ) and forward voltage (Vf1) were 365 mW and 2.97V, respectively.
  • the annular opening of the dielectric layer can improve the semiconductor light-emitting element while ensuring the conduction and injection of current. Reflectivity, thereby improving the luminous efficiency of semiconductor light-emitting elements.
  • This embodiment differs from the first embodiment in that the shape of the annular opening of the dielectric layer 105 in the first embodiment is circular, while the shape of the annular opening of the dielectric layer 105 in this embodiment is square of.
  • This embodiment differs from the first embodiment in that the shape of the annular opening of the dielectric layer 105 in the first embodiment is circular, while the shape of the annular opening of the dielectric layer 105 in this embodiment is a rhombus. of.
  • this embodiment provides another semiconductor light-emitting element, a flip-chip light-emitting diode, which includes the following stacked layers: 201: a substrate; 202: a metal protective layer; 203: metal reflective layer; 204: ohmic contact layer; 205: dielectric layer; 206: first conductivity type semiconductor layer; 207: active layer; 208: second conductivity type semiconductor layer; 209: second pole; 210: first Electrode; 2051: ring-shaped opening of the dielectric layer; 211: insulating protective layer.
  • a flip-chip light-emitting diode which includes the following stacked layers: 201: a substrate; 202: a metal protective layer; 203: metal reflective layer; 204: ohmic contact layer; 205: dielectric layer; 206: first conductivity type semiconductor layer; 207: active layer; 208: second conductivity type semiconductor layer; 209: second pole; 210: first Electrode; 2051: ring-shaped opening of the dielectric layer; 211
  • the substrate 201 is a transparent substrate.
  • the transparent substrate 201 may be a growth substrate used for the growth of a semiconductor barrier crystal stack, or it may be a transparent substrate combined with a semiconductor barrier crystal stack through a transparent adhesive layer, specifically including a planar type.
  • the transparent substrate 201 is selected as a patterned sapphire substrate.
  • the substrate can be thinned or removed to form a thin-film LED chip.
  • the semiconductor barrier crystal stack is located on the transparent substrate 201 and includes a first conductivity type semiconductor layer 206, an active layer 207, and a second conductivity type semiconductor layer 208 stacked in sequence.
  • the first conductivity type semiconductor layer 206 and the second conductivity type semiconductor layer 208 may be p-type GaN or N-type GaN, respectively, and the active layer 207 may be a GaN-based quantum well layer.
  • the active layer 207 may be a GaN-based quantum well layer.
  • other types of epitaxial structures can also be selected according to actual needs, and are not limited to the examples listed here.
  • the local defect region 2211 is located on a part of the first conductivity type semiconductor layer 206 and extends downward to the second conductivity type semiconductor layer 208 to form a mesa structure.
  • the mesa structure exposes the sidewalls of the epitaxial structure, specifically
  • the mesa structure reveals the mesa of the second conductivity type semiconductor layer 208 and the sidewalls of the first conductivity type semiconductor layer 206, the active layer 207, and the second conductivity type semiconductor layer 208.
  • the number of locally defective regions 1211 is at least one, and it can also be increased according to the structure and area of the LED chip.
  • the ohmic contact layer 204 is located on the first conductive type semiconductor layer 206, and the ohmic contact layer 204 may be formed of a transparent conductive layer such as at least one of ITO, IZO, IZTO, IAZO, IGZO, IGTO, AZO, and ATO.
  • the ohmic contact layer 204 may alternatively use a light-transmitting conductive layer and metal.
  • the metal is preferably an alloy material, such as gold zinc, gold germanium, gold germanium nickel, or gold beryllium.
  • the ohmic contact layer 204 may have a single-layer or multi-layer structure.
  • the ohmic contact layer is in ohmic contact with the first conductivity type semiconductor layer 206.
  • the dielectric layer 205 wraps the sidewalls of the ohmic contact layer and covers the sidewalls of the adjacent light-emitting epitaxial structure, wherein the dielectric layer 205 that wraps the sidewalls of the ohmic contact layer 204 is mainly used for ohmic contact
  • the layer 204 and the metal reflective layer 203 constitute an omnidirectional reflective layer (ODR) structure.
  • the dielectric layer 205 covering the sidewalls of the adjacent light-emitting epitaxial structure mainly serves as electrical insulation; further, the dielectric layer has a A series of annular opening structure, as shown in FIG. 7, 2051 is the annular opening of the dielectric layer.
  • a dielectric layer 205 having a ring-shaped opening structure is formed on part of the surface of the epitaxial structure.
  • the dielectric layer 205 may be a low refractive index material, such as a silicon dioxide layer, magnesium fluoride, etc., or a high refractive index material, such as Titanium dioxide or the like, or the dielectric layer 205 may also be a distributed Bragg reflector (DBR) layer including high and low refractive index materials, and is not limited to the examples listed here.
  • DBR distributed Bragg reflector
  • a metal layer is formed on the surface of the dielectric layer 205, and the metal layer may include a multilayer structure, such as a metal reflective layer 203, a metal protective layer 202, etc., and is not limited to the examples listed here.
  • the metal reflective layer 203 is made of Al or Ag highly reflective metal as a mirror (mirror)
  • the metal protective layer 202 is made of TiW alloy, etc., and the metal protective layer 202 can be completely wrapped around the metal reflective layer 203. To protect the metal reflective layer.
  • the metal reflective layer 203 and the dielectric layer 205 form an ODR reflective structure, which returns the light radiated from the semiconductor barrier crystal stack toward the substrate 201 side to the semiconductor barrier crystal stack and radiates out from the transparent substrate 201 side. Improve light output efficiency.
  • the dielectric layer 205 has a plurality of through annular openings, and the metal layer is electrically connected to the first conductive semiconductor layer 206 through the annular openings 2051 to ensure current injection and conduction.
  • the semiconductor light-emitting element can maintain the same working voltage, improve the luminous brightness, and improve the overall luminous efficiency.
  • the semiconductor light-emitting element may also include an insulating protection layer 211 formed on the metal protection layer 202 and the local defect region 2211, and the first via structure 2111 and the insulating protection layer 211 of the insulating protection layer 211 are formed in the insulating protection layer 211
  • the first through-hole structure 2111 serves as a reserved window for the first electrode
  • the second through-hole structure 2112 serves as a reserved window for the second electrode.
  • the first electrode 210 is formed in the reserved window of the first electrode to realize the electrical connection between the first electrode and the first conductivity type semiconductor layer
  • the second electrode 209 is formed in the reserved window of the second electrode, In order to realize the electrical connection between the second electrode and the second conductivity type semiconductor layer.
  • the insulating protection layer 211 can be a low refractive index material, such as a silicon dioxide layer, magnesium fluoride, etc., or a high refractive index material, such as titanium dioxide, etc., or the insulating protection layer 211 can also be a distributed Bragg reflector. Layer (DBR), and is not limited to the examples listed here.
  • DBR distributed Bragg reflector. Layer
  • a third insulating layer (not shown in the figure) can be formed on the first and second electrodes, and a through hole structure can be formed. As the electrode window, the third and fourth electrodes are finally formed in the electrode window.
  • an omnidirectional reflector (ODR) structure is formed by a low-refractive-index dielectric layer and a metal reflective layer, and its reflection effect is better than that of a conventional metal reflective layer or a distributed Bragg reflective layer structure, which enhances the probability of external light extraction of the semiconductor light-emitting element.
  • ODR omnidirectional reflector
  • the semiconductor light-emitting element provided by the present invention can be widely used in display or backlight packages or applications, and can especially meet the high-brightness requirements of backlight products.
  • this embodiment provides a package as shown in FIG. 8, the package including a mounting substrate 30, a semiconductor light emitting element 10 and a sealing resin 305. At least one semiconductor light-emitting element in the foregoing embodiments is mounted on the mounting substrate 30.
  • the mounting substrate 30 is an insulating substrate, such as a package module substrate for RGB display screen or a module substrate for backlight display.
  • One surface of the mounting substrate 30 There is a first electrode terminal 301 and a second electrode terminal 302 that are electrically isolated.
  • the semiconductor light-emitting element is located on one surface of the mounting substrate 30.
  • the first electrode 210 and the second electrode 209 of the semiconductor light-emitting element pass through the first coupling portion 303 and the second coupling portion 304, respectively, and the first electrode terminal 301 and the second electrode terminal 302. connection.
  • the first bonding portion 303 and the second bonding portion 304 include but are not limited to solder, such as eutectic solder or reflow solder.
  • the semiconductor light emitting element package emits light having blue light or mixed colors (for example, white).
  • the semiconductor light emitting element chip emits light in the blue wavelength band, such as light with a peak wavelength of 450 nm
  • the package further includes a transparent sealing resin 306 for protecting the semiconductor light emitting element chip, and also provides light radiation in the corresponding blue wavelength band.
  • the package may include a fluorescence conversion material for wavelength conversion of light emitted from the semiconductor light emitting element chip.
  • the fluorescence conversion material may be provided in the sealing resin 306.
  • the sealing resin 306 may be applied to at least one side of the semiconductor light-emitting element chip by dispensing or pasting, but is not limited thereto.
