WO2021018308A1 - 一种具有环状类y型电极的微尺寸led器件及制备方法 - Google Patents
一种具有环状类y型电极的微尺寸led器件及制备方法 Download PDFInfo
- Publication number
- WO2021018308A1 WO2021018308A1 PCT/CN2020/106458 CN2020106458W WO2021018308A1 WO 2021018308 A1 WO2021018308 A1 WO 2021018308A1 CN 2020106458 W CN2020106458 W CN 2020106458W WO 2021018308 A1 WO2021018308 A1 WO 2021018308A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- boss
- branch
- electrode
- ring
- Prior art date
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 238000002161 passivation Methods 0.000 claims abstract description 24
- 239000000758 substrate Substances 0.000 claims abstract description 21
- 239000010410 layer Substances 0.000 claims description 280
- 238000003892 spreading Methods 0.000 claims description 58
- 230000007480 spreading Effects 0.000 claims description 58
- 229920002120 photoresistant polymer Polymers 0.000 claims description 50
- 238000000034 method Methods 0.000 claims description 24
- 238000005530 etching Methods 0.000 claims description 21
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 15
- 238000005516 engineering process Methods 0.000 claims description 10
- 238000000206 photolithography Methods 0.000 claims description 10
- 238000001039 wet etching Methods 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 8
- 229910002704 AlGaN Inorganic materials 0.000 claims description 7
- 239000003929 acidic solution Substances 0.000 claims description 7
- 238000000137 annealing Methods 0.000 claims description 6
- 238000001312 dry etching Methods 0.000 claims description 5
- 238000005566 electron beam evaporation Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 239000002356 single layer Substances 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 230000008021 deposition Effects 0.000 claims description 3
- 238000005070 sampling Methods 0.000 claims description 3
- 229910052594 sapphire Inorganic materials 0.000 claims description 3
- 239000010980 sapphire Substances 0.000 claims description 3
- 238000007788 roughening Methods 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- 238000009826 distribution Methods 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 230000005540 biological transmission Effects 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000006798 recombination Effects 0.000 description 3
- 238000005215 recombination Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000000233 ultraviolet lithography Methods 0.000 description 2
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- HHAVHBDPWSUKHZ-UHFFFAOYSA-N propan-2-ol;propan-2-one Chemical compound CC(C)O.CC(C)=O HHAVHBDPWSUKHZ-UHFFFAOYSA-N 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/005—Processes
- H01L33/0062—Processes for devices with an active region comprising only III-V compounds
- H01L33/0075—Processes for devices with an active region comprising only III-V compounds comprising nitride compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/14—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a carrier transport control structure, e.g. highly-doped semiconductor layer or current-blocking structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/20—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a particular shape, e.g. curved or truncated substrate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/36—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
- H01L33/38—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes with a particular shape
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/44—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the coatings, e.g. passivation layer or anti-reflective coating
Definitions
- the invention relates to the technical field of light-emitting devices for visible light communication, in particular to a micro-sized LED device with a ring-like Y-shaped electrode and a preparation method.
- the signal can be modulated to the visible light emitted by it for transmission, taking into account the lighting and realizing the visible light wireless communication.
- the modulation bandwidth of the LED is mainly affected by the minority carrier recombination lifetime and the RC time constant in the active region, where R and C are the equivalent resistance and equivalent capacitance of the LED device, respectively.
- Reducing the active area area of the LED device that is, realizing the micron-sized LED, on the one hand, it can effectively reduce the equivalent capacitance, thereby reducing the RC time constant; on the other hand, it can increase the current per unit area of the LED device and reduce the active area
- the recombination lifetime of minority carriers ultimately realizes the improvement of the modulation bandwidth of the device.
- micron-sized LED pixels are small in size, high in integration, and have higher unit current density in the active area.
- the current crowding effect has a more significant impact on it, and the current expansion on the surface of the device appears more For important reasons, the choice of electrode shape directly affects the expansion of the current.
- the LED When the LED is injecting current, because the conductivity of P-type GaN is poor, the current in the vertical direction is greater than the current in the horizontal direction, resulting in that the current cannot be effectively and evenly distributed in the P-type GaN after the current injection, resulting in local current concentration and the LED device turning on voltage If it is too high, the luminescence and heating will be uneven, and the non-radiative recombination of the active layer will increase, resulting in a decrease in internal quantum efficiency. Therefore, improving the uniformity of the lateral expansion of the LED current is very important for improving the performance of the LED, and a reasonable electrode structure can effectively realize the lateral expansion of the current.
- LEDs usually use the most common opaque circular electrode structure.
- the current is mainly concentrated in the part of the area directly below the circular electrode, and the distance between the electrode and the active area is limited, and the current is reached before the lateral expansion is sufficient.
- the active area that is, the light-emitting area in the active area is mainly concentrated in the part of the active area under the electrode, which causes the current crowding effect. Therefore, it is necessary to minimize the vertical current under the P electrode when designing the electrode, and the injection current should maximize the transmission current, that is, the transmission distance should be less than the current transmission length, and the electrode area should not be too large, because the electrode is too large to largely block Light output.
- the purpose of the present invention is to provide a ring-like Y-shaped electrode meter-sized LED device that can reduce output light loss and improve current expansion.
- a method for preparing the micro-size LED device with ring-like Y-shaped electrodes is provided.
- the present invention adopts at least one of the following technical solutions.
- the present invention provides a micro-sized LED device with a ring-like Y-shaped electrode.
- the device includes a substrate and a boss-type structure connected on the substrate.
- the boss-type structure includes a lower part of a boss and an upper part of the boss , The upper part of the boss is located on the lower part of the boss, the cross-sectional area of the upper part of the boss is smaller than the cross-sectional area of the lower part of the boss;
- the lower part of the boss includes a buffer layer, an undoped N-type GaN layer and a first N-GaN layer;
- the upper part of the boss includes a second N-GaN layer, a multiple quantum well layer, a P-type AlGaN layer and a P-GaN layer arranged in order from bottom to top, the first N-GaN layer and the second N-
- the GaN layer is integrally formed; the upper surface of the lower part of the boss is connected to the area outside the upper part of the boss to connect the N
- the P electrode is a ring type Y
- the ring-like Y-shaped electrode includes an annular contact ring and two or more Y-like forks.
- the Y-like fork includes a bottom arm and a first branch and a second branch respectively connected to one end of the bottom arm. Bifurcation, the other end of the bottom arm is connected with the annular contact ring; a passivation layer is deposited on the area of the boss type structure except the P electrode and the N electrode.
- the bottom arm, the first bifurcation and the second bifurcation are all straight lines, the first bifurcation and the second bifurcation are symmetrically distributed on both sides of the bottom arm, and the bifurcation angle is 30° ⁇ 120° .
- the bottom arm and the first branch are straight lines
- the second branch includes a straight line and an arc connected to the straight line
- the straight lines of the first branch and the second branch are symmetrical Distributed on both sides of the bottom arm
- the bifurcation angle is 30° ⁇ 120°
- the second bifurcated arc extends along the arc angle to the side of the second bifurcated straight line, but the arc and other types
- the Y-shaped forks do not touch; the length of the straight line of the first branch is greater than the length of the straight line of the second branch.
- the bottom arm is a straight line
- the first branch and the second branch both include a straight line and an arc connected to the straight line
- the straight lines of the first branch and the second branch are symmetrical Distributed on both sides of the bottom arm
- the bifurcation angle is 30° ⁇ 120°
- the first bifurcated arc extends along the arc angle to the side of the first bifurcated straight line
- the second bifurcated circle The side of the arc to the straight line of the second branch extends along the arc angle, but the arc does not touch other Y-like forks
- the length of the straight line of the first branch is greater than the straight line of the second branch The length of the line.
- the upper part of the boss and the lower part of the boss are of cylindrical structure, and the upper part of the boss is located at the center of the lower part of the boss; the area of the current spreading layer is smaller than the area of the bottom surface of the upper part of the boss; the diameter of the bottom surface of the upper part of the boss is 20um ⁇ 200um, the diameter of the bottom surface of the lower part of the boss is 30um ⁇ 50um larger than the diameter of the bottom surface of the upper part of the boss; the P electrode is located at the center of the upper surface of the current spreading layer; the N electrode is a circular ring, and a rectangle is connected to the outer circle of the circular ring Protrusion, the protrusion is located in the radial direction of the outer circle, the width and length of the protrusion are 5um ⁇ 10um; the N electrode is located in the area between the edge of the upper surface of the first N-GaN layer and the edge of the lower surface of the multiple quantum well layer
- the upper surface of the current spreading layer under the P electrode is a roughened
- the current spreading layer is ITO with a thickness of 100-230 nm;
- the passivation layer is SiO 2 or a double-layer dielectric layer, and the double-layer dielectric layer is two dielectrics with different refractive indexes arranged from bottom to top layers having a refractive index lower than the refractive index of the upper dielectric layer underlying the dielectric layer;
- the upper layer is MgO;
- the lower layer of HfO 2 /SiO 2 is HfO 2 and the upper layer is SiO 2 ;
- the lower layer of MgO/SiO 2 is MgO and the upper layer is SiO 2 ;
- the P electrode and N electrode are Cr/Al/Ti/Au metal layers,
- the total thickness of the metal layer is 1.15um
- the number of Y-like forks in the ring-like Y-shaped electrode is three, and the Y-like forks are evenly connected to the annular contact ring at 120° between two and three Y-like forks.
- the shape is exactly the same.
- the number of Y-like forks in the ring-like Y-shaped electrode is four, and the two Y-like forks are evenly connected to the annular contact ring at 90°, and the size of the four Y-like forks
- the shape is exactly the same.
- the number of Y-like forks in the ring-like Y-shaped electrode is five, and the Y-like forks are evenly connected to the annular contact ring at 72° between two and five Y-like forks.
- the shape is exactly the same.
- the bottom arm, the first bifurcation and the second bifurcation are all straight lines, the first bifurcation and the second bifurcation are symmetrically distributed on both sides of the bottom arm, the bifurcation angle is 60°, and the bottom arm
- the length ratio to the first bifurcation is 1:2, and the length of the first bifurcation is equal to the length of the second bifurcation.