  • the fluorescence conversion material may be a fluorescence conversion material in which red and green are combined, or a yellow phosphor or a fluorescence conversion material in which red, yellow and green are combined. Since the semiconductor light emitting element has an ODR structure with high reflection efficiency in the present invention, the light emitting efficiency of the semiconductor light emitting element can be improved, so that the light emitting efficiency of the entire semiconductor light emitting element package can be improved.

Abstract

A semiconductor light-emitting element, comprising a semiconductor barrier transistor stacked layer, which comprises a first conductive-type semiconductor layer (106, 206), a second conductive-type semiconductor layer (108, 208), and an active layer (107, 207) located between the first conductive-type semiconductor layer (106, 206) and the second conductive-type semiconductor layer (108, 208); a dielectric layer (105, 205) located on the side of the first conductive-type semiconductor layer (106, 206) away from the active layer (107, 207), wherein the dielectric layer (105, 205) is provided with a plurality of through openings; and a metal layer located on the side of the dielectric layer (105, 205) away from the first conductive-type semiconductor layer (106, 206), wherein the metal layer is electrically connected to the first conductive-type semiconductor layer (106, 206) by means of the plurality of openings of the dielectric layer (105, 205); and the plurality of through openings of the dielectric layer (105, 205) are ring-shaped. The dielectric layer (105, 205) uses a design of ring-shaped openings, such that the effect of mirror reflection can also be taken into consideration on the basis of guaranteeing current conduction and injection, thereby improving the light-emitting brightness of the semiconductor light-emitting element, and improving the light-emitting efficiency thereof.

Description

一种半导体发光元件Semiconductor light-emitting element 技术领域Technical field
本发明涉及一种半导体发光元件,属于半导体光电子器件与技术领域。The invention relates to a semiconductor light-emitting element, which belongs to the field of semiconductor optoelectronic devices and technology.
背景技术Background technique
发光二极管(Light Emitting Diode,简称LED)具有发光强度大、效率高、体积小、使用寿命长等优点,被认为是当前最具有潜力的光源之一。近年来,LED已在日常生活中得到广泛应用,例如照明、信号显示、背光源、车灯和大屏幕显示等领域,同时这些应用也对LED的亮度、发光效率提出了更高的要求。Light Emitting Diode (LED for short) has the advantages of high luminous intensity, high efficiency, small size, long service life, etc., and is considered to be one of the most potential light sources at present. In recent years, LEDs have been widely used in daily life, such as lighting, signal display, backlights, car lights, and large-screen displays. At the same time, these applications also put forward higher requirements for the brightness and luminous efficiency of LEDs.
现有的发光二极管包括水平类型和垂直类型。垂直类型的发光二极管通过把半导体垒晶叠层转移到其它的基板如硅、碳化硅或金属基板上,并移除原始外延生长的衬底的工艺获得,相较于水平类型,可以有效改善外延生长衬底带来的吸光、电流拥挤或散热性差的技术问题。衬底的转移一般采用键合工艺,键合主要通过金属-金属高温高压键合,即在半导体垒晶叠层一侧与基板之间形成金属键合层。半导体垒晶叠层的另一侧提供出光侧,出光侧配置有一打线电极提供电流的注入或流出,半导体垒晶叠层的下方的基板提供电流的流出或流入,由此形成电流垂直经过半导体垒晶叠层的发光二极管。Existing light emitting diodes include horizontal type and vertical type. The vertical type of light-emitting diode is obtained by transferring the semiconductor barrier crystal stack to other substrates such as silicon, silicon carbide or metal substrates, and removing the original epitaxially grown substrate. Compared with the horizontal type, it can effectively improve the epitaxy. The growth substrate brings about the technical problems of light absorption, current crowding, or poor heat dissipation. The transfer of the substrate generally uses a bonding process, and the bonding is mainly through metal-metal high-temperature and high-pressure bonding, that is, a metal bonding layer is formed between one side of the semiconductor barrier crystal stack and the substrate. The other side of the semiconductor barrier crystal stack provides a light-emitting side, and the light-emitting side is equipped with a wire electrode to provide current injection or flow. The substrate under the semiconductor barrier crystal stack provides current flow or flow, thereby forming a current that passes through the semiconductor vertically. A light-emitting diode with a barrier crystal stack.
为了提高出光效率,通常会在金属键合层的一侧设计金属反射层与电介质层形成ODR反射结构,将金属键合层一侧的出光反射至出光侧,提高出光效率。若第一导电型半导体层的远离活性层的一侧为整层电介质层,则无法形成电性导通。常见的方法为通过电介质层开口与第一导电型半导体层形成电性连接。常见的电介质层开口设计为圆形开口,如图1(a)所示,电介质层的开孔比例高,与第一导电型半导体层接触的面积大,电流容易导通和扩展,但同时ODR镜面面积减小,LED亮度会降低;反之,如图1(b)所示,电介质层的开孔比例低,与第一导电型半导体层接触的面积小,电流的导通和扩展受到限制,电压会升高,但ODR镜面面积增大,ODR反射结构的反射效率提升,从而LED的发光亮度会增加。In order to improve the light extraction efficiency, a metal reflective layer and a dielectric layer are usually designed to form an ODR reflective structure on one side of the metal bonding layer, and the light from the metal bonding layer is reflected to the light exit side to improve the light extraction efficiency. If the side of the first conductivity type semiconductor layer away from the active layer is the entire dielectric layer, electrical conduction cannot be formed. A common method is to form an electrical connection with the first conductive semiconductor layer through the opening of the dielectric layer. The common dielectric layer opening is designed as a circular opening. As shown in Figure 1(a), the dielectric layer has a high percentage of openings, and the contact area with the first conductivity type semiconductor layer is large. The current is easy to conduct and expand, but at the same time ODR When the mirror area is reduced, the brightness of the LED will decrease; on the contrary, as shown in Figure 1(b), the ratio of openings in the dielectric layer is low, and the area in contact with the first conductivity type semiconductor layer is small, and current conduction and expansion are limited. The voltage will increase, but the ODR mirror area will increase, and the reflection efficiency of the ODR reflection structure will increase, so that the luminous brightness of the LED will increase.
在倒装发光二极管中,金属反射层可与电介质层形成ODR反射结构,也存在上述问题,电介质层的开口比例高时,电流容易导通和扩展,但同时ODR的镜面面积减小,LED发光亮度会降低;反之,电介质层的开口比例低时,电流的导通和扩展受到限制,电压升高,但ODR镜面面积增大,ODR反射结构的反射效率提升,LED的发光亮度也会增加。In flip-chip light-emitting diodes, the metal reflective layer and the dielectric layer can form an ODR reflective structure. There are also the above problems. When the opening ratio of the dielectric layer is high, the current is easy to conduct and expand, but at the same time the ODR mirror area is reduced, and the LED emits light. The brightness will decrease; on the contrary, when the opening ratio of the dielectric layer is low, the conduction and expansion of the current are limited, and the voltage increases, but the ODR mirror area increases, the reflection efficiency of the ODR reflection structure increases, and the light-emitting brightness of the LED also increases.
技术解决方案Technical solutions
为了解决以上的问题,本发明通过电介质层的环形开口设计,可在保证电流导通和注入的基础上,兼顾镜面反射的效果,从而提升半导体发光元件的发光亮度,提升发光效率。In order to solve the above problems, the present invention adopts the annular opening design of the dielectric layer to ensure current conduction and injection, while taking into account the effect of mirror reflection, thereby improving the luminous brightness of the semiconductor light-emitting element and improving the luminous efficiency.
为实现上述目的,本发明提供一种半导体发光元件,其包括:半导体垒晶叠层,包括第一导电型半导体层、第二导电型半导体层和位于第一导电型半导体层和第二导电型半导体层之间的活性层;电介质层,位于所述第一导电型半导体层的远离活性层的一侧,所述电介质层具有多个贯通的开口;金属层,位于所述电介质层的远离第一导电型半导体层的一侧,所述金属层通过所述电介质层的多个开口与第一导电型半导体层进行电性连接;其特征在于,所述电介质层的多个贯通的开口为环形的。In order to achieve the above object, the present invention provides a semiconductor light emitting element, which includes: a semiconductor barrier crystal laminate, including a first conductivity type semiconductor layer, a second conductivity type semiconductor layer, and a semiconductor layer located between the first conductivity type semiconductor layer and the second conductivity type semiconductor layer; The active layer between the semiconductor layers; the dielectric layer is located on the side of the first conductivity type semiconductor layer away from the active layer, the dielectric layer has a plurality of through openings; the metal layer is located on the side of the dielectric layer away from the first One side of a conductive semiconductor layer, the metal layer is electrically connected to the first conductive semiconductor layer through a plurality of openings of the dielectric layer; characterized in that, the plurality of through openings of the dielectric layer are ring-shaped of.
优选地,所述电介质层的环形开口为圆形、方形、星形、菱形或者不规则形状的。Preferably, the annular opening of the dielectric layer is circular, square, star-shaped, diamond-shaped or irregular in shape.
优选地,所述电介质层的环形开口的宽度为0~15um,环形开口的外径尺寸为3~30um,环形开口的面积占整个电介质层面积的比例为10%~95%。Preferably, the width of the annular opening of the dielectric layer is 0-15um, the outer diameter of the annular opening is 3-30um, and the area of the annular opening accounts for 10%-95% of the area of the entire dielectric layer.
优选地,所述的电介质层为至少一层,为氮化物、氧化物或氟化物至少的一种材料组成。Preferably, the dielectric layer is at least one layer composed of at least one material of nitride, oxide or fluoride.
优选地,所述的金属层至少包括金属反射层。Preferably, the metal layer at least includes a metal reflective layer.
更优选地,所述的金属反射层可以由包含Ag、Ni、Al、Rh、Pd、Ir、Ru、Mg、Zn、Pt、Au以及Hf中的至少一个的金属或者合金形成。More preferably, the metal reflective layer may be formed of a metal or alloy containing at least one of Ag, Ni, Al, Rh, Pd, Ir, Ru, Mg, Zn, Pt, Au, and Hf.
优选地,所述金属反射层和所述电介质层形成ODR反射结构,将半导体垒晶叠层发出的光反射至出光侧。Preferably, the metal reflective layer and the dielectric layer form an ODR reflective structure to reflect the light emitted by the semiconductor barrier crystal stack to the light exit side.
优选地,所述半导体垒晶叠层辐射蓝光、绿光、红光或红外光。Preferably, the semiconductor barrier crystal stack radiates blue light, green light, red light or infrared light.
优选地,所述半导体发光元件还包括一第二电极,位于第二导电型半导体层的上部并与第二导电型半导体层电性连接。Preferably, the semiconductor light emitting element further includes a second electrode located on the upper part of the second conductivity type semiconductor layer and electrically connected to the second conductivity type semiconductor layer.
优选地,所述半导体发光元件还包括一第一电极与金属层电性连接。Preferably, the semiconductor light emitting element further includes a first electrode electrically connected to the metal layer.
优选地,所述金属层下方具有基板,所述的基板为导电型基板,基板位于相反电极与金属层之间。Preferably, there is a substrate under the metal layer, the substrate is a conductive substrate, and the substrate is located between the opposite electrode and the metal layer.
优选地,所述导电型基板为硅、碳化硅、金属基板。Preferably, the conductive substrate is silicon, silicon carbide, or metal substrate.
更优选地,所述金属基板优选为铜,钨、钼基板。More preferably, the metal substrate is preferably a copper, tungsten, or molybdenum substrate.
优选地,所述金属层通过欧姆接触层与第一导电型半导体层形成欧姆接触。Preferably, the metal layer forms an ohmic contact with the first conductivity type semiconductor layer through an ohmic contact layer.
优选地,所述欧姆接触层为透明导电层或者金属合金。Preferably, the ohmic contact layer is a transparent conductive layer or a metal alloy.
优选地,所述半导体发光元件还包括一透明基板,位于第二导电类型半导体层之上。Preferably, the semiconductor light emitting element further includes a transparent substrate located on the second conductive type semiconductor layer.
优选地,所述半导体发光元件还包括局部缺陷区,位于部分所述第一导电型半导体层上,并向下延伸至所述第二导电型半导体层形成台面结构,所述台面结构露出有发光外延结构侧壁。Preferably, the semiconductor light emitting element further includes a local defect area located on a part of the first conductivity type semiconductor layer and extending down to the second conductivity type semiconductor layer to form a mesa structure, and the mesa structure is exposed to emit light. Sidewall of the epitaxial structure.
优选地,所述半导体元件还包括第一电极和第二电极,所述第一电极,形成于所述金属层上,与第一导电型半导体层形成电性连接;所述第二电极,形成于所述局部缺陷区,与第二导电型半导体层形成电性连接。Preferably, the semiconductor element further includes a first electrode and a second electrode. The first electrode is formed on the metal layer and is electrically connected to the first conductive semiconductor layer; the second electrode is formed In the local defect area, an electrical connection is formed with the second conductivity type semiconductor layer.
有益效果Beneficial effect
如上所述,本发明提供的半导体发光元件具有以下有益效果:As mentioned above, the semiconductor light emitting element provided by the present invention has the following beneficial effects:
1. 通过电介质层和金属反射层形成ODR反射结构,相对于常规的金属反射层结构或者布拉格反射结构,可提升半导体发光元件的反射率,提升出光效率;1. The ODR reflective structure is formed by the dielectric layer and the metal reflective layer. Compared with the conventional metal reflective layer structure or the Bragg reflective structure, the reflectivity of the semiconductor light-emitting element can be improved, and the light output efficiency can be improved;
2. 通过电介质层的环形开口设计,相比中空的开口设计,可在保证电流注入和导通的情况下,提升光反射效果,从而提升半导体发光元件的发光亮度,提升发光效率。2. Through the annular opening design of the dielectric layer, compared with the hollow opening design, it can improve the light reflection effect while ensuring the current injection and conduction, thereby improving the luminous brightness of the semiconductor light-emitting element and improving the luminous efficiency.
附图说明Description of the drawings
附图用来提供对本发明的进一步理解,并且构成说明书的一部分,与本发明实施例一起用于解释本发明,并不构成对发明的限制。此外,附图数据是描述概要,不是按比例绘制。The accompanying drawings are used to provide a further understanding of the present invention, and constitute a part of the specification. Together with the embodiments of the present invention, they are used to explain the present invention, and do not constitute a limitation to the present invention. In addition, the data in the drawings is a descriptive summary and is not drawn to scale.
图1为现有技术中电介质层开口比例对电流导通和ODR结构反射的影响的示意图。FIG. 1 is a schematic diagram of the influence of the opening ratio of the dielectric layer on the current conduction and the reflection of the ODR structure in the prior art.
图2为实施例1中所提及的半导体发光元件的剖面示意图。FIG. 2 is a schematic cross-sectional view of the semiconductor light-emitting device mentioned in Embodiment 1. FIG.
图3为实施例1中所提及的半导体发光元件的电介质层环形开口为圆形的示意图。FIG. 3 is a schematic diagram of the circular opening of the dielectric layer of the semiconductor light-emitting element mentioned in Embodiment 1. FIG.
图4为实施例1中所提及的半导体发光元件环形开口和无环形开口时电流注入导通时的光电特性交互作用的示意图。4 is a schematic diagram of the photoelectric characteristic interaction of the semiconductor light-emitting element mentioned in the first embodiment with and without the annular opening when the current is injected and turned on.
图5为实施例2中所提及的半导体发光元件的电介质层环形开口为方形的示意图。FIG. 5 is a schematic diagram showing that the annular opening of the dielectric layer of the semiconductor light-emitting element mentioned in Example 2 is square.
图6为实施例3中所提及的半导体发光元件的电介质层环形开口为菱形的示意图。6 is a schematic diagram of the annular opening of the dielectric layer of the semiconductor light-emitting element mentioned in Example 3 being a rhombus.
图7为实施例4中所提及的半导体发光元件为倒装芯片结构的剖面示意图。FIG. 7 is a schematic cross-sectional view of the semiconductor light-emitting device mentioned in Embodiment 4 having a flip-chip structure.
图8为实施例5中所提及的半导体发光元件的封装体的结构示意图。FIG. 8 is a schematic diagram of the structure of the semiconductor light-emitting element package mentioned in Embodiment 5. FIG.
图中:101/201:基板;102:金属键合层;202:金属保护层;103/203:金属反射层;104/204:欧姆接触层;105/205:电介质层;106/206:第一导电型半导体层;107/207:活性层;108/208:第二导电型半导体层;109/209:第二电极;110/210:第一电极;1051/2051:电介质层的环形开口;D1:环形开口的宽度;D2:环形开口的外径;2211:局部缺陷区;2111:绝缘保护层的第一通孔结构;2112:绝缘保护层的第二通孔结构;10:半导体发光元件;30:安装基板;301:第一封装电极;302:第二封装电极;303:第一结合部;304:第二结合部;305:密封树脂。In the figure: 101/201: substrate; 102: metal bonding layer; 202: metal protective layer; 103/203: metal reflective layer; 104/204: ohmic contact layer; 105/205: dielectric layer; 106/206: section A conductive semiconductor layer; 107/207: the active layer; 108/208: the second conductive semiconductor layer; 109/209: the second electrode; 110/210: the first electrode; 1051/2051: the annular opening of the dielectric layer; D1: the width of the annular opening; D2: the outer diameter of the annular opening; 2211: local defect area; 2111: the first through hole structure of the insulating protection layer; 2112: the second through hole structure of the insulating protection layer; 10: semiconductor light emitting element 30: mounting substrate; 301: first package electrode; 302: second package electrode; 303: first bonding part; 304: second bonding part; 305: sealing resin.