- the present invention also provides a method for preparing the micro-sized LED device with ring-like Y-shaped electrodes, which includes the following steps:
- the sample piece includes the substrate arranged in sequence from bottom to top, buffer layer, undoped N-type GaN layer and N-GaN layer, multiple quantum well layer, P-type AlGaN layer and P-GaN layer,
- a first photoresist mask layer is prepared on the P-GaN layer as a mask layer for etching the bump structure, and etched from the P-GaN layer to the N-GaN layer using the ICP dry etching method, exposing part of N -GaN layer, part of the N-GaN layer exposed on the sidewall constitutes the second N-GaN layer, and part of the N-GaN layer exposed on the upper surface constitutes the first N-GaN layer, thereby forming the upper part of the boss, and then removing the first Photoresist mask layer;
- step (1) the upper surface of the exposed part of the P-GaN layer on the upper part of the boss and the first N-GaN layer is combined with an electron beam evaporation coater and a rapid annealing furnace to prepare a current spreading layer, and on the upper part of the boss A second photoresist mask layer is prepared on the upper surface of the current spreading layer on the P-GaN layer.
- the area of the second photoresist mask layer is smaller than the upper surface area of the upper part of the boss.
- an acidic solution at 30°C ⁇ 50°C Perform wet etching with a pH of 3.9-6.1.
- step (3) Prepare a third photoresist mask layer on the upper surface of the exposed part of the first N-GaN layer and the upper surface of the P-GaN layer and the current spreading layer on the upper part of the boss in step (2), and the third photolithography
- the size of the mask layer is larger than the size of the upper surface of the upper part of the boss.
- the first N-GaN layer is etched to the substrate by the ICP dry etching method, the substrate is exposed to form the lower part of the boss, and then the third photoresist is removed Mask layer
- a passivation layer is deposited using dielectric film deposition technology, and then a fourth photoresist mask layer is formed on the upper surface of the passivation layer, and the fourth photoresist mask layer is on the upper part of the boss Openings are provided on the upper surface and the upper surface of the lower part of the boss except for the upper part of the boss.
- the passivation layer is etched by the ICP etching method and the wet etching method, and part of the current spreading layer on the upper surface of the boss and A part of the first N-GaN layer on the lower part of the boss is exposed;
- the fourth photoresist mask layer prepared in step (4) is used as the mask layer of the etching current spreading layer, and the part of the current spreading layer exposed on the upper surface of the boss is roughened by wet etching technology, and then Removing the fourth photoresist mask layer;
- step (5) the P electrode is prepared on the upper surface of the current spreading layer roughened in step (5) by photolithography and metal stripping technology, and prepared on the lower surface of the boss in step (4) N electrode.
- the photoresist mask layer 3 is one of a single-layer photoresist and a double-layer photoresist; the preparation method of the double-layer photoresist is as follows: firstly, pre-baking the sample processed in step (2), Homogenize and bake to form a single layer of photoresist, and then homogenize and bake to form a second layer of photoresist; in step (5), the photoresist mask layer 4 is hardened for 3-6 minutes before wet etching .
- the current spreading layer in step (2) is vapor-deposited by an electron beam evaporation coating machine, and then annealed in a rapid annealing furnace under the conditions of 200-250 sccm N 2 and 30-50 sccm O 2 at 500-600°C Annealing at a temperature of 3 to 5 minutes;
- the roughening of the current spreading layer in step (5) refers to etching the current spreading layer in an ITO etching solution at 30°C to 50°C for 2 to 5 minutes.
- the ITO etching solution is an acid solution with a pH It is 3.9 ⁇ 6.1.
- the acidic solution is an HF solution.
- the present invention has the following beneficial effects and advantages:
- the micro-sized LED device with ring-like Y-shaped electrodes prepared in the present invention the epitaxial layer is a convex structure, and the ring-shaped Y-shaped P electrode is prepared on the current spreading layer on the upper surface of the boss.
- the Y-like P electrode through the annular contact ring and the Y-like fork can effectively improve the current expansion and distribution under the condition of reducing the output light shielding, and achieve uniform light intensity distribution and uniform heating;
- the area of the current spreading layer on the upper surface of the boss is smaller than that of the upper surface of the boss, that is, the edge is farther from the upper boundary of the boss,
- the upper surface of the current spreading layer exposed after the preparation of the passivation layer is a rough structure, which is formed by etching in an acidic solution with a certain temperature for 2 to 5 minutes The temperature of the acidic solution is 30°C-50°C, so that the upper surface of the current spreading layer under the P electrode has a rough structure, which increases the lateral light output to a certain extent and reduces the damage of the light output power;
- Example 1 is a schematic cross-sectional view of a micro-sized LED device structure with ring-like Y-shaped electrodes provided by Example 1;
- FIGS. 2a to 2f are schematic diagrams of the preparation process of a micro-sized LED device with ring-like Y-shaped electrodes provided in Example 1;
- Example 3 is a top view of the N-type electrode provided in Example 1;
- Example 4 is a top view of the toroidal Y-shaped electrode provided in Example 1;
- FIG. 5 is a top view of the annular Y-shaped electrode provided in Example 2.