本发明的实施方式Embodiments of the present invention
以下通过特定的具体实例说明本发明的实施方式,本领域技术人员可由本说明书所揭露的内容轻易地了解本发明的其他优点与功效。本发明还可以通过另外不同的具体实施方式加以实施或应用,本发明中的各项细节也可以基于不同观点与应用,在没有背离本发明的精神下进行各种修饰或改变。The following describes the implementation of the present invention through specific specific examples, and those skilled in the art can easily understand other advantages and effects of the present invention from the content disclosed in this specification. The present invention can also be implemented or applied through other different specific embodiments, and various details in the present invention can also be modified or changed based on different viewpoints and applications without departing from the spirit of the present invention.
需要说明的是,本实施例中所提供的图示仅以示意方式说明本发明的基本构想,遂图示中仅显示与本发明中有关的组件而非按照实际实施时的组件数目、形状及尺寸绘制,其实际实施时各组件的型态、数量及比例可为一种随意的改变,且其组件布局型态也可能更为复杂。It should be noted that the diagrams provided in this embodiment only illustrate the basic idea of the present invention in a schematic manner, so the diagrams only show the components related to the present invention instead of the number, shape, and shape of the components in actual implementation. For the size drawing, the type, quantity, and proportion of each component can be changed at will during actual implementation, and the component layout type may also be more complicated.
实施例一Example one
本发明提供如下一种半导体发光元件,如图2所示的剖面示意图,其包括如下堆叠层:101:基板;102:金属键合层;103:金属反射层;104:欧姆接触层;105:电介质层;106:第一导电型半导体层;107:活性层;108:第二导电型半导体层;109:第二电极;110:第一电极;1051:电介质层的环形开口。The present invention provides the following semiconductor light emitting element, as shown in the schematic cross-sectional view of FIG. 2, which includes the following stacked layers: 101: substrate; 102: metal bonding layer; 103: metal reflective layer; 104: ohmic contact layer; 105: Dielectric layer; 106: first conductivity type semiconductor layer; 107: active layer; 108: second conductivity type semiconductor layer; 109: second electrode; 110: first electrode; 1051: annular opening of the dielectric layer.
下面针对各结构堆叠层进行详细描述。The following is a detailed description of the stacked layers of each structure.
所述的基板101为导电性基板,导电性基板可以为硅、碳化硅、金属基板,金属基板优选为铜,钨或者钼基板。基板101可以具有大约50μm至大约300μm的厚度。The substrate 101 is a conductive substrate, and the conductive substrate may be a silicon, silicon carbide, or a metal substrate. The metal substrate is preferably a copper, tungsten or molybdenum substrate. The substrate 101 may have a thickness of about 50 μm to about 300 μm.
金属层按照功能划分可以为单层或至少两层,更优选的为至少两层功能层,其中至少一层按照功能可以定义为金属键合层102。该金属键合层102为将半导体垒晶叠层一侧粘附到基板101上时使用的键合金属材料,如金、锡、钛、镍、铂等金属,该键合金属层本身可以是多层材料组合。金属层中还可以包括在金属键合层102上侧并更靠近半导体垒晶叠层的金属反射层103,金属反射层103可以由包含Ag、Ni、Al、Rh、Pd、Ir、Ru、Mg、Zn、Pt、Au以及Hf中的至少一个的金属或者合金形成。该金属反射层103能够反射半导体垒晶叠层朝向基板101一侧辐射的光线返回至半导体垒晶叠层,并从出光侧辐射出去。The metal layer may be divided into a single layer or at least two layers according to functions, and more preferably at least two functional layers, of which at least one layer may be defined as the metal bonding layer 102 according to functions. The metal bonding layer 102 is a bonding metal material used when adhering one side of the semiconductor barrier crystal stack to the substrate 101, such as gold, tin, titanium, nickel, platinum and other metals. The bonding metal layer itself may be Multi-layer material combination. The metal layer may also include a metal reflective layer 103 on the upper side of the metal bonding layer 102 and closer to the semiconductor barrier crystal stack. The metal reflective layer 103 may be composed of Ag, Ni, Al, Rh, Pd, Ir, Ru, Mg. , Zn, Pt, Au, and Hf at least one metal or alloy formed. The metal reflective layer 103 can reflect the light radiated from the semiconductor barrier crystal stack toward the side of the substrate 101 back to the semiconductor barrier crystal stack and radiate out from the light exit side.
电介质层105位于所述第一导电型半导体层106的远离活性层107的一侧,所述电介质层105具有多个贯通的开口。所述电介质层105的多个贯通的开口为环形的,该开口可均匀地或非均匀地分布在半导体垒晶叠层的一侧。如图2所示,圆圈圈定部分为电介质层105的环形开口1051。电介质层的环形开口1051的宽度为D1,其范围为0~15um;环形开口的外径尺寸为D2,其范围为3~30um,环形开口的面积占整个电介质层面积的比例为10%~95%。电介质层105可以由具有小于金属反射层103或者欧姆接触层104的导电性的绝缘性材料、具有低导电性的材料、或者肖特基接触第一导电型半导体层106的材料形成。例如,电介质层105可以由氟化物、氮化物或氧化物等至少之一组成,具体的如ZnO、SiO 2、SiO x、SiO xN y、Si 3N 4、Al 2O 3、TiO x、MgF或GaF等至少一个形成。电介质层105为至少一层组成或多层不同折射率的电介质层材料组合形成,所述的电介质层105更优选的为透光电介质层,至少50%的光线能够通过该电介质层。更优选的,所述的电介质层105的折射率低于半导体垒晶叠层的折射率。在本实施例中,优选环形开口的图形为圆形,如图3所示,D1为环形开口的宽度,其范围优选为0~15μm,D2为环形开口的外径的宽度,其范围优选为3~30μm。 The dielectric layer 105 is located on a side of the first conductivity type semiconductor layer 106 away from the active layer 107, and the dielectric layer 105 has a plurality of through openings. The plurality of through openings of the dielectric layer 105 are ring-shaped, and the openings may be uniformly or non-uniformly distributed on one side of the semiconductor barrier crystal stack. As shown in FIG. 2, the circled part is the annular opening 1051 of the dielectric layer 105. The width of the annular opening 1051 of the dielectric layer is D1, and its range is 0~15um; the outer diameter of the annular opening is D2, and its range is 3~30um, and the area of the annular opening accounts for 10%~95 of the area of the entire dielectric layer. %. The dielectric layer 105 may be formed of an insulating material having a conductivity smaller than that of the metal reflective layer 103 or the ohmic contact layer 104, a material having low conductivity, or a material that is Schottky contacting the first conductivity type semiconductor layer 106. For example, the dielectric layer 105 may be composed of at least one of fluoride, nitride, or oxide, such as ZnO, SiO 2 , SiO x , SiO x N y , Si 3 N 4 , Al 2 O 3 , TiO x , At least one of MgF or GaF is formed. The dielectric layer 105 is formed by a combination of at least one layer of composition or multiple layers of dielectric layer materials with different refractive indexes. The dielectric layer 105 is more preferably a light-transmitting dielectric layer, and at least 50% of light can pass through the dielectric layer. More preferably, the refractive index of the dielectric layer 105 is lower than the refractive index of the semiconductor barrier crystal stack. In this embodiment, the pattern of the annular opening is preferably circular. As shown in FIG. 3, D1 is the width of the annular opening, and its range is preferably 0~15μm, and D2 is the width of the outer diameter of the annular opening, and its range is preferably 3~30μm.
金属反射层103与电介质层105之间可以包括欧姆接触层104,欧姆接触层104通过至少填充电介质层105的多个环形开口形成多个区域欧姆接触第一导电类型半导体层106,以将电流从金属层(包括金属反射层103、键合层102)均匀地传递到半导体垒晶叠层,因此欧姆接触层104并不是以整面的形式接触第一导电类型半导体层106一侧。欧姆接触层104可以由透明导电层如ITO、IZO、IZTO、IAZO、IGZO、IGTO、AZO以及ATO中的至少一个形成。欧姆接触层104也可以替代地使用光透射导电层和金属。所述的金属优选为合金材料,如金锌、金锗、金锗镍或金铍等材料,欧姆接触层104可以具有单层或者多层结构。An ohmic contact layer 104 may be included between the metal reflective layer 103 and the dielectric layer 105. The ohmic contact layer 104 forms a plurality of regions to ohmically contact the first conductive type semiconductor layer 106 by filling at least the plurality of annular openings of the dielectric layer 105 to transfer current from The metal layer (including the metal reflective layer 103 and the bonding layer 102) is uniformly transferred to the semiconductor barrier crystal stack, so the ohmic contact layer 104 does not contact the side of the first conductive type semiconductor layer 106 in the form of an entire surface. The ohmic contact layer 104 may be formed of a transparent conductive layer such as at least one of ITO, IZO, IZTO, IAZO, IGZO, IGTO, AZO, and ATO. The ohmic contact layer 104 may alternatively use a light-transmitting conductive layer and metal. The metal is preferably an alloy material, such as gold zinc, gold germanium, gold germanium nickel, or gold beryllium. The ohmic contact layer 104 may have a single-layer or multi-layer structure.
金属反射层103与电介质层105形成ODR反射结构,将半导体垒晶叠层朝向基板101一侧辐射的光线返回至半导体垒晶叠层,并从出光侧辐射出去,提高出光效率。本发明所述电介质层105具有多个贯通的环形开口,一方面欧姆接触层104通过该环形开口与第一导电型半导体层电性连接,保证电流的注入和导通,另一方面,如图4所示,相比电介质层的中空设计,可发现电介质层的开口位置采用内圈外圈的环形开口设计后,电流注入最强的地方,发光强度最强,而内圈外圈的电介质层(ODR)的反射作用可内外加强,可看出有较佳的ODR反射效果,电特性与光特性的交互作用增强。采用电介质层的环形开口设计后,LED可维持相同的工作电压,提升发光亮度,提升整体发光效能。The metal reflective layer 103 and the dielectric layer 105 form an ODR reflective structure, which returns the light radiated from the semiconductor barrier crystal stack toward the substrate 101 to the semiconductor barrier crystal stack and radiates out from the light exit side to improve light extraction efficiency. The dielectric layer 105 of the present invention has a plurality of through annular openings. On the one hand, the ohmic contact layer 104 is electrically connected to the first conductivity type semiconductor layer through the annular openings to ensure current injection and conduction. On the other hand, as shown in the figure As shown in 4, compared with the hollow design of the dielectric layer, it can be found that after the opening position of the dielectric layer adopts the annular opening design of the inner ring and the outer ring, the strongest current injection has the strongest luminous intensity, and the dielectric layer of the inner ring and the outer ring The reflection effect of (ODR) can be enhanced internally and externally. It can be seen that there is a better ODR reflection effect, and the interaction between electrical and optical characteristics is enhanced. After adopting the annular opening design of the dielectric layer, the LED can maintain the same working voltage, increase the luminous brightness, and improve the overall luminous efficiency.
半导体垒晶叠层为通过MOCVD或其它的生长方式获得的半导体垒晶叠层,该半导体垒晶叠层为能够提供常规的如紫外、蓝、绿、黄、红、红外光等辐射的半导体材料,具体的可以是200~950nm的材料,如常见的氮化物,具体的如氮化镓基半导体垒晶叠层,氮化镓基垒晶叠层常见有掺杂铝、铟等元素,主要提供200~550nm波段的辐射;或者常见的铝镓铟磷基或铝镓砷基半导体垒晶叠层,主要提供550~950nm波段的辐射。The semiconductor barrier crystal stack is a semiconductor barrier crystal stack obtained by MOCVD or other growth methods. The semiconductor barrier crystal stack is a semiconductor material that can provide conventional radiation such as ultraviolet, blue, green, yellow, red, and infrared light. , The specific material can be 200~950nm, such as common nitride, specific such as gallium nitride-based semiconductor barrier crystal stack, gallium nitride-based barrier crystal stack is usually doped with aluminum, indium and other elements, mainly to provide Radiation in the 200~550nm band; or the common aluminum gallium indium phosphorus-based or aluminum gallium arsenic-based semiconductor barrier crystal stack, which mainly provides radiation in the 550~950nm band.
半导体垒晶叠层主要包括第一导电型半导体层106、第二导电型半导体层108和第一导电型半导体层106和第二导电型半导体层108之间的活性层107。所述第一导电型半导体层106和第二导电型半导体层108可分别通过n型掺杂或P型掺杂以实现至少分别提供电子或空穴的材料层。n型半导体层可以掺杂有诸如Si、Ge、或者Sn的n型掺杂物,P型半导体层可以掺杂有诸如Mg、Zn、Ca、Sr、或者Ba的P型掺杂物。第一导电型半导体层106、活性层107、第二导电型半导体层108具体可以是铝镓铟氮、氮化镓、铝镓氮、铝铟磷、铝镓铟磷或砷化镓或铝镓砷等材料制作形成。第一导电类型半导体层106或第二导电类型半导体层108中包括提供电子或空穴的覆盖层,以及可以包括其它层材料如电流扩展层、窗口层或欧姆接触层等,根据掺杂浓度或组分含量不同进行设置为不同的多层。活性层107为提供电子和空穴复合提供光辐射的区域,根据发光波长的不同可选择不同的材料,活性层107可以是单量子阱或多量子阱的周期性结构。通过调整活性层107中半导体材料的组成比,以期望辐射出不同波长的光。The semiconductor barrier layer stack mainly includes a first conductivity type semiconductor layer 106, a second conductivity type semiconductor layer 108, and an active layer 107 between the first conductivity type semiconductor layer 106 and the second conductivity type semiconductor layer 108. The first conductive type semiconductor layer 106 and the second conductive type semiconductor layer 108 may be respectively n-type doped or p-type doped to realize a material layer that at least provides electrons or holes, respectively. The n-type semiconductor layer may be doped with n-type dopants such as Si, Ge, or Sn, and the p-type semiconductor layer may be doped with p-type dopants such as Mg, Zn, Ca, Sr, or Ba. The first conductive semiconductor layer 106, the active layer 107, and the second conductive semiconductor layer 108 may specifically be aluminum gallium indium nitride, gallium nitride, aluminum gallium nitride, aluminum indium phosphorus, aluminum gallium indium phosphorus, or gallium arsenide or aluminum gallium. Made of arsenic and other materials. The first conductive type semiconductor layer 106 or the second conductive type semiconductor layer 108 includes a covering layer that provides electrons or holes, and may include other layer materials such as a current spreading layer, a window layer, or an ohmic contact layer, etc., depending on the doping concentration or The content of the components is different, and it is set to different multi-layers. The active layer 107 is a region where electrons and holes are recombined to provide light radiation. Different materials can be selected according to different emission wavelengths. The active layer 107 may be a periodic structure of single quantum well or multiple quantum wells. By adjusting the composition ratio of the semiconductor materials in the active layer 107, light of different wavelengths is expected to be radiated.
第二电极109配置在半导体垒晶叠层的出光侧上,与第二导电型半导体层形成电连接。所述第二电极109主要包括焊盘部分,该焊盘部分主要用于封装时外部打线。第二电极的焊盘可以根据实际的打线需要设计成不同的形状,具体如圆柱状或方块或其它的多边形。作为一个优选的实施方式,第二电极还可以包括从焊盘延伸的延伸部分,该延伸部分可以以预定的图案形状被形成,并且延伸部分可以具有各种形状,具体的如条状。The second electrode 109 is arranged on the light emitting side of the semiconductor barrier crystal stack, and forms an electrical connection with the second conductivity type semiconductor layer. The second electrode 109 mainly includes a pad portion, and the pad portion is mainly used for external wiring during packaging. The pads of the second electrode can be designed in different shapes according to actual wire bonding requirements, such as cylindrical or square or other polygonal shapes. As a preferred embodiment, the second electrode may further include an extension part extending from the pad, the extension part may be formed in a predetermined pattern shape, and the extension part may have various shapes, such as a strip shape.
所述的半导体发光元件还包括第一电极110,所述第一电极110通过金属层与第一导电型半导体层形成电连接。本实施例中所述的第一电极110以整面的形式形成在基板101背面侧,本实施例的基板为导电性支撑基板,第二电极109与第一电极110形成在支撑基板101的两面侧,以实现电流垂直流过半导体垒晶叠层,提供均匀的电流密度。The semiconductor light emitting element further includes a first electrode 110, and the first electrode 110 is electrically connected to the first conductive semiconductor layer through the metal layer. The first electrode 110 described in this embodiment is formed on the back side of the substrate 101 in the form of a whole surface. The substrate of this embodiment is a conductive support substrate, and the second electrode 109 and the first electrode 110 are formed on both sides of the support substrate 101 Side, in order to realize that the current flows vertically through the semiconductor barrier crystal stack to provide a uniform current density.
第二电极109和第一电极110优选为金属材料制成。第二电极109至少焊盘部分以及延伸部分还可以包括实现与半导体发光序列之间形成良好的欧姆接触的金属材料。The second electrode 109 and the first electrode 110 are preferably made of metal materials. At least the pad portion and the extension portion of the second electrode 109 may also include a metal material for forming a good ohmic contact with the semiconductor light emitting sequence.
本发明还制备了对比例的样品,对比例中电介质层的开口为常规圆形开口,除此之外以实施例1相同的条件进行半导体发光元件的制作,且对比例和实施例1中电介质层开口的面积占比相同。The present invention also prepared a sample of a comparative example. The opening of the dielectric layer in the comparative example was a conventional circular opening. In addition, the semiconductor light-emitting element was fabricated under the same conditions as in Example 1, and the comparative example and the dielectric in Example 1 The area of the layer openings accounts for the same proportion.
对上述对比例和实施例一的半导体发光元件进行光电性能测试,其特性结果示于下表1。The photoelectric performance test of the semiconductor light-emitting element of the above-mentioned comparative example and Example 1 was carried out, and the characteristic results are shown in Table 1 below.