- Example 6 is a top view of the toroidal Y-shaped electrode provided in Example 3.
- This embodiment provides a micro-sized LED device with a ring-like Y-shaped electrode.
- the device includes a substrate 1 and a bump-shaped structure connected on the substrate.
- the bump-shaped structure Including the lower part of the boss and the upper part of the boss, the upper part of the boss is located on the lower part of the boss, the cross-sectional area of the upper part of the boss is smaller than the cross-sectional area of the lower part of the boss; the lower part of the boss includes the buffer layer 2 arranged from bottom to top.
- the Y-like fork includes a bottom arm 1121 and a first branch 1122 and a second branch 1123 respectively connected to one end of the bottom arm, and the other end of the bottom arm is connected to the annular contact ring 1120, and three The Y-like fork bottom
- the bottom arm 1121, the first branch 1122 are all straight lines
- the second branch 1123 includes a straight line and an arc connected with the straight line
- the first branch 1122 and the second branch 1123 are straight.
- the lines are symmetrically distributed on both sides of the bottom arm 1121, and the bifurcation angle is 60°; the second bifurcated arc extends along the arc angle to the side of the second bifurcated straight line, but the arc and other types
- the Y-shaped forks do not touch; the length of the straight line of the first branch is greater than the length of the straight line of the second branch.
- the upper part of the boss and the lower part of the boss are cylindrical structures, and the upper part of the boss is located at the center of the lower part of the boss; the area of the current spreading layer 8 is smaller than the area of the bottom surface of the upper part of the boss; the bottom diameter of the upper part of the boss is 160um, and the boss The bottom diameter of the lower part is 30um larger than that of the upper part of the boss; the P electrode 11 is located at the center of the upper surface of the current spreading layer; the N electrode 10 is a circular ring, and a rectangular protrusion is connected to the outer circle of the circular ring. It is located in the radial direction of the outer circle, and the width and length of the protrusion are 5um, as shown in FIG.
- the N electrode 10 is located at the edge of the upper surface of the first N-GaN layer 401 and the edge of the lower surface of the multiple quantum well layer 5 The center of the middle area; the upper surface of the current spreading layer 8 under the P electrode 11 has a roughened structure.
- the current spreading layer 8 of ITO having a thickness of 120 nm, a diameter of 90um; the passivation layer 9 of SiO 2, having a thickness of 1um; P electrode and N-electrode 10 was 11 Cr / Al / Ti / Au metal layer, the metal layer The total thickness is 1.15um; the substrate 1 is made of sapphire material.
- the number of Y-like forks in the ring-like Y-shaped electrode is 3, and the two Y-like forks are evenly connected to the annular contact ring at 120°, and the size and shape of the three Y-like forks are complete Consistent, as shown in Figure 4.
- This embodiment also provides a method for preparing the micro-sized LED device with ring-like Y-shaped electrodes, including the following steps:
- the sample piece includes the substrate 1, the buffer layer 2, the undoped N-type GaN layer 3 and the N-GaN layer, the multiple quantum well layer 5, the P-type AlGaN layer 6 and P-GaN layer 7, a circular first photoresist mask layer is formed on the P-GaN layer 7 by ordinary ultraviolet lithography process as the mask layer for etching the convex structure, the diameter is 100um; the ICP dry method is used
- the etching method is to etch from the P-GaN layer 7 to the N-GaN layer with a depth of 1.3um, exposing part of the N-GaN layer, and part of the N-GaN layer with the exposed sidewalls to form the second N-GaN layer 402, and the exposed part
- the N-GaN layer on the upper surface constitutes the first N-GaN layer 401, thereby forming the upper part of the boss, the diameter of the upper part of the boss is 160um; then the first photoresist mask layer is removed by
- step (2) After the sample processed in step (1) is processed with 511 solution (commercially available) and ammonia (commercially available), on the exposed part of the P-GaN layer 7 and the first N-GaN layer 401 on the upper part of the boss The surface is combined with an electron beam evaporation coating machine in a nitrogen and oxygen atmosphere at 550°C.
- the alloy is rapidly annealed for 3 minutes to prepare the current spreading layer 8, and the current spreading layer 8 is prepared on the upper surface of the P-GaN layer 7 on the upper part of the boss
- the second photoresist mask layer, the area of the second photoresist mask layer is smaller than the upper surface area of the upper part of the boss, and the ITO current with a diameter of 90um is formed at the center of the upper part of the boss by photolithography and wet etching technology
- the corrosion condition of the expansion layer 8 is to etch in an acidic solution at 40°C for 15 minutes.
- the SiO 2 passivation layer 9 is deposited with a thickness of 1um under the condition of 260 °C using dielectric film deposition technology, and then a fourth photoresist mask is formed on the upper surface of the passivation layer 9
- the fourth photoresist mask layer has a circular opening with a diameter of 40um in the center of the upper surface of the upper part of the boss, and the upper surface of the lower part of the boss has a circular opening except for the upper part of the boss.
- Etching method After 13 minutes of etching, use HF acid solution (commercially available) for etching until the ITO current spreading layer 8 and the first N-GaN layer 401 at the opening on the passivation layer 9 are exposed.
- the cross section of the sample is shown in Figure 2d. Expose part of the current spreading layer 8 on the upper surface of the boss and part of the first N-GaN layer 401 on the lower part of the boss;
- the fourth photoresist mask layer prepared in step (4) is used as the mask layer of the corrosion current spreading layer 8, and the fourth photoresist mask layer is hardened by a hot plate at a temperature of 105°C, The time is 5 minutes; then, the ITO current spreading at the opening 9 of the passivation layer on the top of the upper surface of the boss 8 is corroded in an ITO etching solution at 35°C for 5 minutes to form a coarse structure of the ITO current spreading layer.
- the upper surface of the expansion layer 8 has a rough structure, and the lower surface has a normal structure; then the fourth photoresist mask layer is ultrasonically removed with acetone and isopropanol.
- the cross-section of the sample after step (5) is shown in FIG. 2e.
- step (5) use negative photoresist and use ordinary ultraviolet lithography technology to form P electrode 11 and N electrode 10 patterns on the sample, and use electronic vapor deposition technology to prepare Cr/Al/Ti/
- the Au electrode has a total thickness of 1.15um; subsequently, it is stripped using 60°C acetone and 85°C degumming solution to form a P electrode 11 and an N electrode 10.
- the cross section of the device is shown in Fig. 2f.
- This embodiment proposes a micro-sized LED device with a ring-like Y-shaped electrode.
- the structure is as shown in Figures 1 and 3 in Embodiment 1, except that the structure of the P electrode 11 is different.
- the P electrode 11 is shown in Figure 5. As shown, it includes an annular contact ring 1130 and three Y-like forks; the annular contact ring is located at the center of the ITO current spreading layer 8; the Y-like fork includes a bottom arm 1131 and one end of the bottom arm 1131 respectively The first branch 1132 and the second branch 1133 are connected, the other end of the bottom arm is connected to the annular contact ring 1130, and the bottom arms of the three Y-like forks are evenly distributed on the annular contact ring, like Y-like The two forks are evenly connected with the circular contact ring at 120°, and the size and shape of the Y-like forks are exactly the same; the bottom arm 1131, the first branch 1132 and the second branch 1133 are all straight lines
- This embodiment proposes a micro-sized LED device with ring-like Y-shaped electrodes. Its structure and dimensions are as shown in Figures 1 and 3 of Embodiment 1, except that the structure of the P electrode 11 is different, and the P electrode 11 is a ring.
- the Y-shaped electrode includes a ring-shaped contact ring 1160 and three Y-shaped forks; the ring-shaped contact ring 1160 is located at the center of the current spreading layer 8.
- the Y-shaped fork includes a bottom arm 1161 and a bottom arm