表1Table 1
 
Figure 41616dest_path_image001
Figure 41616dest_path_image001
在对比例中,在第一电极和第二电极间流通了电流,发射出峰发光波长为944nm的红外光。另外,如表1所示,在对比例中,正向流通350毫安(mA)的电流时,其正向电压Vf 1为2.98V。正向电流设为350mA时发光的输出功率(P 0)为350mW。对实施例1中半导体发光元件进行测试,正向电流为350mA时,其发光输出功率(P 0)和正向电压(Vf1)分别为365mW,2.97V。实验结果显示,在保证电介质层开口面积占比相同的情况下,电介质层开口采用环形开口,实施例一的Vf 1与对比例的Vf 1相同,但其发光输出功率较对比例提升了3.75%。 In the comparative example, a current was passed between the first electrode and the second electrode, and infrared light with a peak emission wavelength of 944 nm was emitted. In addition, as shown in Table 1, in the comparative example, when a current of 350 milliamperes (mA) was passed in the forward direction, the forward voltage Vf 1 was 2.98V. The luminous output power (P 0 ) when the forward current is set to 350 mA is 350 mW. The semiconductor light-emitting element in Example 1 was tested, and when the forward current was 350 mA, its luminous output power (P 0 ) and forward voltage (Vf1) were 365 mW and 2.97V, respectively. Experimental results show that, in the case where the assurance of the dielectric layer of the same area proportion of the openings, the dielectric layer having an opening using ring opening, for example, a Vf of 1 1 has the same comparative Vf of the embodiment, but the emission output power compared to Comparative enhance 3.75% .
由此可以看出,在保证电介质层开口的面积占比的情况下,相对于电介质层的中空设计,电介质层的环形开口可在保证电流的导通和注入的情况下,提升半导体发光元件的反射率,从而提升半导体发光元件的发光效率。It can be seen from this that, under the condition that the area of the opening of the dielectric layer is guaranteed, compared with the hollow design of the dielectric layer, the annular opening of the dielectric layer can improve the semiconductor light-emitting element while ensuring the conduction and injection of current. Reflectivity, thereby improving the luminous efficiency of semiconductor light-emitting elements.
实施例二Example two
本实施例,如图5所示,与实施例一的区别在于,实施例一中电介质层105的环形开口的形状为圆形的,而本实施例中电介质层105的环形开口的形状为方形的。This embodiment, as shown in FIG. 5, differs from the first embodiment in that the shape of the annular opening of the dielectric layer 105 in the first embodiment is circular, while the shape of the annular opening of the dielectric layer 105 in this embodiment is square of.
实施例三Example three
本实施例,如图6所示,与实施例一的区别在于,实施例一中电介质层105的环形开口的形状为圆形的,而本实施例中电介质层105的环形开口的形状为菱形的。This embodiment, as shown in FIG. 6, differs from the first embodiment in that the shape of the annular opening of the dielectric layer 105 in the first embodiment is circular, while the shape of the annular opening of the dielectric layer 105 in this embodiment is a rhombus. of.
实施例四Example four
如图7所示,不同于实施例一的是,本实施例提供另外一种半导体发光元件,倒装发光二极管,所述半导体发光元件包括如下堆叠层:201:基板;202:金属保护层;203:金属反射层;204:欧姆接触层;205:电介质层;206:第一导电型半导体层;207:活性层;208:第二导电型半导体层;209:第二极;210:第一电极;2051:电介质层的环形开口;211:绝缘保护层。As shown in FIG. 7, different from the first embodiment, this embodiment provides another semiconductor light-emitting element, a flip-chip light-emitting diode, which includes the following stacked layers: 201: a substrate; 202: a metal protective layer; 203: metal reflective layer; 204: ohmic contact layer; 205: dielectric layer; 206: first conductivity type semiconductor layer; 207: active layer; 208: second conductivity type semiconductor layer; 209: second pole; 210: first Electrode; 2051: ring-shaped opening of the dielectric layer; 211: insulating protective layer.
所述基板201为透明基板,所述透明基板201可以是用于半导体垒晶叠层生长的生长基板,也可以是通过透明粘合层与半导体垒晶叠层结合的透明基板,具体包括平面型蓝宝石衬底、图形蓝宝石衬底、碳化硅衬底、氮化镓衬底等。在本实施例中,所述透明基板201选用为图形蓝宝石衬底。在另一些实施例,所述基板可以减薄或者移除,形成薄膜型LED芯片。The substrate 201 is a transparent substrate. The transparent substrate 201 may be a growth substrate used for the growth of a semiconductor barrier crystal stack, or it may be a transparent substrate combined with a semiconductor barrier crystal stack through a transparent adhesive layer, specifically including a planar type. Sapphire substrate, patterned sapphire substrate, silicon carbide substrate, gallium nitride substrate, etc. In this embodiment, the transparent substrate 201 is selected as a patterned sapphire substrate. In other embodiments, the substrate can be thinned or removed to form a thin-film LED chip.
所述半导体垒晶叠层位于所述透明基板201上,包括依次层叠的第一导电型半导体层206、活性层207以及第二导电型半导体层208。在其中一个优选的实施例中,所述第一导电型半导体层206和第二导电型半导体层208可以分别为p型GaN或者N型GaN,所述活性层207可以为GaN基量子阱层。当然,也可以依据实际需求选择其它种类的外延结构,并不限于此处所列举的示例。The semiconductor barrier crystal stack is located on the transparent substrate 201 and includes a first conductivity type semiconductor layer 206, an active layer 207, and a second conductivity type semiconductor layer 208 stacked in sequence. In one of the preferred embodiments, the first conductivity type semiconductor layer 206 and the second conductivity type semiconductor layer 208 may be p-type GaN or N-type GaN, respectively, and the active layer 207 may be a GaN-based quantum well layer. Of course, other types of epitaxial structures can also be selected according to actual needs, and are not limited to the examples listed here.
局部缺陷区2211位于部分所述第一导电型半导体层206上,且向下延伸至所述第二导电型半导体层208形成台面结构,所述台面结构露出有所述外延结构侧壁,具体地,所述台面结构显露有第二导电型半导体层208台面以及第一导电型半导体层206、活性层207及第二导电型半导体层208的侧壁。需要说明的是,局部缺陷区1211的数量至少一个,也可以根据LED芯片的结构、面积大小等进行增加。The local defect region 2211 is located on a part of the first conductivity type semiconductor layer 206 and extends downward to the second conductivity type semiconductor layer 208 to form a mesa structure. The mesa structure exposes the sidewalls of the epitaxial structure, specifically The mesa structure reveals the mesa of the second conductivity type semiconductor layer 208 and the sidewalls of the first conductivity type semiconductor layer 206, the active layer 207, and the second conductivity type semiconductor layer 208. It should be noted that the number of locally defective regions 1211 is at least one, and it can also be increased according to the structure and area of the LED chip.
欧姆接触层204位于第一导电型半导体层206上,欧姆接触层204可以由透明导电层如ITO、IZO、IZTO、IAZO、IGZO、IGTO、AZO以及ATO中的至少一个形成。欧姆接触层204也可以替代地使用光透射导电层和金属。所述的金属优选为合金材料,如金锌、金锗、金锗镍或金铍等材料,欧姆接触层204可以具有单层或者多层结构。欧姆接触层与第一导电型半导体层206欧姆接触。The ohmic contact layer 204 is located on the first conductive type semiconductor layer 206, and the ohmic contact layer 204 may be formed of a transparent conductive layer such as at least one of ITO, IZO, IZTO, IAZO, IGZO, IGTO, AZO, and ATO. The ohmic contact layer 204 may alternatively use a light-transmitting conductive layer and metal. The metal is preferably an alloy material, such as gold zinc, gold germanium, gold germanium nickel, or gold beryllium. The ohmic contact layer 204 may have a single-layer or multi-layer structure. The ohmic contact layer is in ohmic contact with the first conductivity type semiconductor layer 206.
所述电介质层205包裹所述欧姆接触层的侧壁以及覆盖于所述相邻的发光外延结构的侧壁,其中包裹所述欧姆接触层204的侧壁的电介质层205主要用于与欧姆接触层204、金属反射层203构成全方位反射层(ODR)结构,覆盖于所述相邻的发光外延结构的侧壁的电介质层205主要作为电绝缘的作用;进一步地,所述电介质层具有一系列环形开口结构,如附图7中所示,2051为电介质层的环形开口。The dielectric layer 205 wraps the sidewalls of the ohmic contact layer and covers the sidewalls of the adjacent light-emitting epitaxial structure, wherein the dielectric layer 205 that wraps the sidewalls of the ohmic contact layer 204 is mainly used for ohmic contact The layer 204 and the metal reflective layer 203 constitute an omnidirectional reflective layer (ODR) structure. The dielectric layer 205 covering the sidewalls of the adjacent light-emitting epitaxial structure mainly serves as electrical insulation; further, the dielectric layer has a A series of annular opening structure, as shown in FIG. 7, 2051 is the annular opening of the dielectric layer.
于所述外延结构的部分表面形成具有环形开口结构的电介质层205,所述电介质层205可以为低折射率材料,如二氧化硅层、氟化镁等,也可以为高折射率材料,如二氧化钛等,或电介质层205也可以是包括高、低折射率材料的分布布拉格反射层(DBR),且并不限于此处所列举的示例。A dielectric layer 205 having a ring-shaped opening structure is formed on part of the surface of the epitaxial structure. The dielectric layer 205 may be a low refractive index material, such as a silicon dioxide layer, magnesium fluoride, etc., or a high refractive index material, such as Titanium dioxide or the like, or the dielectric layer 205 may also be a distributed Bragg reflector (DBR) layer including high and low refractive index materials, and is not limited to the examples listed here.