- the first branch 1162 and the second branch 1163 are respectively connected at one end, and the other end of the bottom arm is connected to the annular contact ring 1160.
- the three Y-like fork bottom arms 1161 are evenly distributed on the annular contact ring 1160 ,
- the Y-like forks are evenly connected to the circular contact ring at 120° in pairs, and the size and shape of the Y-like forks are exactly the same;
- the bottom arm 1161 is a straight line
- the first branch 1162 and the second branch 1163 both include a straight line and an arc connected to the straight line
- the first branch 1162 and the second branch 1162 The straight lines of the branch 1163 are symmetrically distributed on both sides of the bottom arm, and the branch angle is 60°;
- the arc of the first branch 1161 extends along the arc angle to one side of the straight line of the first branch 1161
- the arc of the second branch 1162 extends along the arc angle to one side of the straight line of the second branch 1163, but the arc does not contact other Y-like forks;
- the straight line of the first branch 1161 The length of is greater than the length of the straight line of the second branch 1162.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Led Devices (AREA)
Abstract
Description
Claims (10)
- 一种具有环状类Y型电极的微尺寸LED器件,其特征在于,所述器件包括衬底和衬底上连接的凸台型结构,所述凸台型结构包括凸台下部和凸台上部,凸台上部位于凸台下部之上,凸台上部的横截面积小于凸台下部的横截面积;凸台下部包括从下到上依次排列的缓冲层、未掺杂N型GaN层和第一N-GaN层;凸台上部包括从下到上依次排列分布的第二N-GaN层、多量子阱层、P型AlGaN层和P-GaN层,第一N-GaN层和第二N-GaN层一体成型;凸台下部的上表面连接凸台上部以外的区域连接N电极;凸台上部的上表面连接电流扩展层,电流扩展层上连接P电极,所述P电极为环状类Y型电极,所述环状类Y型电极包括一个圆环状接触环和两个以上类Y型叉,类Y型叉包括一底臂以及和底臂一端分别连接的第一分叉和第二分叉,底臂的另一端和圆环状接触环连接;凸台型结构上除P电极和N电极以外的区域沉积有一层钝化层。
- 根据权利要求1所述的具有环状类Y型电极的微尺寸LED器件,其特征在于,所述底臂、第一分叉和第二分叉均为直型线条,第一分叉和第二分叉对称分布在底臂的两侧,分叉角度为30°~120°。
- 根据权利要求1所述的具有环状类Y型电极的微尺寸LED器件,其特征在于,所述底臂、第一分叉均为直型线条,第二分叉包括一直型线条以及和直型线条连接的圆弧,第一分叉和第二分叉的直型线条对称分布在底臂的两侧,分叉角度为30°~120°;第二分叉的圆弧向第二分叉的直型线条的一侧沿着圆弧角度延伸,但圆弧和其他类Y型叉不接触;第一分叉的直型线条的长度大于第二分叉的直型线条的长度。
- 根据权利要求1所述的具有环状类Y型电极的微尺寸LED器件,其特征在于,所述底臂为直型线条,第一分叉和第二分叉均包括一直型线条以及和直型线条连接的圆弧,第一分叉和第二分叉的直型线条对称分布在底臂的两侧,分叉角度为30°~120°;第一分叉的圆弧向第一分叉的直型线条的一侧沿着圆弧角度延伸,第二分叉的圆弧向第二分叉的直型线条的一侧沿着圆弧角度延伸,但圆弧和其他类Y型叉不接触;第一分叉的直型线条的长度大于第二分叉的直型线条的长度。
- 根据权利要求1所述的具有环状类Y型电极的微尺寸LED器件,其特征在于,所述凸台上部和凸台下部为圆柱体结构,凸台上部位于凸台下部的中心处;电流扩展层的面积小于凸台上部的底面面积;凸台上部的底面直径为20um~200um,凸台下部的底面直径比凸台上部的底面直径大30um~50um;P电极位于电流扩展层上表面的中心处;所述N电极为圆环,在圆环的外圆上连接一矩形凸起,凸起位于外圆的径向方向上,凸起的宽度与长度为5um~10um;N电极位于第一N-GaN层上表面的边缘与多量子阱层下表面的边缘之间区域的中心;P电极下方的电流扩展层上表面为粗化结构。
- 根据权利要求1所述的具有环状类Y型电极的微尺寸LED器件,其特征在于,电流扩展层为ITO,厚度为100~230nm;所述钝化层为SiO 2或双层介质层,所述双层介质层为从下到上排布的两个折射率不同的介质层组成,且上层介质层的折射率低于下层介质层的折射率;双层介质层为 HfO 2/MgO、HfO 2/SiO 2或MgO/SiO 2; HfO 2/MgO中下层为HfO 2,上层为MgO; HfO 2/SiO 2中下层为HfO 2,上层为SiO 2; MgO/SiO 2中下层为MgO,上层为SiO 2;P电极和N电极为Cr/Al/Ti/Au金属层,金属层的总厚度为1.15um ~1.35um;衬底为蓝宝石材料。
- 根据权利要求1所述的具有环状类Y型电极的微尺寸LED器件,其特征在于,环状类Y型电极中的类Y型叉的个数为3、4或5,相应的类Y型叉之间两两成120°、90°或72°均匀地与圆环状接触环连接,且类Y型叉大小形状完全一致。