金属层形成于所述电介质层205表面,,所述金属层可以包括多层结构,如金属反射层203、金属保护层202等,并不限于此处所列举的示例。作为示例,当金属反射层203选用Al或Ag高反射金属,作为反射镜(mirror)时,金属保护层202(Barrier)选用TiW合金等,金属保护层202可以是完全包裹金属反射层203,用于保护金属反射层。A metal layer is formed on the surface of the dielectric layer 205, and the metal layer may include a multilayer structure, such as a metal reflective layer 203, a metal protective layer 202, etc., and is not limited to the examples listed here. As an example, when the metal reflective layer 203 is made of Al or Ag highly reflective metal as a mirror (mirror), the metal protective layer 202 (Barrier) is made of TiW alloy, etc., and the metal protective layer 202 can be completely wrapped around the metal reflective layer 203. To protect the metal reflective layer.
在本实施例中,金属反射层203与电介质层205形成ODR反射结构,将半导体垒晶叠层朝向基板201一侧辐射的光线返回至半导体垒晶叠层,并从透明基板201侧辐射出去,提高出光效率。所述电介质层205具有多个贯通的环形开口,所述金属层通过该环形开口2051与第一导电型半导体层206电性连接,保证电流的注入和导通,另一方面,如图4所示,相比电介质层的中空设计,可发现电介质层的开口位置采用内圈外圈的环形开口设计后,电流注入最强的地方,发光强度最强,而内圈外圈的电介质层(ODR)的反射作用可内外加强,可看出有较佳的ODR反射效果,电特性与光特性的交互作用增强。采用电介质层的环形开口设计后,半导体发光元件可维持相同的工作电压,提升发光亮度,提升整体发光效能。In this embodiment, the metal reflective layer 203 and the dielectric layer 205 form an ODR reflective structure, which returns the light radiated from the semiconductor barrier crystal stack toward the substrate 201 side to the semiconductor barrier crystal stack and radiates out from the transparent substrate 201 side. Improve light output efficiency. The dielectric layer 205 has a plurality of through annular openings, and the metal layer is electrically connected to the first conductive semiconductor layer 206 through the annular openings 2051 to ensure current injection and conduction. On the other hand, as shown in FIG. 4 It is shown that compared with the hollow design of the dielectric layer, it can be found that after the opening position of the dielectric layer adopts the annular opening design of the inner ring and the outer ring, the strongest current injection has the strongest luminous intensity, and the dielectric layer of the inner ring and the outer ring (ODR The reflection effect of) can be strengthened internally and externally. It can be seen that there is a better ODR reflection effect, and the interaction between electrical and optical characteristics is enhanced. After adopting the annular opening design of the dielectric layer, the semiconductor light-emitting element can maintain the same working voltage, improve the luminous brightness, and improve the overall luminous efficiency.
半导体发光元件中还可以包括绝缘保护层211,形成于金属保护层202、局部缺陷区2211之上,并于绝缘保护层211中形成绝缘保护层211的第一通孔结构2111和绝缘保护层211的第二通孔结构2112。其中第一通孔结构2111作为第一电极的预留窗口,第二通孔结构2112作为第二电极的预留窗口。第一电极210形成于所述第一电极的预留窗口中,以实现第一电极与第一导电型半导体层电性连接;第二电极209形成于所述第二电极的预留窗口中,以实现所述第二电极与第二导电型半导体层电性连接。The semiconductor light-emitting element may also include an insulating protection layer 211 formed on the metal protection layer 202 and the local defect region 2211, and the first via structure 2111 and the insulating protection layer 211 of the insulating protection layer 211 are formed in the insulating protection layer 211 The second through-hole structure 2112. The first through-hole structure 2111 serves as a reserved window for the first electrode, and the second through-hole structure 2112 serves as a reserved window for the second electrode. The first electrode 210 is formed in the reserved window of the first electrode to realize the electrical connection between the first electrode and the first conductivity type semiconductor layer; the second electrode 209 is formed in the reserved window of the second electrode, In order to realize the electrical connection between the second electrode and the second conductivity type semiconductor layer.
作为示例,所述绝缘保护层211可以为低折射率材料,如二氧化硅层、氟化镁等,也可以为高折射率材料,如二氧化钛等,或绝缘保护层211也可以是分布布拉格反射层(DBR),且并不限于此处所列举的示例。As an example, the insulating protection layer 211 can be a low refractive index material, such as a silicon dioxide layer, magnesium fluoride, etc., or a high refractive index material, such as titanium dioxide, etc., or the insulating protection layer 211 can also be a distributed Bragg reflector. Layer (DBR), and is not limited to the examples listed here.
需要说明的是,根据需要,也可以在制作完第一、第二电极之后,再于第一、第二电极之上形成第三绝缘层(图中未示出),并形成通孔结构,作为电极窗口,最后于电极窗口中形成第三、第四电极。It should be noted that, according to needs, after the first and second electrodes are fabricated, a third insulating layer (not shown in the figure) can be formed on the first and second electrodes, and a through hole structure can be formed. As the electrode window, the third and fourth electrodes are finally formed in the electrode window.
本实施例通过低折射率电介质层、金属反射层形成全方位反射层(ODR)结构,其反射效果优于常规的金属反射层或分布布拉格反射层结构,增强半导体发光元件的外部光萃取几率,提高LED器件的亮度;通过对电介质层形成环形开口结构,使金属层与欧姆接触层实现电连通,从而维持半导体发光元件的电压(VF)不上升;通过对电介质层采用环形开口设计,在保证电介质层开口面积的占比情况下,可保证电流的注入和导通,同时提升光的反射效果,提升半导体发光元件的发光效率。In this embodiment, an omnidirectional reflector (ODR) structure is formed by a low-refractive-index dielectric layer and a metal reflective layer, and its reflection effect is better than that of a conventional metal reflective layer or a distributed Bragg reflective layer structure, which enhances the probability of external light extraction of the semiconductor light-emitting element. Improve the brightness of the LED device; by forming a ring-shaped opening structure on the dielectric layer, the metal layer and the ohmic contact layer are electrically connected, so as to maintain the voltage (VF) of the semiconductor light-emitting element not rising; by adopting the ring-shaped opening design for the dielectric layer, it is guaranteed In the case of the proportion of the opening area of the dielectric layer, the injection and conduction of current can be ensured, while the light reflection effect is improved, and the luminous efficiency of the semiconductor light-emitting element is improved.
实施例五Example five
本发明提供的半导体发光元件可以广泛运用于显示或背光的封装体或应用上,尤其可以满足背光产品的高亮度需求。The semiconductor light-emitting element provided by the present invention can be widely used in display or backlight packages or applications, and can especially meet the high-brightness requirements of backlight products.
具体地,本实施例提供如图8所示的封装体,所述封装体包含安装基板30,半导体发光元件10和密封树脂305。至少前述实施例中的一个半导体发光元件安装到安装基板30上,安装基板30为绝缘性基板,如RGB显示屏用的封装模组基板或背光显示用的模组基板,安装基板30的一表面具有电隔离的第一电极端子301和第二电极端子302。半导体发光元件位于安装基板30的一表面上,半导体发光元件的第一电极210和第二电极209分别通过第一结合部303和第二结合部304与第一电极端子301和第二电极端子302连接。第一结合部303和第二结合部304包括但不限于是焊料,如共晶焊或回流焊料。Specifically, this embodiment provides a package as shown in FIG. 8, the package including a mounting substrate 30, a semiconductor light emitting element 10 and a sealing resin 305. At least one semiconductor light-emitting element in the foregoing embodiments is mounted on the mounting substrate 30. The mounting substrate 30 is an insulating substrate, such as a package module substrate for RGB display screen or a module substrate for backlight display. One surface of the mounting substrate 30 There is a first electrode terminal 301 and a second electrode terminal 302 that are electrically isolated. The semiconductor light-emitting element is located on one surface of the mounting substrate 30. The first electrode 210 and the second electrode 209 of the semiconductor light-emitting element pass through the first coupling portion 303 and the second coupling portion 304, respectively, and the first electrode terminal 301 and the second electrode terminal 302. connection. The first bonding portion 303 and the second bonding portion 304 include but are not limited to solder, such as eutectic solder or reflow solder.