- 制备权利要求1至7任一项所述的具有环状类Y型电极的微尺寸LED器件的方法,其特征在于,包括以下步骤:(1)取样片,样片包括从下到上依次排布的衬底,缓冲层、未掺杂N型GaN层和N-GaN层、多量子阱层、P型AlGaN层和P-GaN层,在P-GaN层上制备第一光刻胶掩膜层作为刻蚀凸台型结构的掩膜层,利用ICP干法刻蚀方法从P-GaN层刻蚀至N-GaN层,暴露部分N-GaN层,暴露侧壁的部分N-GaN层构成第二N-GaN层,暴露出部分上表面的N-GaN层构成第一N-GaN层,由此形成凸台上部,然后去除第一光刻胶掩膜层;(2)在步骤(1)凸台上部的P-GaN层和凸台下部的第一N-GaN层暴露的部分上表面上结合电子束蒸发镀膜机和快速退火炉制备电流扩展层,并在凸台上部的P-GaN层上的电流扩展层上表面制备第二光刻胶掩膜层,第二光刻胶掩膜层的面积小于凸台上部的上表面面积,在30℃~50℃的酸性溶液中进行湿法腐蚀,pH为3.9~6.1,当电流扩展层外圈小于第二光刻掩膜层大小出现电流扩展层侧腐蚀,去除第二光刻胶掩膜层;(3)在步骤(2)中第一N-GaN层暴露的部分上表面以及凸台上部上的P-GaN层和电流扩展层上表面制备第三光刻胶掩膜层,第三光刻胶掩膜层的尺寸大于凸台上部上表面的尺寸,利用ICP干法刻蚀方法从第一N-GaN层刻蚀至衬底,暴露部分衬底形成凸台下部,随后去除第三光刻胶掩膜层;(4)在步骤(3)的基础上利用介质薄膜沉积技术沉积钝化层,随后在钝化层上表面形成第四光刻胶掩膜层,第四光刻胶掩膜层在凸台上部上表面以及凸台下部上表面除连接凸台上部以外的区域分别设有开口,利用ICP刻蚀方法和湿法刻蚀方法刻蚀钝化层,将凸台上部上表面的部分电流扩展层以及凸台下部上的部分第一N-GaN层暴露;(5)以步骤(4)制备的第四光刻胶掩膜层作为腐蚀电流扩展层的掩膜层,通过湿法腐蚀技术将凸台上部上表面暴露的部分电流扩展层进行粗化,随后去除第四光刻胶掩膜层;(6)在步骤(5)的基础上,利用光刻技术和金属剥离技术在步骤(5)中粗化后的电流扩展层上表面制备P电极,在步骤(4)的凸台下部表面制备N电极。
- 根据权利要求8所述的制备具有环状类Y型电极的微尺寸LED器件的方法,其特征在于,光刻胶掩膜层3是单层光刻胶、双层光刻胶的一种;双层光刻胶的制备方法为:先将步骤(2)处理后的样片进行预烘、匀胶、烘烤形成单层光刻胶,再次匀胶、烘烤形成第二层光刻胶;步骤(5)中湿法腐蚀前先将光刻胶掩膜层4坚膜3~6分钟。
- 根据权利要求9所述的制备具有环状类Y型电极的微尺寸LED器件的方法,其特征在于,步骤(2)中的电流扩展层采用电子束蒸发镀膜机蒸镀,随后快速退火炉中退火,条件为200~250sccm N 2和30~50sccm O 2的氛围下,以500~600℃的温度退火3~5分钟;步骤(5)中的粗化电流扩展层是指将电流扩展层在30℃~50℃的ITO腐蚀液中腐蚀2~5分钟, ITO腐蚀液为酸性溶液,pH为3.9~6.1。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910704390.3 | 2019-07-31 | ||
CN201910704390.3A CN110459657A (zh) | 2019-07-31 | 2019-07-31 | 一种具有环状类y型电极的微尺寸led器件及制备方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2021018308A1 true WO2021018308A1 (zh) | 2021-02-04 |
Family
ID=68484369
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2020/106458 WO2021018308A1 (zh) | 2019-07-31 | 2020-07-31 | 一种具有环状类y型电极的微尺寸led器件及制备方法 |
Country Status (2)
Country | Link |
---|---|
CN (1) | CN110459657A (zh) |
WO (1) | WO2021018308A1 (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110459657A (zh) * | 2019-07-31 | 2019-11-15 | 华南理工大学 | 一种具有环状类y型电极的微尺寸led器件及制备方法 |
CN111081831B (zh) * | 2019-11-20 | 2021-03-23 | 华南师范大学 | 基于多电极的照明通信器件及其制备方法 |
CN110957402A (zh) * | 2019-11-26 | 2020-04-03 | 晶能光电(江西)有限公司 | MicroLED芯片及其制备方法 |
CN111509097B (zh) * | 2020-06-30 | 2020-10-20 | 华引芯(武汉)科技有限公司 | 一种大功率半导体发光器件及其制备方法 |
CN112635632B (zh) * | 2020-12-31 | 2022-09-20 | 深圳第三代半导体研究院 | 发光二极管及其制造方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070001178A1 (en) * | 2005-01-11 | 2007-01-04 | Tran Chuong A | Coating process |
CN103050599A (zh) * | 2011-10-17 | 2013-04-17 | 大连美明外延片科技有限公司 | 一种具有外环电极的发光二极管及其制造方法 |
CN105609608A (zh) * | 2014-11-13 | 2016-05-25 | 晶元光电股份有限公司 | 发光二极管元件 |
CN107195747A (zh) * | 2017-06-01 | 2017-09-22 | 华南理工大学 | 一种微米尺寸倒装led芯片及其制备方法 |
CN107968140A (zh) * | 2017-10-25 | 2018-04-27 | 华灿光电(浙江)有限公司 | 一种红黄光发光二极管芯片及其制造方法 |
CN110459657A (zh) * | 2019-07-31 | 2019-11-15 | 华南理工大学 | 一种具有环状类y型电极的微尺寸led器件及制备方法 |
CN210607303U (zh) * | 2019-07-31 | 2020-05-22 | 华南理工大学 | 一种具有环状类y型电极的微尺寸led器件 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6614056B1 (en) * | 1999-12-01 | 2003-09-02 | Cree Lighting Company | Scalable led with improved current spreading structures |
JP2004111648A (ja) * | 2002-09-18 | 2004-04-08 | Hamamatsu Photonics Kk | 半導体発光素子 |
JP4974867B2 (ja) * | 2007-12-12 | 2012-07-11 | 昭和電工株式会社 | 発光ダイオード及びその製造方法 |
CN102593233A (zh) * | 2012-03-19 | 2012-07-18 | 中国科学院上海技术物理研究所 | 基于图形化蓝宝石衬底的GaN基PIN探测器及制备方法 |
KR101283444B1 (ko) * | 2012-03-22 | 2013-07-08 | 배정운 | 수평형 파워 led 소자 및 그 제조방법 |
CN102800776A (zh) * | 2012-05-29 | 2012-11-28 | 中山大学 | 一种雪花状led电极结构 |
TWI723886B (zh) * | 2013-03-18 | 2021-04-01 | 晶元光電股份有限公司 | 發光元件 |