半导体发光元件封装件发射具有蓝光或者混合颜色(例如,白色)的光。例如半导体发光元件芯片发射蓝光波段的光,例如峰值波长为450nm的光,封装件还包括用于对半导体发光元件芯片进行保护的透明的密封树脂306,也提供相应蓝光波段的光辐射。或者封装件为了发射白色的光,可以包括用于对从半导体发光元件芯片发射的光进行波长转换的荧光转换材料。荧光转换材料可以设置在密封树脂306中。密封树脂306可通过点胶或贴膜的方式覆盖在半导体发光元件芯片的至少一侧,但不限于此。荧光转换材料可以是红色与绿色组合的荧光转换材料,或者黄色磷光体或者红黄绿组合的荧光转换材料。本发明由于半导体发光元件具有高反射效率的ODR结构,可提升半导体发光元件的发光效率,从而可以提升整个半导体发光元件封装件的发光效率。The semiconductor light emitting element package emits light having blue light or mixed colors (for example, white). For example, the semiconductor light emitting element chip emits light in the blue wavelength band, such as light with a peak wavelength of 450 nm, and the package further includes a transparent sealing resin 306 for protecting the semiconductor light emitting element chip, and also provides light radiation in the corresponding blue wavelength band. Or, in order to emit white light, the package may include a fluorescence conversion material for wavelength conversion of light emitted from the semiconductor light emitting element chip. The fluorescence conversion material may be provided in the sealing resin 306. The sealing resin 306 may be applied to at least one side of the semiconductor light-emitting element chip by dispensing or pasting, but is not limited thereto. The fluorescence conversion material may be a fluorescence conversion material in which red and green are combined, or a yellow phosphor or a fluorescence conversion material in which red, yellow and green are combined. Since the semiconductor light emitting element has an ODR structure with high reflection efficiency in the present invention, the light emitting efficiency of the semiconductor light emitting element can be improved, so that the light emitting efficiency of the entire semiconductor light emitting element package can be improved.
需要说明的是,以上实施方式仅用于说明本发明,而并非用于限定本发明,本领域的技术人员,在不脱离本发明的精神和范围的情况下,可以对本发明做出各种修饰和变动,因此所有等同的技术方案也属于本发明的范畴,本发明的专利保护范围应视权利要求书范围限定。It should be noted that the above embodiments are only used to illustrate the present invention, but not to limit the present invention. Those skilled in the art can make various modifications to the present invention without departing from the spirit and scope of the present invention. Therefore, all equivalent technical solutions also belong to the scope of the present invention, and the scope of patent protection of the present invention should be defined in accordance with the scope of the claims.

Claims (18)

  1. 一种半导体发光元件,其包括: 半导体垒晶叠层,包括第一导电型半导体层、第二导电型半导体层和位于所述第一导电型半导体层和第二导电型半导体层之间的活性层; 电介质层,位于所述第一导电型半导体层的远离活性层的一侧,所述电介质层具有多个贯通的开口; 金属层,位于所述电介质层的远离第一导电型半导体层的一侧,所述金属层通过所述电介质层的多个开口与第一导电型半导体层进行电性连接; 其特征在于,所述电介质层的多个贯通的开口为环形的。A semiconductor light emitting element, comprising: a semiconductor barrier crystal stack, including a first conductivity type semiconductor layer, a second conductivity type semiconductor layer, and an activity located between the first conductivity type semiconductor layer and the second conductivity type semiconductor layer The dielectric layer is located on the side of the first conductivity type semiconductor layer away from the active layer, and the dielectric layer has a plurality of through openings; the metal layer is located on the side of the dielectric layer away from the first conductivity type semiconductor layer On one side, the metal layer is electrically connected to the first conductivity type semiconductor layer through a plurality of openings of the dielectric layer; wherein the plurality of through openings of the dielectric layer are ring-shaped.
  2. 根据权利要求1所述的一种半导体发光元件,其特征在于,所述电介质层的环形开口为圆形、方形、星形、菱形或者不规则形状的。The semiconductor light-emitting element according to claim 1, wherein the annular opening of the dielectric layer is circular, square, star-shaped, diamond-shaped or irregular in shape.
  3. 根据权利要求1所述的一种半导体发光元件,其特征在于,所述电介质层的环形开口的宽度为0~15um,环形开口的外径尺寸为3~30um,环形开口的面积占整个电介质层面积的比例为10%~95%。The semiconductor light-emitting element according to claim 1, wherein the width of the annular opening of the dielectric layer is 0-15um, the outer diameter of the annular opening is 3-30um, and the area of the annular opening occupies the entire dielectric layer. The proportion of area is 10%~95%.
  4. 根据权利要求1所述的一种半导体发光元件,其特征在于,所述电介质层为单层或者多层结构,为氮化物、氧化物或氟化物中至少一种材料组成。The semiconductor light-emitting element according to claim 1, wherein the dielectric layer has a single-layer or multi-layer structure and is composed of at least one of nitride, oxide, or fluoride.
  5. 根据权利要求1所述的一种半导体发光元件,其特征在于,所述金属层至少包括金属反射层。The semiconductor light-emitting element according to claim 1, wherein the metal layer at least includes a metal reflective layer.
  6. 根据权利要求5所述的一种半导体发光元件,其特征在于,所述金属反射层可以为Ag、Ni、Al、Rh、Pd、Ir、Ru、Mg、Zn、Pt、Au以及Hf中的至少一种的金属或者合金形成。The semiconductor light-emitting element according to claim 5, wherein the metal reflective layer can be at least one of Ag, Ni, Al, Rh, Pd, Ir, Ru, Mg, Zn, Pt, Au, and Hf. A kind of metal or alloy is formed.
  7. 根据权利要求6所述的一种半导体发光元件,其特征在于,所述金属反射层和所述电介质层形成ODR反射结构,将半导体垒晶叠层发出的光反射至出光侧。7. The semiconductor light emitting element according to claim 6, wherein the metal reflective layer and the dielectric layer form an ODR reflective structure to reflect the light emitted by the semiconductor barrier crystal stack to the light emitting side.
  8. 根据权利要求1所述的一种半导体发光元件,其特征在于,所述半导体垒晶叠层辐射蓝光、绿光、红光或红外光。The semiconductor light emitting element according to claim 1, wherein the semiconductor barrier crystal laminate radiates blue light, green light, red light or infrared light.
  9. 根据权利要求1所述的一种半导体发光元件,其特征在于,还包括一第二电极,位于所述第二导电型半导体层的上部并与第二导电型半导体层电性连接。The semiconductor light-emitting element according to claim 1, further comprising a second electrode located on the upper part of the second conductivity type semiconductor layer and electrically connected to the second conductivity type semiconductor layer.
  10. 根据权利要求1所述的一种半导体发光元件,其特征在于,还包括一第一电极与金属层电性连接。The semiconductor light emitting device of claim 1, further comprising a first electrode electrically connected to the metal layer.
  11. 根据权利要求10所述的一种半导体发光元件,其特征在于,所述的金属层下方具有基板,所述的基板为导电型基板,基板位于所述第一电极与金属层之间。10. The semiconductor light emitting device according to claim 10, wherein a substrate is provided under the metal layer, the substrate is a conductive substrate, and the substrate is located between the first electrode and the metal layer.
  12. 根据权利要求11所述的一种半导体发光元件,其特征在于,所述的导电型基板为硅、碳化硅、金属基板。The semiconductor light-emitting element according to claim 11, wherein the conductive substrate is silicon, silicon carbide, or metal substrate.
  13. 根据权利要求12所述的一种半导体发光元件,其特征在于,所述的金属基板为铜,钨或者钼基板。The semiconductor light-emitting element according to claim 12, wherein the metal substrate is a copper, tungsten or molybdenum substrate.
  14. 根据权利要求1所述的一种半导体发光元件,其特征在于,所述金属层通过欧姆接触层与第一导电型半导体层形成欧姆接触。The semiconductor light-emitting element according to claim 1, wherein the metal layer forms an ohmic contact with the first conductive semiconductor layer through an ohmic contact layer.
  15. 根据权利要求14所述的一种半导体发光元件,其特征在于,所述欧姆接触层为透明导电层或者金属合金。The semiconductor light-emitting element according to claim 14, wherein the ohmic contact layer is a transparent conductive layer or a metal alloy.
  16. 根据权利要求1所述的一种半导体发光元件,其特征在于,还包括一透明基板,位于第二导电类型半导体层之上。The semiconductor light emitting device according to claim 1, further comprising a transparent substrate on the second conductivity type semiconductor layer.
  17. 根据权利要求16所述的一种半导体发光元件,其特征在于,还包括局部缺陷区,位于部分所述第一导电型半导体层上,并向下延伸至所述第二导电型半导体层形成台面结构,所述台面结构露出有发光外延结构侧壁。The semiconductor light-emitting element according to claim 16, further comprising a local defect area, which is located on a part of the first conductivity type semiconductor layer and extends down to the second conductivity type semiconductor layer to form a mesa Structure, the mesa structure has exposed sidewalls of the light-emitting epitaxial structure.
  18. 根据权利要求17所述的一种半导体发光元件,其特征在于:还包括第一电极和第二电极,所述第一电极,形成于所述金属层上,与第一导电型半导体层形成电性连接;所述第二电极;形成于所述局部缺陷区,与第二导电型半导体层形成电性连接。The semiconductor light-emitting element according to claim 17, further comprising a first electrode and a second electrode, the first electrode is formed on the metal layer and forms an electrical connection with the first conductivity type semiconductor layer. The second electrode; is formed in the local defect area to form an electrical connection with the second conductivity type semiconductor layer.
PCT/CN2020/135236 2019-12-23 2020-12-10 Semiconductor light-emitting element WO2021129405A1 (en)

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