KR20140122970A (ko) * | 2013-04-11 | 2014-10-21 | 서울바이오시스 주식회사 | 전류 스프레딩이 향상된 발광다이오드 |
CN203415611U (zh) * | 2013-06-21 | 2014-01-29 | 诚盟电科技股份有限公司 | 反极性四元发光二极管的n电极结构改良 |
CN107195701B (zh) * | 2017-05-12 | 2019-09-17 | 中国电子科技集团公司第五十研究所 | 台面式砷化镓掺硅阻挡杂质带太赫兹探测器及其制作方法 |
CN108155273A (zh) * | 2018-01-31 | 2018-06-12 | 江苏新广联科技股份有限公司 | 增加led倒装芯片发光面积的结构和制作方法 |
-
2019
- 2019-07-31 CN CN201910704390.3A patent/CN110459657A/zh active Pending
-
2020
- 2020-07-31 WO PCT/CN2020/106458 patent/WO2021018308A1/zh active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070001178A1 (en) * | 2005-01-11 | 2007-01-04 | Tran Chuong A | Coating process |
CN103050599A (zh) * | 2011-10-17 | 2013-04-17 | 大连美明外延片科技有限公司 | 一种具有外环电极的发光二极管及其制造方法 |
CN105609608A (zh) * | 2014-11-13 | 2016-05-25 | 晶元光电股份有限公司 | 发光二极管元件 |
CN107195747A (zh) * | 2017-06-01 | 2017-09-22 | 华南理工大学 | 一种微米尺寸倒装led芯片及其制备方法 |
CN107968140A (zh) * | 2017-10-25 | 2018-04-27 | 华灿光电(浙江)有限公司 | 一种红黄光发光二极管芯片及其制造方法 |
CN110459657A (zh) * | 2019-07-31 | 2019-11-15 | 华南理工大学 | 一种具有环状类y型电极的微尺寸led器件及制备方法 |
CN210607303U (zh) * | 2019-07-31 | 2020-05-22 | 华南理工大学 | 一种具有环状类y型电极的微尺寸led器件 |
Also Published As
Publication number | Publication date |
---|---|
CN110459657A (zh) | 2019-11-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2021018308A1 (zh) | 一种具有环状类y型电极的微尺寸led器件及制备方法 | |
CN107195747B (zh) | 一种微米尺寸倒装led芯片及其制备方法 | |
US20220209065A1 (en) | Micro-sized face-up led device with micro-hole array and preparation method thereof | |
CN110993762B (zh) | 基于III族氮化物半导体的Micro-LED阵列器件及其制备方法 | |
CN110364602B (zh) | 发光二极管的芯片及其制备方法 | |
US20110140081A1 (en) | Method for fabricating semiconductor light-emitting device with double-sided passivation | |
JP2012169615A (ja) | ナノ構造を有する発光ダイオードおよびその製造方法 | |
CN104157765A (zh) | 一种半导体发光器件及其制作方法 | |
US20130214246A1 (en) | Light emitting diode and fabrication method thereof | |
CN111244238A (zh) | 一种高亮度半导体发光二极管芯片及其制作方法 | |
WO2016041471A1 (zh) | 一种具有特殊粗化形貌的led垂直芯片结构及其制备方法 | |
CN210607303U (zh) | 一种具有环状类y型电极的微尺寸led器件 | |
CN111129244B (zh) | 一种银镜大功率倒装芯片及其制备方法 | |
US20110133159A1 (en) | Semiconductor light-emitting device with passivation in p-type layer | |
CN209947839U (zh) | 倒装结构微尺寸光子晶体led阵列芯片 | |
CN108461593B (zh) | 具有纳米级二氧化硅光栅钝化层的GaN基发光二极管及其加工方法 | |
KR101321994B1 (ko) | 광추출 효율이 향상된 발광 다이오드 및 이의 제조방법 | |
CN112349818B (zh) | 一种高压led芯片的深刻蚀方法 | |
CN114864774A (zh) | 图形化衬底的制备方法及具有空气隙的led外延结构 | |
CN211480077U (zh) | 具有温度监控的大功率倒装led芯片 | |
CN100590900C (zh) | 一种金属半导体场效应发光晶体管及其制作方法 | |
CN109244198B (zh) | 芯片级低成本表面处理方法及一种装置 | |
CN214280002U (zh) | 一种具有微米孔阵列的微米尺寸正装led器件 | |
CN103633198B (zh) | Led芯片制作方法以及led芯片 | |
CN116364827B (zh) | 一种mini LED及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 20848024 Country of ref document: EP Kind code of ref document: A1 |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 20848024 Country of ref document: EP Kind code of ref document: A1 |
|
32PN | Ep: public notification in the ep bulletin as address of the adressee cannot be established |
Free format text: NOTING OF LOSS OF RIGHTS PURSUANT TO RULE 112(1) EPC (EPO FORM 1205A DATED 10/10/2022) |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 20848024 Country of ref document: EP Kind code of ref document: A1 |